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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Systematic discovery of pseudomonad genetic factors involved in sensitivity to tailocins

Tailocins are bactericidal protein complexes produced by a wide variety of bacteria that kill closely related strains and may play a role in microbial community structure. Thanks to their high specificity, tailocins have been proposed as precision antibacterial agents for therapeutic applications. Compared to tailed phages, with whom they share an evolutionary and morphological relationship, bacterially produced tailocins kill their host upon production but producing strains display resistance to self-intoxication. Though lipopolysaccharide (LPS) has been shown to act as a receptor for tailocins, the breadth of factors involved in tailocin sensitivity, and the mechanisms behind resistance to self-intoxication, remain unclear. Here, we employed genome-wide screens in four non-model pseudomonads to identify mutants with altered fitness in the presence of tailocins produced by closely related pseudomonads. Our mutant screens identified O-antigen composition and display as most important in defining sensitivity to our tailocins. In addition, the screens suggest LPS thinning as a mechanism by which resistant strains can become more sensitive to tailocins. Furthermore, we validate many of these novel findings, and extend these observations of tailocin sensitivity to 130 genome-sequenced pseudomonads. This work offers insights into tailocin–bacteria interactions, informing the potential use of tailocins in microbiome manipulation and antibacterial therapy.

59 BASIC BIOLOGICAL SCIENCES↗

Molecular hydrodynamic theory of the velocity autocorrelation function

The velocity autocorrelation function (VACF) encapsulates extensive information about a fluid’s molecular-structural and hydrodynamic properties. We address the following fundamental question: How well can a purely hydrodynamic description recover the molecular features of a fluid as exhibited by the VACF? To this end, we formulate a bona fide hydrodynamic theory of the tagged-particle VACF for simple fluids. Our approach is distinguished from previous efforts in two key ways: collective hydrodynamic modes and tagged-particle self-motion are modeled by linear hydrodynamic equations; the fluid’s spatial velocity power spectrum is identified as a necessary initial condition for the momentum current correlation. This formulation leads to a natural physical interpretation of the VACF as a superposition of products of quasinormal hydrodynamic modes weighted commensurately with the spatial velocity power spectrum, the latter of which appears to physically bridge continuum hydrodynamical behavior and discrete-particle kinetics. The methodology yields VACF calculations quantitatively on par with existing approaches for liquid noble gases and alkali metals. Furthermore, we obtain a new, hydrodynamic form of the self-intermediate scattering function whose description has been extended to low densities where the Schmidt number is of order unity; various calculations are performed for gaseous and supercritical argon to support the general validity of the theory. Excellent quantitative agreement is obtained with recent MD calculations for a dense supercritical Lennard-Jones fluid.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Simulation of extra-vehicular activity (EVA) self-rescue

Self-rescue during EVA is examined in terms of the use of a hand-held thruster that is similar to the hand-held maneuvering units HHMU developed for earlier programs. The problem of assessing velocity-increment requirements is addressed by means of examples of simulation technologies for studying EVA. The technologies evaluated include virtual reality systems such as the Virtual Interactive Environment Workstation (VIEW) and the Space Operations Simulator, and standard approaches like the air-bearing floor and the space shuttle. The VIEW is employed for a study of five trained NASA subjects that conduct a simulated return to a spacecraft with an HMMU under variable conditions. The study demonstrates the efficacy of VIEW for obtaining fuel-consumption values, and separation velocity is identified as the most significant determinant of the fuel and time requirements for a self-rescue operation.

Brody, Adam R.↗

Assessing Nonlinear Polarization in Electrochemical Cells using AC Impedance Spectroscopy

AC impedance spectroscopy is widely used to evaluate performance limitations in energy storage and conversion devices (e.g., batteries, supercapacitors, and fuel cells). This work shows that integrating the resistive elements in an equivalent circuit as functions of steady-state current enables one to recover overpotentials associated with different processes (e.g., ion migration, charge transfer, and diffusion) in nonlinear electrochemical power supplies. Closed form expressions for diffusion overpotentials are derived using this method for transmissive and reflective boundary conditions and three electrode symmetries (planar, cylindrical, and spherical). Discussion is also extended to macroscopically homogenous porous electrodes which are relevant for most real-world devices. Overall, the approach described herein is a powerful tool to identify rate-limiting steps and guide material/component design.

25 ENERGY STORAGE↗

Chelation-directed interface engineering of in-place self-cleaning membranes

Water–energy sustainability will depend upon the rapid development of advanced pressure-driven separation membranes. Although energy-efficient, water-treatment membranes are constrained by ubiquitous fouling, which may be alleviated by engineering self-cleaning membrane interfaces. In this study, a metal-polyphenol network was designed to direct the armorization of catalytic nanofilms (ca. 18 nm) on inert polymeric membranes. The chelation-directed mineralized coating exhibits high polarity, superhydrophilicity, and ultralow adhesion to crude oil, enabling cyclable crude oil-in-water emulsion separation. The in-place flux recovery rate exceeded 99.9%, alleviating the need for traditional ex situ cleaning. The chelation-directed nanoarmored membrane exhibited 48-fold and 6.8-fold figures of merit for in-place self-cleaning regeneration compared to the control membrane and simple hydraulic cleaning, respectively. Precursor interaction mechanisms were identified by density functional theory calculations. Here, chelation-directed armorization offers promise for sustainable applications in catalysis, biomedicine, environmental remediation, and beyond.

42 ENGINEERING↗

Improving Satellite-Based Hotspot Detection Through Deep Learning-Enabled Smoke Recognition

While geostationary satellites, such as the GOES-R series, provide wildland fire hotspot readings at a high temporal resolution, they are prone to false negative readings and decreased confidence. One cause of decreased hotspot confidence is cloud contamination. Smoke produced from wildfire is often misinterpreted as cloud contamination, resulting in inaccurate and unsure sensor readings. To this end, we built a deep learning image segmentation model to identify smoke and cloud in true color satellite images. The model is pre-trained using self-supervised learning on over 10,000 GOES-R images to learn the underlying structure of satellite imagery. Then, the model is fine-tuned on a set of 130 labeled documents using supervised learning. The resulting model performs multi-class image segmentation with 85% accuracy and runs in under a minute on a standard personal computer. When paired alongside hotspot data, the model’s outputs can help increase confidence in wildfire location by identifying cases of cloud contamination that are due to smoke. The resulting model can be deployed in a stand-alone application or bundled in an Open Data Integration for wildland fire management (ODIN) application.

Earth observation↗

A Comprehensive Chemistry Evaluation and Diagnostics Package for E3SM – ChemDyg Version 1.1.0

The Chemistry Evaluation and Diagnostics Package (ChemDyg) is an open-source tool designed for the Energy Exascale Earth System Model (E3SM) developed by the U.S. Department of Energy. ChemDyg facilitates routine evaluation, tailored development, and in-depth analysis of atmospheric chemistry through its modular architecture, allowing users to compare model outputs with observational data. Version 1.1.0 introduces a robust set of diagnostic capabilities, including climatology, time evolution of key tracers, diurnal and annual cycle analyses, and extensive budget diagnostics. These features help identify model discrepancies and enhance the representation of atmospheric chemistry in E3SM. Each self-contained diagnostic set includes dedicated scripts and documentation for ease of use. The interactive HTML output improves data accessibility, accelerating chemistry model development. Additionally, ChemDyg's flexible framework allows for customization, enabling users to create unique diagnostic sets for specific scientific contributions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Synoptic Drivers of Atmospheric River Induced Precipitation Near Dronning Maud Land, Antarctica

Atmospheric rivers (ARs) that reach the Antarctic Ice Sheet (AIS) transport anomalous moisture from lower latitudes and can impact the AIS via extreme precipitation and increased downward longwave radiation. ARs contribute significantly to the interannual variability of precipitation over the AIS and thus are likely to play a key role in understanding future changes in the surface mass balance of the AIS. Dronning Maud Land (DML) is one of four maxima in AR frequency over coastal East Antarctica, with AR precipitation explaining 77% of the interannual variability in precipitation for this region. We employ a 16-node self-organizing map (SOM) trained with MERRA-2 sea-level pressure anomalies to identify synoptic-scale environments associated with landfalling ARs in and around DML. Node composites of atmospheric variables reveal common drivers of precipitation associated with ARs reaching DML including anomalous high-low surface pressure couplets, anomalously high integrated water vapor, and coastal barrier jets. Using a quasi-geostrophic framework, we find that upward vertical motion associated with the occlusion process of attendant cyclones dominates atmospheric lift in AR environments. We further identify mechanisms that explain the variability in AR precipitation intensity across nodes, such as the lift associated with the occlusion process of attendant cyclones and the spatial coincidence of ascent induced by the occlusion process and frontogenesis. Here, the latter suggests that ARs making landfall during the mature phase of cyclogenesis result in higher precipitation intensity compared to landfalling ARs that occur during the occluded phase.

54 ENVIRONMENTAL SCIENCES↗

Unconventional Superconductivity Mediated by Exciton Density Wave Fluctuations

Synthetic platforms afford an unparalleled degree of controllability in realizing strongly correlated phases of matter. In this Letter, we study the possibility of electrically tunable exciton-mediated superconductivity arising in charge-imbalanced bilayer semiconductors. Focusing on the case of a bilayer semiconductor heterostructure, we identify the gating conditions required to achieve exciton density wave order within a self-consistent Hartree-Fock approximation. We analyze the role of the coupling of excitonic fluctuations to the fermionic charge carriers to find that the Goldstone mode of the density wave order can mediate attractive interactions leading to superconductivity. Furthermore, when the system is close to the density wave ordering, the interactions mediated by low-energy exciton modes can support an interlayer pair-density wave superconductor of anisotropic character. We discuss experimental signatures associated with these phenomena.

excitons↗

Automated maintenance for complex hybrid systems

Digital computer, Control Computer Subsystem (CCS), possess high degree of fault tolerance. CCS embodies concepts of self-test and repair. It is capable of monitoring its own performance and of identifying and replacing with standby spare any of its units that fail.

Gilley, G. C.↗

Spherical lamellar grating interferometer for airborne astronomical observations of far infrared objects

A lamellar-grating interferometer designed for airborne IR astronomy is described, and its response to a laboratory far-IR source and to Jupiter as viewed from NASA's Kuiper Airborne Observatory is discussed. The theory of lamellar-grating interferometers is reviewed, advantages over Michelson interferometers are noted, and the optical arrangement for the lamellar-grating instrument is indicated. The response of the instrument is illustrated using purged and unpurged spectra of a 1000-K blackbody source as well as a raw spectrum of Jupiter containing many absorption features (probably telluric) identified with rotation bands of H2O. It is noted that the interferometer's self-collimation allows for efficient operation with a minimum of auxiliary optics.

Pipher, J. L.↗

Acoustic Characterization and Prediction of Representative, Small-Scale Rotary-Wing Unmanned Aircraft System Components

In this study, hover performance and acoustic measurements are taken on two different isolated rotors representative of small-scale rotary-wing unmanned aircraft systems (UAS) for a range of rotation rates. Each rotor system consists of two fixed-pitch blades powered by a brushless motor. For nearly the same thrust condition, significant differences in overall sound pressure level (OASPL), up to 8 dB, and directivity were observed between the two rotor systems. Differences are shown to be in part attributed to different rotor tip speeds, along with increased broadband and motor noise levels. In addition to acoustic measurements, aeroacoustic predictions were implemented in order to better understand the noise content of the rotor systems. Numerical aerodynamic predictions were computed using the unsteady Reynoldsaveraged Navier Stokes code OVERFLOW2 on one of the isolated rotors, while analytical predictions were computed using the Propeller Analysis System of the Aircraft NOise Prediction Program (ANOPP-PAS) on the two rotor configurations. Preliminary semi-empirical frequency domain broadband noise predictions were also carried out based on airfoil self-noise theory in a rotational reference frame. The prediction techniques further supported trends identified in the experimental data analysis. The brushless motors were observed to be important noise contributors and warrant further investigation. It is believed that UAS acoustic prediction capabilities must consider both rotor and motor components as part of a combined noise-generating system.

Zawodny, Nikolas S.↗

TPSAS-NF1676L-12156-DND

The IVHM project recommends nine priorities for future IVHM research. Strain measurement technology is one of the nine recommendations. The Decadal Survey of Civil Aeronautics: Foundation for the Future, identified IVHM as the top NASA and national priority within the area of materials and structures. The survey also identified IVHM systems that warrant attention over the next decade such as “locally self-powered, wireless microelectromechanical sensors of various types tiny enough that very large numbers of sensors become practical.” Standard strain gages have been used to detect cracks in aircraft, and have been used to monitor load conditions and fatigue in airframes. High temperature devices will be able to monitor structural health in areas that are inaccessible today.

Cy Wilson↗

Uncertainty Models for the Hybrid Parametric Variation Method of Uncertainty Quantification; Analysis

There is some level of uncertainty in every finite element model (FEM), which flows to a level of uncertainty in predicted results. The purpose of uncertainty quantification (UQ) is to provide statistical bounds on prediction accuracy based on model uncertainty. This is distinct from model updating, which attempts to modify models to improve their accuracy. UQ does not improve the accuracy of models, but accepts that the models are inherently inaccurate and attempts to quantify the impact of that inaccuracy on predicted results. Previously, an alternate method for UQ, called the Hybrid Parametric Variation (HPV) method, was applied to Space Launch System (SLS) Hurty/Craig-Bampton (HCB) components to predict system-level statistics for launch vehicle attitude control transfer functions and core stage section loads due to buffet. The HPV method combines a parametric variation of the HCB fixed-interface (FI) modal frequencies with a nonparametric variation (NPV) method that randomly varies the HCB mass and stiffness matrices as Wishart random matrix distributions using random matrix theory (RMT). Alternatively, the most common method for modeling uncertainty in the structural dynamics community is a parametric approach, which varies physical parameters in the model. However, there are several disadvantages associated with the parametric method. Determining a reduced set of parameters that have a significant impact on the system response can be time consuming, and the selected parameter probability distributions are rarely reliably known. Therefore, in practice, the parameters are surrogates for the actual errors, and the link to parameter uncertainty is unknown. Another major drawback is that the uncertainty that can be represented is limited to the form of the nominal FEM. It is the experience of the authors that based on numerous aerospace programs, almost all FEM errors are in form rather than parameter values. This hypothesis is supported by the observation of the authors that it is almost never possible to ‘tune’ a FEM to match modal test results by only modifying model parameters. Model-form uncertainty cannot be directly represented by FEM input parameters nor included in a parametric approach. However, model-form uncertainty can be modeled using RMT, where a probability distribution is developed for the matrix ensemble of interest. The major advantage of the NPV method is that it covers errors in model form. The HPV method anchors uncertainty at the HCB component level to component modal test results by matching the HCB and test modes based on mode descriptions or other methods, and then applying differing levels of frequency variation. The specific variations depend on the confidence to which a component FEM has been validated through modal testing. The NPV method is layered on the frequency variation to match modal test self-orthogonality and cross-orthogonality (XO) results. Once the component uncertainty models are identified, they are assembled, and the uncertainty is propagated to the system level using a Monte Carlo (MC) analysis approach that generates statistics for system-level predictions This provides a UQ method that can be traced to test data, which can be updated as additional data and improved correlated models become available. The purpose of this paper is to collect and present all of the theory for HPV that has been previously published in reports and papers and to present examples of its application. Specifically, component uncertainty models based on the dispersion of corresponding mass and stiffness matrices using proposed test/analysis correlation metrics are investigated. The first example is purely academic so that the true answers are known, and the validity of the HPV method and the corresponding uncertainty models can be determined. The purpose of this paper is to collect and present all of the theory for HPV that has been previously published in reports and papers and to present examples of its application. Specifically, component uncertainty models based on the dispersion of corresponding mass and stiffness matrices using proposed test/analysis correlation metrics are investigated. The first example is purely academic so that the true answers are known, and the validity of the HPV method and the corresponding uncertainty models can be determined. The second example is an application to a component that is design specific to the SLS. Based on this work and other assessments, the HPV method provides another tool to the toolset used for complex system UQ analysis. From experience gathered to date using the HPV method, additional design specific applications must be investigated to provide further confidence in the validity of the HPV method of UQ analysis.

Uncertainty quantification↗

Initial Progress on Tank Bottom Repair for the DOE EM Tank Waste R&D Program - 25089

Several years prior to the Lab23-EM001 Call Announcement, Washington River Protection Solutions (WRPS) had done a review in identifying tank repair feasibility. [1, 2] The most viable methods of repair identified for the Floor of a Primary Tank identified were Grout Stabilization and Polymer Grout. Grout Stabilization was described as a self-leveling grout which fills the entire bottom of the tank and creates a new or false bottom. These types of materials have been used at the Savannah River Site (SRS) to fill and close waste tanks as well as contaminated spaces within decommissioned reactors. No mention was made as to the chemical composition of these Stabilizing Grouts in the review, however, grouts used at SRS for the mentioned applications have always been a cementitious grout material. A thickness of approximately 12 inches was suggested in the review. It was also suggested that an additional polymeric coating could be applied to this fresh and clean grout surface.

BLUE, KAREEN↗

Effect of heat treatment on the tensile behavior of selective laser melted Ti-6Al-4V by in situ X-ray characterization

Selective Laser Melted Ti-6Al-4V (as-SLMed) exhibits decreased yield strength, increased work hardening, and increased ductility after heat treatment at 730 degrees C (HT-730) or 900 degrees C (HT-900) for 2 h. To understand the change of mechanical properties, in situ high energy X-ray diffraction (HEXRD) is used to examine the phase composition, load partitioning, slip system activity, and dislocation density evolution in all three specimens. The as-SLMed specimen is dominated by martensitic α'. After heat treatment, α' partly or fully decomposes into α+β, reducing the yield strength. In HT-730, beta precipitates with confined size show much higher lattice strain than the α'/α matrix during deformation; in HT-900, the lattice strain difference is mostly eliminated. This is a key reason for the increased ductility in HT-900. From the anisotropic lattice strain development, basal slip is identified as the easiest slip system in α'/α. Using an elasto-plastic self-consistent (EPSC) model, the critical resolved shear stress ratio between prismatic slip and basal slip (CRSS prism /CRSS basal ) is estimated to be 1.31 and 1.16 in the as -SLMed and the HT-900 specimens, respectively. Further, the alpha phase in HT-900 is able to activate multiple slip systems and accumulate more dislocations during plastic deformation. This explains why HT-900 has better ductility and higher work hardening rate than the other two specimens.

36 MATERIALS SCIENCE↗