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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
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NASA NTRS1994

Detection of CO Cameron band emission in comet P/Hartley 2 (1991 XV) with the Hubble Space Telescope

Ultraviolet (UV) spectra of comet P/Hartley 2 (1991 XV) taken with the Faint Object Spectrograph (FOS) on the Hubble Space Telescope (HST) in 1991 September reveal several bands of the Cameron system of CO (a 3 Pi-X 1 Sigma). These band are most likely due to 'prompt' emission from CO2 and, thus, provide a direct tracer of the CO2 abundance in the nucleus. Photodissociative excitation of CO2 is probably the largest contributor to the Cameron band emission, but significant contributions from electron impact excitation of CO, electron impact dissociation of CO2, and dissociative recombination of CO2(+), are also possible. Using our estimate that photodissociative excitation is responsible for approximately 60% of the total excitation of the Cameron system, we derive Q(sub CO2) approximately 2.6 x 10(exp 27) molecules/s, which implies CO2/H20 approximately 4%. If all of the Cameron band emission is due to photodissociative excitation, then CO2/H2O = 7 +/- 2%. For the largest possible contributions from the other excitation mechanisms considered, the CO2 abundance could be as a small as aproximately 2-3%. We did not detect CO Fourth Positive Group emission in our data and derive an upper limit of CO/H2O less than or equal to 1% (3 sigma) for CO coming directly from the nucleus. Comparison of the relative CO2 and CO abundances in P/Hartley 2 to those in P/Halley (CO2/H2O approximately 3%-4%, CO/H20 approximately 4% for the nucleus source) indicates that selective devolatilization of the nucleus may have occurred for P/Hartley 2. A relatively large CO2/CO ratio (i.e., approximately greater than 1) seems to be a common property of cometary nuclei. Since gas phase chemistry, in either the solar nebula or the interstellar medium (ISM), appears incapable of producing large relative CO2 abundances, the CO2 in cometary nuclei is probably produced either by UV and/or cosmic ray irradiation of ISM grains prior to the formation of the Solar System, or by condensation fractionation in the solar nebula.

Weaver, H. A.↗
NASA NTRSDate not supplied

Metal-silicate Partitioning of Re, Ru, Pt, Os, Ti, Nb, and Ta in Reduced Differentiated Planetary Bodies

Siderophile (iron-loving) elements are strongly fractionated during differentiation of planetary bodies into core and mantle [1]. Because the fractionation is controlled by the pressure, temperature, redox conditions, and composition, this group of elements can provide important constraints on the conditions of accretion and core formation in early solar system bodies (planetesimals) and planets (Earth, Mercury, Venus)[2]. At the reducing conditions thought to prevail in the early solar system, Si is known to alloy with FeNi metallic liquids (e.g., [3]) affecting the activity coefficients of siderophile elements in FeNi liquids and thus ultimately their detailed partitioning between metal and silicate melt. The effect of Si can be significant for some siderophile elements, as demonstrated previously by (e.g., [4]: Ni, Co; [5,6]: Ge, As, Sb, Pd, Pt, Au). The effect of Si has not yet been determined for several key groups of siderophile elements including the highly siderophile Re, Ru and Os, and the weakly siderophile Ta, Nb, and Ti. Here, we report new experiments designed to quantify the effect of Si on the partitioning of Re, Pt, Os, Ru, Ti, Ta and Nb between metal and silicate melts. The results will be used to evaluate metal/silicate equilibrium for Nb, Ta, Ti and Nb/Ta ratios in planetary mantles, mantle concentrations of Ru, Re, Pt, Os during accretion, the evolution of Re/Os, Pt/Os ratios in magma oceans, and the role of late veneer in establishing Re and Ru abundances in the terrestrial mantle.

core formation↗
NASA NTRS2024

Chemical and Physical Properties of Cometary Dust

Cometary dust particles are best preserved remnants of the matter present at the onset of the formation of the Solar System. In Space missions, telescopic observations and laboratory analyses advanced the knowledge on the properties of cometary dust. the only samples certified with a cometary origin were returned by the Stardust space mission from comet 81P/Wild2. The “chondritic porous” (here called “chondritic anhydrous”) interplanetary dust particles (CA-IDPs) and micrometeorites (CP-MMs), and the ultracarbonaceous Antarctic MMs (UCAMMs) also show strong evidence for a cometary origin. The elemental composition of cometary dust is generally consistent with the chondritic (CI) composition, with the notable exception of elevated contents in carbon and nitrogen compared with CI. The organic matter of cometary dust is mixed with minor amounts of crystalline (at least 25% of the minerals) and amorphous mineral phases. The most abundant crystalline minerals are ferromagnesian silicates (olivine and low-Ca pyroxenes), but High-Ca pyroxenes, refractory minerals and Low Ni Fe sulfides are also present. The crystalline olivine and low-Ca pyroxene compositions can vary from their Mg-rich end-member (forsterite and enstatite) to relatively Fe-rich compositions. Refractory minerals as well as secondary minerals likeLIME (low-iron, Mn-enriched) olivines, unusual Fe sulfides or mineral aggregates of specific compositions like Kosmochloric high-Ca pyroxene and FeO-rich olivine - KOOL grains) are also found. The presence of carbonates in cometary dust is still debated, but a phyllosilicate-like phase was observed in a UCAMM. The abundance of pyroxene to olivine (in numbers) is larger than in primitive meteorites (e.g. the Px/Ol ratio is usually larger than 1). GEMS phases (glass with embedded metals and sulfides) are abundant in cometary dust, although not systematically found. Some of the organic matter present in cometary dust particle resembles the insoluble organic matter (IOM) present in primitive meteorites, but amorphous carbon and exotic (e.g. N-rich) organic phases are also present. The hydrogen isotopic composition of cometary dust particles (in the organic matter) is usually rich in deuterium, tracing a formation at very low temperatures, either in the protosolar cloud or in the outer regions of the protoplanetary disk. The presolar dust concentration in cometary dust can reach about 1%, which is the most elevated value observed in extraterrestrial samples. The size distribution of cometary dust in comet trails is well represented by a power-law distribution (differential size distribution) with a mean power index N typically ranging from -3 to -4. Polarimetric and light scattering studies of cometary dust suggest mixtures of porous agglomerates of sub-micrometer minerals with organic matter, which is compatible with the in situ analyses of 67P/Churyumov-Gerasimenko by MIDAS (Rosetta) and with the studies of it Stardust samples, CA-IDPs, CP-MMs and UCAMMs. Cometary dust particles have low tensile strength, and low density.

C. Engrand↗
NASA NTRS1974

Possible influence of comets on the chemical evolution of the galaxy

It has been suggested by Cameron (1973) that a cloud of comets containing a mass of condensable elements, comparable to the mass of such elements in the sun, formed on the outskirts of the solar system. If the formation of such comet clouds is a general feature of star formation, they constitute a significant sink of elements heavier than helium. It is shown here that this process provides a possible explanation for the very slow rate at which the mean metal abundance of disk stars has increased during the lifetime of the Galaxy.

Tinsley, B. M.↗
NASA NTRS1977

Evolution of the moon: The 1974 model

The interpretive evolution of the moon can be divided now into seven major stages beginning sometime near the end of the formation of the solar system. These stages and their approximate durations in time are as follows: (1) The Beginning: 4.6 billion years ago, (2) The Melted Shell: 4.6 to 4.4 billion years ago, (3) The Cratered Highlands: 4.4 to 4.1 billion years ago, (4) The Large Basins: 4.1 to 3.9 billion years ago, (5) The Light-colored Plains: 3.9 to 3.8 billion years ago, (6) The Basaltic Maria: 3.8 to 3.0(?) billion years ago, and (7) The Quiet Crust: 3.0(?) billion years ago to the present. The contributions of the Apollo and Luna exploration toward the study of those stages of evolution are reviewed.

Schmitt, H. H.↗
NASA NTRS1978

Experiments on asteroids using hard landers

Hard lander missions to asteroids are examined using the Westphal penetrator study as a basis. Imagery and chemical information are considered to be the most significant science to be obtained. The latter, particularly a detailed chemical analysis performed on an uncontaminated sample, may answer questions about the relationships of asteroids to meteorites and the place of asteroids in theories of the formation of the solar system.

Turkevich, A.↗
NASA NTRS1978

The primitive solar accretion disk and the formation of the planets

The author develops the idea that the formation of the solar system was triggered by the explosion of a supernova near a compressed interstellar cloud, which was further compressed by the supernova ejecta until it went over the threshold for gravitational collapse. During the collapse it is expected that the cloud would fragment into much smaller pieces. The principle source of friction in the collapsing nebula is taken to be turbulent viscosity, the required stirring having been supplied possibly by meridional circulation currents. The theory can be shown to account for how a great deal of condensed matter in the form of cometary bodies could be put into elliptical orbits extending toward 100,000 AU, the region of the Oort reservoir.

Cameron, A. G. W.↗
NASA NTRS1980

Al-26 from red giants

Simplified models of thermally pulsing red giants are investigated, with particular emphasis on predicting the extent to which nuclear processing at the base of the convective envelope in conjunction with processing in the thermally unstable He shell can synthesize Al-26 (tau/1/2/ = 7.2 x 10 to the 5th yr). Values of Al-26/Al-27 of about 0.5-1, with Al-27/Al-27(solar) of about 1-2, are predicted in some cases. It is pointed out that such results can lead to isotope shifts in the absorption lines of AlH and AlO, which should be observationally identifiable in some late-type supergiants. The possible connection with the anomalous Mg-26 content (assigned to the decay of Al-26) detected in some meteorites and the connection with formation of the solar system are also touched on.

Norgaard, H.↗
NASA NTRS1980

Isotopic yields of Mg, Al from the carbon and neon zones in the explosion of a massive star

A model is developed for the nucleosynthetic yields from the supernova explosion of a massive star of the sort which has been proposed as the initiating event in the formation of the solar system by Cameron and Truran (1977). Calculations start with the Hugoniot curves, estimating the preshock conditions from a 25 solar masses model at the start of core collapse. It is shown that the products of static carbon burning dominate abundance patterns in the ejecta. Both explosive carbon burning and explosive neon burning contribute significantly to Al-26. The production of Al-26 in this model is consistent with the trigger hypothesis.

Morgan, J. A.↗
NASA NTRS1980

Sweeping of the Jovian resonances and the evolution of the asteroids

During the formation of the solar system the variation of the gravitational field produced by removal of a nebula with its moderately massive accretion disk led to sweeping of the Jovian commensurability resonances through the asteroid zone. This process produced increased eccentricities and random velocities of the early planetesimals which resulted in collisional comminution rather than accretion. The existence of the asteroids, their low mass density, and their high relative velocities are interpreted as due to disruption of the accretion processes of the terrestrial planets by the influences of Jupiter.

Torbett, M.↗
NASA NTRS1981

Radio observations of molecules in the interstellar gas

Since 1968, radio astronomy has made it possible to identify nearly 50 molecules in the dense concentrations of the interstellar gas now generally termed molecular clouds. Most interstellar molecules are familiar stable compounds. However, one-fifth of the discovered species are ions, radicals, and acetylenic carbon chains so reactive in the laboratory that before being detected in space they had rarely been observed or were entirely unknown. The heavy atom backbone of the known interstellar molecules is a linear chain of C, N, O, or S. Si is found in two diatomic molecules. Rings and branched chains are missing. The most readily observed spectral lines of most interstellar molecules correspond to rotational transitions at millimeter wavelengths. These are generally excited by H2 collisions. A number of rare isotopic species are observed in interstellar molecules. Isotopic ratios differing from those on Earth exist, and can in almost all cases be attributed to stellar nucleosynthesis since the formation of the solar system.

Thaddeus, P.↗
NASA NTRS1980

Ar-39/Ar-40 systematics of Allende inclusions

A laser microprobe was used to measure the Ar isotopic contents of individual mineral grains in four neutron-irradiated Allende samples: two coarse-grained Ca-Al-rich inclusions; one fine-grained Ca-Al-rich inclusion; and one sample with matrix and miscellaneous chondrules. The following K-Ar ages (G.y.) were obtained after degassing low Ar retentive sites by preheating the samples for one hour at 675 C: matrix, 3.5 + or - 0.2; three miscellaneous chondrules, 4.4 + or - 0.1, 4.0 + or - 0.1, and 4.4 + or - 0.1; and the fine-grained inclusion, 4.5 + or - 0.2. The minerals in the coarse-grained Ca-Al-rich inclusions have ubiquitous chlorine, less than 10 ppm K and apparent ages ranging upwards from 4.6 G.y. to well over 10 G.y. Possible explanations for these apparent ages are atmospheric contamination, the decay of K-40 prior to the formation of the solar system, and the trapping of radiogenic Ar-40 lost by the matrix.

Herzog, G. F.↗
NASA NTRS1982

OB associations and the nonuniversality of the cosmic abundances - Implications for cosmic rays and meteorites

The formation of the solar system inside an OB association is examined with particular attention to the elemental abundances which would have been ejected by the association's first few supernovae. It is found that the solar system material may have been significantly contaminated by these supernovae and thus the average interstellar composition may differ from the solar system composition. In particular, we find that many of the so-called isotopic and elemental abundance anomalies (e.g., Ne, C, O, s-process/r-process, etc.) found in meteoritic inclusions and in cosmic rays may be more representative of the average interstellar abundance. In other words, it may be that the average solar system abundances are what is 'anomalous'.

Olive, K. A.↗
NASA NTRS1983

Laboratory measurements of D/H ratios in interplanetary dust

Measurements of noble gas elemental and isotopic abundance patterns have provided evidence that a subset of the particles collected in the upper atmosphere by NASA aircraft are micrometeorites. It is found that the deuterium in two such particles is enriched relative to hydrogen by 500-1100 per thousand when compared with the terrestrial SMOW standard. This result confirms the extraterrestrial origin of the dust particles and demonstrates that the material preserves a potentially unique isotopic record which may reflect a memory of processes occurring during or before the formation of the solar system. In addition, the deuterium enrichment seen in the particles is analogous to that observed in bulk samples of one carbonaceous meteorite and two unequilibrated ordinary chondrites as well as in chemical separates of a number of other meteorites.

Zinner, E.↗
NASA NTRS1983

Continuing investigation of sweeping Jovian resonances - The 7:3 amd 3:2 resonances with further discussion of the 2:1 resonance

The formation of the solar system from an accretion disk around the protosun can have a significant impact on the celestial mechanics of the early solar system. The solids in the disk settled to the midplane and formed a planetesimal swarm while an early-formed Jupiter was present. The gravity of the disk makes the radial force law become non-Keplerian, causing the commensurability resonances of the early-formed Jupiter to be displaced from where they would otherwise be. An analysis similar to that previously applied to the 2:1, 3:1 and 5:2 resonances is presently undertaken for the 7:3 and 3:2 resonances, and a Kirkwood-like gap is obtained for a sweeping 7:3 resonance. An accumulation of objects is obtained near the 3:2 resonance which, with the ejection of objects on either side of the resonance, would resemble the Hilda group of asteroids. Agreement between the exact commensurability location and the gap center is discussed for the 2:1 resonance.

Torbett, M. V.↗
NASA NTRS1985

Carbon isotopes in bulk carbonaceous chondrites

The chemical and physical processes involved in the formation of the solar system are examined. Primitive matter has been found on a microscopic scale in a variety of meteorites: fragments of small solar system bodies that were never part of a large planet. This primitive matter has, in most cases, been identified by the presence of anomalous abundances of some isotopes of the chemical elements. Of particular interest for carbon isotope studies are the primitive meteorites known as carbonaceous chondrites. Using a selective oxidation technique to sort out the carbon contained in different chemical forms (graphite, carbonates, and organic matter), four carbonaceous chondrites are analyzed. The presence of the (13) C-rich component was confirmed and additional carbon components with different, but characteristic, isotopic signatures were resolved.

Halbout, J.↗
NASA NTRS1985

Sizing up the planets

Visual, scaled comparisons are made among prominent volcanic, tectonic, crater and impact basin features photographed on various planets and moons in the solar system. The volcanic formation Olympus Mons, on Mars, is 27 km tall, while Io volcanic plumes reach 200-300 km altitude. Valles Marineris, a tectonic fault on Mars, is several thousand kilometers long, and the Ithasa Chasma on the Saturnian moon Tethys extends two-thirds the circumference of the moon. Craters on the Saturnian moons Tethys and Mimas are large enough to suggest a collision by objects which almost shattered the planetoids. Large meteorite impacts may leave large impact basins or merely ripples, such as found on Callisto, whose icy surface could not support high mountains formed by giant body impacts.

Meszaros, S. P.↗