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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Quinoxaline polymers and copolymers derived from 1, 4-BIS(1'-napthalenyloxayl) benzene

A route for the synthesis of a new monomer, 1,4-bis(1'-naphthalenyl)-oxayl benzene, was devised, and six polymers and copolymers were prepared from this monomer, 1,4-bis(phenyloaxaly)benzene, 3,3'-diaminobenzidine and 3,3',4,4'-tetraaminobenzophenone. Thermogravimetric analysis showed that decomposition of these quinoxaline polymers and copolymers sets in at about 500 C but does not become significant in an inert atmosphere below 600 C. Oxidation becomes significant at about 550 C and the phenylquinoxaline homopolymer is somewhat more oxidation resistant than is the 1-naphthalenylquinoxaline homopolymer. Stress-relaxation measurements showed that, with two exceptions, the homopolymers and copolymers exhibited two second-order transition temperatures, one at about 204.4 C (400 F) and the other at about 315.6 C (600 F). No gross differences in the high temperature plasticity was observed between the naphthalenyl- and the phenyl-quinoaxaline homopolymers. Work was begun on a method for cross-linking polyquinoxalines. A new monomer, p-(methyloxaly)benzil, was synthesized, and model reaction studies showed that cross-linking of 2-methylquinoxaline polymers by a Michael condensation with dimaleimides will probably occur.

Port, W. S.↗
NASA NTRS1974

Evaluation of soft rubber goods

The performance of rubber goods suitable for use as O-rings, seals, gaskets, bladders and diaphragms under conditions simulating those of the space shuttle were studied. High reliability throughout the 100 flight missions planned for the space shuttle was considered of overriding importance. Accordingly, in addition to a rank ordering of the selected candidate materials based on prolonged fluid compatibility and sealability behavior, basic rheological parameters (such as cyclic hysteresis, stress relaxation, indicated modulus, etc.) were determined to develop methods capable of predicting the cumulative effect of these multiple reuse cycles.

Merz, P. L.↗
NASA NTRS1975

Anelastic deformation of boron fibers

The flexural deformation behavior of vapor-deposited boron fibers was examined from 100 to 1100 K by stress-relaxation and internal friction techniques. Only strong thermally-activated anelasticity was observed with no evidence of plasticity up to surface strains of 0.006. The parameters governing the relaxation processes within the anelastic spectra of as-received and annealed fibers were determined. These parameters were correlated with X-ray structure studies to develop preliminary models for the sources of boron's anelasticity. The large relaxation strengths of the dominant Ia processes coupled with their relaxation times and energies suggest a sliding mechanism between certain basic structural subunits common to both the beta-rhombohedral and vapor-deposited boron structures.

Dicarlo, J. A.↗
NASA NTRS1975

Anelastic deformation of boron fibers

The flexural deformation behavior of vapor-deposited boron fibers is investigated in the temperature range from 100 to 1100 K by stress-relaxation and internal friction methods. Strong thermally-activated anelasticity is uniquely observed, and no evidence of plasticity is found up to surface strains of 0.006. The parameters governing the relaxation processes within the anelastic spectra of untreated and annealed fibers are determined and correlated with the results of X-ray structural studies to develop preliminary models for the possible causes of boron's anelasticity. The large relaxation strengths of the dominant Ia processes together with their relaxation times and energies are shown to suggest a sliding mechanism between certain basic structural subunits common to both the beta-rhombohedral and vapor-deposited boron structures.

Dicarlo, J. A.↗
NASA NTRS1975

Potential seal candidates for high-energy propellants

Five potential seal candidates (linear Tefzel, linear Halar, crosslinked Halar, Viton ECD-006, and phosphazine fluoroelastomer) were evaluated for the orbital maneuvering system of the space shuttle. Since this system employs nitrogen tetroxide (N2O4) and monomethyl hydrazine (MMH) as hypergolic propellants, the seal candidates were selected on the basis of projected chemical resistance as well as rheological behavior. Chemical resistance to these high-energy fuels was determined via conventional isothermal and thermal cycling immersion tests. Rheological measurements, however, were performed on O-rings molded from the subject seal candidates. Properties determined, such as cyclic work and hysteresis, stress relaxation, and indicated modulus, therefore, relate to the O-ring seals themselves.

Merz, P. L.↗
NASA NTRS1976

Time temperature-stress dependence of boron fiber deformation

Flexural stress relaxation (FSR) and flexural internal friction (FIF) techniques were employed to measure the time-dependent deformation of boron fibers from -190 to 800 C. The principal specimens were 203 micrometers diameter fibers commercially produced by chemical vapor deposition (CVD) on a 13 micrometer tungsten substrate. The observation of complete creep strain recovery with time and temperature indicated that CVD boron fibers deform flexurally as anelastic solids with no plastic component.

Dicarlo, J. A.↗
NASA NTRS1979

Compatibility of elastomers in alternate jet fuels

The compatibility of elastomeric compositions of known resistance to aircraft fuels was tested for potential use in Jet A type fuels obtainable from alternate sources, such as coal. Since such fuels were not available at the time, synthetic alternate fuels were prepared by adding tetralin to a petroleum based Jet A type fuel to simulate coal derived fuels which are expected to contain higher amounts of aromatic and hydroaromatic hydrocarbons. The elastomeric compounds tested were based on butadiene-acrylonitrile rubber, a castable Thiokol polysulfide rubber, and a castable fluorosilicone rubber. Batches of various cross-link densities of these rubbers were made and their chemical stress relaxation behavior in fuel, air, and nitrogen, their swelling properties, and response to mechanical testing were determined.

Kalfayan, S. H.↗
NASA NTRS1980

Composite wall concept for high temperature turbine shrouds: Survey of low modulus strain isolator materials

Plasma sprayed yttria stabilized zirconium oxide turbine seal specimens, incorporating various low modulus porous metal strain isolator pads between the zirconium oxide and a dense metal substrate, were subjected to cyclic thermal shock testing. Specimens that had a low modulus pad composed of sintered FeNiCrAlY fibermetal survived 1000 thermal shock cycles without spalling of the ceramic. A figure of merit for the low modulus pad materials taking into consideration the elastic modulus, thermal conductivity, strength, and oxidation resistance of the pad was proposed, and showed reasonable agreement with the thermal shock results. A potential surface distress problem on the zirconium oxide, associated with nonuniform temperature distribution and rapid stress relaxation was identified. One approach to solving the surface distress problem through application of laser surface fusion of the zirconium oxide layer showed some promise, but improvements in the laser surface fusion process are necessary to prevent process associated damage to the ceramic.

Bill, R. C.↗
NASA NTRS1981

Heat sterilizable solid-propellant development

The binders tested were polyurethanes made from two hydroxy-terminated polybutadienes, R-45 and Butarez HT, one hydroxy-terminated butadiene-acrylonitrile copolymer, Hycar 1300X 17, and a hydroxy-terminated prepolymer, Esterdiol 560, made from the dimerized fatty acid Empol 1010. The isocyanates used most extensively were isophorone diisocyanate (IPDI) and a polymeric diisocyanate, DDI. Stress relaxation was used to examine the chemical changes that took place in the binder when subjected to the sterilization temperatures. The thermal stability of the oxidizer, ammonium perchlorate (AP), was tested by thermogravimetry in the isothermal and nonisothermal modes. The effect of particle size, recrystallization, moisture content, and doping on the heat stability of AP could be evaluated by this method. The volatile degradation products, obtained when AP samples were aged at 135 C for prolonged periods, were analyzed by mass spectroscopy.

Kalfayan, S. H.↗
NASA NTRS1982

Turbine blade nonlinear structural and life analysis

The utility of advanced structural analysis and life prediction techniques was evaluated for the life assessment of a commercial air-cooled turbine blade with a history of tip cracking. Three dimensional, nonlinear finite element structural analyses were performed for the blade tip region. The computed strain-temperature history of the critical location was imposed on a uniaxial strain controlled test specimen to evaluate the validity of the structural analysis method. Experimental results indicated higher peak stresses and greater stress relaxation than the analytical predictions. Life predictions using the Strainrange Partitioning and Frequency Modified approaches predicted 1200 to 4420 cycles and 2700 cycles to crack initiation, respectively, compared to an observed life of 3000 cycles.

Mcknight, R. L.↗
NASA NTRS1983

Experimental Verification of the Number Relation at Room and Elevated Temperatures

The accuracy of the Neuber equation for predicting notch root stress-strain behavior at room temperature and at 650 C was experimentally investigated. Strains on notched specimens were measured with a non-contacting, interferometric technique and stresses were simulated with smooth specimens. Predictions of notch root stress-strain response were made from the Neuber Equation and smooth specimen behavior. Neuber predictions gave very accurate results at room temperature. However, the predicted interaction of creep and stress relaxation differed from experimentally measured behavior at 650 C.

Lucas, L. J.↗
NASA NTRS1983

A Unified Constitutive Relationship for the Time-dependent Behavior of Fast Breeder Alloys

Constitutive equations based on classical concepts of creep and plasticity generally rest on the assumption that the inelastic strain can be decomposed into two distinct and additive contributions, one time dependent (creep) and the other time dependent (plastic). It is suggested that an approach is to adopt a unified representation in which creep and plasticity are characterized as occurring simultaneously and interactively and time is an essential ingredient throughout. Examples of the inherent time dependency exhibited by some fast breeder alloys at elevated temperature are rate dependency under monotonic and cyclic straining, thermal recovery and strong creep-elasticity interaction. The stron influence of the recent history of plastic straining on stress relaxation is shown.

Robinson, D. N.↗
NASA NTRS1983

Application of an Uncoupled Elastic-plastic-creep Constitutive Model to Metals at High Temperature

A uniaxial, uncoupled constitutive model to predict the response of thermal and rate dependent elastic-plastic material behavior is presented. The model is based on an incremental classicial plasticity theory extended to account for thermal, creep, and transient temperature conditions. Revisions to he combined hardening rule of the theory allow for better representation of cyclic phenomenon including the high rate of strain hardening upon cyclic reyield and cyclic saturation. An alternative approach is taken to model the rate dependent inelastic deformation which utilizes hysteresis loops and stress relaxation test data at various temperatures. The model is evaluated and compared to experiments which involve various thermal and mechanical load histories on 5086 aluminum alloy, 304 stainless steel and Hastelloy-X.

Haisler, W. E.↗
NASA NTRS1983

Embedded cavity drag in steady and unsteady flows

The numerical solution of the laminar boundary-layer flow over an embedded cavity is studied. The purpose is to examine the relevant drag characteristics of laminar cavity flow. The solution field is obtained in terms of velocity and vorticity variables, with the stream function and pressure derivable from the directly computed variables. An analysis and comparison is made among four square cavities, ranging in size from 0.25 to 1.00 boundary-layer thicknesses deep. The dominant flow features are examined in the vicinity of the cavity by means of the stream function and iso-vorticity contours. The dominant physics in the overall drag characteristics of the flow is examined by an analysis of the pressure and wall shear stress distributions in the cavity, and upstream and downstream of the cavity. Pressure forces and frictional forces in, and in the vicinity of, the cavity are determined. Stress relaxation distances, both upstream and downstream of the cavity, are calculated and analyzed. The flow dynamics of the boundary-layer flow over an embedded cavity is summarized. Finally, the relevance of the results to the control of flow separation in such flows is discussed.

Gatski, T. B.↗
NASA NTRS1984

A computer program for predicting nonlinear uniaxial material responses using viscoplastic models

A computer program was developed for predicting nonlinear uniaxial material responses using viscoplastic constitutive models. Four specific models, i.e., those due to Miller, Walker, Krieg-Swearengen-Rhode, and Robinson, are included. Any other unified model is easily implemented into the program in the form of subroutines. Analysis features include stress-strain cycling, creep response, stress relaxation, thermomechanical fatigue loop, or any combination of these responses. An outline is given on the theoretical background of uniaxial constitutive models, analysis procedure, and numerical integration methods for solving the nonlinear constitutive equations. In addition, a discussion on the computer program implementation is also given. Finally, seven numerical examples are included to demonstrate the versatility of the computer program developed.

Chang, T. Y.↗
NASA NTRS1984

Embedded cavity drag in steady and unsteady flows

The numerical solution of the laminar boundary-layer flow over an embedded cavity is studied. The purpose of the study is to examine the relevant drag characteristics of laminar cavity flow. The solution field is obtained in terms of velocity and vorticity variables, with the stream function and pressure derivable from the directly computed variables. An analysis and comparison is made among four square cavities, ranging in size from 0.25 to 1.00 boundary-layer thicknesses deep. The dominant flow features are examined in the vicinity of the cavity by means of the stream function and iso-vorticity contours. The dominant physics in the overall drag characteristics of the flow is examined by an analysis of the pressure and wall shear stress distributions in the cavity, and upstream and downstream of the cavity. Pressure forces and frictional forces in, and in the vicinity of, the cavity are determined. Stress relaxation distances, both upstream and downstream of the cavity, are calculated and analyzed. The flow dynamics of the boundary-layer flow over an embedded cavity is summarized. Finally, the relevance of the present results to the control of flow separation in such flows is discussed.

Gatski, T. B.↗
NASA NTRS1984

Free Volume Considerations in Thermoplastic and Thermosetting Resins

The direct measurement of physical aging and of the volume changes which go on during the course of this aging is discussed. Data on PMMA showing its physical aging as measured by its stress relaxation response and the accompanying volume changes are presented. An indication of how one can measure the free volume both directly from the volume change itself and relatively directly via a new technique is given. The application of this new technique (electron spin resonance spectroscopy) to other polymer systems is demonstrated.

Landel, R. F.↗
NASA NTRS1985

Some advances in experimentation supporting development of viscoplastic constitutive models

The development of a biaxial extensometer capable of measuring axial, torsion, and diametral strains to near-microstrain resolution at elevated temperatures is discussed. An instrument with this capability was needed to provide experimental support to the development of viscoplastic constitutive models. The advantages gained when torsional loading is used to investigate inelastic material response at elevated temperatures are highlighted. The development of the biaxial extensometer was conducted in two stages. The first involved a series of bench calibration experiments performed at room temperature. The second stage involved a series of in-place calibration experiments conducted at room and elevated temperature. A review of the calibration data indicated that all performance requirements regarding resolution, range, stability, and crosstalk had been met by the subject instrument over the temperature range of interest, 21 C to 651 C. The scope of the in-place calibration experiments was expanded to investigate the feasibility of generating stress relaxation data under torsional loading.

Ellis, J. R.↗