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At least 253 records · Page 14
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NASA NTRS1992

Preliminary results of an experimental study of the interactions of basalt glass and a water vapor atmosphere: Implications for weathering on Mars

Models of weathering processes on the surface of Mars invoke hydrothermal alteration as the primary mechanism responsible for clay formation. Previous experimental studies of basalt glass interactions with water under hydrothermal conditions demonstrate that phyllosilicates and zeolites are the primary alteration minerals. Gas-solid weathering is thought to be less thermodynamically favorable and relatively unimportant, however, the experimental alteration of basalt glass under vapor ion conditions (large SA/V) can result in the formation of clay minerals, zeolites, and hydrated calcium silicates. We have undertaken a study of the reacted layers formed on basalt glasses experimentally altered under vapor hydration conditions to resolve this issue. High SA/V ratios promote reaction product buildup in solution and promote alteration mineral formation. It was previously shown that these reaction conditions promote weathering processes similar to those found in nature for tektite glasses, rhyolitic glasses, and basalt glasses. The hydration of basalt glass is described for 100 percent relative humidity experiments at temperatures of 150, 175, and 200 C for up to 400 days. Preliminary characterization of the alteration layers with analytical electron and scanning microscopy suggest that the reaction mechanism includes precipitation of a smectite clay on the outermost surface of the glass. Between the clay and the unreacted glass is an amorphous gel-like phase (palagonite). Our results provide an experimental basis for proposing that basalt glass interactions with vapor atmospheres can be an important source of clay minerals.

Mazer, J. J.↗
NASA NTRS1993

Minor and trace element composition and age of Yukon probable-microtektites

Major, minor, and trace element composition of the candidate micro tektites from Yukon Territory suggest a possible impact site of hydrothermally altered limestone and sand or chert, or possibly a carbonatite. Their REE/chondrite curve is similar in character to, but higher than, shale composites of North America, Australia, and Europe. Relative to these same composites, the Yukon droplets are enriched in Y, F, S, Sr, P, Mn, Mg, and Ca. They are depleted in Rb, Li, Th, Nb, Ti, K, Na, Fe, Si, and Al. Biostratigraphic constraints on the droplets indicate they are Middle to Late Devonian, more likely Middle Devonian, in age.

Boundy-Sanders, S. Q.↗
NASA NTRS1993

Projectile-target mixing in melted ejecta formed during a hypervelocity impact cratering event

Tektites contain little to no projectile contamination while, in contrast, some distal ejecta deposits can be relatively projectile-rich (e.g. the Cretaceous-Tertiary (K-T) boundary clay). This compositional difference motivated an experimental study of hypervelocity target-projectile mixing processes. We hope to scale up the results from these experiments and apply them to terrestrial impact structures like the Chicxulub Crater, Yucutan, Mexico, the leading contender as the site for the impact that caused the mass extinction that marks the K-T boundary. Shock decomposition of the approximately 500m thickness of anhydrite, or greater thickness of limestone, in the target rocks at Chicxulub may have been a critical mechanism for either global cooling via SO3, and subsequently H2SO4, formation, or possibly, global warming via increased CO2 formation. Understanding target-projectile mixing processes during hypervelocity impact may permit more accurate estimates of the amount of potentially toxic, target-derived material reaching stratospheric heights.

Evans, Noreen Joyce↗
NASA NTRS1993

Cretaceous-tertiary boundary spherules and Cenozoic microtektites: Similarities and differences

Bohor and Betterton pointed out that the K-T spherules can be divided into three groups. Their Type 1 spherules appear to be found in or adjacent to North America, particularly the Western Interior and in Haiti and Mexico. The Type 1 spherules occur in the lower part of the K-T boundary clay below an Ir anomaly. It is the Type 1 spherules which are most similar to microtektites. The discovery of K-T boundary spherules in Beloc, Haiti, and Mimbral, Mexico, with residual tektite-like glass cores supports the hypothesis that the Type 1 spherules are diagenetically altered microtektites. The similarities and differences of the Type 1 K-T boundary spherules to previously described Cenozoic microtektites are discussed.

Glass, B. P.↗
NASA NTRS1994

The Twenty-Fifth Lunar and Planetary Science Conference. Part 3: P-Z

Various papers on lunar and planetary science are presented, covering such topics as: impact craters, tektites, lunar geology, lava flow, geodynamics, chondrites, planetary geology, planetary surfaces, volcanology, tectonics, topography, regolith, metamorphic rock, geomorphology, lunar soil, geochemistry, petrology, cometary collisions, geochronology, weathering, and meteoritic composition.

Source record↗
NASA NTRS1993

Assumptions about the presence of natural glasses on Mars

Natural glasses occur not only on Earth but also in lunar rocks and in some meteorites. On geological grounds, natural glasses could be expected on the surface of Mars and their presence would have important implications for the weathering and alteration of the near-surface layer. Ultramafic and mafic magmatism rich in iron and some volatiles appears to have been important on Mars as has been impact cratering, volcanism, and possibly hydrothermal alteration. Available data indicate that we can presume the past or present existence of volcanic basaltic glasses, impact glasses formed by thermal fusion of meteorite-impact targets, and diaplectic (mainly maskelynite) glasses. Conditions appear unsuitable for the formation of tektites on the Martian surface, and the production of measurable amounts of fulgurite or combustion glass seems improbable. Prospects for the remote and in-situ identification of Martian glasses and their subsequent weathering products are discussed and include orbital reflectance and thermal emission spectroscopic measurements and Mossbauer spectroscopy from a surface lander.

Bouska, Vladimir↗
NASA NTRS1994

Provenance of mineral phases in the Cretaceous-Tertiary boundary sediments exposed on the southern peninsula of Haiti

Acid-insoluble mineral residua of tektite-bearing Cretaceous-Tertiary boundary sediments in the Beloc Formation of Haiti contain abundant shocked quartz and lesser amounts of shocked plagioclase. The shocked quartz grains typically have 2 or 3 sets of planar deformation features, although grains with up to 15 sets were observed. The proportion of shocked quartz in the boundary sediments increases with stratigraphic height; at least 70 +/- 11% of the proportion of the quartz grains are shocked in the uppermost stratigraphic interval. The proportion of shocked quartz throughout the boundary sediments indicates that these grains were excavated primarily from crystalline silicate units, which may have been covered with a small amount of porous quartz-bearing sediments. Polyhedral and moderately sutured margins in shocked polycrystalline quartz grains, the size of the crystal units in these grains and the presence of shocked plagioclase, indicate these ejecta components were excavated from a target with continental affinites, containing quartzites or metaquartzites and a sialic metamorphic and/or igneous component. Other evidence suggests the target may also have contained a significant amount of calcium carbonate and/or sulfate. The large size and amount of shocked quartz grains deposited in Haiti indicate the crater from which they were excavated was produced in the proto-Caribbean region.

Kring, David A.↗
NASA NTRS1993

Assumptions About the Presence of Natural Glasses on Mars

Natural glasses occur not only on Earth but also in lunar rocks and in some meteorites. On geological grounds, natural glasses could be expected on the surface of Mars and their presence would have important implications for the weathering and alteration of the near-surface layer. Ultramafic and mafic magmatism rich in iron and some volatiles appears to have been important on Mars as has been impact cratering, volcanism, and possibly hydrothennal alteration. Available data indicate that we can presume the past or present existence of volcanic basaltic glasses, impact glasses formed by thermal fusion of meteorite-impact targets, and diaplectic (mainly maskelynite) glasses. Conditions appear unsuitable for the formation of tektites on the Martian surface, and the production of measurable amounts of fulgurite or combustion glass seems improbable. Prospects for the remote and in situ identification of Martian glasses and their subsequent weathering products are discussed and include orbital reflectance and thermal emission spectroscopic measurements and Mossbauer spectroscopy from a surface lander.

Bouska, Vladimir↗
NASA NTRS1993

Assumption About the Presence of Natural Glasses on Mars

Natural glasses occur not only on Earth but also in lunar rocks and in some meteorites. On geological grounds, natural glasses could be expected on the surface of Mars and their presence would have important implications for the weathering and alteraton of the near-surface layer. Ultramafic and mafic magmatism rich in iron and some volatiles appears to have been important on Mars as has been impact cratering, volcanism, and possibly hydrothertnal alteration, Available data indicate that we can presume the past or present existence of volcanic basaltic glasses, impact glasses formed by thermal fusion of meteorite-impact targets, and diaplectic (mainly maskelynite) glasses. Conditions appear unsuitable for the formation of tektites on the Martian surface, and the production of measurable amounts of fulgurite or combustion glass seems improbable. Prospects for the remote and in situ identificaton of Martian glasses and their subsequent weathering products are discussed and include orbital reflectance and thermal emission spectroscopic measurements and Mossbauer spectroscopy from a surface lander.

Bouska, Vladimir↗
NASA NTRS1961

New Investigations of the Alleged Meteorite from Igast, Estonia

This paper presents the results of a reinvestigation of the object which allegedly fell at Igast, Estonia, in 1855, and which may be the only example of a meteorite with the chemical composition of a tektite. R is concluded that generally quoted opinions of the artificial nature of this object are based on spurious samples, specifically melted brick and quartz basalt porphyry distributed by a Russian collector. Possibly genuine specimens from this observed fall are in the British Museum, the Paris Museum, and perhaps at the University of Dorpat, Estonia. It is recommended that these specimens be re-examined and that a search for similar objects be made.

OKeefe, John A.↗
NASA NTRS2000

Upper Eocene Spherules at ODP Site 1090B

Our two labs independently discovered upper Eocene microtektites and microkrystites at ODP Site 1090, a new South Atlantic locality near the Agulhus Ridge. This is a significant new data point for the strewn fields of these spherules, which were recently extended into the Atlantic sector of the Southern Ocean when they were reported at ODP Site 689 on the Maude Rise. The microtektites have been regarded as related to North American tektites and the microkrystites as belonging to the clinopyroxene-bearing (cpx) spherule strewn field. Initial reports indicate that Site 1090 contains a complete sequence of upper Eocene sediments composed of diatom and nannofossil oozes. The magneto- and bio-stratigraphy indicate that impact-age sediments should occur in core 30X of Hole 1090B. One of us (FTK) took 2 cc samples at 10 cm intervals over 600 cm of core for Ir analyses and the senior author (SL) took 3 cc samples at 20 cm intervals to search for spherules. Both studies proved successful and additional samples were obtained to confirm initial results and better define the Ir anomaly and spherule abundances. Peak Ir concentrations of 0.97 ng/g were found at 1090B-30X-5, 105-106cm and 0.78 ng/g at 115-116 cm. Anomalous Ir concentrations (greater than 0.1 ng/g) extend over about 100 cm of core. Preliminary results indicate that the excess Ir at this site is about 25 ng per sq cm. About 380 microtektites (>63 pm) and 2492 microkrystites (>63 pm) were recovered over a 1.8 m interval with a peak abundance of microtektites (106/gram) and microkrystites (562/gram) at 1090B-30X- 5, 114-115 cm. The largest microtektite is approximately 960 x 1140 micron in size. About 55 % are spherical, and the rest are disc, cylinder, dumbbell, teardrop, or fragments. Most of the microtektites are transparent colorless, but a few are transparent pale brown or green. Preliminary data indicate that the microtektites at Site 1090 have similar major oxide compositions to those at Site 689. About 50% of the cpx spherules are spherical, the rest are fragments. They range from yellowish translucent to dark opaque. Based on stratigraphic data, occurrence of a positive Ir anomaly, and similar appearance and major oxide compositions of the Site 1090 spherules to those at Site 689, we believe that the spherule layer(s) are the same at both sites. However, there are significant differences between these two sites. At Site 689 the peak abundance of the cpx spherules is slightly below that of the microtektites. We can distinguish no such separation at Site 1090, despite a somewhat higher sediment accumulation rates. Peak Ir concentrations are about four times higher at Site 1090, resulting in a similarly higher total flux of Ir for this site compared to Site 689 on the Maude Rise. This is generally consistent with the flux of cpx spherules (greater than 63 pm) which is estimated to be approximately -2100 per sq cm, about twice that of Site 689D (1040 sq cm) and with the cpx-spherule component being a principal carrier of the Ir signal. The number of microtektites per sq cm (greater than 63 micron) is nearly the same at both sites, approximately 300 in 1090B and 280 in 689B. A decrease in the greater than 63 micron size fraction (consisting primarily of diatoms and radiolaria) is coincident with the spherule layer at both sites suggesting that the impact(s) that produced the spherule layer(s) may have had an adverse affect on the marine plankton.

Liu, S.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Effects of Impacts: Shock and Awe

This document discusses the following topics: Zircon as a Shock Indicator in Impactites of Drill Core Yaxcopoil-1, Chicxulub Impact Structure, Mexico; Experimental Investigation of Shock Effects in a Metapelitic Granulite; Experimental Reproduction of Shock Veins in Single-Crystal Minerals; Post-Shock Crystal-Plastic Processes in Quartz from Crystalline Target Rocks of the Charlevoix Impact Structure; Shock Reequilibration of Fluid Inclusions; How Does Tektite Glass Lose Its Water?; Assessing the Role of Anhydrite in the KT Mass Extinction: Hints from Shock-loading Experiments; A Mineralogical and Geochemical Study of the Nonmarine Permian/Triassic Boundary in the Southern Karoo Basin, South Africa; Extraterrestrial Chromium in the Permian-Triassic Boundary at Graphite Peak, Antarctica; Magnetic Fe,Si,Al-rich Impact Spherules from the P-T Boundary Layer at Graphite Peak, Antarctica; A Newly Recognized Late Archean Impact Spherule Layer in the Reivilo Formation, Griqualand West Basin, South Africa; Initial Cr-Isotopic and Iridium Measurements of Concentrates from Late Eocene Cpx-Spherule Deposits; An Ordinary Chondrite Impactor Composition for the Bosumtwi Impact Structure, Ghana, West Africa: Discussion of Siderophile Element Contents and Os and Cr Isotope Data.

Kyte, F. T.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Impact-Related Deposits

The session "Impact-Related Deposits" included:Evidence for a Lightning-Strike Origin of the Edeowie Glass; 57Fe M ssbauer Spectroscopy of Fulgurites: Implications for Chemical Reduction; Ca-Metasomatism in Crystalline Target Rocks from the Charlevoix Structure, Quebec, Canada: Evidence for Impact-related Hydrothermal Activity; Magnetic Investigations of Breccia Veins and Basement Rocks from Roter Kamm Crater and Surrounding Region, Namibia; Petrologic Complexities of the Manicouagan Melt Sheet: Implications for 40Ar-39Ar Geochronology; Laser Argon Dating of Melt Breccias from the Siljan Impact Structure, Sweden: Implications for Possible Relationship to Late Devonian Extinction Events; Lunar Impact Crater, India: Occurrence of a Basaltic Suevite?; Age of the Lunar Impact Crater, India: First Results from Fission Track Dating; The Fluidized Chicxulub Ejecta Blanket, Mexico: Implications for Mars; Low Velocity Ejection of Boulders from Small Lunar Craters: Ground Truth for Asteroid Surfaces; Ejecta and Secondary Crater Distributions of Tycho Crater: Effects of an Oblique Impact; Potassium Isotope Systematics of Crystalline Lunar Spherules from Apollo 16; Late Paleocene Spherules from the North Sea: Probable Sea Floor Precipitates: A Silverpit Provenance Unproven; A Lithological Investigation of Marine Strata from the Triassic-Jurassic Boundary Interval, Queen Charlotte Islands, British Columbia, Including a Search for Shocked Quartz; Triassic Cratered Cobbles: Shock Effects or Tectonic Pressure?; Regional Variations of Trace Element Composition Within the Australasian Tektite Strewn Field; Cretaceous-Tertiary Boundary Microtektite-bearing Sands and Tsunami Beds, Alabama Gulf Coastal Plain; Sand Lobes on Stewart Island as Probable Impact-Tsunami Deposits; Distal Impact Ejecta, Uppermost Eocene, Texas Coastal Plain; and Continental Impact Debris in the Eltanin Impact Layer.

Source record↗
NASA NTRS1992

Proximal impact deposits at the Cretaceous-Tertiary boundary in the Gulf of Mexico: a restudy of DSDP Leg 77 Sites 536 and 540

Restudy of Deep Sea Drilling Project Sites 536 and 540 in the southeast Gulf of Mexico gives evidence for a giant wave at Cretaceous-Tertiary boundary time. Five units are recognized: (1) Cenomanian limestone underlies a hiatus in which the five highest Cretaceous stages are missing, possibly because of catastrophic K-T erosion. (2) Pebbly mudstone, 45 m thick, represents a submarine landslide possibly of K-T age. (3) Current-bedded sandstone, more than 2.5 m thick, contains anomalous iridium, tektite glass, and shocked quartz; it is interpreted as ejecta from a nearby impact crater, reworked on the deep-sea floor by the resulting tsunami. (4) A 50-cm interval of calcareous mudstone containing small Cretaceous planktic foraminifera and the Ir peak is interpreted as the silt-size fraction of the Cretaceous material suspended by the impact-generated wave. (5) Calcareous mudstone with basal Tertiary forams and the uppermost tail of the Ir anomaly overlies the disturbed interval, dating the impact and wave event as K-T boundary age. Like Beloc in Haiti and Mimbral in Mexico, Sites 536 and 540 are consistent with a large K-T age impact at the nearby Chicxulub crater.

NASA Discipline Exobiology↗
NASA NTRS2005

Why Moldavites are Reduced

Moldavite tektites are colored a bright bottle green by reduced Fe, despite the originating sediments being completely oxidized. The high temperature processing of silicates often results in very reduced products, such as Si-bearing Fe metal in type-1 chondrules [1], lunar regolith agglutinates [2], and multiple Si-Fe metal phases in fulgurites [3,4]. Previous work on silicate reduction has often focused on the need for reducing agents such as carbon or hydrogen; we show that for a moldavite composition these are not necessary. The isentropic cooling path is inherently reducing.

Sheffer, A.↗
NASA NTRS2017

Ne-20/Ne-22 in the Martian Atmosphere: New Evidence from Martian Meteorites

Analyses of Ne trapped in "pods" of impact melt in the Elephant Moraine 79001 (EET 79001) Martian meteorite led to suggest (Ne-20/Ne-22) approx.10 in the Martian atmosphere (MA). In contrast, obtained trapped (Ne-20/Ne-22)Tr approx.7 from an impact melt vein in Yamato 793605 (Y-793605) and concluded that the isotopic composition of Martian Ne remained poorly defined. A "pyroxene-rich" separate from Dhofar 378 (Dho 378) analyzed gave a comparatively high trapped Ne concentration and (Ne-20/Ne-22) = 7.3+/-0.2 in agreement with the Y-793605 value. We explore the hypothesis that Martian Ne was trapped in the Dho 378 meteorite in a manner similar to entrapment of terrestrial Ne in tektites strengthening the "Martian atmosphere" interpretation. We also report new data for Northwest Africa 7034 (NWA 7034) that are consistent with the Ne data for Dho 378.

Park, J.↗