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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Near-Global Variability of Stratospheric Water Vapor Observed by SAGE III/ISS

The Stratospheric Aerosol and Gas Experiment III instrument on the International Space Station (SAGE III/ISS) has been making high quality solar occultation measurements of stratospheric water vapor since June 2017. Here we evaluate the large-scale geophysical variability of the SAGE III/ISS water vapor measurements for the first 3 years of observations (2017–2020) as part of data validation for retrieval version 5.1 (v5.1). Detailed comparisons of SAGE III/ISS v5.1 with the Aura Microwave Limb Sounder (MLS) version 5 retrievals show overall excellent agreement in terms of seasonal mean structure and large-scale variability. SAGE III/ISS data capture the well-known seasonal variations in water vapor including the vertically propagating “tape recorder” in the tropics and lower stratospheric maxima linked to the NH summer monsoons. The high vertical resolution (∼2 km) measurements from SAGE III/ISS demonstrate contributions of the monsoons to the wet phase of “tape recorder” during the Northern Hemisphere (NH) summer. Interannual variations over the short data record are also consistent between SAGE III/ISS and MLS in the stratosphere between 16 and 30 km. We furthermore evaluate large-scale variations in relative humidity (RH) derived from the high vertical resolution SAGE III/ISS water vapor measurements, highlighting the detailed seasonal behavior and links to thermal structure near the tropical tropopause. Spatial distributions of RH at the cold point tropopause (CPT) show a close link between high RH and the minimum CPT temperature in both the NH winter and summer, consistent with temperature control of water vapor near the tropopause.

water vapor↗
NASA NTRS2008

Stable Calibration of Raman Lidar Water-Vapor Measurements

A method has been devised to ensure stable, long-term calibration of Raman lidar measurements that are used to determine the altitude-dependent mixing ratio of water vapor in the upper troposphere and lower stratosphere. Because the lidar measurements yield a quantity proportional to the mixing ratio, rather than the mixing ratio itself, calibration is necessary to obtain the factor of proportionality. The present method involves the use of calibration data from two sources: (1) absolute calibration data from in situ radiosonde measurements made during occasional campaigns and (2) partial calibration data obtained by use, on a regular schedule, of a lamp that emits in a known spectrum determined in laboratory calibration measurements. In this method, data from the first radiosonde campaign are used to calculate a campaign-averaged absolute lidar calibration factor (t(sub 1)) and the corresponding campaign-averaged ration (L(sub 1)) between lamp irradiances at the water-vapor and nitrogen wavelengths. Depending on the scenario considered, this ratio can be assumed to be either constant over a long time (L=L(sub 1)) or drifting slowly with time. The absolutely calibrated water-vapor mixing ratio (q) obtained from the ith routine off-campaign lidar measurement is given by q(sub 1)=P(sub 1)/t(sub 1)=LP(sub 1)/P(sup prime)(sub 1) where P(sub 1) is water-vapor/nitrogen measurement signal ration, t(sub 1) is the unknown and unneeded overall efficiency ratio of the lidar receiver during the ith routine off-campaign measurement run, and P(sup prime)(sub 1) is the water-vapor/nitrogen signal ratio obtained during the lamp run associated with the ith routine off-campaign measurement run. If L is assumed constant, then the lidar calibration is routinely obtained without the need for new radiosonde data. In this case, one uses L=L(sub 1) = P(sup prime)(sub 1)/t(sub 1), where P(sub 1)(sup prime) is the water-vapor/nitrogen signal ratio obtained during the lamp run associated with the first radiosonde campaign. If L is assumed to drift slowly, then it is necessary to postpone calculation of a(sub 1) until after a second radiosonde campaign. In this case, one obtains a new value, L(sub 2), from the second radiosonde campaign, and for the ith routine off-campaign measurement run, one uses an intermediate value of L obtained by simple linear time interpolation between L(sub 1) and L(sub 2).

Leblanc, Thierry↗
DOE OSTI2023

Water vapor isotopic composition during TRACER IOP

The TRACER-Iso project took place from June 1 to September 30, 2022 as part of the intensive observation period (IOP) of the Tracking Aerosol Convection Interactions (TRACER) project at the main project site at the La Porte, Texas, municipal airport. The project sought to use measurements of the stable isotopic composition of water vapor to better understand cloud-aerosol interactions in deep convection in a polluted urban setting. Water vapor isotopologue and humidity measurements were determined using a Picarro L2130 Water Vapor Isotope Analyzer. The instrument was deployed in the guest van and consists of three main components: a water vapor isotope analyzer, and a Los Gatos Research Water Vapor Isotope Standard Source (WVISS), and a Los Gatos Research Dry Air Source. Ambient air samples were collected through an inlet located about one meter above roof of the shipping container. Samples were then delivered to the analyzer through teflon tubing by use of an external pump to minimize the transport time between the inlet and analyzer. The inlet tubing was surrounded by a Briskheat heat trace and insulating material to ensure ambient air samples did not fall below the dew point and result in condensation. The analyzer uses cavity ringdown spectroscopy to report isotopic ratios of ambient air samples at a frequency of 1 Hz. The calibration unit of the instrument was used in conjunction with the dry air source to periodically measure the δ values of standard waters. It uses a nebulizer to push small water droplets into a hot chamber that vaporizes the water without fractionation. This vapor was then transported to the analyzer using a built-in compressor and the dry air source, which allows each standard with known δ values to be measured at a wide range of humidity values for post-measurement calibration of ambient air samples. There are multiple sources of uncertainty introduced at different stages during the data collection and processing. These include (1) instrument precision, (2) uncertainty in the secondary standards, (3) humidity-correction uncertainty, and (4) VSMOW-SLAP calibration uncertainty. Uncertainty from each step is propagated in quadrature to calculate a total uncertainty of each isotopologue. Uncertainty was determined to be 2.3‰ for δD and 0.4‰ for δ18O.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Using ground-based lidar data to investigate the water–vapor budget in the daytime atmospheric boundary layer

The moisture advection term in the water–vapor budget equation is investigated with a combination of a vertically-staring water–vapor lidar and Doppler lidar systems. These instruments make it possible to get the mean profile of moisture tendency and the latent heat flux (LHF) divergence. We use data of the Land–Atmosphere Feedback Experiment (LAFE) at the Atmospheric Radiation Measurement (ARM) Program’s Southern Great Plains (SGP) site, Oklahoma, USA, collected on 30 August 2017 between 15 and 24 UTC, which corresponds to 09 to 18 LT. The lidars provide turbulence resolving profiles of moisture and vertical wind fluctuations. The LHF profile is derived from the covariance of these moisture and vertical wind fluctuations. The mean boundary layer height z i is determined from the peak of the moisture variance. The results demonstrate that the combination of two remote sensing instruments can be applied for determining the dominant water–vapor budget terms, namely moisture tendency, latent heat flux divergence and moisture advection.

Advection↗
NASA NTRS1982

Mars water vapor, near-surface

In a previous paper we concluded that the temperature sensors aboard the Viking landers (VL-1 and VL-2) were detecting the water vapor frost point. Analysis of one Mars year of data at both lander sites substantiates this conclusion. At VL-1 it is found that the water vapor mixing ratio is constant with height through the bulk of the atmosphere, most of the time. Exceptions are during the onset phases of the two major dust storms when temporary enhancement of near-surface vapor occurs (the same phenomenon is observed at VL-2), and some depletion of near-surface vapor during the decay phase of the first storm, possibly the second storm as well. The former suggests near-surface, northward transport of water vapor with the storms. The latter suggests adsorption of vapor on dust particles followed by surface deposition. At VL-2, severe near-surface depletion of water vapor occurs during northern autumn and winter. The residual vapor is in equilibrium with the surface condensate observed at the site during this period, indicating that the source region for the condensate must be aloft with downward transport by dust fall-out. Since the near-surface water vapor mixing ratio and concentration at VL-1 generally parallels the column abundance over VL-1 obtained by the orbiters, this suggests that VL-1 can be used to give a measure of column abundance for as long as the temperature sensors remain operational.

Ryan, J. A.↗
NASA NTRS1990

An algorithm for retrieving water vapor profiles in clear and cloudy atmospheres from 183 GHz radiometric measurements - Simulation studies

The latent heat represented by atmospheric water vapor is extremely important to the energetics of the earth system. Future satellites (NOAA and DMSP) will carry microwave radiometers designed to measure the profile of water vapor globally. The problem of retrieving water vapor from the measurements is highly nonlinear even in clear atmospheres and the addition of clouds only makes it more so. In this paper, an algorithm with several novel features, which will retrieve water vapor profiles from microwave radiometric measurements even in the presence of clouds, is developed. Simulations with this algorithm show a vertical resolution on the order of 3 km and that clouds are well handled in many, but not all, circumstances. The most surprising result is that clouds can actually improve the vertical resolution of the retrieval.

Wilheit, Thomas T.↗
NASA NTRS1985

Hurricane Debby - An illustration of the complementary nature of VAS soundings and cloud and water vapor motion winds

The utility of VISSR Atmospheric Sounder (VAS) temperature and moisture soundings and cloud and water vapor motion winds in defining a storm and its surroundings at subsynoptic scales has been examined using a numerical analysis and prognosis system. It is shown that the VAS temperature and moisture data, which specify temperature and moisture well in cloud-free areas, are complemented by cloud and water vapor motion data generated in the cloudy areas. The cloud and water vapor 'winds' provide thermal gradient information for interpolating the soundings across cloudy regions. The loss of analysis integrity due to the reduction of VAS sounding density in the cloudy regions associated with synoptic activity is ameliorated by using cloud and water vapor motion winds. The improvement in numerical forecasts resulting from the addition of these data to the numerical analysis is recorded.

Le Marshall, J. F.↗
NASA NTRS1993

Eddy transport of water vapor in the Martian atmosphere

Viking orbiter measurements of the Martian atmosphere suggest that the residual north polar water-ice cap is the primary source of atmospheric water vapor, which appears at successively lower northern latitudes as the summer season progresses. Zonally symmetric studies of water vapor transport indicate that the zonal mean meridional circulation is incapable of transporting from north polar regions to low latitudes the quantity of water vapor observed. This result has been interpreted as implying the presence of nonpolar sources of water. Another possibility is the ability of atmospheric wave motions, which are not accounted for in a zonally symmetric framework, to efficiently accomplish the transport from a north polar source to the entirety of the Northern Hemisphere. The ability or inability of the full range of atmospheric motions to accomplish this transport has important implications regarding the questions of water sources and sinks on Mars: if the full spectrum of atmospheric motions proves to be incapable of accomplishing the transport, it strengthens arguments in favor of additional water sources. Preliminary results from a three dimensional atmospheric dynamical/water vapor transport numerical model are presented. The model accounts for the physics of a subliming water-ice cap, but does not yet incorporate recondensation of this sublimed water. Transport of vapor away from this water-ice cap in this three dimensional framework is compared with previously obtained zonally symmetric (two dimensional) results to quantify effects of water vapor transport by atmospheric eddies.

Murphy, J. R.↗
NASA NTRS1990

A comparison of ER-2 measurements of stratospheric water vapor between the 1987 Antarctic and 1989 Arctic Airborne missions

Vertical profiles of water vapor inside the Antarctic vortex have been compared with those taken outside it over Punta Arenas (53 deg S, 71 deg W). A similar exercise was performed with Arctic vortex profiles and those taken over Stavanger (59 deg N, 6 deg E). Residual water, defined as the stratospheric water vapor mixing ratio with the contribution from methane oxidation subtracted, is also shown as profiles inside and outside the vortex for both missions. The Arctic and Antarctic profiles of water vapor and residual water are compared. Locally dehydrated air was evident both inside and outside the Antarctic vortex, but such dehydration was not evident in and around the Arctic vortex. Arctic profiles of residual water are consistent with nontropical entry for some air.

Kelly, K. K.↗
NASA NTRS1995

Millimeter-wave Imaging Radiometer (MIR) data processing and development of water vapor retrieval algorithms

This document describes the progress of the task of the Millimeter-wave Imaging Radiometer (MIR) data processing and the development of water vapor retrieval algorithms, for the second six-month performing period. Aircraft MIR data from two 1995 field experiments were collected and processed with a revised data processing software. Two revised versions of water vapor retrieval algorithm were developed, one for the execution of retrieval on a supercomputer platform, and one for using pressure as the vertical coordinate. Two implementations of incorporating products from other sensors into the water vapor retrieval system, one from the Special Sensor Microwave Imager (SSM/I), the other from the High-resolution Interferometer Sounder (HIS). Water vapor retrievals were performed for both airborne MIR data and spaceborne SSM/T-2 data, during field experiments of TOGA/COARE, CAMEX-1, and CAMEX-2. The climatology of water vapor during TOGA/COARE was examined by SSM/T-2 soundings and conventional rawinsonde.

Chang, L. Aron↗
DOE OSTI2022

How the Hydrophobic Interface between a Perfluorosulfonic Acid Polymer and Water Vapor Controls Membrane Hydration

Stable hydration in perfluorinated polyelectrolyte membranes such as Nafion is essential to maintain good ion conductivity and manage permeation, especially in vapor-fed devices where water content depends on relative humidity in a gas stream. Extensive studies in the literature have shown that Nafion hydration in water vapor is controlled by its interfacial transport resistance. Nafion forms a fluorine-rich layer at the polymer-gas interface, and it has been proposed that this layer blocks water transport due to its hydrophobicity. To develop a molecular-level description of the physics underlying transport resistance in this system, we have performed a computational reaction-diffusion kinetics study of water evaporation from Nafion. Two distinct models are examined, one mimicking the blocking function proposed in the literature and the other assuming that there is no blocking, treating instead water evaporation as a dynamic balance between uptake from the gas and desorption from the polymer surface. Simulation results are compared to time-dependent infrared data over a range of 100-0% relative humidity from the literature. Only the dynamic model successfully reproduces experimental observations. This indicates that the physical nature of interfacial transport resistance is not slow diffusion across an interfacial layer; rather, it is due to the competition between dehydration and rehydration. The simulation data provide details on the accompanying water distributions throughout the membrane and on interfacial kinetics, showing that they are characterized by strong fluctuations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2000

Processes Controlling Water Vapor in the Winter Arctic Stratospheric Middleworld

Abstract: Water vapor in the winter arctic stratospheric middleworld (that part of the stratosphere with potential temperatures lower than the tropical tropopause) is important for two reasons: (1) the arctic middleworld is a source of air for the upper troposphere because of the generally downward motion, and thus its water vapor content helps determine upper tropospheric water, a critical part of the earth's radiation budget; and (2) under appropriate conditions, relative humidities will be large even to the point of stratospheric cirrus cloud formation, leading to the production of active chlorine species that could destroy ozone. On a number of occasions during SOLVE, clouds were observed in the stratospheric middleworld by the DC-8 aircraft. The relationship between ozone and CO from aircraft measurements taken during the early, middle and late part of the winter of 1999-2000 show that recent mixing with tropospheric air extends up to ozone values of about 350-450 ppbv. Above that level, the relationship suggests stratospheric air with minimal tropospheric influence. The transition is quite abrupt, particularly in early spring. Trajectory analyses are consistent with these relationships, with a significant drop-off in the percentage of trajectories with tropospheric PV values in their 10-day history as in-situ ozone increases above 400 ppbv. The water distribution is affected by these mixing characteristics, and by cloud formation. Significant cloud formation along trajectories occurs up to ozone values of about 400 ppbv during the early spring, with small, but nonzero probabilities extending to 550 ppbv. Cloud formation in the stratospheric middleworld is minimal during early and midwinter. Also important is the fact that, during early spring 30% of the trajectories near the tropopause (ozone values less than 200 ppbv) have minimum saturation mixing ratios less than 5 ppmv. Such parcels can mix out into the troposphere and could lead to very dry conditions in the upper troposphere at high latitudes during spring,

Pfister, Leonhard↗
NASA NTRS1995

Ground-based measurements of water vapor in the middle atmosphere

We present measurements of the middle atmospheric water vapor mixing ratio profile obtained using the ground-based Naval Research Laboratory (NRL) water vapor millimeter-wave spectrometer (WVMS) instrument at the Jet Propulsion Laboratory (JPL) Table Mountain Observatory. The measurements cover a period of 262 days from January 23, 1992, to October 13, 1992. During this campaign it was possible to retrieve useful daily mixing ratio profiles for 186 days. We thus have a nearly continuous record of water vapor mixing ratios for altitudes from approximately equals 35 to 75 km. The retrievals are obtained using the optimal estimation method. Details of the error analysis are presented, and a technique is introduced that reduces baseline effects and helps to estimate the baseline error. The high-altitude (greater than or approx. equal to 65 km) data show a sharp rise prior to the expected maximum near the summer solstice and a gradual decline in the following months. The mixing ratios generally peak between 55 and 65 km, at which point the mixing ratios are 6 - 7 parts per million by volume. The highest peaks occur in January, May, and October.

Nedoluha, Gerald E.↗
NASA NTRS2010

Water-Vapor Raman Lidar System Reaches Higher Altitude

A Raman lidar system for measuring the vertical distribution of water vapor in the atmosphere is located at the Table Mountain Facility (TMF) in California. Raman lidar systems for obtaining vertical water-vapor profiles in the troposphere have been in use for some time. The TMF system incorporates a number of improvements over prior such systems that enable extension of the altitude range of measurements through the tropopause into the lower stratosphere. One major obstacle to extension of the altitude range is the fact that the mixing ratio of water vapor in the tropopause and the lower stratosphere is so low that Raman lidar measurements in this region are limited by noise. Therefore, the design of the TMF system incorporates several features intended to maximize the signal-to-noise ratio. These features include (1) the use of 355-nm-wavelength laser pulses having an energy (0.9 J per pulse) that is high relative to the laser-pulse energy levels of prior such systems, (2) a telescope having a large aperture (91 cm in diameter) and a narrow field of view (angular width .0.6 mrad), and (3) narrow-bandpass (wavelength bandwidth 0.6 nm) filters for the water-vapor Raman spectral channels. In addition to the large-aperture telescope, three telescopes having apertures 7.5 cm in diameter are used to collect returns from low altitudes.

Leblanc, Thierry↗
NASA NTRS1980

Microwave radiometry as a tool to calibrate tropospheric water-vapor delay

Microwave radiometers were used to measure the emission line due to the water vapor molecules of atmospheric emission. Four separate field tests were completed which compared radiometers to other techniques which measure water vapor. It is shown that water vapor induced delay can be estimated with an accuracy of plus or minus 2 cm for elevation angles above 17 degrees.

Resch, G. M.↗
DOE OSTI2024

Recent trends and variability of temperature and atmospheric water vapor over South Asia

This study examines the recent trends and variability of temperature and atmospheric water vapor over South Asia during the summer monsoon season from 1970 to 2022. We employ gridded reanalysis and observational datasets to assess the trends and variability in surface temperature and further investigate the associated physical processes. Our results show that the surface temperature over South Asia has increased by 0.5 °C per decade. Notably, we find a statistically significant major transition in the surface temperature series in 1995, such that 1970–1994 (1995–2022) is associated with anomalous cooling (anomalous warming). Since 1995, not only have the temporal variations in regional surface temperature, atmospheric water vapor, and clear-sky downward longwave radiation been synchronous at interannual scales, but their largest spatial variations have been located mainly over the same region. A diagnosis of the atmospheric moisture budget reveals that the observed changes in water vapor convergence over South Asia are dominated by changes in mean circulation dynamics, while the change in thermodynamics is relatively small. The enhancement of the Somali low-level jet may contribute to increased water vapor in South Asia by modulating low-level circulations.

Atmospheric circulations↗
NASA NTRS1995

Water vapor spectroscopy in the 815-nm wavelength region for Differential Absorption Lidar measurements

The differential absorption lidar (DIAL) technique was first applied to the remote measurement of atmospheric water vapor profiles from airborne platforms in 1981. The successful interpretation of the lidar profiles relies strongly on an accurate knowledge of specific water vapor absorption line parameters: line strength, pressure broadening coefficient, pressure-induced shift coefficient and the respective temperature-dependence factors. NASA Langley Research Center has developed and is currently testing an autonomous airborne water vapor lidar system: LASE (Lidar Atmospheric Sensing Experiment). This DIAL system uses a Nd:YAG-pumped Ti:Sapphire laser seeded by a diode laser as a lidar transmitter. The tunable diode has been selected to operate in the 813-818 nm wavelength region. This 5-nm spectral interval offers a large distribution of strengths for temperature-insensitive water vapor absorption lines. In support of the LASE project, a series of spectroscopic measurements were conducted for the 16 absorption lines that have been identified for use in the LASE measurements. Prior to this work, the experimental data for this water vapor absorption band were limited - to our knowledge - to the line strengths and to the line positions.

Ponsardin, Patrick↗