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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

What Good is Raman Water Vapor Lidar?

Raman lidar has been used to quantify water vapor in the atmosphere for various scientific studies including mesoscale meteorology and satellite validation. Now the international networks of NDACC and GRUAN have interest in using Raman water vapor lidar for detecting trends in atmospheric water vapor concentrations. What are the data needs for addressing these very different measurement challenges. We will review briefly the scientific needs for water vapor accuracy for each of these three applications and attempt to translate that into performance specifications for Raman lidar in an effort to address the question in the title of "What good is Raman water vapor Iidar."

Whitman, David↗

A Portable Electronic Nose for Toxic Vapor Detection, Identification, and Quantification

The Space Program and military use large quantities of hydrazine and monomethyl hydrazine as rocket propellant, which are very toxic and suspected human carcinogens. Current off-the-shelf portable instruments require 10 to 20 minutes of exposure to detect these compounds at the minimum required concentrations and are prone to false positives, making them unacceptable for many operations. In addition, post-mission analyses of grab bag air samples from the Shuttle have confirmed the occasional presence of on-board volatile organic contaminants, which also need to be monitored to ensure crew safety. A new prototype instrument based on electronic nose (e-nose) technology has demonstrated the ability to qualify (identify) and quantify many of these vapors at their minimum required concentrations, and may easily be adapted to detect many other toxic vapors. To do this, it was necessary to develop algorithms to classify unknown vapors, recognize when a vapor is not any of the vapors of interest, and estimate the concentrations of the contaminants. This paper describes the design of the portable e-nose instrument, test equipment setup, test protocols, pattern recognition algorithms, concentration estimation methods, and laboratory test results.

Linnell, B. R.↗

Using Satellites to Investigate the Sensitivity of Longwave Downward Radiation to Water Vapor at High Elevations

Many studies suggest that high-elevation regions may be among the most sensitive to future climate change. However, in situ observations in these often remote locations are too sparse to determine the feedbacks responsible for enhanced warming rates. One of these feedbacks is associated with the sensitivity of longwave downward radiation (LDR) to changes in water vapor, with the sensitivity being particularly large in many high-elevation regions where the average water vapor is often low. We show that satellite retrievals from the Moderate Resolution Imaging Spectroradiometer (MODIS) and Clouds and the Earth's Radiant Energy System (CERES) can be used to expand the current ground-based observational database and that the monthly averaged clear-sky satellite estimates of humidity and LDR are in good agreement with the well-instrumented Center for Snow and Avalanche Studies ground-based site in the southwestern Colorado Rocky Mountains. The relationship between MODIS-retrieved precipitable water vapor and surface specific humidity across the contiguous United States was found to be similar to that previously found for the Alps. More important, we show that satellites capture the nonlinear relationship between LDR and water vapor and confirm that LDR is especially sensitive to changes in water vapor at high elevations in several midlatitude mountain ranges. Because the global population depends on adequate fresh water, much of which has its source in high mountains, it is critically important to understand how climate will change there. We demonstrate that satellites can be used to investigate these feedbacks in high-elevation regions where the coverage of surface-based observations is insufficient to do so.

Naud, Catherine M.↗

Vapor-barrier Vacuum Isolation System

A system includes a collimated beam source within a vacuum chamber, a condensable barrier gas, cooling material, a pump, and isolation chambers cooled by the cooling material to condense the barrier gas. Pressure levels of each isolation chamber are substantially greater than in the vacuum chamber. Coaxially-aligned orifices connect a working chamber, the isolation chambers, and the vacuum chamber. The pump evacuates uncondensed barrier gas. The barrier gas blocks entry of atmospheric vapor from the working chamber into the isolation chambers, and undergoes supersonic flow expansion upon entering each isolation chamber. A method includes connecting the isolation chambers to the vacuum chamber, directing vapor to a boundary with the working chamber, and supersonically expanding the vapor as it enters the isolation chambers via the orifices. The vapor condenses in each isolation chamber using the cooling material, and uncondensed vapor is pumped out of the isolation chambers via the pump.

Weinstein, Leonard M.↗

Thermal Design of Vapor Cooling of Flight Vehicle Structures Using LH2 Boil-Off

Using hydrogen boil-off vapor to cool the structure of a flight vehicle cryogenic upper stage can reduce heat loads to the stage and increase the usable propellant in the stage or extend the life of the stage. The hydrogen vapor can be used to absorb incoming heat as it increases in temperature before being vented overboard. In theory, the amount of heat leaking into the hydrogen tank from the structure will be reduced if the structure is cooled using the propellant boil-off vapor. However, the amount of boil-off vapor available to be used for cooling and the reduction in heat leak to the propellant tank are dependent to each other. The amount of heat leak reduction to the LH2 tank also depends on the total heat load on the stage and the vapor cooling configurations.

heat transfer↗

Possible Near-IR Channels for Remote Sensing Precipitable Water Vapor from Geostationary Satellite Platforms

Remote sensing of tropospheric water vapor profiles from current geostationary weather satellites are made using a few broadband infrared (IR) channels in the 6 to 13- micrometers region. Uncertainties greater than 20 percent exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micrometer water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micrometer. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor...

Green, R. O.↗

Evaluating the SAGE III/ISS Version 5.2 Water Vapor Retrieval in the Presence of Aerosol Loading

The Stratospheric Aerosol and Gas Experiment operating on the International Space Station (SAGE III/ISS) is an occultation instrument that retrieves aerosol extinction and ozone, water vapor, and other trace gas concentrations. Water vapor in the stratosphere plays a role in ozone depletion and global temperature regulation making it an important species to monitor. The SAGE III/ISS instrument provides high quality, vertically resolved profiles of water vapor throughout the stratosphere and upper troposphere. In previous versions of SAGE water vapor products, a dry bias was noted in comparison to other satellite retrievals in the presence of elevated aerosol optical depth. Several updates for the version 5.2 water vapor algorithm will be presented and compared with previous versions of the data and other satellite products during different periods of aerosol loading.

M Heitz↗

Thermodynamic Properties of Nitrogen Including Liquid and Vapor Phases from 63K to 2000K with Pressures to 10,000 Bar

Tables of thermodynamic properties of nitrogen are presented for the liquid and vapor phases for temperatures from the freezing line to 2000K and pressures to 10,000 bar. The tables include values of density, internal energy, enthalpy, entropy, isochoric heat capacity, isobaric heat capacity velocity of sound, the isotherm derivative, and the isochor derivative. The thermodynamic property tables are based on an equation of state, P=P (p,T), which accurately represents liquid and gaseous nitrogen for the range of pressures and temperatures covered by the tables. Comparisons of property values calculated from the equation of state with measured values for P-p-T, heat capacity, enthalpy, latent heat, and velocity of sound are included to illustrate the agreement between the experimental data and the tables of properties presented here. The coefficients of the equation of state were determined by a weighted least squares fit to selected P-p-T data and, simultaneously, to isochoric heat capacity data determined by corresponding states analysis from oxygen data, and to data which define the phase equilibrium criteria for the saturated liquid and the saturated vapor. The vapor pressure equation, melting curve equation, and an equation to represent the ideal gas heat capacity are also presented. Estimates of the accuracy of the equation of state, the vapor pressure equation, and the ideal gas heat capacity equation are given. The equation of state, derivatives of the equation, and the integral functions for calculating derived thermodynamic properties are included.

Thermodynamic properties↗

Moisture Performance of Unvented Attics With Vapor Diffusion Ports and Buried Ducts in Hot, Humid Climates

Energy efficiency measures, such as cool roofs, radiant barriers, interior radiative control coatings, and buried ducts are increasing in popularity and are promoted by energy codes because of their energy-saving potential. However, these strategies can also pose moisture risks in attics by lowering surface temperatures and increasing condensation potential and moisture accumulation. Of particular concern in hot-humid climates is dripping condensation on cold air-conditioning ductwork in the summer - commonly referred to as duct "sweating" - which threatens the attic floor with conditions conducive to mold growth and rot. One strategy to mitigate these moisture issues is to wrap ductwork in thicker duct-wrap insulation with an integrated exterior vapor barrier, but thick duct wrap can be difficult to come by, expensive, and unwieldy to work with. This study explores an alternative strategy of reducing moisture issues while embracing energy efficiency by using unvented attics with vapor diffusion ports and buried ductwork in hot-humid climates. Vapor diffusion ports have been studied so far in a wide range of U.S. climates, mostly in the context of conditioned attics. In this study, the strategy is implemented in the novel context of hot-humid climates with ductwork sitting atop blown-in attic floor insulation in unconditioned attics. Using a combination of field experiments and hygrothermal modeling, the findings of this project indicate that an unvented attic with vapor diffusion ports and buried ducts may be a key part of a successful low-cost method for reducing the attic moisture load by venting excess moisture out of the attic, keeping duct-jacket surfaces above dew point temperature, and keeping the roof deck safe from winter moisture accumulation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Comparison of Upper Tropospheric Water Vapor from AIRS and Cryogenic Frostpoint Hygrometers

Upper tropospheric water vapor (UTWV) from the Atmospheric Infrared Sounder (AIRS) experiment on NASA's Aqua spacecraft has the potential of addressing several important climate questions. The specified AIRS system measurement uncertainty for water vapor is 20 percent absolute averaged over 2 km layers. Cryogenic frostpoint hygrometers (CFH) are balloon-borne water vapor sensors responsive from the surface into the lower stratosphere. Several dozen coincident, collocated CFH profiles have been obtained for AlRS validation. The combination of CFH sensitivity and sample size offers a statistically compelling picture of AIRS UTWV measurement capability. We present a comparison between CFH observations and AlRS retrievals. We focus on the altitude range from the middle troposphere up to heights at the limits of AlRS sensitivity to water vapor, believed to be around 100-1 50 hPa.

validation↗

Validation of MIPAS IMK-IAA Temperature, Water Vapor, and Ozone Profiles with MOHAVE-2009 Campaign Measurements

MIPAS observations of temperature, water vapor, and ozone in October 2009 as derived with the scientific level-2 processor run by Karlsruhe Institute of Technology (KIT), Institute for Meteorology and Climate Research (IMK) and CSIC, Instituto de Astrofısica de Andalucıa (IAA) and retrieved from version 4.67 level-1b data have been compared to co-located field campaign observations obtained during the MOHAVE-2009 campaign at the Table Mountain Facility near Pasadena, California in October 2009. The MIPAS measurements were validated regarding any potential biases of the profiles, and with respect to their precision estimates. The MOHAVE-2009 measurement campaign provided measurements of atmospheric profiles of temperature, water vapor/relative humidity, and ozone from the ground to the mesosphere by a suite of instruments including radiosondes, ozonesondes, frost point hygrometers, lidars, microwave radiometers and Fourier transform infrared (FTIR) spectrometers. For MIPAS temperatures (version V4O_T_204), no significant bias was detected in the middle stratosphere; between 22 km and the tropopause MIPAS temperatures were found to be biased low by up to 2 K, while below the tropopause, they were found to be too high by the same amount. These findings confirm earlier comparisons of MIPAS temperatures to ECMWF data which revealed similar differences. Above 12 km up to 45 km, MIPAS water vapor (version V4O_H2O_203) is well within 10% of the data of all correlative instruments. The well-known dry bias of MIPAS water vapor above 50 km due to neglect of non-LTE effects in the current retrievals has been confirmed. Some instruments indicate that MIPAS water vapor might be biased high by 20 to 40% around 10 km (or 5 km below the tropopause), but a consistent picture from all comparisons could not be derived. MIPAS ozone (version V4O_O3_202) has a high bias of up to +0.9 ppmv around 37 km which is due to a non-identified continuum like radiance contribution. No further significant biases have been detected. Cross-comparison to co-located observations of other satellite instruments (Aura/MLS, ACE-FTS, AIRS) is provided as well.

MIPAS validation↗

Contrasting Effects of Central Pacific and Eastern Pacific El Nino on Stratospheric Water Vapor

Targeted experiments with a comprehensive chemistry-climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.

water vapor↗

Demonstration of Multilayer Insulation, Vapor Cooling of Structure, and Mass Gauging for Large Scale Upper Stages: Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) Final Report

Testing was completed on the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) between August 2019 and January 2020. SHIIVER was designed to be a test bed for the scaling of cryogenic fluid management technologies as applied to large upper stages and long duration in-space stages. The hardware consists of a 4 meter diameter stainless steel tank, structural skirts supporting the tank in the aft direction, and an aluminum forward skirt with vapor cooling channels bolted to it. The initial testing of the SHIIVER hardware was with liquid hydrogen and liquid nitrogen (as a substitute fluid for liquid oxygen and liquid methane) and sought to demonstrate the use of boil-off vapor to intercept heat on a structural skirt, multilayer insulation (MLI) on the tank domes, and the radio frequency mass gauge (RFMG). Testing was completed in four stages: a baseline thermal vacuum test prior to installation of the MLI, a thermal vacuum test after the MLI installation, a reverberant acoustic test, and a subsequent thermal vacuum test to verify that no damage occurred during the reverberant acoustic testing. Each thermal vacuum test with chamber wall at ambient temperature and vacuum level in the 10-6 torr range was conducted continuously between approximately 90% full and 25% full. Test results showed that the vapor cooling reduced the heat load to the tank by approximately 10%, but the boil-off by less than 3% at 50% full with no MLI on the domes. It reduced the heat load to the tank by approximately 10%, but the boil-off was essentially unchanged at 50% full whether or not vapor cooling was operational with MLI on the domes. The MLI reduced the heat load to the tank by approximately 40% at all fill levels, but the boil-off by approximately 25% at 90% full and 45% below 65% full. The RFMG performed well over all fill ranges, and several RF tank modes were used to gauge the mass of fluid in the tank. SHIIVER was then exposed to an acoustic environment of 147 dB OASPL (overall sound pressure level) in a reverberant chamber. The acoustic environment and profile envelopes the upper stage internal acoustic level of several different modern launch vehicles. No structural or thermal performance changes were observed as a result of acoustic testing. Final thermal vacuum testing after the acoustic testing showed no degradation to the MLI due to the acoustic environment as measured via system heat loads.

SHIIVER↗

Review of Vapor Compression Refrigeration in Microgravity Environments

Using a vapor compression cycle for cooling in microgravity environments was already suggested in the 1970s to leverage the high coefficient of performance. Since then, only a few systems have operated in microgravity with scarce documentation of these flights. The lack of measured data and detailed documentation makes identifying the necessary next steps difficult for researchers entering the field of refrigeration in space. This paper provides a review of available literature for vapor compression systems flown in microgravity by outlining the history of vapor compression devices in space and presenting performance data. Moreover, gaps in the literature are highlighted and open questions are posed based on the reviewed material. Next steps of research are suggested to support and ultimately achieve reliable vapor compression refrigeration in space. Calculating equivalent masses for a fair comparison of different microgravity cooling technologies is proposed by capturing both energy consumption and used volume.

Vapor compression↗

Equivalent Mass Benefits from Employing Vapor Compression Refrigeration on Spacecraft

Thermoelectric cooling, reversed Brayton cycles and Stirling cycle devices are common cooling technologies employed on spacecraft where temperatures below the radiator temperature are needed. Although used less often in microgravity, vapor compression refrigeration was proposed for microgravity applications as early as the 1970s. Researchers proposed the vapor compression cycle over other cooling technologies for its superior energy efficiency in the typical refrigerator/freezer and air-conditioning temperature range. The higher energy efficiency should alleviate the mass penalty of the thermal system, conceivably both for satellites and manned spacecraft. Despite numerous propositions, the literature lacks a discussion of the absolute equivalent mass benefit achievable and the value of it relative to the total mass of the thermal system of the spacecraft or the spacecraft itself. This paper presents the equivalent mass benefits of employing a vapor compression system over other cooling technologies using a mass penalty factor for power consumption. Additionally, a prototype vapor compression cooler sized to fit into an ISS locker is presented.

refrigerator↗

Possible Role of Mixing on Water Vapor and Ozone Anomalies During RF05

We investigate the possible role of mixing on the observed variations in water vapor and ozone anomalies during DCOTSS 29 July 2021 flight. Preliminary results indicate that enhanced water vapor is more often associated with enhanced ozone, opposite of what one might expect during convective plume encounters. We use the turbulence eddy dissipation rate as a proxy of mixing to show that when water vapor is significantly enhanced (> 30 ppmv), water vapor anomalies are negatively correlated with mixing strength: strong turbulence and large mixing are associated with relatively dry air. The mechanism behind this relationship as well as the origins of the observed turbulence and mixing will be investigate in the figure.

Mixing↗

Convective Impact on the Global Lower Stratospheric Water Vapor Budget

Water vapor in the stratosphere is primarily controlled by temperatures in the tropical upper troposphere and lower stratosphere. However, the direct impact of deep convection on the global lower stratospheric water vapor budget is still an actively debated issue. Two complementary modeling approaches are used to investigate the convective impact in boreal winter and summer. Convective influence is diagnosed by tracing trajectories through convective cloud top altitude fields derived from global rainfall and brightness temperature data. Backward trajectory model simulations coupled with a detailed treatment of cloud microphysical processes indicate that convection moistens the global lower stratosphere by approximately 0.3 ppmv in boreal winter and summer 2010. The diurnal peak in convection is responsible for about half of the total convective moistening during winter and nearly all of the convective moistening during summer. Deep convective clouds overshooting the tropopause have relatively minor effect on global lower stratospheric water vapor. A forward trajectory model coupled with a simplified cloud module is used to estimate the relative magnitude of the interannual variability of the convective impact. Combining the results from the two models, we find that the convective impact on the global lower stratospheric water vapor during 2006-2016 is approximately 0.3 ppmv with year-to-year variations of up to 0.1 ppmv. An important mechanism of convective hydration of the lower stratosphere is via the detrainment of saturated air and ice into the tropical uppermost troposphere and the subsequent upward transport of some of these moist air parcels across relatively warm and subsaturated tropopause.

CONVECTION↗

Observing and Projecting the Lasting Fate of the Hunga Eruption on Atmospheric Water Vapor and Hydroxyl Radical

On 15th Jan. 2022 the submarine Hunga volcano erupted injecting approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes and beyond with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over more than 2 years since the eruption and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the Hunga eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and have continued the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the Hunga eruption is perturbing atmospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. Modeling suggests that the water rich eruption enhanced stratospheric hydroxyl radiacal (OH) and is supported by the speed of the observed conversion of SO2 into sulfate aerosol. These simulations also suggest a significant reduction in tropospheric OH over the mid-high latitude Southern Hemisphere, which has implications for numerous species that are impacted by this radical. The Hunga eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding and in making new connections.

Hunga volcano↗