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At least 253 records · Page 14

Impact of temperature variations on BISON predictions of Ag release in AGR-1 and AGR-2 experiments

Understanding and quantifying the release of fission products like silver (Ag) from TRistructural ISOtropic (TRISO) fuel particles is important to assess the safe operation of advanced high temperature reactors. Although the silicon carbide (SiC) layer of TRISO particles is effective as the main fission product barrier, Ag can be released from intact TRISO particles. A mechanistic model for the effective Ag diffusivity, D eff , was previously developed as a function of temperature and microstructure variables informed by atomistic modeling of Ag diffusivity on the mesoscale. Here in this study, we use this model to explore how experimental temperature uncertainties impact the overall predicted Ag release. This analysis shows that temperature uncertainties have a significant impact on the overall Ag release predictions. Furthermore, we show that the time average volume average temperature (TAVA) temperature is not an appropriate proxy for temperature histories to predict fission product release. We attribute this to the Arrhenius dependence of Ag diffusivity with respect to temperature. The detailed temperature histories, therefore, provide the most accurate results are are of most importance for modeling efforts. Overall, this work shows the importance of considering the experimental uncertainty of the temperature on computational predictions of fission product transport and release and the need for more accurate temperature histories from future experiments.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

One‐at‐a‐Time Parameter Perturbation Ensemble of the Community Land Model, Version 5.1

Comprehensive land models are subject to significant parametric uncertainty, which can be hard to quantify due to the large number of parameters and high model computational costs. We constructed a large parameter perturbation ensemble (PPE) for the Community Land Model version 5.1 with biogeochemistry configuration (CLM5.1-BGC). We performed more than 2,000 simulations perturbing 211 parameters across six forcing scenarios. This provides an expansive data set, which can be used to identify the most influential parameters on a wide range of output variables globally, by biome, or by plant functional type. We found that parameter effects can exceed scenario effects and that a small number of parameters explains a large fraction of variance across our ensemble. The most important parameters can differ regionally and also based on the forcing scenario. The software infrastructure developed for this experiment has greatly reduced the human and computer time needed for CLM PPEs, which can facilitate routine investigation of parameter sensitivity and uncertainty, as well as automated calibration.

Kennedy, Daniel [NSF National Center for Atmospher↗

Mountain Basin Controls on the Snow-to-Streamflow Signal: An AIC-Weighted Multiple Linear Regression Framework

A regression-based analysis quantifies how basin characteristics modulate the snow-to-streamflow signal. First, we use the ERA5-Land reanalysis gridded product (European Centre for Medium Range Weather Forecasts reanalysis 5 -Land component) for 4,655 hydrologic unit code - 10 (HUC10) mountain basins across the western United States (US) for water years 1987–2024. Linear regressions are performed for peak snow water equivalent (SWE) and annual streamflow for each mountain basin. Models use ordinary least squares in Python’s statsmodels package. After which, an Akaike Information Criterion (AIC)–weighted ensemble multiple linear regression (MLR) framework with 47 watershed traits is used to predict the linear regression coefficient of determination (r-squared) defining the ability of peak SWE to predict annual streamflow across all mountain basin. Predictor sets are constrained to avoid multicollinearity by excluding models with variance inflation factors (VIF) greater than 5. Mountain basin traits included in the MLR include seasonal climate, topography, vegetation type and structure, and bedrock geology. Accepted models are considered if their AIC is within 2.0 of the model with the minimum AIC, or best model. To compare predictor influence across acceptable models, we computed standardized regression coefficients. To evaluate structural redundancy among models, we constructed binary inclusion vectors for each acceptable model, denoting whether a predictor was present (1) or absent (0). Core predictor variables are defined as occurring in at least 67% of the acceptable models. For this regional analysis, only one model was found acceptable, with higher snow-to-streamflow translation (higher r-squared) occurring in colder mountain basins with higher relative winter precipitation, more snow accumulation and a lower fraction of annual precipitation that falls in the spring and summer. The second component of the data package uses previously published, high-resolution output from an integrated hydrological model of the East River watershed using the U.S. Geological Survey Groundwater and Surface water Flow model (GSFLOW, doi:10.15485/1998576). East River MLR expands upon the approach described above to explore the response of five streamflow metrics—annual streamflow, runoff efficiency, 7-day minimum flow, low-flow duration, and non-perennial stream fraction to snow system indicators including peak SWE, snow-covered area, snow disappearance date, and the fraction of basin area characterized by low-to-no snow, as well as seasonal precipitation and temperature, and annual hydrologic variables representing soil moisture, evapotranspiration (ET), the partitioning of incoming precipitation to evapotranspiration (ET/P), groundwater storage, and groundwater inflow to streams. MLR was done on all water years (P0: 1987-2024) and for each period as determined in the split analysis using pooled regression techniques (P1: 1987-2011 and P2: 2012-2024) to evaluate shifting predictor variable emphasis on streamflow generation. Results indicate that since 2012, peak SWE has lost statistical strength in its prediction of annual streamflow and runoff efficiency, and the indirect influence of spring temperature has emerged as critically important. Low-flow metrics remain largely influenced by soil moisture, vegetation water use and groundwater inflows with summer precipitation becoming a direct influence on minimum summer flow. Together, these data and Python-based analysis tools provide a framework for identifying the key watershed characteristics that control how streamflow responds to snow from year to year. The package also helps quantify uncertainty in statistical models and assess how snow–streamflow relationships vary across regions and over time. This dataset contains comma-separated values files (.csv), text files (.txt), python code files (.py), figure files (.png), and shapefiles (.cpg, .dbf, .prj, .sbn, .sbx, .shp, .xml). Further details on file contents and MLR execution can be found in the readme file and the FLMD files. Work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

54 ENVIRONMENTAL SCIENCES↗

Understanding and Modeling Pooled Rideshare Acceptance: Influential Factors, Preferred User Experiences, and Implications

This dissertation explores factors influencing pooled rideshare (PR) adoption to provide actionable insights for transportation network companies (TNCs) and policymakers. PR allows travelers to share rides with unknown passengers, offering benefits such as cost reduction and congestion relief. However, adoption remains limited due to safety concerns, privacy issues, and trust in rideshare platforms. A national U.S. survey with 5,385 respondents examined transportation preferences and barriers to PR adoption. Exploratory and confirmatory factor analyses identified five key factors influencing PR consideration—safety, service experience, privacy, traffic/environment, and time/cost. Second factor analyses examined ways to optimize PR experiences, revealing four factors—comfort/ease of use, convenience, vehicle technology/accessibility, and passenger safety. Privacy concerns, for instance, using regression analysis, were found to reduce the likelihood of PR adoption by 77%, and convenience had the potential to increase it by 156%. The Pooled Rideshare Acceptance Model (PRAM), based on the Technology Acceptance Model, assessed the impact of these factors using the Structural Equation Model (SEM). Privacy, safety, trust, and convenience had a large effect (Cohen's f2 > 0.35) on PR acceptance, while multigroup analyses (PRAMMA) explored 16 demographic variables such as gender, generation, and income, emphasizing the need for tailored strategies. Based on all the statistical analysis and workshops using descriptive statistics, 95 actionable recommendations were made from the riders' perspective. Findings highlight the importance of customized services, user experience improvements, and policy interventions to enhance PR adoption. This dissertation provides a roadmap for future research and policy development, ensuring evidence-based, practical strategies to improve PR services in the U.S. and beyond.

Gangadharaiah, Rakesh↗

The impact of urban configuration types on urban heat islands, air pollution, CO 2 emissions, and mortality in Europe: a data science approach

The world is becoming increasingly urbanized. As cities around the world continue to grow, it is important for urban planners and policymakers to understand how different urban configuration patterns affect the environment and human health. We aimed at identifying European urban configuration types, based on the Local Climate Zones categories and street design variables from Open Street Map, and evaluating their association with motorized traffic flows, Surface Urban Heat Island (SUHI) intensities, tropospheric nitrogen dioxide (NO 2 ), CO 2 per capita emissions and age-standardized mortality. We considered 946 European cities from 31 countries for the analysis defined in the 2018 Urban Audit database, of which 919 European cities were analysed. Data were collected at a 250 m × 250 m grid cell resolution. We divided all cities into five concentric rings based on the Burgess concentric urban planning model and calculated the mean values of all variables for each ring. First, to identify distinct urban configuration types, we applied the Uniform Manifold Approximation and Projection for Dimension Reduction method, followed by the k-means clustering algorithm. Next, statistical differences in exposures (including SUHI) and mortality between the resulting urban configuration types were evaluated using a Kruskal–Wallis test followed by a post-hoc Dunn's test. We identified four distinct urban configuration types characterising European cities: compact high density (n=246), open low-rise medium density (n=245), open low-rise low density (n=261), and green low density (n=167). Compact high density cities were a small size, had high population densities, and a low availability of natural areas. In contrast, green low-density cities were a large size, had low population densities, and a high availability of natural areas and cycleways. The open low-rise medium and low-density cities were a small to medium size with medium to low population densities and low to moderate availability of green areas. Motorised traffic flows and NO 2 exposure were significantly higher in compact high density and open low rise medium density cities when compared with green low density and open low-rise low density cities. Additionally, green low-density cities had a significantly lower SUHI effect compared with all other urban configuration types. Per person CO 2 emissions were significantly lower in compact high density cities compared with green low density cities. Lastly, green low density cities had significantly lower mortality rates when compared with all other urban configuration types. Our findings indicate that, although the compact city model is more sustainable, European compact cities still face challenges related to poor environmental quality and health. Our results have notable implications for urban and transport planning policies in Europe and contribute to the ongoing discussion on which city models can bring the greatest benefits for the environment, climate, and health.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Rapid organic carbon spiraling in a headwater stream linked with streamflow, biogeochemistry, and canopy phenology

Headwater streams are abundant worldwide and important to global biogeochemical cycles, serving as critical processors and transporters of C. C spiraling is a useful way to understand the retention and mineralization of organic C (OC) in streams. However, analyses of seasonal and interannual variability in OC spiraling are currently limited. In this study, we aimed to understand the temporal patterns and driving mechanisms of OC spiraling, which will inform our understanding of future OC changes under climate change. We used 7 y of daily data in a small headwater stream (Walker Branch, Tennessee, USA) to assess seasonal and interannual variability in OC spiraling length (S OC ) and mineralization velocity (v fOC ), as well as their potential related variables. On average, S OC in Walker Branch was ~10× shorter than in previously studied small streams, indicating strong connections between the water column and the benthic environment where OC mineralization mostly takes place. OC spiraling was faster during the more biologically active periods of spring and autumn compared with more elongated OC spiraling in summer and winter, when OC retention was lower and downstream transport was higher. Gross primary production (GPP) was most strongly related to S OC and v fOC . Photosynthetically active radiation (PAR) and NO 3 − were also positively and negatively related to v fOC , respectively. Trends toward earlier and longer canopy cover and reduced GPP and PAR may result in longer S OC and slower v fOC , reducing localized instream processing of OC and potentially shunting more OC downstream. However, long-term observations indicate reduced NO 3 − at Walker Branch, suggesting opposing effects to those of GPP and PAR, leading to faster v fOC and greater OC retention. Time-series analyses of OC spiraling in streams can enhance our understanding of current and future responses of OC processing and downstream transport to climate change, as well as implications for downstream OC dynamics.

biological activity↗

First Measurements of Differential Cross Sections In Kinematic Imbalance Variables With The MicroBooNE Detector

Making high-precision measurements of neutrino oscillation parameters requires an unprecedented understanding of neutrino-nucleus scattering. In this presentation, we present the first muon neutrino charged current double-differential cross sections in kinematic imbalance variables. These variables characterize the imbalance in the plane transverse to an incoming neutrino. We use events with a single muon above 100 MeV/c, a single final state proton above 300 MeV/c, and no recorded final state pions. Thus, these variables act as a direct probe of nuclear effects such as final state interactions, Fermi motion, and multi-nucleon processes. We also present a complementary ongoing analysis using electron neutrinos. This channel is of the utmost importance for the extraction of neutrino oscillation parameters by making high-precision measurements. Our measurements allow us to constrain systematic uncertainties associated with neutrino oscillation results performed by near-future experiments of the Short Baseline Neutrino (SBN) program, as well as by future large-scale experiments like DUNE.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Investigation of the Effect of Framework Flexibility on Adsorption in SIFSIX-3-Cu using a Machine-Learned Force Field

Metal-organic frameworks (MOFs) are a promising class of adsorbents. The performance of MOF sorbents relies on high selectivity and low regeneration energy. This work focuses on the use of machine learned force fields (MLFFs) to model adsorption in a flexible MOF, SIFSIX-3-Cu. A DeePMD-based MLFF was trained to reproduce DFT (PBE+D3) energies, forces, and stresses, using an iterative sampling scheme combining sampling based on molecular dynamics, Monte Carlo, and geometry optimization to capture both attractive and repulsive regions of the potential energy surface. Flexibility of the MOF was explicitly included in this model. Hybrid Monte Carlo/molecular dynamics (MC/MD) simulations using the MLFF predicted adsorption isotherms in good agreement with experimental data for a range of pressures (40 Pa – 104 Pa) in contrast to rigid models, which overpredict CO2 adsorption at low pressures. The improvement was the result of a description of the variability of fluorine-fluorine diagonal distances at adsorption sites. This detailed description of flexibility afforded by the MLFF resulted in more accurate predictions adsorption isotherms when compared to the experimentally measured values. These results underscore the importance of including framework flexibility when modeling adsorption phenomena in MOFs, particularly for low pressure applications and provide a robust procedure for training MLFF models for MOFs.

Atomistic Simulation↗

First Measurements of Differential Cross Sections In Kinematic Imbalance Variables With The MicroBooNE Detector

Making high-precision measurements of neutrino oscillation parameters requires an unprecedented understanding of neutrino-nucleus scattering. In this presentation, we present the first muon neutrino charged current double-differential cross sections in kinematic imbalance variables. These variables characterize the imbalance in the plane transverse to an incoming neutrino. We use events with a single muon above 100 MeV/c, a single final state proton above 300 MeV/c, and no recorded final state pions. Thus, these variables act as a direct probe of nuclear effects such as final state interactions, Fermi motion, and multi-nucleon processes. We also present a complementary ongoing analysis using electron neutrinos. This channel is of the utmost importance for the extraction of neutrino oscillation parameters by making high-precision measurements. Our measurements allow us to constrain systematic uncertainties associated with neutrino oscillation results performed by near-future experiments of the Short Baseline Neutrino (SBN) program, as well as by future large-scale experiments like DUNE.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

First Measurements of Differential Cross Sections In Kinematic Imbalance Variables With The MicroBooNE Detector

Making high-precision measurements of neutrino oscillation parameters requires an unprecedented understanding of neutrino-nucleus scattering. In this presentation, we present the first muon neutrino charged current double-differential cross sections in kinematic imbalance variables. These variables characterize the imbalance in the plane transverse to an incoming neutrino. We use events with a single muon above 100 MeV/c, a single final state proton above 300 MeV/c, and no recorded final state pions. Thus, these variables act as a direct probe of nuclear effects such as final state interactions, Fermi motion, and multi-nucleon processes. We also present a complementary ongoing analysis using electron neutrinos. This channel is of the utmost importance for the extraction of neutrino oscillation parameters by making high-precision measurements. Our measurements allow us to constrain systematic uncertainties associated with neutrino oscillation results performed by near-future experiments of the Short Baseline Neutrino (SBN) program, as well as by future large-scale experiments like DUNE.

43 PARTICLE ACCELERATORS↗

Investigating Particle Phase State Dependencies during a Historic Pacific Northwest Wildfire Event

The function and lifetime of an atmospheric particle are greatly dependent upon its phase state. Studying particle phase states from specific ambient source types is often challenging due to uncontrolled environmental conditions and multiple source contributions. However, a historic Pacific Northwest wildfire event occurred in September 2020, providing a rare opportunity to study a pseudo-single particle type ambient sample (i.e., wildfire) over time. Sampling was performed in Richland, Washington, capturing aged particles from shifting wildfire sources. In addition to source variability, temporal variation in wildfire particle phase state was observed from single particle analyses. Despite this, single particle elemental compositions were homogenous over time (=87% carbonaceous) with no significant temporal variation in organic functional group abundances within individual particles either (e.g., 4% relative standard deviation in alkene contributions). While particle composition is indeed known to affect phase state, water uptake appeared to be the most significant contributor to phase state variability amongst single particles here, as particle aspect ratios (related to phase state) linearly correlated with ambient relative humidity during sampling (R2 = 0.65). Therefore, while limited to a case study, meteorological considerations are found to convey greater comparative importance than particle composition for aged particle phase state predictions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluating Limits of Machine Learning-Assisted Raman Spectroscopy in Classification of Biological Samples

Machine learning (ML)-assisted Raman spectroscopy has become a powerful analytical tool for the classification and identification of analytes; however, technical challenges impacting its detection accuracy have not been thoroughly investigated. This study explores experimental factors affecting classification performance. Among the evaluated ML models, ML algorithms show minimal impact on classification accuracy. Instead, experimental factors, including spectral similarity between tested samples and data quality, dominate detection performance. Increases in spectral noise and spectral similarity significantly reduce classification accuracy. In well-controlled samples with low experimental noise, ML-assisted Raman spectroscopy can discriminate lipid mixtures with a composition difference of 1.85 mol %. To assess the effect of biological heterogeneity, we analyzed single-cell Raman spectra from Saccharomyces cerevisiae strains carrying single, double, or triple gene mutations. Intrinsic cell-to-cell variability introduced substantial spectral differences, severely reducing the accuracy of multiclass classification of these genetically similar strains at the single-cell level. Averaging Raman spectra across multiple cells improved classification accuracy by reducing this spectral variability. We also assess the effectiveness of transfer learning across different Raman spectrometers, specifically by applying an ML model trained on one instrument to another Raman spectrometer. Transfer learning can be improved with proper instrument calibration, highlighting the importance of instrument standardization. Overall, our results demonstrate that data quality and spectral similarity are the primary bottlenecks in ML-assisted Raman spectroscopy. Careful attention to sample preparation, data acquisition, measurement conditions, and instrument calibration is critical to achieving robust and reliable classification performance.

Fungi↗

Widespread 2013-2020 decreases and reduction challenges of organic aerosol in China

Abstract High concentrations of organic aerosol (OA) occur in Asian countries, leading to great health burdens. Clean air actions have resulted in significant emission reductions of air pollutants in China. However, long-term nation-wide trends in OA and their causes remain unknown. Here, we present both observational and model evidence demonstrating widespread decreases with a greater reduction in primary OA than in secondary OA (SOA) in China during the period of 2013 to 2020. Most of the decline is attributed to reduced residential fuel burning while the interannual variability in SOA may have been driven by meteorological variations. We find contrasting effects of reducing NO x and SO 2 on SOA production which may have led to slight overall increases in SOA. Our findings highlight the importance of clean energy replacements in multiple sectors on achieving air-quality targets because of high OA precursor emissions and fluctuating chemical and meteorological conditions.

Chen, Qi (ORCID:0000000335598914)↗

Effect of growth dynamics on the structural, photophysical and pseudocapacitance properties of famatinite copper antimony sulphide colloidal nanostructures (including nanosheets)

Facile phase selective synthesis of copper antimony sulphide (CAS) nanostructures is important because of their tunable photoconductive and electrochemical properties. In this study, off-stoichiometric famatinite phase CAS (fCAS) quasi-spherical and quasi-hexagonal colloidal nanostructures (including nanosheets) of sizes, 2.4–18.0 nm were grown under variable conditions of temperature (60–200 °C), time and oleylamine capping ligand concentration using copper(II) acetylacetonate and antimony(III) diethyldithiocarbamate precursors. Data from powder X-ray diffraction, Raman spectroscopy and high-resolution scanning/transmission electron microscopy confirm the tetragonal structure of the famatinite phase. X-ray photoelectron spectroscopy, transmission electron microscopy and scanning electron microscopy-energy dispersive X-ray spectroscopy data suggest a correlation of particle size, morphology and composition of the off-stoichiometric fCAS nanostructures with growth temperature and time, and oleylamine concentration. The off-stoichiometric Cu 3-a Sb 1+b S 4±c (a, b, c – mole fractions) nanostructures being severely copper-deficient and antimony-rich, exhibit shallow-lying acceptor copper vacancy states, deep-lying donor states of antimony interstitials, sulphur vacancies and antimony-copper antisites and shallow-lying acceptor surface trapping states. Further, these electronic states are likely implicated in tunable UV-visible absorption and bandgaps between 2.3 and 2.8 eV, and broad visible-NIR photoluminescence with fast recombination of radiative lifetimes between 0.2 and 6.2 ns, confirmed from absorption, steady-state and time-resolved photoluminescence spectroscopies. Additionally, cyclic voltammetry and electrochemical impedance spectroscopy confirm that electrodes of the fCAS nanostructures display slightly variable pseudocapacitance of charge-storage primarily via possible sodium ion intercalation with a high specific capacitance of ~84 F g -1 obtained at a scan rate of 5 mV s -1 . Overall, these results show the influence of composition, in particular point defects, phase quality and morphology on the optical and pseudocapacitance properties of fCAS nanostructures, suitable as solar absorbers or electrodes for energy storage devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Accessible, uniform protein property prediction with a scikit-learn based toolset AIDE

Summary Protein property prediction via machine learning with and without labeled data is becoming increasingly powerful, yet methods are disparate and capabilities vary widely over applications. The software presented here, “Artificial Intelligence Driven protein Estimation (AIDE)”, enables instantiating, optimizing, and testing many zero-shot and supervised property prediction methods for variants and variable length homologs in a single, reproducible notebook or script by defining a modular, standardized application programming interface (API), i.e. drop-in compatible with scikit-learn transformers and pipelines. Availability and implementation AIDE is an installable, importable python package inheriting from scikit-learn classes and API and is installable on Windows, Mac, and Linux. Many of the wrapped models internal to AIDE will be effectively inaccessible without a GPU, and some assume CUDA. The newest stable, tested version can be found at https://github.com/beckham-lab/aide_predict and a full user guide and API reference can be found at https://beckham-lab.github.io/aide_predict/. Static versions of both at the time of writing can be found on Zenodo.

36 MATERIALS SCIENCE↗

Geographical Insights into Suicide Mortality Through Spatial Machine Learning

Suicide mortality is a leading cause of death in the United States, with an upward trend that emphasizes its significance as a public health issue. Previous research has employed global models like ordinary least squares (OLS) regression and local models such as geographically weighted regression (GWR). While local models are useful for analyzing spatial variations in suicide mortality, they share limitations with traditional global models, particularly about their inability to handle multi-collinearity and non-linear relationships. Machine learning approaches, like random forests (RF), can address some of these limitations but often fail to account for spatial variability. This gap highlights the need for spatial ML models specifically designed to tackle suicide mortality. This research seeks to fill this void by using a geographically weighted random forest model (GWRF) to examine the associations between county-level suicide mortality in the U.S. from 2010 to 2020 and various social and environmental determinants of health. A key aspect of our methodology is disciplined feature selection, which reduces the pool of explanatory variables by about 90%. This refinement enhances the explanatory power of both global (R2 improved from 0.59 to 0.67) and local (R2 improved from 0.64 to 0.67) RF models while reducing their run times. An analysis of the importance scores for these selected features reveals that the drivers of suicide mortality vary by context. Thus, to effectively address regional disparities and inform targeted public health interventions, a holistic approach that incorporates multiple county-level characteristics is essential.

Lebakula, Viswadeep [ORNL] (ORCID:0000000152935914↗

Atmospheric Variability Drives Anomalies in the Bering Sea Air–Sea Heat Exchange

Abstract High latitudes, including the Bering Sea, are experiencing unprecedented rates of change. Long-term Bering Sea warming trends have been identified, and marine heatwaves (MHWs), event-scale elevated sea surface temperature (SST) extremes, have also increased in frequency and longevity in recent years. Recent work has shown that variability in air–sea coupling plays a dominant role in driving Bering Sea upper-ocean thermal variability and that surface forcing has driven an increase in the occurrence of positive ocean temperature anomalies since 2010. In this work, we characterize the drivers of the anomalous surface air–sea heat fluxes in the Bering Sea over the period 2010–22 using ERA5 fields. We show that the surface turbulent heat flux dominates the net surface heat flux variability from September to April and is primarily a result of near-surface air temperature and specific humidity anomalies. The airmass anomalies that account for the majority of the turbulent heat flux variability are a function of wind direction, with southerly (northerly) wind advecting anomalously warm (cool), moist (dry) air over the Bering Sea, resulting in positive (negative) surface turbulent flux anomalies. During the remaining months of the year, anomalies in the surface radiative fluxes account for the majority of the net surface heat flux variability and are a result of anomalous cloud coverage, anomalous lower-tropospheric virtual temperature, and sea ice coverage variability. Our results indicate that atmospheric variability drives much of the Bering Sea upper-ocean temperature variability through the mediation of the surface heat fluxes during the analysis period. Significance Statement A long-term ocean warming trend and a recent increase in marine heatwaves in the Bering Sea have been identified. Previous work showed that anomalies in the exchange of heat between the ocean and the atmosphere were the primary driver of Bering Sea temperature variability, but the processes responsible for the heat exchange anomalies were unknown. In this work, we show that the atmosphere is the primary driver of anomalies in the Bering Sea air–sea heat exchange and therefore plays an important role in altering the thermal state of the Bering Sea. Our results highlight the importance of understanding more about how the ocean and the atmosphere interact at high latitudes and how this relationship will be affected by future climate change.

Hayden, Emily E. [a College of Earth, Ocean, and A↗

Hydropower Flexibility Framework (Final Technical Report)

The Hydropower Flexibility Framework (HFF) tool focuses on providing the hydropower community with an effective means of assessing optimized hydropower plant outcomes. This tool combines both site specific characteristics, which act to constrain plant operation, and the hydrologic and grid characteristics which drive hydropower plant operation. The hydropower community faces a confluence of factors which drive the importance of developing such a capability, including an aging hydropower fleet subject to a range of modernization opportunities, a large number of hydropower plant relicensing activities which may affect operational requirements, an electrical grid with increasing levels of variable resources which must be balanced to maintain grid stability, and climate change influencing riverine hydrologic patterns outside of design characteristics. With support from the hydropower community, the project team developed the HFF tool and demonstrated the tool through a series of Use Cases. This guidance was developed as a part of the larger HFF tool User’s Manual (see Appendix B), a resource designed to inform other users and to empower community uptake of the tool. The HFF tool, hosted at https://hfftool.com/, was developed with the support of the U.S. Department of Energy (DOE) Water Power Technologies Office (WPTO). EPRI is currently exploring alternatives to support the continued maintenance and functionally of the online tool.

13 HYDRO ENERGY↗