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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

HOM Spectra Measurements in 1.3 GHz Cavities for LCLS-II

Fermilab recently completed production and testing of 1.3 GHz cryomodules for the LCLS-II project. Each cryomodule consists of eight TESLA-shaped super-conducting elliptical cavities equipped with two High Order Mode (HOM) coupler ports. Measurement of the HOM spectrum is part of the incoming quality control of cavities at room temperature and the final qualification cold test of cryomodules at the Cryomodule Test Facility (CMTF). In this paper we describe the procedure for measuring the HOM spectrum along with further data processing. Finally, we present accumulated statistics of individual HOM frequencies and quality factors related to various cavity vendors and dis-cuss the possible contribution of HOMs to heat loads and beam dynamics.

Lunin, A.↗
DOE OSTI2024

Results of High Order Modes Spectra Measurements in 1.3 GHz Cavities for LCLS-II

Fermilab recently completed production and testing of 1.3 GHz cryomodules for the LCLS-II project. Each cryomodule consists of eight TESLA-shaped superconducting elliptical cavities equipped with two High Order Mode (HOM) coupler ports. Measurement of the HOM spectrum is part of the incoming quality control of cavities at room temperature and the final qualification cold test of cryomodules at the Cryomodule Test Facility (CMTF). In this paper we describe the procedure for measuring the HOM spectrum along with further data processing. Finally, we present accumulated statistics of individual HOM frequencies and quality factors related to various cavity vendors and discuss the possible contribution of HOMs to heat loads and beam dynamics.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Rain-Induced Stratification of the Equatorial Indian Ocean and Its Potential Feedback to the Atmosphere

Surface freshening through precipitation can act to stably stratify the upper ocean, forming a rain layer (RL). RLs inhibit subsurface vertical mixing, isolating deeper ocean layers from the atmosphere. This process has been studied using observations and idealized simulations. The present ocean modeling study builds upon this body of work by incorporating spatially resolved and realistic atmospheric forcing. Fine-scale observations of the upper ocean collected during the Dynamics of the Madden-Julian Oscillation field campaign are used to verify the General Ocean Turbulence Model (GOTM). Spatiotemporal characteristics of equatorial Indian Ocean RLs are then investigated by forcing a 2D array of GOTM columns with realistic and well-resolved output from an existing regional atmospheric simulation. RL influence on the ocean-atmosphere system is evaluated through analysis of RL-induced modification to surface fluxes and sea surface temperature (SST). This analysis demonstrates that RLs cool the ocean surface on time scales longer than the associated precipitation event. A second simulation with identical atmospheric forcing to that in the first, but with rainfall set to zero, is performed to investigate the role of rain temperature and salinity stratification in maintaining cold SST anomalies within RLs. Approximately one third, or 0.1°C, of the SST reduction within RLs can be attributed to rain effects, while the remainder is attributed to changes in atmospheric temperature and humidity. The prolonged RL-induced SST anomalies enhance SST gradients that have been shown to favor the initiation of atmospheric convection. These findings encourage continued research of RL feedbacks to the atmosphere.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Cold compressor performance and energy consumption improvements at Jefferson Lab’s Central Helium Liquefiers

Abstract Jefferson Lab operates two central helium liquefiers (CHLs) which both utilize full cold compression from the saturation pressure at operating temperature (approximately 2.1 K) to just over atmospheric pressure. The original plant, CHL1, was recently outfitted with a replacement subatmospheric cold box (SC1R) containing state-of-the-art cold compressor technology, while the newer plant, CHL2, uses an older cold compressor system. In both cases, the heat of compression is absorbed at low temperature at the expense of electrical power consumed by the warm compressors. Due to the superior efficiency and turndown capabilities of SC1R, a new operating mode has been identified for CHL1 in which the required number of operating warm compressors is reduced by one. A cost-based method for optimizing cold compressor stability and efficiency has been developed and applied to CHL2, improving its turndown and lowering the warm compressor discharge pressure. As a result of these efforts, power consumption of the combined CHLs during normal operations has been reduced by nearly 10%, or a total of 650 kW. The observed performance of CHL1 with SC1R, as well as the cold compressor optimization method, leading to this improved energy consumption rate will be discussed in detail.

Mastracci, B [Thomas Jefferson National Accelerato↗
DOE OSTI2026

Solar Heat for Industrial Processes: Integration with Chemical Reactors

The integration of solar thermal systems with chemical reactors has been proposed as part of a larger effort to develop and deploy solar heat for industrial processes (SHIP) technologies. A strong motivation for SHIP processes and technologies is the potential for high thermal efficiency coupled with low-cost thermal energy storage (TES) which can enable commercial deployment of such systems. While there are different ways to categorize SHIP technologies, one important such distinction is between directly irradiated systems and indirect off-sun process driven by a SHIP system. While directly irradiated systems can provide high thermal efficiencies and high fluxes, they usually require complex engineering solutions due to the need for redesigning the established processes and unit operations. In most cases, it is also more challenging to couple such a process to a TES system, losing some of the benefits of SHIP. On the other hand, using a SHIP system to drive an industrial process off-sun can allow better integration with existing process chains, easier TES capabilities, and potential for more applications fitting a specific SHIP technology. However, the integration of SHIP systems with the industrial processes is not fully explored in detail, especially in the case of high-temperature processes such as reforming, cracking, cement manufacturing, and iron/steelmaking. Many of these systems require heating fluxes of >50 kW/m^2, supplied via combustion of hydrocarbons in a fire box and benefitting from radiative heat transfer between the flue gases and the reaction zones. As such, using SHIP systems for such processes is more complex than providing the same thermal input in the form of a heat transfer medium (HTM) entering the reactor, kiln, or furnace. Moreover, in case convective heat transfer using SHIP is envisioned, for example using supercritical CO2 as the HTM from a particle receiver, the thermal integration might be more challenging than initially envisioned: lower heat transfer coefficients and limited approach temperature might require large flow rates, causing a mismatch between the process thermal requirements and the thermal capacity of the SHIP system. In addition, even if the heat exchange between SHIP and reactor is effective, there is still a cold leg HTM at the reaction temperature or slightly below it. Chemical plants usually include a set of heat exchangers, heat recovery steam generators, and even power generation units - in a tightly integrated design - to recover the flue gases which are eventually vented. With SHIP systems mostly operating on a closed HTM loop, bottoming the cold leg is crucial. In this talk, we will present different modeling results for a variety of syngas production reactions, using catalytic and chemical looping processes, and discuss some of the challenges and design considerations for off-sun chemical reactors using SHIP systems.

14 SOLAR ENERGY↗
DOE OSTI2022

Copper Single Atom-Triggered Niobia–Ceria Catalyst for Efficient Low-Temperature Reduction of Nitrogen Oxides

To reduce nitrogen oxide (NO x ) emission from diesel engines in the cold-start process benefitting the atmospheric environment, catalysts with superior low-temperature NO x removal efficiency are highly demanded. Herein, we report an efficient Nb 2 O 5 /CuO/CeO 2 (NbCuCe) oxide catalyst for the selective catalytic reduction (SCR) of NO x , showing much higher DeNO x activity below 200 °C, superior sulfur resistance, faster response, and much less NH 3 slip than the state-of-the-art Cu-CHA zeolite catalyst. Additionally, atomically dispersed Cu species facilitate the strong interaction between Cu and the Nb/Ce base catalyst, which significantly improves the low-temperature redox properties at Cu–O–Ce sites and NH 3 adsorption/activation at Nb–O–Cu sites, thus contributing to the superior SCR performance of NbCuCe at low temperatures. The developed NbCuCe catalyst is highly promising for efficient DeNO x from cold-start diesel engines and can be coupled with Cu-CHA to achieve a broad operation temperature window.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Magnetic field transport in propagating thermonuclear burn

High energy gain in inertial fusion schemes requires the propagation of a thermonuclear burn wave from hot to cold fuel. We consider the problem of burn propagation when a magnetic field is orthogonal to the burn wave. Using an extended-MHD model with a magnetized α energy transport equation, we find that the magnetic field can reduce the rate of burn propagation by suppressing electron thermal conduction and α particle flux. Magnetic field transport during burn propagation is subject to competing effects: the field can be advected from cold to hot regions by ablation of cold fuel, while the Nernst and α particle flux effects transport the field from hot to cold fuel. These effects, combined with the temperature increase due to burn, can cause the electron Hall parameter to grow rapidly at the burn front. This results in the formation of a self-insulating layer between hot and cold fuel, which reduces electron thermal conductivity and α transport, increases the temperature gradient, and reduces the rate of burn propagation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Heat transfer from glass melt to cold cap: Computational fluid dynamics study of cavities beneath cold cap

Efficient glass production depends on the continuous supply of heat from the glass melt to the floating layer of batch, or cold cap. Computational fluid dynamics (CFD) are employed to investigate the formation and behavior of gas cavities that form beneath the batch by gases released from the collapsing primary foam bubbles, ascending secondary bubbles, and in the case of forced bubbling, from the rising bubbling gas. The gas phase fraction, temperature, and velocity distributions below the cold cap are used to calculate local and average heat transfer rates as a function of the bubbling rate. It is shown that the thickness of the cavities is nearly independent of the cold cap shape and the amount of foam evolved during batch conversion. Furthermore, it is ~7 mm and up to ~15 mm for the cases without and with forced bubbling used to promote circulation within the melt, respectively. Using computed velocity and temperature profiles, the melting rate of the simulated high-level nuclear waste glass batch was estimated to increase with the bubbling rate to the power of ~0.3 to 0.9, depending on the flow pattern. The simulation results are in good agreement with experimental data from laboratory- and pilot-scale melter tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Local transport dynamics of cold pulses in tokamak plasmas

Abstract For over two decades, our fundamental understanding of energy transport dynamics in the core of tokamak plasmas had been challenged by the striking observation of temperature perturbation reversals following the injection of cold pulses at the plasma edge. These phenomena were first discovered by Gentle et al. (Phys. Rev. Lett. 74(18):3620–3623, 1995) in 1995 and had long been suggested to be evidence of nonlocal transport effects. In recent years, a new explanation to these phenomena has emerged, fully consistent with the theory of turbulent transport in magnetized plasmas and in remarkable agreement with experiment. This article reviews the experimental observation of temperature reversals in tokamak plasmas and presents the explanation based on local transport physics.

Rodriguez-Fernandez, P. (ORCID:0000000273611131)↗
DOE OSTI2025

Microstructure refinement of hot deformed Dy-free NdFeB magnets through a novel cold sintering approach by pressure-assisted spark plasma sintering

Anisotropic fine-grained Dy-free NdFeB high-performance magnets were produced using a novel cold sintering approach by pressure-assisted spark plasma sintering (SPS). The NdFeB nanocrystalline ribbon powders were subjected to cold sintering below 450 °C using pressure-assisted SPS, followed by hot deformation at 710 °C and 810 °C via SPS. Results indicate that cold sintering below 450 °C effectively restricts grain growth in the NdFeB magnets, yielding sub-100 nm scale grains across both fine-grained regions and most coarse-grained regions. The refined grain structure achieved through cold sintering allows for a lower hot deformation temperature as compared with the magnet by conventional sintering, as finer grains allow easier deformation and grain sliding/rotation. This process produces a highly fine-grained and anisotropic microstructure to achieve high magnetic performance (i.e., high intrinsic coercivity, remanence, and maximum energy product) in the magnets. The cold sintering (at 350 °C) and lower hot deformation temperatures required (e.g., 710 °C) help control grain coarsening and limit grain size that is commensurate with the size of a single magnetic domain of the Nd 2 Fe 14 B magnetic matrix phase, resulting in high intrinsic coercivity (H ci =11.4 kOe). Furthermore, the reduced hot deformation temperature mitigates the formation of coarse grain bands, leading to improved magnetic properties, specifically an increased remanence (B r = 14.3 kGs) and a high maximum energy product ((BH) max = 48 MGOe). In conclusion, cold sintered hot deformed NdFeB magnet also shows good thermal stability with reversible temperature coefficient α(B r )= -0.097 %/K and α(H ci )= -0.616 %/K at elevated temperatures up to 400 K.

Cold Sintering↗
DOE OSTI2024

Experimental testing of additively manufactured embedded fiber optic smart devices for clean energy applications

Abstract An additively manufactured prototype smart device was created to investigate in-flow temperature distributions using embedded high-definition fiber optic sensors within a component for clean energy systems. The devices were created using Ultrasonic Additive Manufacturing to create a unique embedded pathway within a flow conditioner for the high-definition fiber optic sensors to be placed within. The fibers used allowed for temperature measurements to be taken every 0.65 mm along the fiber. The high-resolution fibers were thermally calibrated enable the 2D reconstruction of the temperature profile in the flow path of the structure. This is due to the temperature-related strain response of the material and strain measurements of the fibers. Hot airflow testing of these devices showed the ability to identify localized temperature differences in the flow. The observed strain response within the smart device had higher strain concentrations in the thicker web regions than in the thinner web regions. These higher strain regions resulted in higher uncertainties for the temperature responses. Further calibration is needed to improve the accuracy of the smart devices, specifically within the inner web structures of a flow straightening component. Further investigations of the devices within flow showed the temperature sensing to be independent of the effects of flow velocity. The devices were able to distinguish temperature differences within single and two-phase flow and showed local sensitivity to the temperature changes with the identification of hot and cold spots. The presented results showed the viability of the smart device for obtaining detailed temperature distributions using common industrial components. Eventually, the goal for these smart devices will be to withstand higher temperature and pressure environments such as those experienced in nuclear, fusion, and concentrated solar energy systems.

Donlan, Connor F. (ORCID:0000000223317882)↗
DOE OSTI2021

Performance Considerations for Ground Source Heat Pumps in Cold Climates: Preprint

Remote, cold climates present challenges to finding safe and affordable options to heat homes. In Alaska, residential ground source heat pumps (GSHPs) have been gaining in popularity to fill this gap. However, there is little research on their long-term performance or effect on soil temperatures. The extended heating season and cold soils of Alaska provide a harsh testing ground for GSHPs, even those designed and marketed for colder climates. The large and unbalanced heating load of cold climates creates a challenging environment for GSHPs. In 2013 the Cold Climate Housing Research Center (CCHRC) installed a GSHP at its Research and Testing Facility (RTF) in Fairbanks, Alaska. The heat pump replaced an oil-fired condensing boiler heating a 464 m2 office space via an in-floor hydronic radiant heating system. The ground heat exchanger (GHE) was installed in moisture-rich silty soils underlain with permafrost near 0°C. The intent of the installation was to observe and monitor the system over a 10-year period in order to develop a better understanding of the performance of GSHPs in sites with permafrost and to help inform future design. As of this writing, the heat pump system has been running for seven heating seasons. The efficiency in those seven heating seasons has been variable with ups and downs that have been difficult to explain. This paper seeks to understand the variability in performance as well as make recommendations for GSHP use in other cold climates.

cold climate↗
DOE OSTI2024

The effect of temperature on photosystem II efficiency across plant functional types and climate

Modeling terrestrial gross primary productivity (GPP) is central to predicting the global carbon cycle. Much interest has been focused on the environmentally induced dynamics of photosystem energy partitioning and how improvements in the description of such dynamics assist the prediction of light reactions of photosynthesis and therefore GPP. The maximum quantum yield of photosystem II (Φ PSIImax ) is a key parameter of the light reactions that influence the electron transport rate needed for supporting the biochemical reactions of photosynthesis. Φ PSIImax is generally treated as a constant in biochemical photosynthetic models even though a constant Φ PSIImax is expected only for non-stressed plants. We synthesized reported Φ PSIImax values from pulse-amplitude-modulated fluorometry measurements in response to variable temperatures across the globe. We found that Φ PSIImax is strongly affected by prevailing temperature regimes with declined values in both hot and cold conditions. To understand the spatiotemporal variability in Φ PSIImax , we analyzed the temperature effect on Φ PSIImax across plant functional type (PFT) and habitat climatology. The analysis showed that temperature's impact on Φ PSIImax is shaped more by climate than by PFT for plants with broad latitudinal distributions or in regions with extreme temperature variability. There is a trade-off between the temperature range within which Φ PSIImax remains maximal and the overall rate of decline of Φ PSIImax outside the temperature range such that species cannot be simultaneously tolerant and resilient to extreme temperatures. Our study points to a quantitative approach for improving electron transport and photosynthetic productivity modeling under changing climates at regional and global scales.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Modification of Ni-20Cr corrosion dealloying behavior in molten fluorides via cold work induced plastic deformation

The corrosion dealloying behavior of cold-worked (CW) Ni20Cr alloy (wt%) was studied in molten LiF-NaF-KF (or FLiNaK) salts at 600 °C, equal to a homologous temperature (TH) of 0.52. Alloys were cold-rolled to achieve reductions of thickness of 10%, 30%, and 50% introducing plastic deformation and a high density of dislocations. Potentiostatic holds (Eapplied) were applied in two different electrode potential regimes. At 1.75VK+/K$${\text{V}}_{{\text{K}}^{+}/{\text{K}}}$$, Cr dealloying to Cr(II) and Cr(III) is predominant, while at 1.90 VK+/K$${\text{V}}_{{\text{K}}^{+}/{\text{K}}}$$, both Ni and Cr are oxidized in molten FLiNaK at 600 °C. In these potential regimes, dealloyed Ni20Cr displayed bicontinuous porosity within the grain interior and at grain boundaries, driven by the high driving force for Cr dissolution and sustained by defect mediated outward solid state diffusion of Cr in parallel with surface diffusion of Ni. The bicontinuous porous structure developed was observed to undergo further coarsening and densification of the Ni-rich ligaments at a higher electrode potential. The main effect of CW observed is the introduction of plastic deformation and dislocation substructures that serve as short-circuit paths for Cr solid state diffusion to surfaces exposed to FLiNaK. This modified the evolution of the bicontinuous porous structure which increased with CW substantially. Kinetic analysis reveals that the Cr dealloying at +1.75 VK+/K$${\text{V}}_{{\text{K}}^{+}/{\text{K}}}$$ and 1.90 VK+/K$${\text{V}}_{{\text{K}}^{+}/{\text{K}}}$$ is initially charge transfer controlled, except for the 50% CW condition at 1.90 VK+/K$${\text{V}}_{{\text{K}}^{+}/{\text{K}}}$$, where the process becomes limited by slow Cr defect mediated bulk diffusion. The rate determining factors are explored and compared to experimental results.

Chan, Ho Lun↗
DOE OSTI2022

Conversion degree and heat transfer in the cold cap and their effect on glass production rate in an electric melter

A predictive model of melt rate in waste glass vitrification operations is needed to inform melter operations during normal and off-normal operations. This paper describes the development of a model of the cold cap (the reacting melter feed floating on molten glass in a glass melter) that couples heat transfer with the feed-to-glass conversion kinetics. The model was applied to four melter feeds designed for high-level and low-activity nuclear waste feeds using the material properties, either measured or estimated, to obtain temperature and conversion distribution within the cold cap. The cold cap model, when coupled with a computational fluid dynamics model of a Joule-heated glass melter, allows the prediction of the glass production rate and power consumption. The results show reasonable agreement with the melting rates measured during pilot-scale melter tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Cold air quench control of local crystallization environment in fully air-processed carbon-based perovskite solar cells

Carbon-based perovskite solar cells (C-PSCs) present a low-cost route to efficient photovoltaic technology. Gas quenching is an essential process commonly used for solvent extraction in scalable module fabrication using solution processes, but film quality remains highly sensitive to the localized environmental processing temperature, especially during intermediate phase transitions before perovskite film high temperature annealing. In this study, we introduce a cold air quench strategy to precisely control the local crystallization temperature that simultaneously promotes uniform crystallization and facilitates strain relaxation in fully air-processed C-PSCs. It is found that implementing dry air at 10 °C as the quenching gas yields a champion power conversion efficiency (PCE) of 20.52 %, with preferential (110) orientation and reduced, homogenized in-plane strain. This newly developed technique of a cost-effective low temperature air quenching process also enhances carrier lifetime, reduces interface recombination, and improves charge extraction. Furthermore, this work presents cold air quenching as a scalable, economic method to control perovskite crystallization and strain in C-PSC fabrication, advancing the industrial viability of high-performance perovskite modules.

14 SOLAR ENERGY↗
DOE OSTI2021

High Density of Strong yet Deformable Intermetallic Nanorods Leads to an Excellent Room Temperature Strength-Ductility Combination in a High Entropy Alloy

This paper introduces a new microstructural template for high entropy alloys (HEAs), where the face centered cubic (FCC) complex concentrated solid solution is reinforced with a high density of strong, yet deformable, nanorods of an ordered multi-component intermetallic L12 compound. Thermodynamic modeling has been employed to design this HEA with a large L12 volume fraction. Thermo-mechanical processing by isothermal annealing of the conventionally processed bulk cold-rolled alloy directly at precipitation temperatures, has been applied to produce a high density of uniformly distributed L12 nanorods within refined FCC grains, resulting from concomitant recrystallization and discontinuous precipitation processes. The nanorod morphology of the discontinuous L12 product has been established from three-dimensional atom probe tomography. The refined grains result in a complete coverage of the microstructure with discontinuously precipitated intermetallic nanorods. This nanorod strengthened HEA exhibits an exceptionally high room temperature yield strength of ~1630 MPa, good tensile ductility of ~15%, and an ultimate tensile strength of ~1720 MPa. Furthermore, a single L12 phase alloy, melted based on the precipitate composition in the two-phase FCC + L12 HEA, exhibits very high compressive deformability and strain hardenability, unusual for ordered intermetallic compounds. These results open a new strategy for design of fine-grained microstructures strengthened via ordered intermetallic phases, exploiting the beneficial effects of discontinuous precipitation, for achieving very high room temperature tensile strengths while maintaining good ductility.

Gwalani, Bharat↗