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NASA NTRS1976

Electrophoretic separation of proteins in space

Commercially available and synthetic wide range and short range ampholytes used in the isoelectric focusing of proteins was analyzed by ion exchange chromatography. A pH gradient over the pH range 3.8 to 11.0 was used to elute the ampholytes from a column of a sulfonated polystyrene resin. The wide range ampholytes were resolved into some 60 to 70 ninhydrin positive components. The recovery obtained with the method was quantitative. Acid short range ampholytes have approximately 35 components which elute readily from the ion exchange resin. Basic short range ampholytes gave about 50 components, most of which eluted at alkaline pH.

Brown, R. K.↗

NASA NTRSDate not supplied

Polarimeter + Lidar Derived Aerosol Particle Number Concentration

In this study, we propose a simple method to derive vertically resolved aerosol particle number concentration (Na) using combined polarimetric and lidar remote sensing observations. This method relies on accurate polarimeter retrievals of the fine-mode column-averaged aerosol particle extinction cross section and accurate lidar measurements of vertically resolved aerosol particle extinction coefficient such as those provided by multiwavelength high spectral resolution lidar. We compare the resulting lidar + polarimeter vertically resolved Na product to in situ Na data collected by airborne instruments during the NASA aerosol cloud meteorology interactions over the western Atlantic experiment (ACTIVATE). Based on all 35 joint ACTIVATE flights in 2020, we find a total of 32 collocated in situ and remote sensing profiles that occur on 11 separate days, which contain a total of 322 cloud-free vertically resolved altitude bins of 150 m resolution. We demonstrate that the lidar + polarimeter Na agrees to within 106% for 90% of the 322 vertically resolved points. We also demonstrate similar agreement to within 121% for the polarimeter-derived column-averaged Na. We find that the range-normalized mean absolute deviation (NMAD) for the polarimeter-derived column-averaged Na is 21%, and the NMAD for the lidar + polarimeter-derived vertically resolved Na is 16%. Taken together, these findings suggest that the error in the polarimeter-only column-averaged Na and the lidar + polarimeter vertically resolved Na are of similar magnitude and represent a significant improvement upon current remote sensing estimates of Na.

Aerosol number concentration↗

NASA NTRS2006

On detecting a trend in the residual circulation from observations of column HCl

The troposphere is the part of the atmosphere where people live. The troposphere goes up to about 12 km above the earth over places at middle latitudes like Washington, D.C. The next layer of air up in the atmosphere is called the stratosphere. The tropopause separates the troposphere and stratosphere. Most of the ozone in the atmosphere is in the stratosphere where it protects people from the harmful rays in sunlight. Near the earth s surface, ozone is a pollutant. In general, air travels from the troposphere to the stratosphere through upward motion in the tropics. Most of the air comes back down to the troposphere at middle latitudes. The so-called "stratospheric residual circulation" moves the air in the stratosphere from the tropics to the middle latitudes. In this way, the amount of air that moves out of the stratosphere into the troposphere at middle latitudes depends on the strength of the residual circulation. This overturning of the atmosphere is important as it brings chemicals produced by the activities of people into the stratosphere. Most notable are chlorofluorocarbons (CFCs) that destroy stratospheric ozone. The transport of air out of the stratosphere removes ozone-destroying chemicals, but also brings ozone into the troposphere.

Olsen, M. A.↗

NASA NTRS2013

A Suzaku X-ray Observation of One Orbit of the Supergiant Fast X-ray Transient IGR J16479-4514

We report on a 250 ks long X-ray observation of the supergiant fast X-ray transient (SFXT) IGR J16479-4514 performed with Suzaku in 2012 February. During this observation, about 80% of the short orbital period (P(sub orb) approximates 3.32 days) was covered as continuously as possible for the first time. The source light curve displays variability of more than two orders of magnitude, starting with a very low emission state (10(exp −13) erg / sq cm/s; 1-10 keV) lasting the first 46 ks, consistent with being due to the X-ray eclipse by the supergiant companion. The transition to the uneclipsed X-ray emission is energy dependent. Outside the eclipse, the source spends most of the time at a level of 6-7X10)(exp−12) erg/sq. cm/s) punctuated by two structured faint flares with a duration of about 10 and 15 ks, respectively, reaching a peak flux of 3-4X10(exp −11) erg/sq. cm./S, separated by about 0.2 in orbital phase. Remarkably, the first faint flare occurs at a similar orbital phase of the bright flares previously observed in the system. This indicates the presence of a phase-locked large scale structure in the supergiant wind, driving a higher accretion rate onto the compact object. The average X-ray spectrum is hard and highly absorbed, with a column density, NH, of 10*exp 23)/sq cm, clearly in excess of the interstellar absorption. There is no evidence for variability of the absorbing column density, except that during the eclipse, where a less absorbed X-ray spectrum is observed. A narrow Fe K-alpha emission line at 6.4 keV is viewed along the whole orbit, with an intensity which correlates with the continuum emission above 7 keV. The scattered component visible during the X-ray eclipse allowed us to directly probe the wind density at the orbital separation, resulting in rho(sub w)=7X10(exp −14) g/cubic cm. Assuming a spherical geometry for the supergiant wind, the derived wind density translates into a ratio M(sub w)/v(sub infinity) = 7X10(exp −17) Solar M/km which, assuming terminal velocities in a large range 500-3000 km/s, implies an accretion luminosity two orders of magnitude higher than that observed. As a consequence, a mechanism should be at work reducing the mass accretion rate. Different possibilities are discussed.

J164794514↗

NASA NTRS2005

Assimilation of MLS and OMI Ozone Data

Ozone data from Aura Microwave Limb Sounder (MLS) and Ozone Monitoring Instrument (OMI) were assimilated into the ozone model at NASA's Global Modeling and Assimilation Office (GMAO). This assimilation produces ozone fields that are superior to those from the operational GMAO assimilation of Solar Backscatter Ultraviolet (SBUV/2) instrument data. Assimilation of Aura data improves the representation of the "ozone hole" and the agreement with independent Stratospheric Aerosol and Gas Experiment (SAGE) III and ozone sonde data. Ozone in the lower stratosphere is captured better: mean state, vertical gradients, spatial and temporal variability are all improved. Inclusion of OMI and MLS data together, or separately, in the assimilation system provides a way of checking how consistent OMI and MLS data are with each other, and with the ozone model. We found that differences between OMI total ozone column data and model forecasts decrease after MLS data are assimilated. This indicates that MLS stratospheric ozone profiles are consistent with OMI total ozone columns. The evaluation of error characteristics of OMI and MLS ozone will continue as data from newer versions of retrievals becomes available. We report on the initial step in obtaining global assimilated ozone fields that combine measurements from different Aura instruments, the ozone model at the GMAO, and their respective error characteristics. We plan to use assimilated ozone fields in estimation of tropospheric ozone. We also plan to investigate impacts of assimilated ozone fields on numerical weather prediction through their use in radiative models and in the assimilation of infrared nadir radiance data from NASA's Advanced Infrared Sounder (AIRS).

Stajner, I.↗

NASA NTRS1997

SYNTHESIS OF NOVEL ALL-DIELECTRIC GRATING FILTERS USING GENETIC ALGORITHMS

We are concerned with the design of inhomogeneous, all dielectric (lossless) periodic structures which act as filters. Dielectric filters made as stacks of inhomogeneous gratings and layers of materials are being used in optical technology, but are not common at microwave frequencies. The problem is then finding the periodic cell's geometric configuration and permittivity values which correspond to a specified reflectivity/transmittivity response as a function of frequency/illumination angle. This type of design can be thought of as an inverse-source problem, since it entails finding a distribution of sources which produce fields (or quantities derived from them) of given characteristics. Electromagnetic sources (electric and magnetic current densities) in a volume are related to the outside fields by a well known linear integral equation. Additionally, the sources are related to the fields inside the volume by a constitutive equation, involving the material properties. Then, the relationship linking the fields outside the source region to those inside is non-linear, in terms of material properties such as permittivity, permeability and conductivity. The solution of the non-linear inverse problem is cast here as a combination of two linear steps, by explicitly introducing the electromagnetic sources in the computational volume as a set of unknowns in addition to the material unknowns. This allows to solve for material parameters and related electric fields in the source volume which are consistent with Maxwell's equations. Solutions are obtained iteratively by decoupling the two steps. First, we invert for the permittivity only in the minimization of a cost function and second, given the materials, we find the corresponding electric fields through direct solution of the integral equation in the source volume. The sources thus computed are used to generate the far fields and the synthesized triter response. The cost function is obtained by calculating the deviation between the synthesized value of reflectivity/transmittivity and the desired one. Solution geometries for the periodic cell are sought as gratings (ensembles of columns of different heights and widths), or combinations of homogeneous layers of different dielectric materials and gratings. Hence the explicit unknowns of the inversion step are the material permittivities and the relative boundaries separating homogeneous parcels of the periodic cell.

Zuffada, Cinzia↗

NASA NTRS1976

Neutral hydrogen in the direction of the Small Magellatic Cloud and the limits of an extragalactic soft X-ray flux

Previously reported X-ray data from the vicinity of the Small Magellanic Cloud (SMC) have been reanalyzed using H I data from a more detailed and sensitive 21-cm survey of this region. The results support the previous conclusion: assuming that the interstellar material absorbs according to the cross sections of Brown and Gould (1970), at least 75 per cent of the observed 0.25-keV X-ray flux is of local origin. The corollary problem of placing a cosmologically useful upper limit on the extragalactic flux will be difficult to solve until the behavior of the local component is better understood; but if the local flux is isotropic, a 3-sigma upper limit of 240 photons per (sq cm s sr keV) at 0.25 keV may be placed on a flux originating beyond the SMC. Tables of H I column density are given for an area 30 deg by 30 deg about the SMC. The high-velocity component, presumably associated with the Magellanic Cloud system, and the galactic disk component are tabulated separately.

Mccammon, D.↗

NASA NTRS1990

Creeping flow of a conducting fluid past axisymmetric bodies in the presence of an aligned magnetic field

The use of strong magnetic fields for the control of particle settling in metallic systems is investigated by altering the fluid mechanics in the melt. The fluid mechanism of particle settling is analyzed for the motion around single, axisymmetric particles in the limit of creeping flow for a fluid with a large electrical conductivity. The drag is found to increase proportionately to the intensity of the magnetic field or the Hartmann number Ha. The flowfield forms boundary layers, which thin out with increasing Ha, along the surfaces parallel to the flow. For axisymmetric bodies, the boundary layer separates as the poles of the surface are approached and encloses regions of almost stagnant fluid. These regions spread upstream and downstream along the body with increasing Ha, thereby trapping the particle in a column of stagnant fluid.

Kyrlidis, A.↗

NASA NTRS1993

Theory of Metastable State Relaxation in a Gravitational Field for Non-Critical Binary Systems with Non-Conserved Order Parameter

A new mathematical ansatz is developed for solution of the time-dependent Ginzburg-Landau nonlinear partial differential equation describing metastable state relaxation in binary (solute+solvent) non-critical solutions with non-conserved scalar order parameter in presence of a gravitational field. It has been demonstrated analytically that in such systems metastability initiates heterogeneous solute redistribution which results in the formation of a non-equilibrium singly-periodic spatial solute structure in the new solute-rich phase. The critical radius of nucleation and the induction time in these systems are gravity-dependent. It has also been proved that metastable state relaxation in vertical columns of supersaturated non-critical binary solutions leads to formation of the solute concentration gradient. Analytical expression for this concentration gradient is found and analysed. It is concluded that gravity can initiate phase separation (nucleation or spinodal decomposition).

Izmailov, Alexander F.↗

NASA NTRS2001

Ultraviolet Broad Absorption Features and the Spectral Energy Distribution of the QSO PG 1351+64

We present a moderate-resolution (approximately 20 km s(exp -1) spectrum of the mini broad absorption line QSO PG 1351+64 between 915-1180 A, obtained with the Far Ultraviolet Spectroscopic Explorer (FUSE). Additional low-resolution spectra at longer wavelengths were also obtained with the Hubble Space Telescope (HST) and ground-based telescopes. Broad absorption is present on the blue wings of C III (lambda)977, Ly(beta), O VI (lambda)(lambda)1032,1038, Ly(alpha), N V (lambda)(lambda)1238,1242, Si IV (lambda)(lambda)1393,1402, and C IV (lambda)(lambda)1548,1450. The absorption profile can be fitted with five components at velocities of approximately -780, -1049, -1629, -1833, and -3054 km s(exp -1) with respect to the emission-line redshift of z = 0.088. All the absorption components cover a large fraction of the continuum source as well as the broad-line region. The O VI emission feature is very weak, and the O VI/Ly(alpha) flux ratio is 0.08, one of the lowest among low-redshift active galaxies and QSOs. The UV (ultraviolet) continuum shows a significant change in slope near 1050 A in the restframe. The steeper continuum shortward of the Lyman limit extrapolates well to the observed weak X-ray flux level. The absorbers' properties are similar to those of high-redshift broad absorption-line QSOs. The derived total column density of the UV absorbers is on the order of 10(exp 21) cm(exp -2), unlikely to produce significant opacity above 1 keV in the X-ray. Unless there is a separate, high-ionization X-ray absorber, the QSO's weak X-ray flux may be intrinsic. The ionization level of the absorbing components is comparable to that anticipated in the broad-line region, therefore the absorbers may be related to broad-line clouds along the line of sight.

Zheng, W.↗

NASA NTRS2013

Enabling Microliquid Chromatography by Microbead Packing of Microchannels

The microbead packing is the critical element required in the success of on-chip microfabrication of critical microfluidic components for in-situ analysis and detection of chiral amino acids. In order for microliquid chromatography to occur, there must be a stationary phase medium within the microchannel that interacts with the analytes present within flowing fluid. The stationary phase media are the microbeads packed by the process discussed in this work. The purpose of the microliquid chromatography is to provide a lightweight, low-volume, and low-power element to separate amino acids and their chiral partners efficiently to understand better the origin of life. In order to densely pack microbeads into the microchannels, a liquid slurry of microbeads was created. Microbeads were extracted from a commercially available high-performance liquid chromatography column. The silica beads extracted were 5 microns in diameter, and had surface coating of phenyl-hexyl. These microbeads were mixed with a 200- proof ethanol solution to create a microbead slurry with the right viscosity for packing. A microfilter is placed at the outlet via of the microchannel and the slurry is injected, then withdrawn across a filter using modified syringes. After each injection, the channel is flushed with ethanol to enhance packing. This cycle is repeated numerous times to allow for a tightly packed channel of microbeads. Typical microbead packing occurs in the macroscale into tubes or channels by using highly pressurized systems. Moreover, these channels are typically long and straight without any turns or curves. On the other hand, this method of microbead packing is completed within a microchannel 75 micrometers in diameter. Moreover, the microbead packing is completed into a serpentine type microchannel, such that it maximizes microchannel length within a microchip. Doing so enhances the interactions of the analytes with the microbeads to separate efficiently amino acids and amino acid enantiomers.

Balvin, Manuel↗

NASA NTRS2014

Enabling Microliquid Chromatography by Microbead Packing of Microchannels

Balvin, Manuel↗

NASA NTRS1992

PHOTCAL: The IRAF photometric calibration package

The IRAF photmetric calibration package PHOTCAL is discussed. PHOTCAL is a set of tasks designed to derive the transformation from the instrumental photometric system to the standard photometric system, and apply the transformation to the observations. The PHOTCAL package contains tasks for: (1) creating and/or editing standard star catalogs and observations catalogs, (2) creating, checking and editing the configuration file which specifies the format of the standard star and observations catalogs and the form of the transformation equations, (3) solving the transformation equations interactively or non-iteractively using non-linear least squares fitting routines, and (4) applying the transformation to the observations. PHOTCAL standard star and observations catalogs are simple text files, whose columns are delimited by whitespace, and whose first column contains the star names. This format makes it relatively easy to interface the output of non-IRAF photometry programs as well as the output of the IRAF APPHOT and DAOPHOT photometry packages to PHOTCAL. PHOTCAL maintains a standard star catalog directory for the convenience of the user, but users can easily create their own standard star catalogs and/or define their own standard star catalog directory. Separate observations files produced by APPHOT, DAOPHOT or a user program containing data for stellar fields taken through different filters, can be combined into observations catalogs using one of the PHOTCAL preprocessor tasks. The input configuration file required by PHOTCAL is a text file, consisting of a series of instructions written by the user in a mini-language understood by the PHOTCAL parser. These instructions: (1) assign names to the input data columns in the standard star and observations catalogs, (2) assign names and initial values to the parameters to be fit, (3) define and describe how to solve the transformation equations. The mini-language approach permits great flexibility in the format of the input catalogs and the form of the transformation equations.

Davis, L. E.↗

NASA NTRS1983

An ab initio study of core-valence correlation

Especially in the cases of the first two columns of the periodic table, the inclusion of core-valence correlation in ab initio CI calculations yields a contraction of the atomic valence shell and improves both calculated atomic ionization potentials and atomic energy separations. For the alkali dimers Na2, K2, and Rb2, the presently calculated bond lengths are in excellent agreement with experiments when core-valence is included. In addition, the valence dissociation energies are accurate.

Partridge, H.↗

NASA NTRS2007

Influences of Local Sea-Surface Temperatures and Large-scale Dynamics on Monthly Precipitation Inferred from Two 10-year GCM-Simulations

Two parallel sets of 10-year long: January 1, 1982 to December 31, 1991, simulations were made with the finite volume General Circulation Model (fvGCM) in which the model integrations were forced with prescribed sea-surface temperature fields (SSTs) available as two separate SST-datasets. One dataset contained naturally varying monthly SSTs for the chosen period, and the oth& had the 12-monthly mean SSTs for the same period. Plots of evaporation, precipitation, and atmosphere-column moisture convergence, binned by l C SST intervals show that except for the tropics, the precipitation is more strongly constrained by large-scale dynamics as opposed to local SST. Binning data by SST naturally provided an ensemble average of data contributed from disparate locations with same SST; such averages could be expected to mitigate all location related influences. However, the plots revealed: i) evaporation, vertical velocity, and precipitation are very robust and remarkably similar for each of the two simulations and even for the data from 1987-ENSO-year simulation; ii) while the evaporation increased monotonically with SST up to about 27 C, the precipitation did not; iii) precipitation correlated much better with the column vertical velocity as opposed to SST suggesting that the influence of dynamical circulation including non-local SSTs is stronger than local-SSTs. The precipitation fields were doubly binned with respect to SST and boundary-layer mass and/or moisture convergence. The analysis discerned the rate of change of precipitation with local SST as a sum of partial derivative of precipitation with local SST plus partial derivative of precipitation with boundary layer moisture convergence multiplied by the rate of change of boundary-layer moisture convergence with SST (see Eqn. 3 of Section 4.5). This analysis is mathematically rigorous as well as provides a quantitative measure of the influence of local SST on the local precipitation. The results were recast to examine the dependence of local rainfall on local SSTs; it was discernible only in the tropics. Our methodology can be used for computing relationship between any forcing function and its effect(s) on a chosen field.

Sud, Y. C.↗

NASA NTRS2016

A Simple and Sensitive LC-MS/MS Method for the Determination of Free 8-Hydroxy-2'-Deoxyguanosine in Human Urine

Urinary free 8-hydroxy-2'-deoxyguanosine (8OHdG), an oxidized product of DNA, and is frequently chosen as a biomarker of oxidative stress in humans, including studies of oxidative DNA damage during space flight. It is challenging to accurately and efficiently quantify urinary free 8OHdG in large scale human studies. LC-MS/MS is emerging as a preferable analytical technique owing its high sensitivity, selectivity and efficiency, compared to some traditional methods such as ELISA and HPLC. A simple and sensitive LC-MS/MS method has been developed for the determination of free 8OHdG in human urine. Sample preparation was done by solid phase extraction with a Waters Oasis HLB 96 well plate. A Waters Alliance 2795 HT Separation Module combined with a Quattro Micro tandem mass spectrometer was used as the LC-MS/MS system. The runtime of one injection can be less than 5 minutes using a reversed phase C18 column and an isocratic flow of methanol/water. ESI positive ions were quantified in the multiple reaction modes (MRM) using m/z 284 yields 168 for 8OHdG and m/z 289 yields173 for stable isotope labeled internal standard [(15)N5] 8OHdG. With this method for 8OHdG, a lower limit of quantitation of 1.0 nM (0.28 ng/mL) has been achieved using 100 microliter urine sample. The analytical range is between 1.0 and 100 nM with a correlation coefficient greater than or equal to 0.99. Good reproducibility can be obtained with intra-assay and inter-assay CVs less than or equal to 10% for 8OHdG spiked urine QC samples. This method can be used in high-throughput routine analysis of free 8OHdG in human urine.

Wang, Zuwei↗

NASA NTRS2023

NuSTAR Observations of Four Mid-IR-Selected Dual AGN Candidates in Galaxy Mergers

Mergers of galaxies are a ubiquitous phenomenon in the universe and represent a natural consequence of the “bottom-up” mass accumulation and galaxy evolution cosmological paradigm. It is generally accepted that the peak of active galactic nucleus (AGN) accretion activity occurs at nuclear separations of ≲10 kpc for major mergers. Here we present new NuSTAR and XMM-Newton observations for a subsample of mid-IR preselected dual AGN candidates in an effort to better constrain the column densities along the line of sight (LOS) for each system. Only one dual AGN candidate, J0841+0101, is detected as a single, unresolved source in the XMMNewton and NuSTAR imaging, while the remaining three dual AGN candidates, J0122+0100, J1221+1137, and J1306+0735, are not detected with NuSTAR; if these nondetections are due to obscuration alone, these systems are consistent with being absorbed by column densities of log ( N H /cm −2 ) ≽ 24.9, 24.6, and 24.3, which are roughly consistent with previously inferred column densities in these merging systems. In the case of J0841+0101, the analysis of the 0.3–30 keV spectra reveal an LOS column density of N H ≳ 10 24 cm −2 , significantly larger than the column densities previously reported for this system and demonstrating the importance of the higher signal-to-noise ratio XMM-Newton spectra and access to the >10 keV energies via NuSTAR. Though it is unclear if J0841+0101 truly hosts a dual AGN, these results are in agreement with the high obscuring columns expected in AGNs in late-stage mergers.

AGN host galaxies↗

NASA NTRS1994

Participation in TOMS missions

In the past year we have been investigating a new algorithm for the derivation of column sulfur dioxide, column ozone, and aerosol optical depth from the Total Ozone Mapping Spectrometer (TOMS) High Density TOMS (HDT) archived albedos. Simulations of the measured albedos were made using a radiative transfer model, and a technique developed to separate the effects of the aerosol optical depth from the absorption optical depth. The retrieval adopted obtained values from the three parameters with high accuracy. This retrieval was then applied to the TOMS data.

Hudson, Robert D.↗