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NASA NTRS1993

An experimental study of the organic molecules produced in cometary and interstellar ice analogs by thermal formaldehyde reactions

Results of an experimental study tracing thermal formaldehyde reactions in astrophysically relevant ices in dense molecular clouds are reported. The formaldehyde chemistry during warm-up of ices containing H2CO and one or more of the molecules H2O, CH3OH, CO, O2, and NH3 were monitored using IR spectroscopy. Conversion of H2CO into residues was observed to start at about 40 K for NH3:H2CO ices and at about 80 K in H2O-rich ices. A total of five different organic products of these reactions were distinguished: POM and reaction products of H2CO and H2O, CH3OH, and NH3. Given the measured reaction paths and efficiencies, it is estimated that on the order of 1 percent of the organics found in the coma of Comet P/Halley could have been produced by thermal formaldehyde reactions taking place in the nucleus.

Schutte, W. A.↗

NASA NTRS2006

AstroBiology Explorer Mission Concepts (ABE/ASPIRE)

The AstroBiology Explorer (ABE) and the Astrobiology Space InfraRed Explorer (ASPIRE) Mission Concepts are two missions designed to address the questions (1) Where do we come from? and (2) Are we alone? as outlined in NASA s Origins Program using infrared spectroscopy to explore the identity, abundance, and distribution of molecules of astrobiological importance throughout the Universe. The ABE mission s observational program is focused on six tasks to: (1) Investigate the evolution of ice and organics in dense clouds and star formation regions, and the young stellar/planetary systems that form in them; (2) Measure the evolution of complex organic molecules in stellar outflows; (3) Study the organic composition of a wide variety of solar system objects including asteroids, comets, and the planets and their satellites; (4) Identify organic compounds in the diffuse interstellar medium and determine their distribution , abundance, and change with environment; (5) Detect and identify organic compounds in other galaxies and determine their dependence on galactic type; and (6) Measure deuterium enrichments in interstellar organics and use them as tracers of chemical processes. The ASPIRE mission s observational program expands upon ABE's core mission and adds tasks that (7) Address the role of silicates in interstellar organic chemistry; and (8) Use different resolution spectra to assess the relative roles and abundances of gas- and solid-state materials. ABE (ASPIRE) achieves these goals using a highly sensitive, cryogenically-cooled telescope in an Earth drift-away heliocentric orbit, armed with a suite of infrared spectrometers that cover the 2.5-20(40) micron spectral region at moderate spectral resolution (R>2000). ASPIRE's spectrometer complement also includes a high-resolution (R>25,000) module over the 4-8 micron spectral region. Both missions target lists are chosen to observe a statistically significant sample of a large number of objects of varied types in support of the tasks outline above. The ABE and ASPIRE mission lifetimes are designed to be 14 months and 3 years, respectively, both with significant cryogen and propellant lifetime margins to support an extended observing campaign. The ABE/ASPIRE mission concepts and their supporting Science Teams are led by Principal Investigator Dr. Scott Sandford of NASA s Ames Research Center, with industry partner Ball Aerospace Technologies Ltd., and managed by Jet Propulsion Laboratory. The ABE/ASPIRE Science Operations will be carried out at NASA s Ames Research Center, and the ABE/ASPIRE database will be archived at Caltech/IPAC.

Sandford, Scott↗

NASA NTRS2009

Laboratory Studies of Ethane Ice Relevant to Outer Solar System Surfaces

Oort Cloud comets, as well as TNOs Makemake (2045 FYg), Quaoar, and Pluto, are known to contain ethane. However, even though this molecule is found on several outer Solar System objects relatively little information is available about its amorphous and crystalline phases. In new experiments, we have prepared ethane ices at temperatures applicable to the outer Solar System, and have heated and ion-irradiated these ices to study phase changes and ethane's radiation chemistry using mid-IR spectroscopy (2.2 - 16.6 microns). Included in our work is the meta-stable phase that exists at 35 - 55 K. These results, including newly obtained optical constants, are relevant to ground-based observational campaigns, the New Horizons mission, and supporting laboratory work. An improved understanding of solid-phase ethane may contribute to future searches for this and other hydrocarbons in the outer Solar System.

Moore, Marla H.↗

NASA NTRS1991

Lunar and Planetary Science Conference, 21st, Houston, TX, Mar. 12-16, 1990, Proceedings

The present conference on lunar and planetary science discusses the geology and geophysics of Venus; the lunar highlands and regolith; magmatic processes of the moon and meteorites; remote sensing of the moon and Mars; chondrites, cosmic dust, and comets; ammonia-water mixtures; and the evolution of volcanism, tectonics, and volatiles on Mars. Attention is given to volcanism on Venus, pristine moon rocks, the search for Crisium Basin ejecta, Apollo 14 glasses, lunar anorthosites, the sources of mineral fragments in impact melts 15445 and 15455, and argon adsorption in the lunar atmosphere. Also discussed are high-pressure experiments on magnesian eucrite compositions, the early results of thermal diffusion in metal-sulfide liquids, preliminary results of imaging spectroscopy of the Humorum Basin region of the moon, high-resolution UV-visible spectroscopy of lunar red spots, and a radar-echo model for Mars. Other topics addressed include nitrogen isotopic signatures in the Acapulco Meteorite, tridymite and maghemite formation in an Fe-SiO smoke, and the enigma of mottled terrain on Mars.

Ryder, Graham↗

NASA NTRS2018

Water-Rock Interactions in Outer Solar System Bodies: Evidence from the Coordinated Analysis of Interplanetary Dust

NASA has an ongoing program of collecting interplanetary dust particles (IDPs) in the stratosphere using high altitude research aircraft. The collected IDPs are derived from asteroids and comets and here we report studies of a subset of hydrated IDPs rich in carbonaceous matter that are proposed to have a cometary origin. Our studies are aimed at understanding the evolution of oxygen reservoirs in the Solar System and their interaction with cometary minerals and organic matter. The small size (<20 μm) and fragility of these IDPs present a number of analytical challenges. We have pioneered techniques for performing chemical, mineralogical, isotopic, and spectroscopic measurements on the same sample in a carefully coordinated sequence. Coordinated analyses of nanogram-size samples is made possible by several delicate sample preparation techniques. To avoid organic contamination, we embed IDPs in elemental sulfur and use ultramicrotomy to partly section the particles (the first few micrometers). Multiple thin sections (50-70 nm thick) are placed on different substrates depending on the analysis technique. We use a JEOL 2500SE scanning, transmission electron microscope (STEM) to determine the mineralogy, microstructure, and elemental compositions of constituent minerals in the thin sections through a combination of high resolution imaging, electron diffraction, quantitative energy-dispersive x-ray mapping, and electron energy-loss spectroscopy. Following the STEM analyses, we use a NanoSIMS 50L for high spatial resolution isotopic measurements of H, C, N, and O to search for presolar grains and to understand the origin of the indigenous organic matter. The isotopic analyses are performed on the same sections analyzed in the STEM in order to correlate isotopic properties with the elemental and mineralogical data. We reserve other thin sections for non-destructive analyses utilizing synchrotron-based techniques including Fourier-transform infrared (FTIR) micro-spectroscopy and X-ray absorption near-edge structure (XANES) analyses, especially for functional group analysis of organic matter in the particles. The remainder of the IDP is extracted from the sulfur bead that was used for microtomy and is pressed into Au foil for quantitative analysis (including light elements) using a JEOL 8530F field emission electron probe microanalyzer (EPMA). After the EPMA measurements, high precision oxygen isotopic analyses are obtained using Cameca IMS1270/1290 instruments at UCLA. The hydrated IDPs in this study are dominated by saponitic clays, with minor magnetite, carbonate and abundant organic matter. The remarkable oxygen isotopic compositions, high carbon contents, and the abundance of isotopically anomalous organic matter, together suggest that the high carbon, hydrated IDPs are derived from primitive sources not yet represented in meteorite collections such as outer main belt P- and D-type asteroids or comets.

Keller, Lindsay P.↗

NASA NTRS1988

Planetary Fabry-Perot spectroscopy

Application of high spectral resolution, Earth-based Fabry-Perot spectroscopy to the study of planetary atmospheres, for which current topics are outer planet HD and H2 spectra (atmospheric structure, D/H ratio), Mars CO2, CO, O2, and H2O spectra (atomspheric photochemistry), Venus H2O and HDO, associated laboratory spectroscopy (especially H2 overtone bands, HDO) was accomplished. Monochromatic charge coupled device (CCD) imaging photometry of the Jovian nebula, with images taken in rapid sequence among the diagnostic spectral lines of ionized sulfur species, provided self-supporting snapshots of the Jupiter/Io plasma conditions (spatially resolved electron and ion densities and temperatures), covering the post-Voyager period from 1981 and leading up to the Galileo tour in the early 1990s. High spectral resolution Fabry-Perot/charge coupled device (CCD) imaging of comets (OI, CI, and H2O(+) velocity maps and spatial distriubtions), and Io's charge exchanged neutral jet was studied.

Trauger, J. T.↗

NASA NTRS1989

Interplanetary dust particles collected in the stratosphere - Observations of atmospheric heating and constraints on their interrelationships and sources

TEM and IR spectroscopy investigations of the interplanetary dust particles (IDPs) collected in the stratosphere have shown the majority of IDPs in the layer-lattice silicate and pyroxene classes to not have been heated to temperatures above 600 C during atmospheric entry. This implies that they arrive at the upper atmosphere with low geocentric encounter velocities, and limits the possible encounter trajectories for these particles to relatively circular prograde orbits. On this basis, it is judged unlikely that these IDPs are from earth-crossing comets or asteroids; collected IDPs dominated by olivine include a larger portion of above-600 C-heated particles, suggesting their capture from more eccentric orbits.

Sandford, Scott A.↗

NASA NTRS2012

A Quantum Band Model of the nu3 Fundamental of Methanol (CH3OH) and Its Application to Fluorcescence Spectra of Comets

Methanol (CH3OH) radiates efficiently at infrared wavelengths, dominating the C-H stretching region in comets, yet inadequate quantum-mechanical models have imposed limits on the practical use of its emission spectra. Accordingly, we constructed a new line-by-line model for the 3 fundamental band of methanol at 2844 / cm (3.52 micron) and applied it to interpret cometary fluorescence spectra. The new model permits accurate synthesis of line-by-line spectra for a wide range of rotational temperatures, ranging from 10 K to more than 400 K.We validated the model by comparing simulations of CH3OH fluorescent emission with measured spectra of three comets (C/2001 A2 LINEAR, C/2004 Q2 Machholz and 8P/Tuttle) acquired with high-resolution infrared spectrometers at high-altitude sites. The new model accurately describes the complex emission spectrum of the nu3 band, providing distinct rotational temperatures and production rates at greatly improved confidence levels compared with results derived from earlier fluorescence models. The new model reconciles production rates measured at infrared and radio wavelengths in C/2001 A2 (LINEAR). Methanol can now be quantified with unprecedented precision and accuracy in astrophysical sources through high-dispersion spectroscopy at infrared wavelengths

Villanueva, Geronimo L.↗

NASA NTRS1995

10 micron spectroscopy of younger stars in the rho Ophiuchi cloud

Spectra in the 10 micrometer region were obtained of 14 young stars associated with the central core of the rho Oph dark cloud complex. Silicate dust emission and absorption features can be fairly well reproduced with simple models using the emissivity of the silicates in the Orion Trapezium region, believed to be typical of molecular cloud dust. A spectrum of the Trapezium star theta(sup 1) Ori D was obtained to define the emissivity more precisely. The emissivity of silicate dust around the late-type giant Mu Cep does not improve the fits to the absorption features and provides a poorer match to the emission features. None of the sources display a strong 11.2 micrometer peak like that seen in comet Halley and attributed to crystalline olivine. A broad weak feature near 11.2 micrometer, possibly related to the comet feature, may be present in the emission spectrum of the Herbig Ae star HD 150193. Absorption features toward two of the objects are narrower than would be expected from Trapezium-like silicates, suggesting differences in the composition of the silicates. The relation between the silicate extinction band depth and H2O ice band depths is determined for the deeply embedded objects. One late-type object, Elias 14, clearly shows the 11.25 micrometer aromatic hydrocarbon emission feature, possibly excited by the nearby B star, HD 147889, though the latter does not exhibit the feature.

Hanner, M. S.↗

NASA NTRS2005

TEM and NanoSIMS Study of Hydrated/Anhydrous Phase Mixed IDPs: Cometary or Asteroidal Origin?

Chondritic interplanetary dust particles (IDPs) are subdivided into (1) particles that form highly porous aggregates (chondritic porous "CP" IDPs), and (2) smooth particles ("CS" IDPs). Infrared (IR) spectroscopy has been a valuable tool for non-destructively determining the bulk mineralogy of IDPs. Most IDPs fall within three distinct IR groups: (1) olivine-rich particles, (2) pyroxene-rich particles, and (3) phyllosilicate-rich particles. From the IR studies, IDPs dominated by anhydrous minerals tend to be fine grained (CP), while phyllosilicate-rich IDPs are mostly CS. CP IDPs have been linked to cometary sources based on their compositions, spectral properties, and atmospheric entry velocities. Since no spectral signatures of hydrated minerals have been detected in comets, CS IDPs are thought to derive from primitive asteroids. Transmission electron microscopy (TEM) studies have revealed that the mineralogical distinctions between CP and CS IDPs are not always clear. Previous investigators have reported trace amounts of hydrous minerals in dominantly anhydrous particles. A better understanding of these particles will help to elucidate whether there is a genetic relationship between anhydrous and hydrated IDPs, provide insight into the earliest stages of aqueous alteration of primitive materials, and may help to determine whether comets have experienced any aqueous processing. Here we report a combined TEM and isotopic imaging study of an unusual anhydrous IDP with hydrated phases. Additional information is included in the original extended abstract.

Nakamura, K.↗

NASA NTRS2004

Isolation of Purines and Pyrimidines from the Murchison Meteorite Using Sublimation

The origin of life on Earth, and possibly on other planets such as Mars, would have required the presence of liquid water and a continuous supply of prebiotic organic compounds. The exogenous delivery of organic matter by asteroids, comets, and carbonaceous meteorites could have contributed to the early Earth s prebiotic inventory by seeding the planet with biologically important organic compounds. A wide variety of prebiotic organic compounds have previously been detected in the Murchison CM type carbonaceous chondrite including amino acids, purines and pyrimidines. These compounds dominate terrestrial biochemistry and are integral components of proteins, DNA and RNA. Several purines including adenine, guanine, hypoxanthine, and xanthine, as well as the pyrimidine uracil, have previously been detected in water or formic acid extracts of Murchison using ion-exclusion chromatography and ultraviolet spectroscopy. However, even after purification of these extracts, the accurate identification and quantification of nucleobases is difficult due to interfering UV absorbing compounds. In order to reduce these effects, we have developed an extraction technique using sublimation to isolate purines and pyrimidines from other non-volatile organic compounds in Murchison acid extracts.

Glavin, D. P.↗

NASA NTRS2009

Evidence for Changes in 81PIWild 2 Organic Matter Since Collection and Comparison of 82PIWild 2 and IDP Organic Matter to Access the Thermal Effects of Aerogel Capture

NASA s Stardust spacecraft collected cometary material during its passage through the dust coma of comet 81P/Wild 2 on January 2nd, 2004 and delivered this material to Earth on January 15th 2006. The first fragment we analyzed during the preliminary examination was partially vaporized by the X-ray beam. The carbonaceous material that survived was re-analysis approx.2 months later and the carbon spectrum for this material had significantly changed from what we first observed.. We have observed similar changes to the carbonaceous matter in some interplanetary dust particles ( IDPs). Some of the 81P/Wild 2 organic matter volatilized upon impact with the aerogel as observed using IR spectroscopy where IR spectra were collected several mms away from sample tracks [1]. The time-temperature profile experienced by any particular 81P/Wild 2 grain during aerogel capture is not known, although Brownlee, et al. suggest that fine-grained materials, <1 micron in size, fragmented and then partially vaporized during collection, while particles much larger then 1 micron in size were captured intact [2]. Nearly all organic matter is subject to thermal alteration. To assess the heating and alteration experienced by the 81P/Wild 2 organic matter during capture we are comparing 81P/Wild2 organic matter with IDP organic matter where we have evidence of heating in the IDP [3,4].

Wirick, S.↗

NASA NTRS2006

Focused Ion Beam Recovery of Hypervelocity Impact Residue in Experimental Craters on Metallic Foils

The Stardust sample return capsule will return to Earth in January 2006 with primitive debris collected from Comet 81P/Wild-2 during the fly-by encounter in 2004. In addition to the cometary particles embedded in low-density silica aerogel, there will be microcraters preserved in the Al foils (1100 series; 100 micrometers thick) that are wrapped around the sample tray assembly. Soda lime spheres (approximately 49 m in diameter) have been accelerated with a light-gas-gun into flight-grade Al foils at 6.35 km s(sup -1) to simulate the potential capture of cometary debris. The preserved crater penetrations have been analyzed using scanning electron microscopy (SEM) and x-ray energy dispersive spectroscopy (EDX) to locate and characterize remnants of the projectile material remaining within the craters. In addition, ion beam induced secondary electron imaging has proven particularly useful in identifying areas within the craters that contain residue material. Finally, high-precision focused ion beam (FIB) milling has been used to isolate and then extract an individual melt residue droplet from the interior wall of an impact penetration. This enabled further detailed elemental characterization, free from the background contamination of the Al foil substrate. The ability to recover pure melt residues using FIB will significantly extend the interpretations of the residue chemistry preserved in the Al foils returned by Stardust.

Graham, G. A.↗

NASA NTRS1982

The High Resolution Spectrograph for the Space Telescope

The High Resoltuion Spectrograph (HRS) in conjunction with the Space Telescope (ST), extends ultraviolet astronomical spectroscopy to higher spectra, spatial, and time resolutions than previously achieved, as well as to fainter and more distant celestial objects. Other significant advances inherent in the instrument are high photometric accuracy and efficient operation via exposure meter control and real time rejection of bad data. These capabilities are provided to accomplish the scientific programs of the HRS investigation definition team, which concern the interstellar medium, stellar winds, and evolutionary aspects of stellar atmosphere studies; the determination of chemical abundances relevant to stellar evolution; the investigation of quasars and Seyfert galaxy nuclei; and the analysis of the atmospheres of solar system objects, including comets.

Brandt, J. C.↗

NASA NTRS2002

High Abundance of Ions in Cosmic Ices

Water-rich, mixed molecular ices and polycyclic aromatic hydrocarbons (PAHs) are common throughout interstellar molecular clouds and the Solar System. Vacuum ultraviolet (VUV) irradiation and particle bombardment of these abiotic ices produces complex organic species, including important biogenic molecules such as amino acids and functionalized PAHs which may have played a role in the origin of life. This ability of such water-rich, oxygen dominated ices to promote production of complex organic species is surprising and points to an important, unusual, but previously overlooked mechanism at play within the ice. Here we report the nature of this mechanism using electronic spectroscopy. VUV-irradiation of PAH/H2O ices leads to an unprecedented and efficient (greater than 70 %) conversion of the neutral PAHs to their cation form (PAH+). Further, these H2O/PAH+ ices are stabile at temperatures below 50 K, a temperature domain common throughout interstellar clouds and the Solar System. Between 50 and 125 K they react to form the complex organics. In view of this, we conclude that charged PAHs and other molecular ions should be common and abundant in many cosmic ices. The chemical, spectroscopic and physical properties of these ion-rich ices can be of fundamental importance for objects as diverse as comets, planets, and molecular clouds and may account for several poorly understood phenomena associated with each of these object classes.

Gudipati, Murthy S.↗

NASA NTRS1983

Observing Comet Halley with Space Telescope

The NASA Space Telescope (ST) to be launched into LEO by STS in late 1985 is characterized, and its potential use for observations of Comet Halley shortly after the perihelion passage in February, 1986, is discussed. The ST comprises a 2.4-m MgF2-coated primary reflector (with maximum field of view 2.7 x 2.7 arcmin, wavelength coverage 120-1100 nm, and maximum tracking rate 0.21 arcsec/sec) and five first-generation scientific instruments (wide-field planetary camera, faint-object camera, high-resolution and faint-object spectrographs, and high-speed photometer). Planned ST observations of Halley include periods of continuous observation much longer than can be obtained from the ground, provision of supplementary data and navigation information to Giotto and other deep-space missions, emission spectroscopy, UV polarimetry, and possible detection of 124-nm H2O absorption. Before March 11, 1986, earth occultation or similar procedures will be required to observe Halley because it will be within the ST 50-deg solar-elongation-distance limit.

Caldwell, J.↗

NASA NTRS1997

Meteorites, Microfossils and Exobiology

The discovery of evidence for biogenic activity and possible microfossils in a Martian meteorite may have initiated a paradigm shift regarding the existence of extraterrestrial microbial life. Terrestrial extremophiles that live in deep granite and hydrothermal vents and nanofossils in volcanic tuffs have altered the premise that microbial life and microfossils are inconsistent with volcanic activity and igneous rocks. Evidence for biogenic activity and microfossils in meteorites can no longer be dismissed solely because the meteoritic rock matrix is not sedimentary. Meteorite impact-ejection and comets provide mechanisms for planetary cross-contamination of biogenic chemicals, microfossils, and living microorganisms. Hence, previously dismissed evidence for complex indigenous biochemicals and possible microfossils in carbonaceous chondrites must be re-examined. Many similar, unidentifiable, biological-like microstructures have been found in different carbonaceous chondrites and the prevailing terrestrial contaminant model is considered suspect. This paper reports the discovery of microfossils indigenous to the Murchison meteorite. These forms were found in-situ in freshly broken, interior surfaces of the meteorite. Environmental Scanning Electron Microscope (ESEM) and optical microscopy images indicate that a population of different biological-like forms are represented. Energy Dispersive Spectroscopy reveals these forms have high carbon content overlaying an elemental distribution similar to the matrix. Efforts at identification with terrestrial microfossils and microorganisms were negative. Some forms strongly resemble bodies previously isolated in the Orgueil meteorite and considered microfossils by prior researchers. The Murchison forms are interpreted to represent an indigenous population of the preserved and altered carbonized remains (microfossils) of microorganisms that lived in the parent body of this meteorite at diverse times during the past 4.5 billion years (Gy).

Hoover, Richard B.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Asteroids, Meteors, and Comets

The session "Asteroids, Meteors, and Comets" contained the following reports:Ejecta Generation and Redistribution on 433 Eros: Modeling Ejecta Launch Conditions; Macroscopic Voids in Small Asteroids: Effects of Cohesion; The Seismic Effect of Impacts on Asteroid Surface Morphology: Early Modeling Results; Photometric Studies of Eros from NEAR Data; Quantitative Aspects of Space Weathering: Implications for Regolith Breccia Meteorites and Asteroids; Diversity of Types of Hydrated Minerals on C-Class Asteroids; Mineralogical Variations Among High Albedo E-Type Asteroids: Implications for Asteroid Igneous Processes; Multi-Wavelength Observations of 2100 Ra-Shalom: Radar and Lightcurves; What are the P-type Asteroids Made Of?; Sodium Overabundance in Meteoroids from Meteor Spectroscopy; Migration Processes and Volatiles Inventory to the Inner Planets; Characterization of the Surface Properties of MUSES-C/Hayabusa Spacecraft Target; Asteroid 25143 Itokawa; and Sample Return Science by Hayabusa Near-Earth Asteroid Mission.

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