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At least 253 records · Page 14

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NASA NTRS1985

The non-mass-dependent oxygen isotope effect in the electrodissociation of carbon dioxide - A step toward understanding NoMaD chemistry

A non-mass dependent (NoMaD) oxygen isotope effect is demonstrated in the dissociation of CO2 similar to that observed in the electrosynthesis of ozone. The molecular oxygen produced carries the signature of two separate isotopic fractionation processes; a mass-dependent fractionation probably due to CO2 + O isotopic exchange, and a secondary NoMaD fractionation (delta O-17 = 0.97 + or - 0.09 delta O-18, with the O2 depleted in O-17 and O-18). It is suggested that the effect is due to either the formation or relaxation of ozone in an excited electronic state. This represents the latest advance in the understanding of chemical NoMaD effects which may be essential to the explanation of non-mass-dependent fractionations observed in meteorites.

Heidenreich, J. E., III↗

NASA NTRS1985

Finite element simulation of temperature dependent free surface flows

The method of Engelman and Sani (1984) for a finite-element simulation of incompressible surface flows with a free and/or moving fluid interface, such as encountered in crystal growth and coating and polymer technology, is extended to temperature-dependent flows, including the effect of temperature-dependent surface tension. The basic algorithm of Saito and Scriven (1981) and Ruschak (1980) has been generalized and implemented in a robust and versatile finite-element code that can be employed with relative ease for the simulation of free-surface problems in complex geometries. As a result, the costly dependence on the Newton-Raphson algorithm has been eliminated by replacing it with a quasi-Newton iterative method, which nearly retains the superior convergence properties of the Newton-Raphson method.

Engelman, M. S.↗

NASA NTRS1986

Statistical dependency in visual scanning

A method to identify statistical dependencies in the positions of eye fixations is developed and applied to eye movement data from subjects who viewed dynamic displays of air traffic and judged future relative position of aircraft. Analysis of approximately 23,000 fixations on points of interest on the display identified statistical dependencies in scanning that were independent of the physical placement of the points of interest. Identification of these dependencies is inconsistent with random-sampling-based theories used to model visual search and information seeking.

Ellis, Stephen R.↗

NASA NTRS1986

The onset of time-dependent convection in spherical shells as a clue to chaotic convection in the earth's mantle

This work presents a detailed numerical study of the dynamical behavior of convection in a spherical shell, as applied to mantle convection. From both two-dimensional (120 radial and 360 tangential points) and three-dimensional (60 radial levels and spherical harmonics up to order and degree L = 33, m = 33), it is shown that for a spherical shell (with inner-to-outer radii ratio eta = 0.62) convection becomes time-dependent, with l = 2 dominating, at a Rayleigh number of about 31 times supercritical for a constant-viscosity, base-heated configuration. This secondary instability is characterized by oscillatory time dependence, with higher frequencies involved, at slightly higher Rayleigh numbers. In illustrating the onset of time dependence, the analysis is extended to show that the onset of weak turbulence in spherical-shell convection takes place at about 60 times the critical Rayleigh number via a quasi-periodic mode.

Machetel, Philippe↗

NASA NTRS1987

The localization and crystallographic dependence of Si suboxide species at the SiO2/Si interface

X-ray photoemission spectroscopy has been used to examine the localization and crystallographic dependence of Si(+), Si(2+), and Si(3+) suboxide states at the SiO2/Si interface for (100)and (111)-oriented substrates with gate oxide quality thermal oxides. The Si(+) and Si(2+) states are localized within 6-10 A of the interface while the Si(3+) state extends about 30 A into the bulk SiO2. The distribution of Si(+) and Si(2+) states shows a strong crystallographic dependence with Si(2+) dominating on (100) substrates and Si(+) dominating on (111) substrates. This crystallographic dependence is anticipated from consideration of ideal unreconstructed (100) and (111) Si surfaces, suggesting that (1) the Si(+) and Si(2+) states are localized immediately within the first monolayer at the interface and (2) the first few monolayers of substrate Si atoms are not significantly displaced from the bulk. The total number of suboxide states observed at the SiO2/Si interface corresponds to 94 and 83 percent of a monolayer for these (100) and (111) substrates, respectively.

Grunthaner, P. J.↗

NASA NTRS1987

X-ray studies of quasars with the Einstein Observatory. IV - X-ray dependence on radio emission

The X-ray properties of a sample of 114 radio-loud quasars observed with the Einstein Observatory are examined, and the results are compared with those obtained from a large sample of radio-quiet quasars. The results of statistical analysis of the dependence of X-ray luminosity on combined functions of optical and radio luminosity show that the dependence on both luminosities is important. However, statistically significant differences are found between subsamples of flat radio spectra quasars and steep radio spectra quasars with regard to dependence of X-ray luminosity on only radio luminosity. The data are consistent with radio-loud quasars having a physical component, not directly related to the optical luminosity, which produces the core radio luminosity plus 'extra' X-ray emission.

Worrall, D. M.↗

NASA NTRS1988

Estimation of time- and state-dependent delays and other parameters in functional differential equations

A parameter estimation algorithm is developed which can be used to estimate unknown time- or state-dependent delays and other parameters (e.g., initial condition) appearing within a nonlinear nonautonomous functional differential equation. The original infinite dimensional differential equation is approximated using linear splines, which are allowed to move with the variable delay. The variable delays are approximated using linear splines as well. The approximation scheme produces a system of ordinary differential equations with nice computational properties. The unknown parameters are estimated within the approximating systems by minimizing a least-squares fit-to-data criterion. Convergence theorems are proved for time-dependent delays and state-dependent delays within two classes, which say essentially that fitting the data by using approximations will, in the limit, provide a fit to the data using the original system. Numerical test examples are presented which illustrate the method for all types of delay.

Murphy, K. A.↗

NASA NTRS1988

Electron-temperature dependence of the recombination of electrons with O4(+) ions

The coefficient for recombination of O4(+) ions with electrons has been measured as a function of Te by analyzing electron- and ion-density decays in microwave-generated afterglow plasmas in neon-oxygen mixtures. Te values in the afterglow were elevated above those of the neutral species and ions by continuous application of microwave power. The data analysis included effects on the Te arising from inelastic collisions of electrons with the minority oxygen molecules and spatial nonuniformities of Te due to the spatially nonuniform microwave heating field. Over the temperature range Te = 143-5500 K the recombination coefficients were found to have a Te exp -z dependence, with z = 0.48 + 0.1 or - 0.05. While the values of the recombination coefficients for this dimer ion are an order of magnitude larger than those of the monomer ions, the temperature dependence is close to the Te exp -0.5 dependence predicted and often observed for diatomic ions.

Dulaney, J. L.↗

NASA NTRS1988

First-guess dependence of a physically based set of temperature-humidity retrievals from HIRS2/MSU data

The first-guess dependence of temperature and humidity fields retrieved from HIRS2/MSU data using the GLA (Goddard Laboratory for Atmospheres) physically based retrieval scheme is examined. Retrievals were performed over the ALPEX region for two successive synoptic periods, 1200 UTC March 4 and 00000 UTC March 5, 1982, using three different initial guesses for each period. Results show rather low first-guess dependence for the thickness fields and larger first-guess dependence for the precipitable water fields, especially close to the surface. The humidity retrieval algorithm used is described. The processing system has the property of maintaining the accuracy of a good guess and improving a poor one for both thickness and precipitable water at all levels.

Reuter, D.↗

NASA NTRS1988

A nonlinear history-dependent damage model for low cycle fatigue

A nonlinear damage postulate that embodies the dependence of the damage rate on cycle-dependent changes in the bulk microstructure and the surface topography is examined. The postulate is analytically formulated in terms of the deformation history dependence of the bulk behavior. This formulation is used in conjunction with baseline data in accordance with the damage postulate to predict the low cycle fatigue resistance of OFE copper. Close comparison of the predictions with experimentally observed behavior suggests that the postulate offers a viable basis for nonlinear damage analysis.

Leis, B. N.↗

NASA NTRS1989

Context dependent prediction and category encoding for DPCM image compression

Efficient compression of image data requires the understanding of the noise characteristics of sensors as well as the redundancy expected in imagery. Herein, the techniques of Differential Pulse Code Modulation (DPCM) are reviewed and modified for information-preserving data compression. The modifications include: mapping from intensity to an equal variance space; context dependent one and two dimensional predictors; rationale for nonlinear DPCM encoding based upon an image quality model; context dependent variable length encoding of 2x2 data blocks; and feedback control for constant output rate systems. Examples are presented at compression rates between 1.3 and 2.8 bits per pixel. The need for larger block sizes, 2D context dependent predictors, and the hope for sub-bits-per-pixel compression which maintains spacial resolution (information preserving) are discussed.

Beaudet, Paul R.↗

NASA NTRS1990

The intensity dependent spread model and color constancy

Odetics is investigating the use of the intensity dependent spread (IDS) model for determining color constancy. Object segmentation is performed effortlessly by the human visual systems, but creating computer vision that takes an image as input and performs object identification on the basis of color has some difficulties. The unknown aspects of the light illuminating a scene in space or anywhere can seriously interfere with the use of color for object identification. The color of an image depends not only on the physical characteristics of the object, but also on the wavelength composition of the incident illumination. IDS processing provides the extraction of edges and of reflectance changes across edges, independent of variations in scene illumination. IDS depends solely on the ratio of the reflectances on the two sides of the edge. Researchers are in the process of using IDS to recover the reflectance image.

Kurrasch, Ellie↗

NASA NTRS1990

Dependence of the microwave radar cross section on ocean surface variables - Comparison of measurements and theory using data from the Frontal Air-Sea Interaction Experiment

The purpose of this investigation was to study the ability of theoretical radar cross section (RCS) models to predict the absolute magnitude of the ocean radar cross section under a wide variety of sea and atmospheric conditions. The dependence of the RCS on wind stress (as opposed to wind speed) was also studied. An extensive amount of experimental data was acquired during the Frontal Air-Sea Interaction Experiment. Measurements across an ocean front demonstrated that the vertical polarization and horizontal polarization radar cross section were more strongly dependent on wind stress than on wind magnitude. Current theoretical models for the RCS, based on stress, were tested with this data. In situations where the Bragg scattering theory does not agree with the measured radar cross section (magnitude and angle dependence), revisions are hypothesized and evaluated.

Weissman, David E.↗

NASA NTRS1990

A three-dimensional time-dependent model of the plasmasphere

A three-dimensional, time-dependent, nonlinear, hydrodynamic model of the plasmasphere has been developed which includes the self-consistent coupling of conjugate hemispheres within the plasmasphere as well as the effects of cross-L drifts due to convection electric fields. The inner region of the plasmasphere was modeled from an L of 1.5 to an L of 3.5 to 4.5, depending on local time. In this first study of the global plasmasphere, the model was run for solar minimum conditions until diurnally reproducible results were obtained, indicating that the plasmasphere was fully filled. The results of the model were then compared with applicable measurements of the plasmasphere. It was found that the model tends to overestimate densities somewhat, although it is within a factor of 2 of an average of June and December whistler observations. The model predicts densities within a factor of 2 of most of the satellite observations as well. As anticipated, the diurnal variation of the plasmasphere was found to depend on magnetic latitude. At low latitudes the diurnal variation in density was relatively small, with the largest densities occurring in the afternoon time sector. However, near the plasmapause, the effects of changes in volume of drifting tubes of plasma due to cross-L drifts led to a factor of 3 variation in equatorial density, with the highest densities occurring near local midnight where the volume was lowest. Various limitations of the current model and suggested improvements are also discussed.

Rasmussen, C. E.↗

NASA NTRS1990

Long-term study of longitudinal dependence in primary particle precipitation in the north Jovian aurora

The wavelength-dependent absorption apparent in IUE spectra of the north Jovian aurora is analyzed to determine the column density of hydrocarbons above the altitude of the FUV auroral emission. Both the magnetotail and torus auroral zone models are considered in estimating zenith angles, with very similar results obtained for both models. It is found that the hydrocarbon column density above the FUV emission displays a consistent dependence on magnetic longitude, with the peak density occurring approximately coincident with the peak in the observed auroral intensity. Two distinct scenarios for the longitude dependence of the column density are discussed. In one, the Jovian upper atmosphere is longitudinally homogeneous, and the variation in optical depth is due to a variation in penetration, and thus energy, of the primary particles. In the other, the energy of the primaries is longitudinally homogeneous, and it is aeronomic properties which change, probably due to auroral heating.

Livengood, T. A.↗

NASA NTRS1990

Estimation of time- and state-dependent delays and other parameters in functional differential equations

Murphy, K. A.↗

NASA NTRS1990

Canopy bidirectional reflectance dependence on leaf orientation

The dependence of the bidirectional reflectance (BR) on the inclination and azimuthal orientation of a leaf is analyzed, with the primary assumption that, in terms of both obscuration and shadowing, the entire canopy consists of the same leaves. The BR patterns of a dense canopy are examined as a function of canopy architecture. It is assumed that the leaves are opaque Lambertian reflectors, having identical orientation and relfecting properties throughout the canopy, and distributed randomly with respect to the the irradiation field and the viewing direction. Analytical expressions are presented and analyzed for the BR factor. It is noted that maximal BR occurs at large viewing zenith angles. A complex and often steep dependence of the BR on azimuthal location is reported, noting that the BR thus depends on the leaf azimuth as well as the zenith angle. It is concluded that the question of azimuthal distribution has to be addressed when conducting model inversions to infer canopy characteristics and architecture.

Brakke, Thomas W.↗

NASA NTRS1990

Time-dependent shock acceleration of energetic electrons including synchrotron losses

The present investigation of the time-dependent particle acceleration problem in strong shocks, including synchrotron radiation losses, solves the transport equation analytically by means of Laplace transforms. The particle distribution thus obtained is then transformed numerically into real space for the cases of continuous and impulsive injections of particles at the shock. While in the continuous case the steady-state spectrum undergoes evolution, impulsive injection is noted to yield such unpredicted features as a pile-up of high-energy particles or a steep power-law with time-dependent spectral index. The time-dependent calculations reveal varying spectral shapes and more complex features for the higher energies which may be useful in the interpretation of outburst spectra.

Fritz, Klaus-Dieter↗