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Molecular collisions. V.

Transport coefficient expressions for collisions between rigid diatomic molecules, using perturbation method

TRANSPORT COEFFICIENT↗

Photosynthetic action spectra and adaptation to spectral light distribution in a benthic cyanobacterial mat

We studied adaptation to spectral light distribution in undisturbed benthic communities of cyanobacterial mats growing in hypersaline ponds at Guerrero Negro, Baja California, Mexico. Microscale measurements of oxygen photosynthesis and action spectra were performed with microelectrodes; spectral radiance was measured with fiber-optic microprobes. The spatial resolution of all measurements was 0.1 mm, and the spectral resolution was 10 to 15 nm. Light attenuation spectra showed absorption predominantly by chlorophyll a (Chl a) (430 and 670 nm), phycocyanin (620 nm), and carotenoids (440 to 500 nm). Blue light (450 nm) was attenuated 10-fold more strongly than red light (600 nm). The action spectra of the surface film of diatoms accordingly showed activity over the whole spectrum, with maxima for Chl a and carotenoids. The underlying dense Microcoleus population showed almost exclusively activity dependent upon light harvesting by phycobilins at 550 to 660 nm. Maximum activity was at 580 and 650 nm, indicating absorption by phycoerythrin and phycocyanin as well as by allophycocyanin. Very little Chl a-dependent activity could be detected in the cyanobacterial action spectrum, even with additional 600-nm light to excite photosystem II. The depth distribution of photosynthesis showed detectable activity down to a depth of 0.8 to 2.5 mm, where the downwelling radiant flux at 600 nm was reduced to 0.2 to 0.6% of the surface flux.

NASA Discipline Exobiology↗

Gulf of Maine Water Resources: Assessing the Use of Nasa Earth Observations for Identifying Harmful Algal Blooms of Pseudo-Nitzschia in the Gulf of Maine

The Gulf of Maine has a history of harmful algal blooms (HABs) that have been increasing in frequency and intensity in recent years, raising concerns in the community. Specifically, the Pseudo-nitzschia genus possesses harmful toxins that can induce food-borne illnesses and infect humans through ambient water. We observed in-situ data from known 2016 and 2020 Pseudo-nitzschia blooms as case studies to test the feasibility of using satellite data to track bloom events. In order to map the frequency and distribution of Pseudo-nitzschia bloom events, we used satellite data from the Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) and Sentinel-3 Ocean and Land Colour Instrument (OLCI). We utilized Earth observation data to calculate normalized fluorescence line height (nFLH) and absorption by phytoplankton (aph443), which are satellite products that more accurately depict phytoplankton reflectance. We compared these products with in-situ observations in order to analyze ocean color differences and distinguish diatomic algal particles from other organic and inorganic particles.

harmful algal blooms↗

Tabulated Values of Bond Dissociation Energies, Ionization Potentials, and Electron Affinities for Some Molecules Found in High-Temperature Chemical Reactions

Values of the bond dissociation energies, ionization potentials, and electron affinities that were taken from the literature are presented in tables for some monatomic, diatomic, and polyatomic molecules which are found in many high-temperature chemical reactions including combustion reactions. Much of the information came from literature published after 1950 which either reported experimental and theoretical energy values or gave a review of previous literature on the subject. In some cases values for the bond dissociation energies were calculated from recently published heats of formation.

IONIZATION POTENTIAL↗

Application of Dorodnitsyn's Integral Method to Nonequilibrium Flows over Pointed Bodies

Dorodnitsyn's integral method is used to obtain an approximate solution to the supersonic nonequilibrium flow over pointed bodies with attached shock waves. The partial differential equations governing the flow are converted to an approximate set of ordinary equations, which are solved by numerical integration starting at the body tip. Detailed analytical and numerical results for the first approximation are presented, considering the vibrational relaxation of a diatomic gas over a wedge or cone. It is shown that the first approximation yields: (1) The exact flow-variable gradients at the wedge tip (2) Expressions for the flow-variable gradients at the cone tip which are in agreement with extrapolations of characteristics calculations (3) A good approximate algebraic solution for frozen or equilibrium conical flow (4) An approximate expression for the nonequilibrium-flow stream function which affords a means of obtaining variations across the shock layer of the temperature and vibrational energy. Numerical results for both the wedge and cone compare favorably with identical cases computed by the method of characteristics.

NONEQUILIBRIUM FLOW↗