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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Spacecraft charging in the auroral plasma: Progress toward understanding the physical effects involved

The work is presented in four parts. First, main differences between the plasma environments in geostationary orbit and low polar orbit with regard to high-voltage charging situations are reviewed. Next, results are presented from a calculation of secondary-electron escape currents from negatively-charged spacecraft surfaces having various orientations relative to the local magnetic-field direction. It is shown that for finite ranges of combinations of electric and magnetic field directions, secondary-electron escape is completely suppressed and therefore cannot help to discharge the spacecraft. In such circumstances, secondary electrons may travel distances many times their gyroradii before reimpacting, and this may produce greatly increased secondary-electron surface currents. Thirdly, a simple rough estimate of the required conditions for high-voltage auroral-zone charging is developed. The results suggest that for any given spacecraft, surface potentials are likely to depend more strongly on the ratio of ambient flux of high-energy electrons to that of all ions, than on any other environmental parameter. Finally, preliminary results are presented of numerical simulation work directed toward testing this hypothesis. Numerical instabilities encountered in doing this simulation work probably are closely related to physical sensitivities inherent in the physics of the ion wake behind the spacecraft, and especially to beam-like constituents of the ion population in the wake.

Laframboise, J. G.↗
DOE OSTI2021

Deployment of salt sample extraction system at an engineering-scale electrorefiner

The goal of the salt sampling program at Argonne is to develop and deploy automated molten salt sampling approaches for interfacing relevant unit operations with salt analysis to improve the timeliness of sampling-based accountancy measurements. Two technologies under development in support of this goal are a vacuum sampling loop module and a high-throughput pneumatic sample generator module. Compared to traditional point sampling approaches (i.e., dip probes), the vacuum sampling loop facilitates the collection of a larger cross-section of the bulk salt in order to collect more representative samples. The vacuum sampling approach also eliminates the risk of dross contamination of samples and avoids the use of moving parts in the salt. The pneumatic sample generator module is used to facilitate high-throughput sample analysis to improve the measurement precision of any given analytical technique by averaging out random sampling and measurement errors. In FY21, two methods for integrating these two modules were tested including direct fluidic coupling and coupling using a solid salt transfer mechanism. Solid salt transfer was ultimately selected over fluidic coupling, primarily to enable the transport of samples over longer distances to support automated at-line integration with high-precision techniques (such as microcalorimetry) that cannot withstand the conditions near an electrorefining process. To facilitate rapid solid salt coupling, new mechanisms were developed for rapidly charging and discharging salt sample tubes at the vacuum sampling loop and pneumatic sample generator modules, respectively. While the charging mechanism will be deployed in FY22, the discharge mechanism was tested in FY21 and is described here. The solid salt tube transfer method was deployed at one of Argonne’s engineering-scale electrorefiners to implement at-line high-throughput pneumatic micro-sample generation capabilities. The approach was used to generate precise uranium- and lanthanide-bearing electrorefiner micro-samples with the specific dimensions requested by researchers at Los Alamos National Laboratory for use in testing their novel microcalorimeter x-ray techniques. The solid salt transfer mechanism proved not only to be an effective means of integrating the precision sample generator with vacuum sampling, but also improved the performance of the sampler generator. To discharge salt from the sample tubes at the sampler generator, tube segments were inserted directly into the sample generator’s Helmholtz chamber and pressure pulse actuations were used to generate precision molten salt samples directly from the tube segments. The direct insertion of sample tubes into the sample generator enabled rapid loading of the salt and prevented salt from contacting most of the interior surfaces of the sample generator, which eliminated cross-contamination between runs. The vacuum sampling-loop tube charging mechanism will support high-throughput tube sampling operations by employing a dynamic vacuum filling process to fill short charge tubes that are configured to be rapidly connected and disconnected from the loop. The dynamic vacuum sampling operation will be automated, and sample tube handling can be executed with simple overhead actuation. Because the modular sampling approach described here eliminates the need for new high-radiation sample handling capabilities, salt-wetted seals, salt-wetted moving parts, and heated transfer lines outside the electrorefiner, it will address most of the remaining technical challenges for the at-line deployment of high-precision analytical techniques which will enable significant reductions in the time delay for sampling-based high-precision accountancy measurements.

42 ENGINEERING↗
DOE OSTI2022

A long-life lithium-oxygen battery via a molecular quenching/mediating mechanism

The advancement of lithium-oxygen (Li-O 2 ) batteries has been hindered by challenges including low discharge capacity, poor energy efficiency, severe parasitic reactions, etc. We report an Li-O 2 battery operated via a new quenching/mediating mechanism that relies on the direct chemical reactions between a versatile molecule and superoxide radical/Li 2 O 2 . The battery exhibits a 46-fold increase in discharge capacity, a low charge overpotential of 0.7 V, and an ultralong cycle life >1400 cycles. Featuring redox-active 2,2,6,6-tetramethyl-1-piperidinyloxy moieties bridged by a quenching-active perylene diimide backbone, the tailor-designed molecule acts as a redox mediator to catalyze discharge/charge reactions and serves as a reusable superoxide quencher to chemically react with superoxide species generated during battery operation. The all-in-one molecule can simultaneously tackle issues of parasitic reactions associated with superoxide radicals, singlet oxygen, high overpotentials, and lithium corrosion. The molecular design of multifunctional additives combining various capabilities opens a new avenue for developing high-performance Li-O 2 batteries.

25 ENERGY STORAGE↗
NASA NTRS1983

Photographs of lightning from the Space Shuttle

The equipment used in the Nighttime Daytime Optical Survey of Lightning experiment, carried out on the second and fourth Space Shuttle missions, is described. Attention is then given to one of the more spectacular lightning photographs, that of a Y-shaped discharge taken by Thomas K. Mattingly II on the night of June 29, 1982, over southern Brazil. Since the orientation of the camera with respect to the earth is not known, the scale of the photograph cannot be determined accurately. If the camera had been looking directly down from the vehicle at its altitude of 300 km, the Y-shaped pattern would be approximately 60 km long and 40 km wide. If, as is thought probable, the camera was not looking directly down, the pattern would have somewhat greater dimensions. The photographs show that illumination from lightning discharges can cover a rather wide area.

Vonnegut, B.↗
NASA NTRS1984

Ion thruster performance model

A model of ion thruster performance is developed for high flux density, cusped magnetic field thruster designs. This model is formulated in terms of the average energy required to produce an ion in the discharge chamber plasma and the fraction of these ions that are extracted to form the beam. The direct loss of high energy (primary) electrons from the plasma to the anode is shown to have a major effect on thruster performance. The model provides simple algebraic equations enabling one to calculate the beam ion energy cost, the average discharge chamber plasma ion energy cost, the primary electron density, the primary-to-Maxwellian electron density ratio and the Maxwellian electron temperature. Experiments indicate that the model correctly predicts the variation in plasma ion energy cost for changes in propellant gas (Ar, Kr and Xe), grid transparency to neutral atoms, beam extraction area, discharge voltage, and discharge chamber wall temperature. The model and experiments indicate that thruster performance may be described in terms of only four thruster configuration dependent parameters and two operating parameters. The model also suggests that improved performance should be exhibited by thruster designs which extract a large fraction of the ions produced in the discharge chamber, which have good primary electron and neutral atom containment and which operate at high propellant flow rates.

Brophy, J. R.↗
NASA NTRS1975

Electrolyte concentration changes during operation of the nickel cadmium cell

The concentration and distribution of aqueous potassium hydroxide (KOH) electrolyte in a sealed nickel cadmium cell is considered. The reactions at both electrodes during charge and discharge involve the production or utilization of hydroxyl ion (OH) or water (H2O) which directly affects concentration. Changes in electrolyte concentration relative to the individual electrode reactions is discussed. Quantitative values are provided for the changes in concentration for 6, 12, and 20 ah cells with accepted quantities of precharge and accepted initial quantity of 31% aqueous KOH. Consideration is given to a more correct equation which includes net changes in hydroxyl concentration in addition to water. Also, expected concentrations of electrolyte in cells in the fully charged, 75% charged, 50% charged, 25% charged and discharged condition are calculated. The expected concentration changes for cells in the accelerated tests are also tabulated and compared with measured values. All calculations are made on the assumption that there are no side reactions. Various properties which depend on KOH concentration are listed. The variables include O2, H2, and Cd(OH)2 solubilities in addition to viscosity and conductivity.

Halpert, G.↗
DOE OSTI2024

Pilot-Scale Algal Oil Production

The main objective of the project is complete: development of a preliminary planning and design for a pilot-scale algal oil cultivation and processing facility, FEL-3 design with -5% / +15% cost estimate accuracy, and conversion of the algal oil to biofuel in an off-site existing bio-oil refinery. The design basis includes 10 tons per day of dried algae cultivated with CO 2 supplied by direct air capture, electricity supplied solar power, well water supply, zero liquid discharge, off-site extraction, and off-site conversion of oil to biofuel. The design and permitting package is an important milestone in the path to commercialization of algal biofuels and bioproducts as it provides the preliminary design, permitting path, long-term land lease, planning documents, and team needed for success in future engineering, construction, start-up and operations of a pilot-scale farm at a site in Paso Robles, CA. Outcomes of the business assessment include (i) identification of a product spectrum for economical algal biofuels using co-products with markets that are commensurate with production of 6-7 billion gallons per year of sustainable aviation fuel (SAF), renewable diesel, and renewable gasoline, (ii) a path toward near-term contribution of algae oil to SAF, and (iii) an approach for long-term operation of a pilot-scale farm.

09 BIOMASS FUELS↗
NASA NTRS1972

Ultraviolet atomic emission detector

A device and method are provided for performing qualitative and quantitative elemental analysis through the utilization of a vacuum UV chromatographic detector. The method involves the use of a carrier gas at low pressure. The gas carries a sample to a gas chromatograph column; the column output is directed to a microwave cavity. In this cavity, a low pressure microwave discharge produces fragmentation of the compounds present and generates intense atomic emissions in the vacuum ultraviolet. These emissions are isolated by a monochromator and measured by photometer to establish absolute concentration for the elements.

Braun, W.↗
NASA NTRS1972

Studies of the inner shelf and coastal sedimentation environment of the Beaufort Sea from ERTS-1

The author has identified the following significant results. Field studies of the initiation of river flow onto the frozen Arctic Ocean were made by a group of scientists from May 15 to June 10, 1972. A time lapse camera mounted on a 40-ft. tower near the mouth of the Kaparuk River, west of Prudhoe Bay, provided a detailed 10-day record (24 hours a day) of flow direction and water level. It is believed that wind build-up, discharge variance of the river, and through-ice drainage rates are the prime factors influencing overflow onto the sea ice. Current meter, transmissometer, temperature, salinity, and thermoprobe data were collected from holes drilled in the shorefast ice from seal holes and from the river water overflow. Depth and a real distribution of the overflow water were monitored from the ice using snowmobiles, and from the air using helicopters and fixed-wing aircraft. Photographic records were made on 35mm KII, KX, Ektachrome IR, Plus X, and IR black and white film. A simple two camera frame permitted simultaneous exposures of two types of film. Preliminary comparisons of the IR and conventional films, both color and black and white, showed no advantage to using the infrared film. However, the low altitude photography taken during this study will be very helpful in the interpretation of ERTS-1 imagery.

Reimnitz, E.↗
NASA NTRS1972

Dynamic behavior of coastal sedimentation in the Lions Gulf

The author has identified the following significant results. The most important result is that MSS 6 and 7 very clearly shows the former shorelines of the Rhone Delta and enable them to be mapped directly. Another result is the change in shape of the Var mouth discharge with changing meteorological conditions. If good photographs of the western part of the Gulf of Lions are available in the future, the GOLION project will be performed as planned.

Guy, M.↗
NASA NTRS1973

Energy distribution in parallel plate plasma accelerators

A parallel plate accelerator operated in the quasi-steady regime of argon mass flow discharges permits, on account of its geometry, the appraisal of the initial ratio of energy disposition into the kinetic and thermal modes of the plasma while retaining the essential features of coaxial high power self-field MPD accelerators. The energy disposition ratio, calculated as the ratio of kinetic energy to enthalpy in the exhaust flow, shows reasonable agreement with the ratio of the induced emf in the accelerator to resistive voltage drop. Both these ratios indicate that the discharge imparts more energy to the flow by resistive heating than by direct body force acceleration. This is turn suggests that other acceleration mechanisms must be responsible for the high performance of conventional MPD arcs.

Dicapua, M. S.↗
NASA NTRS1982

Investigation of possibilities for solar-powered high-energy lasers in space

Solar pumped lasers were investigated. The literature was reviewed for possible solar laser candidates from optical pumping experiments. A baseline CO electric discharge laser system was shown to be technically feasible. The most promising direct solar pumped laser was identified to be CF3I. Using the 'STAG' solar laser concept and CF3I, it was found that such a system could be weight competitive with the baseline CO laser system.

Source record↗
NASA NTRS1982

Optical measurement of the velocity of dielectric surface arcs

Surface flashover arc discharge velocities on electron-beam-charged polymer sheets have been measured directly by detecting the light emitted at two points along a straight arc and measuring the time interval between light pulses. For Mylar, the average velocity is 1.2 x 10 to the 6th m/s, and for Teflon the average velocity is approximately 7.3 x 10 to the 5th m/s independent of sheet thickness. These velocities are about two to four times higher than previous measurements. The techniques employed to produce single, straight surface arcs are described.

Balmain, K. G.↗
NASA NTRS1984

Deflagration plasma thruster

This paper introduces the application of the magnetized plasma deflagration process to space propulsion. The deflagration process has the unique capability of efficiently converting input energy into kinetic energy in the accelerating direction. To illustrate the totally divergent characters of 'snowplow' detonation and deflagration discharges, examples of the differences between deflagration and detonation 'snowplow' discharges are expressed in terms of current densities, temperature, and particle velocities. Magnetic field profiles of the deflagration mode of discharges are measured. Typical attainable plasma characteristics are described in terms of velocity, electron temperature, and density, as well as measurement techniques. Specific impulses measured by piezo-electric probe and pendulum methods are presented. The influence of the transmission line in the discharge circuits on plasma velocity is measured by means of a microwave time-of-flight method. The results for the deflagration thruster are compared with other space thrusters. Further research areas are identified.

Cheng, D. Y.↗
NASA NTRS1986

Space and time variability of the surface color field in the northern Adriatic Sea

A time series of coastal zone color scanner images for the years 1979 and 1980 was used to observe the spatial and temporal variability of bio-optical processes and circulation patterns of the northern Adriatic Sea on monthly, seasonal, and interannual scales. The chlorophyll-like pigment concentrations derived from satellite data exhibited a high correlation with sea truth measurements performed during seven surveys in the summer of both years. Comparison of the mean pigment fields indicates a general increase in concentration values and larger scales of coastal features from 1979 to 1980. This variability may be linked to the different patterns of nutrient influx due to coastal runoff in the 2 years. The distribution of surface features is consistent with the general cyclonic circulation pattern. The pigment heterogeneity appears to be governed by fluctuations of freshwater discharge, while the dominant wind fields do not appear to have important direct effects. The Po River presents a plume spreading predominantly in a southeastern direction, with scales positively correlated with its outflow. The spatial scales of the western coastal layer, in contrast, are negatively correlated with this outflow and the plume scales. Both results are consistent with, and may be rationalized by, recent theoretical and experimental results involving a dynamical balance between nonlinear advection and bottom friction, with alternate predominance of one of the two effects.

Barale, Vittorio↗
NASA NTRS1991

Compression, bend, and tension studies on forged Al67Ti25Cr8 and Al66Ti25Mn(g) L1(2) compounds

Cast, homogenized, and isothermally forged aluminum-rich L1(2) compounds Al67Ti25Cr8 and Al66Ti25Mn(g) were tested in compression as a function of temperature and as a function of strain rate at elevated temperatures (1000 K and 1100 K). Three-point bend specimens were tested as a function of temperature in the range 300 K to 873 K. Strain gages glued on the tensile side of the ambient and 473 K specimens enabled direct strain measurements. A number of 'buttonhead' tensile specimens were electro-discharge machined, fine polished, and tested between ambient and 1073 K for yield strength and ductility as a function of temperature. Scanning electron microscope (SEM) examination of fracture surfaces from both the bend and tensile specimens revealed a gradual transition from transgranular cleavage to intergranular failure with increasing temperature.

Kumar, K. S.↗
NASA NTRS2004

Modeling of Optical Waveguide Poling and Thermally Stimulated Discharge (TSD) Charge and Current Densities for Guest/Host Electro Optic Polymers

A charge density and current density model of a waveguide system has been developed to explore the effects of electric field electrode poling. An optical waveguide may be modeled during poling by considering the dielectric charge distribution, polarization charge distribution, and conduction charge generated by the poling field. These charge distributions are the source of poling current densities. The model shows that boundary charge current density and polarization current density are the major source of currents measured during poling and thermally stimulated discharge These charge distributions provide insight into the poling mechanisms and are directly related to E(sub A), and, alpha(sub r). Initial comparisons with experimental data show excellent correlation to the model results.

Watson, Michael D.↗