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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1950

Time histories of horizontal-tail loads, elevator loads, and deformations on a jet-powered bomber airplane during abrupt pitching maneuvers at approximately 20,000 feet

Time histories are presented of horizontal-tail loads, elevator loads, and deformations on a jet-powered bomber during abrupt pitching maneuvers at a pressure altitude of approximately 20,000 feet. The normal and pitching accelerations measured varied from -0.90b to 3.41g and from -0.73 to 0.80 radian per second per second (sic), respectively, with a Mach number variation of from 0.40 to o.75. The maximum horizontal-tail load measured was 17,250 pounds down. The maximum elevator load was 1900 pounds up. The stabilizer twisted a maximum of 0.76 degrees leading edge down at the tip. The greatest fuselage deflection at the tail was about 1.7 inches down.

Wiener, Bernard↗
NASA NTRS2009

Blended-Wing-Body Transonic Aerodynamics: Summary of Ground Tests and Sample Results

The Blended-Wing-Body (BWB) concept has shown substantial performance benefits over conventional aircraft configuration with part of the benefit being derived from the absence of a conventional empennage arrangement. The configuration instead relies upon a bank of trailing edge devices to provide control authority and augment stability. To determine the aerodynamic characteristics of the aircraft, several wind tunnel tests were conducted with a 2% model of Boeing's BWB-450-1L configuration. The tests were conducted in the NASA Langley Research Center's National Transonic Facility and the Arnold Engineering Development Center s 16-Foot Transonic Tunnel. Characteristics of the configuration and the effectiveness of the elevons, drag rudders and winglet rudders were measured at various angles of attack, yaw angles, and Mach numbers (subsonic to transonic speeds). The data from these tests will be used to develop a high fidelity simulation model for flight dynamics analysis and also serve as a reference for CFD comparisons. This paper provides an overview of the wind tunnel tests and examines the effects of Reynolds number, Mach number, pitch-pause versus continuous sweep data acquisition and compares the data from the two wind tunnels.

Carter, Melissa B.↗
NASA NTRS2011

Sloshing of the Magnetized Cool Gas in the Cores of Galaxy Clusters

X-ray observations of many clusters of galaxies reveal the presence of edges in surface brightness and temperature, known as "cold fronts". In relaxed clusters with cool cores, these edges have been interpreted as evidence for the "sloshing" of the core gas in the cluster's gravitational potential. The smoothness of these edges has been interpreted as evidence for the stabilizing effect of magnetic fields "draped" around the front surfaces. To check this hypothesis, we perform high-resolution magnetohydrodynamics simulations of magnetized gas sloshing in galaxy clusters initiated by encounters with subclusters. We go beyond previous works on the simulation of cold fronts in a magnetized intracluster medium by simulating their formation in realistic, idealized mergers with high resolution ((Delta)x approx. 2 kpc). Our simulations sample a parameter space of plausible initial magnetic field strengths and field configurations. In the simulations, we observe strong velocity shears associated with the cold fronts amplifying the magnetic field along the cold front surfaces, increasing the magnetic field strength in these layers by up to an order of magnitude, and boosting the magnetic pressure up to near-equipartition with thermal pressure in some cases. In these layers, the magnetic field becomes strong enough to stabilize the cold fronts against Kelvin-Helmholtz instabilities, resulting in sharp, smooth fronts as those seen in observations of real clusters. These magnetic fields also result in strong suppression of mixing of high and low-entropy gas in the cluster, seen in our simulations of mergers in the absence of a magnetic field. As a result, the heating of the core due to sloshing is very modest and is unable to stave off a cooling catastrophe.

ZuHone, J. A.↗
NASA NTRS1957

Some Effects of Bluntness on Boundary-Layer Transition and Heat Transfer at Supersonic Speeds

Large downstream movements of transition observed when the leading edge of a hollow cylinder or a flat plate is slightly blunted are explained in terms of the reduction in Reynolds number at the outer edge of the boundary layer due to the detached shock wave. The magnitude of this reduction is computed for cones and wedges for Mach numbers to 20. Concurrent changes in outer-edge Mach number and temperature occur in the direction that would increase the stability of the laminar boundary layer. The hypothesis is made that transition Reynolds number is substantially unchanged when a sharp leading edge or tip is blunted. This hypothesis leads to the conclusion that the downstream movement of transition is inversely proportional to the ratio of surface Reynolds number with blunted tip or leading edge to surface Reynolds number with sharp tip or leading edge. The conclusion is in good agreement with the hollow-cylinder result at Mach 3.1.

Moeckel, W E↗
NASA NTRS1953

A study of the use of leading-edge notches as a means for improving the low-speed pitching-moment characteristics of a thin 45-degree swept wing of aspect ratio 4

In an effort to develop a simple but effective means for controlling the stall progression of swept wings, a low-speed investigation has been undertaken primarily to determine the effectiveness of leading-edge notches. The investigation included consideration of notch size, location, and shape, as well as combined effects of notch—chord-extension and notch-fence arrangements. The wing used in the study had 45° quarter-chord sweep, aspect ratio 4, taper ratio 0.3, and NACA 65A006 airfoil sections streamwise. The results of the investigation indicated that although substantial improvements were obtained in the wing pitching-moment characteristics at moderate angles of attack, by use of outboard leading-edge notches, none of these notches produced desirable wing stability characteristics throughout the angle-of-attack range. The wing pitching-moment characteristics were relatively insensitive to notch size and to small changes in span-wise location. The use of a notch at the inboard end of a chord-extension increased the effectiveness of the chord-extension near stall and produced the same results as a chord-extension having an equivalent inboard overhang. Small localized notch—chord-extension combinations were found to produce the same pitching-moment characteristics as much larger chord-extension configurations. A leading-edge root cutout used in conjunction with a small outboard notch—chord-extension combination resulted in fairly desirable overall wing pitching-moment characteristics.

Joseph Weil↗
NASA NTRS1955

Longitudinal Stability and Control Characteristics as Determined by the Rocket-Model Technique for an Inline, Cruciform, Canard Missile Configuration with a Low-Aspect-Ratio Wing Having Trailing-Edge Flap Controls for a Mach Number Range of 0.7 to 1.8

Two full-scale models of an inline, cruciform, canard missile configuration having a low-aspect-ratio wing equipped with flap-type controls were flight tested in order to determine the missile's longitudinal aerodynamic characteristics. Stability derivatives and control and drag characteristics are presented for a range of Mach number from 0.7 to 1.8. Nonlinear lift and moment curves were noted for the angle-of-attack range of this test (0 deg to 8 deg ). The aerodynamic-center location for angles of attack near 5 deg remained nearly constant for supersonic speeds at 13.5 percent of the mean aerodynamic chord; whereas for angles of attack near O deg, there was a rapid forward movement of the aerodynamic center as the Mach number increased. At a control deflection of O deg, the missile's response to the longitudinal control was in an essentially fixed space plane which was not coincident with the pitch plane as a result of the missile rolling. As a consequence, stability characteristics were determined from the resultant of pitch and yaw motions. The damping-in-pitch derivatives for the two angle-of-attack ranges of the test are in close agreement and varied only slightly with Mach number. The horn-balanced trailing-edge flap was effective in producing angle of attack over the Mach number range.

Baber, H. T., Jr.↗
NASA NTRS1955

Longitudinal Stability and Control Characteristics as Determined by the Rocket-model Technique for an Inline, Cruciform, Canard Missile Configuration with a Low-aspect-ratio Wing Having Trailing-edge Flap Controls for a Mach Number Range of 0.7 to 1.

Two full-scale models of an inline, cruciform, canard missile configuration having a low-aspect-ratio wing equipped with flap-type controls were flight tested in order to determine the missile's longitudinal aerodynamic characteristics. Stability derivatives and control and drag characteristics are presented for a range of Mach number from 0.7 to 1.8. Nonlinear lift and moment curves were noted for the angle - of-attack range of this test (0 deg to 8 deg). The aerodynamic-center location for angles of attack near 50 remained nearly constant for supersonic speeds at 13.5 percent of the mean aerodynamic chord; whereas for angles of attack near 0 deg, there was a rapid forward movement of the aerodynamic center as the Mach number increased. At a control deflection of 0 deg, the missile's response to the longitudinal control was in an essentially fixed space plane which was not coincident with the pitch plane as a result of the missile rolling. As a consequence, stability characteristics were determined from the resultant of pitch and yaw motions. The damping-in-pitch derivatives for the two angle -of-attack ranges of the test are in close agreement and varied only slightly with Mach number. The horn-balanced trailing-edge flap was effective in producing angle of attack over the Mach number range.

Baber, Hal T , Jr↗
DOE OSTI2022

Using distributed power electronics-based devices to improve the voltage and frequency stability of distribution systems

Methods include, in response to a line frequency variation of a power grid, adjusting a voltage setpoint of a voltage regulator coupled to the power grid at a grid edge to maintain a voltage at the grid edge, wherein the adjusting the regulated voltage setpoint is configured to reduce the line frequency variation to stabilize the line frequency of the power grid. Apparatus include a voltage regulator configured to couple to a power grid at a grid edge and to maintain a voltage at the grid edge, wherein the voltage regulator is further configured to adjust a voltage setpoint of a voltage regulator in response to a line frequency variation of the power grid to reduce the line frequency variation and stabilize the line frequency of the power grid.

Du, Wei↗
DOE OSTI2024

Dislocation-Activated Low Platinum-Loaded PtCu Nanoparticles Welded onto the Substrate for Practical Acidic Hydrogen Generation

Although transition metal (M) alloying with platinum (Pt) is a promising approach to reduce the Pt dosage required in the hydrogen evolution reaction (HER), the catalytic activity and durability of PtM alloy are often unsatisfactory for acidic HER, especially at high currents, due to a reduced number of highly active sites (Pt) at the atomic level and challenges in stabilizing them to prevent detachment and aggregation. Herein, we report a robust functional structure integrated electrode (D-PtCu/CF) with abundant edge dislocations and very low platinum content (0.1 mg cm -2 ) to achieve high activity and stability in acidic HER within a proton exchange membrane water electrolysis cell (PEMWE). D-PtCu/CF exhibits high Pt mass activity (10.28 A mg Pt -1 ) and excellent operational stability (negligible decay after 200 h). X-ray absorption spectroscopy and in situ electrochemical experiments reveal that the lattice distortion caused by edge dislocations in PtCu mainly affects Pt atoms by compressing strain, reducing their ability to adsorb H. At the same time, Cu atoms are subjected to tensile strain, enhancing the bonding between Cu and H. Therefore, edge dislocations not only improve the intrinsic catalytic activity of Pt atoms but also increase the number of active sites (Cu) available for hydrogen adsorption, which synergistically accelerates the kinetics of the HER reaction. Finally, the PEMWE employing the D-PtCu/CF catalytic electrode can operate stably for 100 h at an industrial-level current density of 500 mA cm -2 with 1.63 V.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS1987

Wind-tunnel investigation of a full-scale general aviation airplane equipped with an advanced natural laminar flow wing

An investigation was conducted in the Langley 30- by 60-Foot Wind Tunnel to evaluate the performance, stability, and control characteristics of a full-scale general aviation airplane equipped with an advanced laminar flow wing. The study focused on the effects of natural laminar flow and advanced boundary layer transition on performance, stability, and control, and also on the effects of several wing leading edge modifications on the stall/departure resistance of the configuration. Data were measured over an angle-of-attack range from -6 to 40 deg and an angle-of-sideslip range from -6 to 20 deg. The Reynolds number was varied from 1.4 to 2.4 x 10 to the 6th power based on the mean aerodynamic chord. Additional measurements were made using hot-film and sublimating chemical techniques to determine the condition of the wing boundary layer, and wool tufts were used to study the wing stall characteristics. The investigation showed that large regions of natural laminar flow existed on the wing which would significantly enhance cruise performance. Also, because of the characteristics of the airfoil section, artificially tripping the wing boundary layer to a turbulent condition did not significantly effect the lift, stability, and control characteristics. The addition of a leading-edge droop arrangement was found to increase the stall angle of attack at the wingtips and, therefore, was considered to be effective in improving the stall/departure resistance of the configuration. Also the addition of the droop arrangement resulted in only minor increases in drag.

Murri, Daniel G.↗
DOE OSTI2021

Importance of resistivity on edge-localized mode onset in spherical tokamaks

In this work, we explore the impact of realistic plasma resistivity on the linear stability of peeling-ballooning (PB) modes in tokamak discharges with low-aspect ratio. For this study we consider discharges that are subject to edge-localized modes (ELMs) in the National Spherical Torus Experiment (NSTX). Employing the state of the art extended-magnetohydrodynamic (MHD) code M3D-C1 it is demonstrated that non-ideal effects can significantly affect PB stability thresholds in NSTX discharges. In particular, robust resistive PB modes are found to exist well before the ideal PB stability threshold is met. These novel results can explain why ideal-MHD theory often does not accurately describe ELM onset in spherical torus configurations, and also present a valuable basis for the development of a predictive model for ELMs in low-aspect ratio tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Site-specific electronic structure of covalently linked bimetallic dyads from nitrogen K-edge x-ray absorption spectroscopy

A nitrogen K-edge x-ray absorption near-edge structure (XANES) survey is presented for tetrapyrido[3,2-a:',3'-c:3'',2''-h:2''',3'''-j]phenazine (tpphz)-bridged bimetallic assemblies that couple chromophore and catalyst transition metal complexes for light driven catalysis, as well as their individual molecular constituents. We demonstrate the high N site sensitivity of the N pre-edge XANES features, which are energetically well-separated for the phenazine bridge N atoms and for the individual metal-bound N atoms of the inner coordination sphere ligands. By comparison with the time-dependent density functional theory calculated spectra, we determine the origins of these distinguishable spectral features. We find that metal coordination generates large shifts toward higher energy for the metal-bound N atoms, with increasing shift for 3d < 4d < 5d metal bonding. This is attributed to increasing ligand-to-metal σ donation that increases the effective charge of the bound N atoms and stabilizes the N 1s core electrons. In contrast, the phenazine bridge N pre-edge peak is found at a lower energy due to stabilization of the low energy electron accepting orbital localized on the phenazine motif. While no sensitivity to ground state electronic coupling between the individual molecular subunits was observed, the spectra are sensitive to structural distortions of the tpphz bridge. Here these results demonstrate N K-edge XANES as a local probe of electronic structure in large bridging ligand motifs, able to distinctly investigate the ligand-centered orbitals involved in metal-to-ligand and ligand-to-ligand electron transfer following light absorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Reconfiguring the band-edge states of photovoltaic perovskites by conjugated organic cations

The band edges of metal-halide perovskites with a general chemical structure of ABX 3 (A, usually a monovalent organic cation; B, a divalent cation; and X, a halide anion) are constructed mainly of the orbitals from B and X sites. Hence, the structural and compositional varieties of the inorganic B–X framework are primarily responsible for regulating their electronic properties, whereas A-site cations are thought to only help stabilize the lattice and not to directly contribute to near-edge states. We report a π-conjugation–induced extension of electronic states of A-site cations that affects perovskite frontier orbitals. The π-conjugated pyrene-containing A-site cations electronically contribute to the surface band edges and influence the carrier dynamics, with a properly tailored intercalation distance between layers of the inorganic framework. Lastly, the ethylammonium pyrene increased hole mobilities, improved power conversion efficiencies relative to that of a reference perovskite, and enhanced device stability.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Effect of CO 2 on the water slip flow at silica surfaces for nanometer slit pores of talc

In our previous study, Molecular Dynamics (MD) simulated water flow with no dissolved gas in nanometer slit pores of the hydrophobic talc surfaces revealed a slip length of about 0.5 nm, which is close to the size of “water exclusion zone” but much less than experimental slip length. Atomic Force Microscopy (AFM) imaging confirmed the presence of pancake shape nanobubbles at the hydrophobic talc (001) surface (size from tens to hundreds of nanometers). The effect of CO 2 on water slip flow in talc nanopores is reported to reveal the importance of dissolved gas for confined fluid flow. MD simulated 7 nm CO 2 nanobubbles were found to attach and spread at the talc (001) surface, consistent with the AFM observation. Simulated CO 2 saturated water flow in the slit pores of talc (001) surfaces predicted the generation of CO 2 nanobubbles at the end of the slit pore, due to the stabilization of a CO 2 film at the talc (001) surfaces and a water barrier at the edge surfaces of talc. A “critical thickness” of about 1.5 nm was found for CO 2 nanobubbles to be stabilized at the end of the talc (001) surface. With 1.5 nm CO 2 nanobubbles at the talc (001) surface of a 6 nm slit pore, a water slip length of 1.8 nm was determined. Furthermore, the nanometer slit pore simulations with dissolved CO 2 in water revealed an increased slip length. It is expected that an increased slip length value would be found with an increased CO 2 film thickness.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Boosting the H 2 –D 2 Exchange Activity of Dilute Nanoporous Ti–Cu Catalysts through Oxidation–Reduction Cycle–Induced Restructuring

The use of nanoporous metals as catalysts has attracted significant interest in recent years. Their high-curvature, nanoscale ligaments provide not only high surface area but also a high density of undercoordinated step edge and kink sites. However, their long-term stability, especially at higher temperatures, is often limited by thermal coarsening and the associated loss of surface area. Herein, it is demonstrated that the nanoscale morphology of nanoporous Cu can be regenerated by applying oxidation/reduction cycles at 250 °C. Specifically, the morphological evolution and H 2 dissociation activity of hierarchical nanoporous Cu catalysts doped with Ti during structural rearrangement triggered by oxidative and reductive atmospheres at elevated temperatures are studied. In addition to coarsening of the structure at elevated temperatures, oxidation at 400 °C causes an expansion of the ligaments. Further, subsequent reduction at 400 °C leads to the formation of particles and a drop in the H 2 dissociation activity compared the fresh catalyst. However, performing the redox cycle at 250 °C reverses coarsening and boosts the H 2 dissociation activity for the hydrogen–deuterium (H 2 –D 2 ) reaction. Herein, the possibility to reverse coarsening is demonstrated, thereby mitigating the loss of activity frequently observed in nanoporous catalysts.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Mechanistic study of direct coupling of CO 2 and C 2 H 4 over atomically dispersed metal at graphene edges

Direct coupling of CO 2 and ethylene (hereinafter DCCE) to acrylic acid is valuable for valorizing CO 2 to manufacture acrylate-derived products. However, previous studies in DCCE have been limited on molecular catalysts with challenges in improving catalytic performance. In this work, we employed density functional theory calculations and ab initio molecular dynamics simulations to investigate the heterogeneous catalysis of DCCE over atomically dispersed metal centers at nitrogen-doped zigzag edge of graphene. Based on competitive adsorption and structural stability, Mo, Cr, V, Ru, and Ni active sites are chosen to explore the reaction kinetics. Here, we find that the activation barriers are determined by the charge redistribution at transition states, which explains the trend of activity for the C-C coupling and the hydrogen transfer, two key steps in DCCE. Furthermore, we show that the intramolecular hydrogen transfer (rate-limiting step) is hindered due to the lack of local coordinate at the active sites. We thus propose to use co-adsorbed water as a “proton-exchanger” following a water-assisted route, and show that the activation barriers are reduced over all metal centers. Particularly, water promotes the hydrogen transfer over metals with strong CO 2 -ethylene co-activation and facile C-C coupling kinetics, which could be considered promising for DCCE. In both mechanisms, the stability of metallactone intermediate can be used to predict the catalytic activity. It is anticipated that the insights from this work can provide guidelines for mimicking well-defined multifunctional active sites in molecular catalysts to design heterogeneous catalysts for such C-C coupling, which advances catalytic utilization of CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗