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At least 253 records · Page 14

Elucidating the Role of Electric Fields in Fe Oxidation via an Environmental Atom Probe

We quantify the effects of intensely applied electric fields on the Fe oxidation mechanism. The specimen are pristine Fe single crystals exposing a variety of surface structures identified by field ion microscopy. These crystals are simultaneously exposed to low pressures of pure oxygen gas, on the order of 10 −7 mbar, while applying intense electric fields on their surface of several tens of volts per nanometer. The local composition of the different surface structures is probed directly and in real time using an Environmental Atom Probe and successfully compared with first principles-based models. We found that rough Fe{244} and Fe{112} facets are more reactive toward oxygen than compact Fe{024} and Fe{011} facets. Results demonstrate that the influence of an electric field on the oxidation kinetics depends on the timescales that are involved as the system evolves toward equilibrium. The initial oxidation kinetics show that strong increases in electric fields facilitate the formation of an oxide. However, as one approaches equilibrium, high field values mitigate this formation. Ultimately, this study elucidates how high externally applied electric fields can be used to dynamically exploit reaction dynamics at the nanoscale towards desired products in a catalytic reaction at mild reaction conditions.

09 BIOMASS FUELS↗

Electric fields and convection velocities associated with flux transfer events

A survey of the electric field and (E x B)/B-squared convection velocities associated with 23 flux transfer events (FTEs) in the magnetosheath and magnetosphere is presented. Twelve-second averaged electric field data show perturbations in the component of the electric field perpendicular to the magnetopause, with an average magnitude of 3.5 mV/m associated with the FTEs. Direct flux transfer events have a northward, and reverse flux transfer events a southward, E x B velocity component, in agreement with the current FTE model. The flux tubes moved across the magnetopause plane at an average E x B speed of 125 km/s with respect to the ambient E x B flow, with events located on the dawn (dusk) side tending to move downward (duskward). No large spiky electric fields of the type observed elsewhere in the magnetosphere were detected.

Dailey, R.↗

Electric field variations during substorms: OGO-6 measurements

The OGO-6 electric field measurements make it clear that the general pattern of high latitude electric fields in magnetic time-invariant latitude coordinates is not highly variable and that when unusual variations, or field distributions, occur they are relatively isolated in time and spatial extent. Thus, electric field changes on a global scale cannot, in general, be evoked as a direct cause of substorms. Polar traverses along the 18(h) to 6(h) magnetic time meridian show that the sum of potential drops across the evening auroral belt and morning auroral belt approximately equals the potential drop across the polar cap. The integrated polar cap potential drop ranges from 20 to 100 keV and values in the center of this range are most common under conditions of moderate magnetic disturbance. Roughly near 18(h) magnetic local time, a latitudinally narrow strip at the transition between auroral belt and polar cap fields exhibits unusually large field fluctuations immediately following the sudden onset of a negative bay at later magnetic local times. It appears likely that this spatially isolated correlation is related to an effect rather than a cause of substorm enhancement.

Heppner, J. P.↗

Dielectric screening and electric field control of ferromagnetism at the CaMnO 3 /CaRuO 3 interface

Control of magnetism by an applied electric field is a desirable technique for the functionalization of magnetic materials. Motivated by recent experiments, we study the electric field control of the interfacial magnetism of CaRuO 3 /CaMnO 3 (CRO/CMO) (001), a prototype interface between a non-magnetic metal and an antiferromagnetic insulator. Even without the electric field, the interfacial CMO layer acquires a ferromagnetic moment due to a spin-canted state, caused by the Anderson-Hasegawa double exchange (DEX) between the Mn moments and the leaked electrons from the CRO side. An electric field would alter the carrier density at the interface, leading to the possibility of controlling the magnetism, since DEX is sensitive to the carrier density. We study this effect quantitatively using density-functional calculations in the slab geometry. We find a text-book like dielectric screening of the electric field, which introduces polarization charges at the interfaces and the surfaces. The extra charge at the interface enhances the ferromagnetism via the DEX interaction, while away from the interface the original AFM state of the Mn layers remains unchanged. The effect could have potential application in spintronics devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electric field mill network products to improve detection of the lightning hazard

An electric field mill network has been used at Kennedy Space Center for over 10 years as part of the thunderstorm detection system. Several algorithms are currently available to improve the informational output of the electric field mill data. The charge distributions of roughly 50 percent of all lightning can be modeled as if they reduced the charged cloud by a point charge or a point dipole. Using these models, the spatial differences in the lightning induced electric field changes, and a least squares algorithm to obtain an optimum solution, the three-dimensional locations of the lightning charge centers can be located. During the lifetime of a thunderstorm, dynamically induced charging, modeled as a current source, can be located spatially with measurements of Maxwell current density. The electric field mills can be used to calculate the Maxwell current density at times when it is equal to the displacement current density. These improvements will produce more accurate assessments of the potential electrical activity, identify active cells, and forecast thunderstorm termination.

Maier, Launa M.↗

Electric Potential and Electric Field Imaging with Applications

The technology and techniques for remote quantitative imaging of electrostatic potentials and electrostatic fields in and around objects and in free space is presented. Electric field imaging (EFI) technology may be applied to characterize intrinsic or existing electric potentials and electric fields, or an externally generated electrostatic field may be used for (illuminating) volumes to be inspected with EFI. The baseline sensor technology, electric field sensor (e-sensor), and its construction, optional electric field generation (quasistatic generator), and current e-sensor enhancements (ephemeral e-sensor) are discussed. Demonstrations for structural, electronic, human, and memory applications are shown. This new EFI capability is demonstrated to reveal characterization of electric charge distribution, creating a new field of study that embraces areas of interest including electrostatic discharge mitigation, crime scene forensics, design and materials selection for advanced sensors, dielectric morphology of structures, inspection of containers, inspection for hidden objects, tether integrity, organic molecular memory, and medical diagnostic and treatment efficacy applications such as cardiac polarization wave propagation and electromyography imaging.

Generazio, Ed↗

Observations of large magnetospheric electric fields during the onset phase of a substorm

An auroral substorm is a highly transient process which is triggered on auroral L shells and leads to an abrupt change of state in the nightside magnetosphere. Direct measurements of electric fields in the outer magnetosphere are of critical importance to understand the processes involved in sudden substorm enhancements. Shepard et al. (1980) reported direct measurements of electric fields from the GEOS 2 satellite at equatorial latitudes which showed 15 mV/m westward inductive electric fields in association with tail collapses. Similar direct electric field measurements of the westward inductive electric field at low latitudes from the ISEE 1 satellite during the onset phase of an auroral substorm are reported in the present investigation. The observations show a rapid inward magnetic field (westward electric field) motion near midnight at low or equatorial latitudes simultaneous with the sudden onset of auroral substorm enhancements near the foot of the satellite field line.

Aggson, T. L.↗

Bubble Detachment in Variable Gravity Under the Influence of Electric Fields

The objective of the research is to investigate the behavior of individual air bubbles injected through an orifice into an electrically insulating liquid under the influence of a static electric field. Situations were considered with both uniform and nonuniform electric fields. Bubble formation and detachment were visualized in terrestrial gravity as well as for several levels of reduced gravity (lunar, martian and microgravity) using a high-speed video camera. Bubble volume, dimensions and contact angles at detachment were measured. In addition to the experimental studies, a simple model, predicting bubble characteristics at detachment in an initially uniform electric field was developed. The model, based on thermodynamic considerations, accounts for the level of gravity as well as the magnitude of the uniform electric field. The results of the study indicate that the level of gravity and the electric field magnitude significantly affect bubble behavior as well as shape, volume and dimensions.

Herman, Cila↗

Conductivity and electric field variations with altitude in the stratosphere

Data regarding electric field, derived current density, and conductivity are presented for two balloons from the Electrodynamics of the Middle Atmosphere experiment which underwent the longest period of daily altitude variation. The magnetic L values range from 4.3 to 9.5 for the 18 days of Southern Hemisphere statistics, and the average conductivity and vertical electric fields are given. Simultaneous measurements of the average conductivity scale height and the vertical electric-field scale height indicate that vertical current density does not vary with altitude in the 10-28-km range. The measured conductivity varies significantly at a given altitude on a particular day, and some conductivity data sets are similar to other measurements between 10 and 30 km. Comparisons of the measured data to predictions from models of stratospheric conductivity demonstrate significant discrepancies.

Holzworth, Robert H.↗

A model for polar cap electric fields

A model is proposed relating polar cap ionospheric electric fields to the parameters of the solar wind near the orbit of the earth. The model ignores the notion of field line merging. An essential feature is the role played by velocity shear instabilities in regions of the outer magnetosphere, in which mapping of the magnetosheath electric field would produce sunward convection. The anomalous resistivity which arises from velocity shear turbulence, suffices to essentially disconnect the magnetosphere from the magnetosheath, at any place where that resistivity is large enough. The magnetosheath-magnetosphere system, as a consequence, acts as a kind of diode or rectifier for the magnetosheath electric fields. Predictions of the model are compared with several observations related to polar cap convection.

Dangelo, N.↗

Motions of charged particles in the Magnetosphere under the influence of a time-varying large scale convection electric field

The motions of charged particles under the influence of the geomagnetic and electric fields were quite complex in the region of the inner magnetosphere. The Volland-Stern type large scale convection electric field was used successfully to predict both the plasmapause location and particle enhancements determined from Explorer 45 measurements. A time dependence in this electric field was introduced based on the variation in Kp for actual magnetic storm conditions. The particle trajectories were computed as they change in this time-varying electric field. Several storm fronts of particles of different magnetic moments were allowed to be injected into the inner magnetosphere from L = 10 in the equatorial plane. The motions of these fronts are presented in a movie format.

Smith, P. H.↗

Analyzing Electric Field Morphology Through Data-Model Comparisons of the GEM IM/S Assessment Challenge Events

The storm-time inner magnetospheric electric field morphology and dynamics are assessed by comparing numerical modeling results of the plasmasphere and ring current with many in situ and remote sensing data sets. Two magnetic storms are analyzed, April 22,2001 and October 21-23,2001, which are the events selected for the Geospace Environment Modeling (GEM) Inner Magnetosphere/Storms (IM/S) Assessment Challenge (IMSAC). The IMSAC seeks to quantify the accuracy of inner magnetospheric models as well as synthesize our understanding of this region. For each storm, the ring current-atmosphere interaction model (RAM) and the dynamic global core plasma model (DGCPM) were run together with various settings for the large-scale convection electric field and the nightside ionospheric conductance. DGCPM plasmaspheric parameters were compared with IMAGE-EUV plasmapause extractions and LANL-MPA plume locations and velocities. RAM parameters were compared with Dst*, LANL-MPA fluxes and moments, IMAGE-MENA images, and IMAGE-HENA images. Both qualitative and quantitative comparisons were made to determine the electric field morphology that allows the model results to best fit the plasma data at various times during these events. The simulations with self-consistent electric fields were, in general, better than those with prescribed field choices. This indicates that the time-dependent modulation of the inner magnetospheric electric fields by the nightside ionosphere is quite significant for accurate determination of these fields (and their effects). It was determined that a shielded Volland-Stern field description driven by the 3-hour Kp index yields accurate results much of the time, but can be quite inconsistent. The modified Mcllwain field description clearly lagged in overall accuracy compared to the other fields, but matched some data sets (like Dst*) quite well. The rankings between the simulations varied depending on the storm and the individual data sets, indicating that each field description did well for some place, time, and energy range during the events, as well as doing less well in other places, times, and energies. Several unresolved issues regarding the storm-time inner magnetospheric electric field are discussed.

Liemohn, Michael W.↗

Quantifying the Impact of Electric Fields on the Local Structure and Migration of Potassium Ions at the Orthoclase (001) Surface

Developing an understanding of the response of mineral/water interfaces to applied electric fields is central to detecting and interpreting signatures of interfacial processes in the subsurface. Here we focus density functional theory calculations on understanding K + cation binding and diffusion across the (001) surface of orthoclase feldspar under various applied electric fields with and without surface hydration. The calculations reveal how water ligands labilize surface K + cations for diffusion while also increasing their sensitivity to electric field effects on the binding energy at different surface sites. The calculations also show how the direction and strength of the electric field systematically affect surface cation mobility, sorption, and hydration behavior. Specifically, electric fields directed toward the surface increase the potassium binding energies, facilitate K + diffusion across multiple binding sites, and increase the propensity of surface K + ions to lose their hydration shells. Furthermore, the findings help fill a major knowledge gap into the impact of electric fields on mineral/water interface structure and dynamics more generally, featuring in this case a commonly found type of feldspar involved in a multitude of atmospheric and geochemical processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elucidating the Role of Electric Fields in Fe Oxidation via an Environmental Atom Probe

Abstract We quantify the effects of intensely applied electric fields on the Fe oxidation mechanism. The specimen are pristine Fe single crystals exposing a variety of surface structures identified by field ion microscopy. These crystals are simultaneously exposed to low pressures of pure oxygen gas, on the order of 10 −7 mbar, while applying intense electric fields on their surface of several tens of volts per nanometer. The local composition of the different surface structures is probed directly and in real time using an Environmental Atom Probe and successfully compared with first principles‐based models. We found that rough Fe{244} and Fe{112} facets are more reactive toward oxygen than compact Fe{024} and Fe{011} facets. Results demonstrate that the influence of an electric field on the oxidation kinetics depends on the timescales that are involved as the system evolves toward equilibrium. The initial oxidation kinetics show that strong increases in electric fields facilitate the formation of an oxide. However, as one approaches equilibrium, high field values mitigate this formation. Ultimately, this study elucidates how high externally applied electric fields can be used to dynamically exploit reaction dynamics at the nanoscale towards desired products in a catalytic reaction at mild reaction conditions.

Lambeets, Sten V. [Physical and Computational Scie↗

Generation of a Strong Parallel Electric Field and Embedded Electron Jet in the Exhaust of Moderate Guide Field Reconnection

Abstract Magnetospheric Multiscale observed an extended current layer concurrent with a strong parallel electric field. The current layer is embedded in the reconnection exhaust and is consistent with an extended magnetized jet expected in roughly symmetric moderate guide field reconnection. The strong parallel electric field observed at the jet balances a strong gradient in the parallel electron pressure caused by a transition between magnetized electrons with T e ‖ > T e ⊥ on one side of the jet and demagnetized, roughly isotropic electrons across the thin current layer. Simulation results show how this transition can occur and how the associated electron pressure gradients in Ohm's law balance the parallel electric field.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Pulsed Electric Field Processing of Apples

Pulsed electric field (PEF) processing is a nonthermal technology that has the potential to improve the efficiency of apple processing, particularly for firm cultivars that are growing in popularity. This study evaluated the effects of PEF pretreatment on the processability and product quality of Cosmic Crisp apples, a modern cultivar known for its firmness. Apples were treated with PEF and assessed for tissue softening, mechanical energy requirements, particle size reduction, browning tendencies, and juice yield. PEF treatment significantly softened the apple tissue, as demonstrated by reduced compression forces in Instron testing, and this softening translated to decreased grinding energy during applesauce production. There were no changes to the particle size distribution of the resulting applesauce. PEF treatment also altered browning behavior and produced higher juice yields following mechanical disruption, suggesting enhanced membrane permeability and mass transfer. Together, these results show that PEF pretreatment can reduce mechanical energy demands and increase extractability without reducing product quality in firm apple varieties. These outcomes highlight the potential of PEF to increase the value recovered from processing-grade apples and to support more efficient and sustainable apple processing operations.

32 - ENERGY CONSERVATION, CONSUMPTION, AND UTILIZA↗

Investigating Electric Field and Light Induced Degradation in Perovskite Solar Cells through Nanometer-Scale Potential Imaging

Electric field and light induced degradations in perovskite solar cells were evaluated through nanometer-scale potential imaging across the device by using in-situ Kelvin probe force microscopy (KPFM). We derived the electric field profile from potential profiles at different bias voltages to evaluate the locations and quality of junctions across the device. We found relative changes in electric field peak intensity at the HTL/perovskite and perovskite/ETL interfaces upon stressing devices separately under voltage or light. KPFM results during 12-hour stress/rest cycling under electrical bias show both reversible and irreversible changes in the device's interfacial fields. We also observed change in the electric field profile between control and degraded devices after 100 hours of stress/rest cycling under light. Our results demonstrate how nanometer-scale potential imaging can be used to understand the impacts of external electric fields and light soaking on both irreversible degradation and reversible metastability in perovskite solar cells.

Kelvin probe force microscopy↗

A new source of horizontal electric fields in the mid-latitude stratosphere

Superpressure balloon-borne instruments that measure the vector stratospheric electric field at latitudes near 45 + or - 10 deg S reveal several features in fair weather that cannot be attributed to ionospheric, thunderstorm, or other known sources. Over 180 days of electric field, conductivity, and current density data have been taken at the constant altitude of 26 km, using long-duration balloon flights in the Southern Hemisphere. Throughout these data the fair-weather horizontal electric field has a magnitude (10-50 mV/m) that cannot be due to mid-latitude ionospheric dynamo action. Furthermore, the fields are highly variable in amplitude, almost turbulent in appearance, while the vector direction steadily rotates in a counterclockwise manner. The period of this rotation is close to the quasi-inertial wave period for the latitude of the balloon. For these flights, the electric field rotation period varies between 14 and 21 hours. Some possible causes that might explain the electric field and current measurements reported herein are discussed.

Holzworth, R. H.↗