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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Generation of plasma waves by thick-target electron beams, and the expected radiation signature

The production of plasma waves by a nonthermal beam of high-energy electrons injected into a background thermal plasma was investigated. The coupled kinetic equations for nonthermal electrons were solved, and the level of the plasma waves produced by the bump-on-tail instability arising as a result of the Coulomb collisions of nonthermal electrons with background plasma was estimated. In addition, the radiation signatures of these waves were examined. It is shown that the wave-particle interactions have a significant effect on the overall distribution of the electrons and that it is unlikely that such effects can be discerned in the observed bremsstrahlung or synchrotron radiation of the nonthermal electrons. However, a significant fraction of the energy lost by the beam is transferred to plasma waves and is then dissipated by the thermal plasma.

Hamilton, Russell J.↗
NASA NTRS1989

The Hard X-rays and Gamma-rays from Solar Flares

Radiation of energies from 10 KeV to greater than 10 MeV has been observed during solar flares, and is interpreted to be due to bremsstrahlung by relativistic electrons. A complete treatment of this problem requires solution of the kinetic equation for relativistic electrons and inclusion of synchrotron energy losses. Using the electron distributions obtained from numerical solutions of this equation the bremsstrahlung spectra in the impulsive x ray and gamma-ray regimes are calculated, and the variation of these spectral indices and directivities with energy and observation angle are described. The dependences of these characteristics of the radiation of changes in the solar atmospheric model, including the convergence of the magnetic field, the injected electron spectral index, and most importantly, in the anisotropy of the injected electrons and of the convergence of the magnetic field are also described. The model results are compared with stereoscopic observations of individual flares and the constraints that this data sets on the models are discussed.

Mctiernan, James M.↗
NASA NTRS1990

The hard X-rays and gamma rays from solar flares

Radiation of energies from 10 KeV to greater than 10 MeV has been observed during solar flares, and is interpreted to be due to bremsstrahlung by relativistic electrons. A complete treatment of this problem requires solution of the kinetic equation for relativistic electrons and inclusion of synchrotron energy losses. Using the electron distributions obtained from numerical solutions of this equation the bremsstrahlung spectra in the impulsive X-ray and gamma ray regimes are calculated, and the variation of these spectral indices and directivities with energy and observation angle are described. The dependences of these characteristics of the radiation of changes in the solar atmospheric model, including the convergence of the magnetic field, the injected electron spectral index, and most importantly, in the anisotropy of the injected electrons and of the convergence of the magnetic field are also described. The model results are compared with stereoscopic observations of individual flares and the constraints that this data sets on the models are discussed.

Mctiernan, James M.↗
NASA NTRS2017

Wave-Particle Energy Exchange Directly Observed in a Kinetic Alfven-Branch Wave

Alfven waves are fundamental plasma wave modes that permeate the universe. At small kinetic scales they provide a critical mechanism for the transfer of energy between electromagnetic fields and charged particles. These waves are important not only in planetary magnetospheres, heliospheres, and astrophysical systems, but also in laboratory plasma experiments and fusion reactors. Through measurement of charged particles and electromagnetic fields with NASAs Magnetospheric Multiscale (MMS) mission, we utilize Earths magnetosphere as a plasma physics laboratory. Here we confirm the conservative energy exchange between the electromagnetic field fluctuations and the charged particles that comprise an undamped kinetic Alfven wave. Electrons confined between adjacent wave peaks may have contributed to saturation of damping effects via non-linear particle trapping. The investigation of these detailed wave dynamics has been unexplored territory in experimental plasma physics and is only recently enabled by high-resolution MMS observations.

magnetohydrodynamic↗
DOE OSTI2024

Surface science insight note: Optimizing XPS instrument performance for quantification of spectra

X-ray photoelectron spectroscopy (XPS) provides quantitative information from photoemission peaks and shapes observed within the background due to the inelastic scattering of photoelectrons. To quantify the signal, both photoemission peaks and background in spectra must be adjusted for instrumental transmission variations that are a consequence of changes in efficiency when recording electrons with different kinetic energy. While it is generally assumed that correcting spectroscopic data for transmission is a necessary part of quantification by XPS, there are consequences for the quantification of spectra measured using an instrument for which transmission has significant curvature. In this Insight, the implications of curvature in transmission characteristics are discussed and a method based on XPS microscopy is proposed that ensures the transmission response of an instrument is free from significant curvature. An example of an instrument for which a flat transmission response is presented is achieved through collecting spectra using lens modes designed to measure stigmatic images.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Electrolyte-Induced Restructuring of Acid-Stable Oxygen Evolution Catalysts

Crystalline metal oxide catalysts operating under oxygen evolution reaction (OER) conditions invariably restructure, resulting in active sites with hydroxo/oxo species in an amorphous environment. An increase in the population of terminal hydroxo/oxo species (i.e., edge sites) facilitates proton-coupled electron-transfer (PCET) kinetics for oxygen generation and thus improves catalyst competency. While amorphous films benefit from a greater density of active sites, they suffer from diminished charge transport as compared to that of extended crystalline lattices. Managing this amorphous–crystalline dichotomy is essential when designing OER catalysts, which we highlight with the examination of electrodeposited PbO x materials, which historically are very poor OER catalysts. Along these lines, the presence of phosphate during PbO x electrodeposition truncates the growth of an extended lattice owing to its strong bonding to oxide surfaces to afford an amorphous catalyst film (A-PbO x ) with significant charge-transfer resistance (138 ± 42 Ω) and poor OER kinetics (420 ± 105 mV dec –1 Tafel slope). Conversely, electrodeposition of Pb 2+ in the presence of less coordinating electrolytes such as nitrate affords crystalline β-PbO2 with improved charge-transfer resistance (42.6 ± 1.1 Ω), though still poor OER kinetics (134 ± 36 mV dec –1 Tafel slope). By operating amorphous A-PbOx in less coordinating electrolytes, however, a new partially crystalline material can be generated (μc-PbO x ) with further reduced charge-transfer resistance (33.0 ± 1.4 Ω) and improved OER kinetics (70 ± 15 mV dec –1 Tafel slope). The enhanced OER activity of μc-PbO x is the result of coupling the high edge-site population of an amorphous PbOx phase with crystalline-like charge transport properties. Finally, the ability to use an electrolyte to induce OER activity in an inactive amorphous form of PbO x highlights the benefits of optimizing the amorphous–crystalline phase compositions in the design of active OER catalysts.

catalysts↗
DOE OSTI2025

Microstructurally Strained Pyrochlore–Perovskite Biphasic Electrocatalysts for the Oxygen Evolution Reaction

Efficiency of water splitting for hydrogen production is often limited by the sluggish kinetics of multiple electronic transfers required in the heterogeneous oxygen evolution reaction (OER). Catalyst design for reducing the high OER overpotential remains a major scientific challenge. Lattice-strain engineering, a method for tuning the electronic structure and surface geometric configuration of active sites, may greatly affect the interaction between adsorbates and catalytic surfaces for high activity and stability. Here, in this study, we present the synthesis of biphasic oxides of YPrSrRuMnO x , which consists of distinct phases of Y 2 Ru 2 O 7 pyrochlore and (Pr 0.7 Sr 0.3 )MnO 3 perovskite, and the development of a suitable analytical approach to study the strain–catalytic property relationship. Linear sweep voltammetry results reveal that the biphasic oxide exhibits approximately 3.1 times greater mass activity and 2.4 times larger turnover frequency (TOF) than single-phase Y 2 Ru 2 O 7 in the 0.1 M HClO 4 electrolyte. The biphasic catalyst is also about 3 times more stable than the single-phase oxide under acidic conditions. X-ray photoelectron spectroscopy, nitrogen isotherm, and electrochemical surface area analyses indicate that the oxidation state, specific surface area, and electrochemical surface area do not cause enough difference in the observed enhancement of OER performance. We examined the effects of microstrain on electrocatalysis, originating from lattice mismatch between different phases, using three different structural models. Specifically, we compared the Williamson–Hall method, standard stress–strain analysis, and Rietveld refinement in analyzing the structure–property relationship. Strain mapping using geometric phase analysis (GPA) further revealed significant microstrain and lattice dislocations localized near phase boundaries in the biphasic oxide, in contrast to the uniform strain in single-phase materials. The results reveal that the increased microstrain correlates well with the improved OER performance, as the biphasic oxide catalyst exhibits 2–3 times greater microstrain than Y 2 Ru 2 O 7 pyrochlore.

electrocatalysts↗
DOE OSTI2024

New millimeter-wave diagnostics to locally probe internal density and magnetic field fluctuations in National Spherical Torus Experiment-Upgrade (invited)

A set of new millimeter-wave diagnostics will deliver unique measurement capabilities for National Spherical Torus Experiment-Upgrade to address a variety of plasma instabilities believed to be important in determining thermal and particle transport, such as micro-tearing, global Alfvén eigenmodes, kinetic ballooning, trapped electron, and electron temperature gradient modes. These diagnostics include a new integrated intermediate-k Doppler backscattering (DBS) and cross-polarization scattering (CPS) system (four channels, 82.5–87 GHz) to measure density and magnetic fluctuations, respectively. The system can access reasonably large normalized wavenumbers k θ ρ s ranging from ≤0.5 to 15 (where ion sound gyroradius ρ s = 1 cm and k θ is the binormal density turbulence wavenumber). The system addresses the challenges for making useful DBS/CPS measurements with a remote control of launch polarization (X- or O-mode), probed wavenumber, polarization match of the launch beam with the edge magnetic field pitch angle, and beam steering of the launched beam for wave-vector alignment. In addition, a low-k DBS system consisting of eight fixed frequencies (34–52 GHz) and four tunable frequencies (55–75 GHz) for low-k density turbulence and fast ion physics will be located at a nearby port location. Finally, the combined systems cover the near LCFS and pedestal regions (34–52 GHz), the pedestal or mid-radius (50–75 GHz), and core plasmas (82.5–87 GHz).

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Collaborative Research: Vlasov–Maxwell Simulations to resolve electron heating and dissipation, in quasiperpendicular shocks (Final Technical Report)

The project is to study electron heating at quasi-perpendicular shocks. We have analyzed measurements from the Magnetosphere Multiscale (MMS) spacecraft and particle-in-cell simulations to address the question. One key discovery is that waves and are excited in the shock transition region, which further develop into complicated structures and thin current layers, which contribute to accelerate and heat electrons. We further investigated the excitation and evolution of these waves and structures, and their association with ion and electron dynamics. In addition, the analysis technique of Vlasov equation terms is further applied to study electron dynamics at the dayside magnetopause, to understand the effect of density, velocity and temperature variations on electron distributions and kinetics.

58 GEOSCIENCES↗
DOE OSTI2024

A Bottom-Up Approach to Rational Design of Crystalline Materials: Investigation of Vibronic Coherences Underlying Exciton Dynamics in Semiconductors

In this project we uncovered structure-function relationships of donor-acceptor co-crystals used to develop next-generation optoelectronic devices. Unraveling the photodynamics of molecular crystalline materials poses many challenges for spectroscopy due to broad, overlapping features representing numerous underlying dynamical processes. This leads researchers to make many assumptions about the dynamics of a system in choosing an appropriate kinetic fitting model. Computationally, electronic structure methods are either prohibitively expensive or underdeveloped for computing the excited state structure of molecular materials, especially states that exhibit charge transfer. Researchers must therefore perform calculations of excited electronic states using truncated models of molecular materials. Here we present a joint experimental-theoretical approach to bridging the gap between the photodynamics of a molecular material and its constituent molecules. We focus our efforts on quantifying the timescales and mechanisms of photoexcitation in donor-acceptor co-crystals and donor-acceptor dimers where the lowest-lying excited state is characterized by charge transfer from the donor to the acceptor. We employ ultrafast UV pump, UV-Vis probe transient absorption spectroscopy to unravel the time-resolved spectroscopic signatures of the photodynamics in both the crystalline material and donor-acceptor dimers in solution. We perform electronic structure and excited state dynamics calculations of the dimers to inform kinetic fitting models and assign the spectral features. The photodynamics of the crystal vs. dimer systems have many similarities, enabling unprecedented insights into the formation and evolution of charge transfer excitons in the crystalline systems.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Theory and experiment of low transitions in CO discharge lasers

A self-consistent model which couples the kinetics of the electrons and heavy particles with the optical and fluid dynamic processes has been employed to identify the various parameters and explain the mechanism responsible for producing low-lying transitions in slow-flowing CO lasers. Both theory and experiment indicate that low-lying transitions can be achieved at low temperatures for low pressures (or low-flow rates) together with high partial pressures of He and N2. The role of N2 has been identified as an additive responsible for reducing the electron temperature to a range where the transfer of electrical power to the lower vibrational modes of CO is optimum.

Sidney, B.↗
NASA NTRS1977

Factors affecting ion kinetic temperature, number density, and containment time in the NASA Lewis bumpy-torus plasma

The degree of toroidal symmetry of the plasma, the number of midplane electrode rings, the configuration of electrode rings, and the location of the diagnostic instruments with respect to the electrode rings used to generate the plasma are discussed. Impurities were deliberately introduced into the plasma, and the effects of the impurity fraction on ion kinetic temperature and electron number density were observed. It is concluded that, if necessary precautions are taken, the plasma communicates extremely well along the magnetic field lines and displays a high degree of symmetry from sector to sector for a wide range of electrode ring configurations and operating conditions. Finally, some characteristic data taken under nonoptimized conditions are presented, which include the highest electron number density and the longest particle containment time (1.9 msec) observed. Also, evidence from a paired comparison test is presented which shows that the electric field acting along the minor radius of the toroidal plasma improves the plasma density and the calculated containment time more than an order of magnitude if the electric field points inward, relative to the values observed when it points (and pushes ions) radially outward.

Roth, J. R.↗
NASA NTRS1980

Particle energization in the inner, nonazimuthally symmetric magnetospheres of neutron stars

The energization process of magnetic pumping, a combination of time dependent magnetic mirror fields with pitch-angle scattering, is applied to trapped charged particles drifting in corotating, azimuthally nonsymmetric neutron star magnetospheres. When particle energization is balanced by synchrotron radiation loss, it is found that protons, rather than electrons, reach considerable kinetic energies and radiate, in the X-ray regime, at rates up to the 10 to the 6th power MeV/proton/sec.

Borovsky, J. E.↗
NASA NTRS1984

Impact cratering: The process and its effects on planetary evolution

The potential for silicate-carbon dioxide reactions as a geochemical weathering agent on Venus was studied. A tholetitic basalt close to the composition determined by the XRF experiment at the Venera 14 sites was subjected to high temperature and pressure (with pure CO2 as the pressure medium) for varying time durations. The starting basalt material and the run products were examined optically and by X-ray diffraction and electron microscopy. The kinetics of the silicate-carbonate reactions is discussed. A study to elucidate details of impact processes and to assess the effects of impact cratering on planetary evolution is mentioned.

Grieve, R. A. F.↗
NASA NTRS1986

Signatures of current loop coalescence in solar flares

The nonlinear coalescence instability of current carrying solar loops can explain many of the characteristics of the solar flares such as their impulsive nature, heating and high energy particle acceleration, amplitude oscillations of electromagnetic emission as well as the characteristics of 2-D microwave images obtained during a solar flare. The physical characteristics of the explosive coalescence of currents are presented in detail through computer simulation and theory. Canonical characteristics of the explosive coalescence are: (1) a large amount of impulsive increase of kinetic energies of electrons and ions; (2) simultaneous heating and acceleration of electrons and ions in high and low energy spectra; (3) ensuing quasi-periodic amplitude oscillations in fields and particle quantities; and (4) the double peak (or triple peak) structure in these profiles, participate in the coalescence process, yielding varieties of phenomena.

Sakai, J.↗
NASA NTRS1987

The formation of a double layer leading to the critical velocity phenomenon

The formation of a double layer is proposed as the mechanism which produces the critical velocity phenomenon. This hypothesis was examined qualitatively and it was found that the double layer can be a very efficient mechanism for transferring the kinetic energy of the neutral gas into the kinetic energy of electrons which, in turn, will ionize the neutral gas if the critical velocity was reached or exceeded.

Williams, A. C.↗
NASA NTRS1986

Analysis of coronal H I Lyman-alpha measurements in a polar region of the sun observed in 1979

Measurements of the intensities and spectral line profiles of resonantly scattered hydrogen Ly-alpha radiation have been used to determine hydrogen kinetic temperatures and electron densities between r = 1.5 and 2.2 solar radii in a polar region of the corona observed in 1979 near solar maximum. The mean temperature, 1.8 x 10 to the 6th K, in this region is significantly higher, by about 60 percent, than that obtained in a similar region observed in a 1980 rocket flight. The densities in these two polar regions are similar and are a factor of about 4 larger than in polar coronal holes observed at solar minimum. The flow velocities in both regions are most likely subsonic for r less than about 4 solar radii. The results reported here support the hypothesis that polar coronal holes observed at different times during the solar cycle can have different temperatures, densities, and possibly flow velocities.

Withbroe, G. L.↗
NASA NTRS1987

The formation of a double layer leading to the critical velocity phenomenon

The formation of a double layer is proposed as the mechanism which produces the critical velocity phenomenon. This hypothesis is examined qualitatively, and it is found that the double layer can be a very efficient mechanism for transferring the kinetic energy of the neutral gas into the kinetic energy of electrons which, in turn, will ionize the neutral gas if the critical velocity has been reached or exceeded.

Williams, A. C.↗