SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Multilayer beam splitter system yielding nearly equal broadband infrared reflectance and transmittance in the 5 to 50 micron spectral region has been developed which will significantly reduce size and cost of light path compensating devices in infrared spectral instruments.
The translucent nature of ceramic oxide thermal barrier coatings (TBCs) provides an opportunity to employ optical probes to monitor temperature gradients and buried damage propagation within the coating. An important advantage of noncontact optical diagnostics is that they are amendable to health monitoring of TBCs in service. In this paper, two optical diagnostic approaches, operating in different wavelength regimes, are discussed. The first approach is the use of mid-infrared reflectance (MIR) to monitor the progression of TBC delamination produced by thermal cycling. This approach takes advantage of the maximum transparency of the TBCs at mid-infrared wavelengths, in particular, between 3 and 5 microns. Recent progress in extending the MIR method to a more practical visual inspection tool will be presented. A second approach, using visible wavelengths, is the embedding of thermographic phosphors within the TBC to add sensing functions to the coating that can provide depth-selective information about temperature gradients and TBC integrity. Emphasis will be given to the use of fluorescence decay time measurements to provide temperature readings from a thermographic phosphor layer residing beneath the TBC.
Net ecosystem CO2 exchange was measured during the 1990 growing season (June to August) along a transect starting 10 km inland from James Bay and extending 100 km interior to Kinosheo Lake, Ontario. Sites were chosen in three distinct areas: a coastal fen, an interior fen, and a bog. For the most productive sites in the bog, net daily uptake rates reached a maximum of 2.5 g C-CO2 m(exp -2)/d with an area-weighted exchange of 0.3 g C-CO2 m(exp -2)/d near midsummer. This site was estimated to be a net carbon source of 9 g C-CO2 m(exp -2) to the atmosphere over a 153-day growing season. The interior fen was less productive on a daily basis with a net maximum uptake of 0.5 g C-CO2 m(exp -2)/d and with corresponding area-weighted uptake of 0.1 g C-CO2 m(exp -2)/d during midsummer. Early and late season release of carbon to the atmosphere resulted in a net loss of 21 g C-CO2 m(exp -2) over the growing season from this site. The coastal fen was the most productive site with uptake rates peaking near 1.7 g C-CO2 m(exp -2)/d which corresponded to an area-weighted uptake of 0.8 g C-CO2 m(exp -2)/d during midsummer and an estimated net uptake of 6 g C-CO2 m(exp -2) for the growing season. Associated with net CO2 exchange measurements, multispectral reflectance properties of the sites were measured over the growing season using portable radiometers. These properties were related to exchange rates with the goal of examining the potential for satellite remote sensing to monitor biosphere/atmosphere CO2 exchange in this biome. The normalized difference vegetation index (NDVI) computed from surface reflectance was correlated with net CO2 exchange for all sites with the exception of areas with large proportions of Sphagnum moss cover. These mosses have greater near-infrared reflectance than typical surrounding vegetation and may require special adjustment for regional exchange/remote sensing applications.
The SOC 400 Surface Inspection Machine/Infrared (SIMIR) is a small, ruggedized Fourier transform infrared spectrometer having dedicated diffuse reflectance optics. The SOC 400 was designed for the purpose of detecting (qualitatively and quantitatively) oil stains on the inside surface of solid rocket motor casings in the as-sandblasted and cleaned condition at levels approaching 1 mg. sq ft. The performance of this instrument is described using spectral mapping techniques.
We demonstrate the use of inbred imaging to locate crystals mounted in cryoloops and cryopreserved in a nitrogen gas stream at 100K. In the home laboratory crystals are clearly seen in the infrared images with light transmitting through the sample while irradiating the crystal from behind, and with illumination from a direction perpendicular to the direction of view. The crystals transmit and reflect infrared radiation differently from the surrounding mother liquor and loop. Because of differences in contrast between crystals and their surrounding mother liquor, it is possible to clearly identify the crystal position. In use at the synchrotron, with robotically mounted crystals the small depth of field of the lens required the recording of multiple images at different focal points. Image processing techniques were then used to produce a clear image of the crystal. The resulting infrared images and intensity profiles show that infrared imaging can be a powerful complement to visual imaging in locating crystals in cryocooled loops.
During the past six years several thousand reflectance spectra of corn, soybean, and wheat canopies were acquired and analyzed. The relationships of biophysical variables, including leaf area index, percent soil cover, chlorophyll and water content, to the visible and infrared reflectance of canopies are described. The effects on reflectance of cultural, environmental, and stress factors such as planting data, seeding rate, row spacing, cultivar, soil type and nitrogen fertilization are also examined. The conclusions are that several key agronomic variables including leaf area index, development stage and degree of stress are strongly related to spectral reflectance and that it should be possible to estimate these descriptions of crop condition from satellite acquired multispectral data.
We report results from a recent field experiment to test the validity of using physics-based synthetic infrared spectra to serve as endmembers in a spectral database targeted at chemical deposits. Specifically, the optical constants n and k, (the real and imaginary part of the refractive index) were used to first model infrared reflectance spectra for different thicknesses of chemical layers (e.g. acetaminophen, methylphosphonic acid – MPA, etc.) on various conducting and insulating substrates such as aluminum, wood, and glass. In the experimental portion of the research, thin films of the solid and liquid analytes were deposited onto such substrates to form micron-thick layers of the analytes at different thicknesses: Standoff data from an imaging instrument were then recorded and analyzed to not only identify the different analytes, but also quantify the layer/deposit thickness. To gauge success, the detection results using the synthetic data were compared to the results from hemispherical reflectance (HRF) spectra that were collected for the same sample planchets measured in the field via standoff methods. Preliminary results indicate good agreement between the synthetic reference data as compared to the lab-measured HRF data in terms of their ability to quantitatively reduce longwave infrared data. Specifically, modeled IR spectra for acetaminophen on an aluminum planchet at various thicknesses (1, 2, 5, 10, 15, and 20 µm) were synthesized and compared with standoff field reflectance data as well as HRF laboratory reflectance spectra for two samples: a 5.2 µm- and 12.8 µm-thick layer of acetaminophen on aluminum. Using a first-order approximation, analysis of the field data estimates the thicknesses of the samples to be 2 and 10 µm for the two samples, respectively, while the HRF laboratory data yields thickness estimates of between 5-10 µm and 10 µm, respectively. Both yield reasonable estimates, with the uncertainty most likely due to factors yet to be accounted for in the synthetic spectra such as light scattering.
A pseudo-Brewster-angle infrared radiometer has been proposed for use in noncontact measurement of the surface temperature of a large body of water (e.g., a lake or ocean). This radiometer could be situated on a waterborne, airborne, or spaceborne platform. The design of the pseudo-Brewster-angle radiometer would exploit the spectral-emissivity and polarization characteristics of water to minimize errors attributable to the emissivity of water and to the reflection of downwelling (e.g., Solar and cloud-reflected) infrared radiation. The relevant emissivity and polarization characteristics are the following: . The Brewster angle is the angle at which light polarized parallel to the plane of incidence on a purely dielectric material is not reflected. The pseudo-Brewster angle, defined for a lossy dielectric (somewhat electrically conductive) material, is the angle for which the reflectivity for parallel-polarized light is minimized. For pure water, the reflectivity for parallel-polarized light is only 2.2 x 10(exp -4) at its pseudo- Brewster angle of 51deg. The reflectivity remains near zero, several degrees off from the 51deg optimum, allowing this angle of incidence requirement to be easily achieved. . The wavelength range of interest for measuring water temperatures is 8 to 12 microns. The emissivity of water for parallel- polarized light at the pseudo-Brewster angle is greater than 0.999 in this wavelength range. The radiometer would be sensitive in the wavelength range of 8 to 12 microns, would be equipped with a polarizer to discriminate against infrared light polarized perpendicular to the plane of incidence, and would be aimed toward a body of water at the pseudo- Brewster angle (see figure). Because the infrared radiation entering the radiometer would be polarized parallel to the plane of incidence and because very little downwelling parallel-polarized radiation would be reflected into the radiometer on account of the pseudo-Brewster arrangement, the radiation received by the radiometer would consist almost entirely of thermal emission from the surface of the water. Because the emissivity of the water would be very close to 1, the water could be regarded as a close approximation of a blackbody for the purpose of computing its surface temperature from the radiometer measurements by use of the Planck radiation law.
A brief assessment of remote sensing applied to geological studies is given. An analysis of thematic mapping data on oak-hickory forests in southern Missouri is discussed. It was found that there is a control on the infrared reflectance (bands 4, 5, and 7 of the Thematic Mapper (TM) of the forests that correlates with rock and soil types. During the growing season, soils with low water retention capacities correlate with high infrared (band 4, lesser with band 5 and 7) signatures. A metamorphic core complex called the Meatiq located in the Eastern Desert of Egypt was studied. The dome provides exposure of most of the rock units of the Arabian-Nubian Precambrian Shield. The dome bears many resemblances to Cordilleran metamorphic complexes. LANDSAT TM data was used to improve on reconnaissance maps of the dome. The remote sensing data was interpreted in the context of field observations, petrographic, and chemical analysis of rock units in the dome, in order to map similar domes in the Eastern Desert from TM data. Mapping projects such as the one just described will help constrain the geologic evolution of the Arabian-Nubian Shield. Two particular hypotheses that researchers hope to test for the development of the shield are: (1) closure of a proto-Red Sea; and (2) accretion of a primitive island arc system onto the shield.
The author has identified the following significant results. Reflectance characteristics of agronomic crops are of major importance in the energy exchanges of a surface. In addition, unique reflectance patterns may be an aid in crop identification by means of remote sensing. This study suggests that the ratio of the reflectances of the 545-nm to to the 655-nm wavebands provides information about the viewed surface, regardless of the crop. The reflectance ratio is less than unity early and late in the growing season. For all crops studied, the ratio closely followed crop growth and development and appeared to be more desirable than the near-infrared reflectance as an index of growth.
Detailed biomass and structure measurements as well as photosynthetically active radiation (PAR) balance and bidirectional and polarized reflectances in various wavebands from 450 nm to 1750 nm have been conducted over a sunflower canopy in France. Preliminary results show that the vegetation indices (NDVI or TSAVI) computed from the red and near-infrared reflectances exhibit strong directional and temporal (variation with the sun zenith angle) features. The relationship between the vegetation indices and the PAR fraction absorbed or intercepted by the canopy is likely to vary greatly with these factors.
Here, we present an infrared spectroscopy study of the layered topological semimetal TaNiTe 5 , a material with a quasi-one-dimensional structure and strong in-plane anisotropy. Despite its structural features, infrared reflectivity and electronic transport measurements along the 𝑎 and 𝑐 crystallographic axes show metallic behavior without evidence of reduced dimensionality. Optical conductivity reveals an anisotropic but conventional metallic response with low scattering rates and a single sharp infrared-active phonon mode at 396cm −1 (49meV). Ab initio calculations closely match the experimental optical data and confirm a three-dimensional electronic structure. Our results demonstrate that TaNiTe 5 behaves as a three-dimensional anisotropic semimetal in its electronic and optical properties.
Thin films of the metals Cu, Ni, Pt, Au, Sn, Mo, and W deposited on fused silica flats were exposed at ambient temperature on the leading and trailing faces of the LDEF. Reflectances of these films were measured from 250 to 2500 nm and compared with controls. The exposed films were subjected to the LDEF external environment including atomic oxygen, molecular contamination, and solar ultraviolet. Major changes in optical and infrared reflectance were seen for Cu, Mo, Ni, and W films on the leading face of LDEF and are attributed to partial conversion of metal to metal oxide. Smaller changes in optical properties are seen on all films and are probably caused by thin contaminant films deposited on top of the metal. The optical measurements are correlated with film thickness measurements, x-ray photoelectron spectroscopy, optical calculations, and, in the case of Cu, with x-ray diffraction measurements. In a few cases, comparisons with results from a similar UAH experiment on STS-8 have been drawn.
The seasonality of sunlight and rainfall regulates net primary production in tropical forests. Previous studies have suggested that light is more limiting than water for tropical forest productivity, consistent with greening of Amazon forests during the dry season in satellite data.We evaluated four potential mechanisms for the seasonal green-up phenomenon, including increases in leaf area or leaf reflectance, using a sophisticated radiative transfer model and independent satellite observations from lidar and optical sensors. Here we show that the apparent green up of Amazon forests in optical remote sensing data resulted from seasonal changes in near-infrared reflectance, an artefact of variations in sun-sensor geometry. Correcting this bidirectional reflectance effect eliminated seasonal changes in surface reflectance, consistent with independent lidar observations and model simulations with unchanging canopy properties. The stability of Amazon forest structure and reflectance over seasonal timescales challenges the paradigm of light-limited net primary production in Amazon forests and enhanced forest growth during drought conditions. Correcting optical remote sensing data for artefacts of sun-sensor geometry is essential to isolate the response of global vegetation to seasonal and interannual climate variability.
The Chandeleur Islands are the first line of defense against tropical storms and hurricanes for coastal Louisiana. They provide habitats for birds species and are a wildlife refuge; however, distressingly, they are eroding and transgressing at an alarming rate. In 1998, Hurricane Georges caused severe damage to the chain, prompting restoration and monitoring efforts by both Federal and State agencies. Since then, storm events have steadily diminished the condition of the islands. Quantification of shoreline erosion, vegetation, and land loss, from 1979 to 2009, was achieved through the analysis of imagery from Landsat 2-4 Multispectral Scanner, Landsat 4 & 5 Thematic Mapper, and Advanced Spaceborne Thermal Emission and Reflection Radiometer sensors. QuickBird imagery was used to validate the accuracy of these results. In addition, this study presents an application of Moderate Resolution Imaging Spectroradiometer data to assist in tracking the transgression of the Chandeleur Islands. The use of near infrared reflectance calculated from MOD09 surface reflectance data from 2000 to 2009 was analyzed using the Time Series Product Tool. The scope of this project includes not only assessments of the tropical cyclonic events during this time period, but also the effects of tides, winds, and cold fronts on the spatial extent of the islands. Partnering organizations, such as the Pontchartrain Institute for Environmental Research, will utilize those results in an effort to better monitor and address the continual change of the island chain.
The tree canopy characterization presented herein provided ground and tree canopy data for different types of tree canopies in support of EO-1 reflective and thermal infrared validation studies. These characterization efforts during August and September of 2001 included stem and trunk location surveys, tree structure geometry measurements, meteorology, and leaf area index (LAI) measurements. Measurements were also collected on thermal and reflective spectral properties of leaves, tree bark, leaf litter, soil, and grass. The data presented in this report were used to generate synthetic reflective and thermal infrared scenes and images that were used for the EO-1 Validation Program. The data also were used to evaluate whether the EO-1 ALI reflective channels can be combined with the Landsat-7 ETM+ thermal infrared channel to estimate canopy temperature, and also test the effects of separating the thermal and reflective measurements in time resulting from satellite formation flying.
Remote sensing of the Martian surface from the ground and from orbiting spacecraft has provided some first-order insight into the mineralogical-chemical composition and the weathering state of Martian surface materials. Much more detailed information can be gathered from performing such measurements in situ at the landing sites or from a rover in combination with analogous measurements from orbit. Measurements in the wavelength range of approximately 0.3 to 12.0 micrometers appear to be suitable to characterize much of the physical, mineralogical, petrological, and chemical properties of Martian surface materials and the weathering and other alteration processes that have acted on them. It is of particular importance to carry out measurements at the same time over a broad wavelength range since the reflectance signatures are caused by different effects and hence give different and complementing information. It appears particularly useful to employ a combination of active and passive methods because the use of active laser spectroscopy allows the obtaining of specific information on thermal infrared reflectance of surface materials. It seems to be evident that a spectrometric survey of Martian materials has to be focused on the analysis of altered and fresh mafic materials and rocks, water-bearing silicates, and possibly carbonates.
Recent progress in satellite observations has provided unprecedented opportunities to monitor vegetation activity at global scale. However, a major challenge in fully utilizing remotely sensed data to constrain land surface models (LSMs) lies in inconsistencies between simulated and observed quantities. For example, gross primary productivity (GPP) and transpiration (T) that traditional LSMs simulate are not directly measurable from space, although they can be inferred from spaceborne observations using assumptions that are inconsistent with those LSMs. In comparison, canopy reflectance and fluorescence spectra that satellites can detect are not modeled by traditional LSMs. To bridge these quantities, we presented an overview of the next generation land model developed within the Climate Modeling Alliance (CliMA), and simulated global GPP, T, and hyperspectral canopy radiative transfer (RT; 400–2,500 nm for reflectance, 640–850 nm for fluorescence) at hourly time step and 1° spatial resolution using CliMA Land. CliMA Land predicts vegetation indices and outgoing radiances, including solar-induced chlorophyll fluorescence (SIF), normalized difference vegetation index (NDVI), enhanced vegetation index (EVI), and near infrared reflectance of vegetation (NIRv) for any given sun-sensor geometry. The spatial patterns of modeled GPP, T, SIF, NDVI, EVI, and NIRv correlate significantly with existing data-driven products (mean R 2 = 0.777 for 9 products). CliMA Land would be also useful in high temporal resolution simulations, for example, providing insights into when GPP, SIF, and NIRv diverge.