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At least 253 records · Page 14

Development of an automated potable water bactericide monitoring unit

A monitor unit has been developed that permits the direct determination of the level of elemental iodine, used for microbiological control, in a spacecraft potable water supply system. Salient features of unit include low weight, volume and maintenance requirements, complete automatic operation, no inflight calibration, no expendables (except electrical current) and high accuracy and precision. This unit is capable of providing a signal to a controller that, in turn, automatically adjusts the addition rate of iodine to the potable water system so that a predetermined level of iodine can be maintained. In addition, the monitor provides a reading whereby the crewman can verify that the proper amount of iodine (within a range) is present in the water. A development history of the monitor is presented along with its design and theory of operation. Also presented are the results generated through testing of the unit in a simulated Shuttle potable water system.

Walsh, J. M.↗

Regenerating Water-Sterilizing Resins

Iodine-dispensing resin can be regenerated after iodine content has been depleted, without being removed from water system. Resin is used to make water potable by killing bacteria, fungi, and viruses. Regeneration technique may be come basis of water purifier for very long space missions. Enough crystalline iodine for multiple regenerations during mission can be stored in one small cartridge. Cartridge could be inserted in waterline as necessary on signal from iodine monitor or timer.

Colombo, G. V.↗

Defect chemistry and characterization Hg(1-x)Cd(x)Te

Iodine doped single crystal samples of mercury cadmium telluride were annealed at temperatures varying from 450 C to 600 C in Hg vapor and quenched to room temperature. Hall effect measurements at 77 K on the crystals cooled to room temperature indicate the samples to be n-type after anneals at high Hg pressures whereas they turn p-type after anneals at low Hg pressures; the electron concentration increases with increase in Hg pressure. The results are explained on the basis that the crystals are saturated with (Hg,Cd)I2, with a fraction of the iodine being present as donor occupying tellurium lattice sites and a fraction being present as acceptors resulting from the iodine on tellurium lattice sites pairing with the doubly ionized native acceptor defects. The solubility of the donor species increases with increase in Hg pressure, whereas that of the acceptor species increases with decrease in Hg pressure. Equilibrium constants for the incorporation of the iodine species as well as the pairing reaction were established.

Vydyanath, H. R.↗

Thin-film chemical sensors based on electron tunneling

The physical mechanisms underlying a novel chemical sensor based on electron tunneling in metal-insulator-metal (MIM) tunnel junctions were studied. Chemical sensors based on electron tunneling were shown to be sensitive to a variety of substances that include iodine, mercury, bismuth, ethylenedibromide, and ethylenedichloride. A sensitivity of 13 parts per billion of iodine dissolved in hexane was demonstrated. The physical mechanisms involved in the chemical sensitivity of these devices were determined to be the chemical alteration of the surface electronic structure of the top metal electrode in the MIM structure. In addition, electroreflectance spectroscopy (ERS) was studied as a complementary surface-sensitive technique. ERS was shown to be sensitive to both iodine and mercury. Electrolyte electroreflectance and solid-state MIM electroreflectance revealed qualitatively the same chemical response. A modified thin-film structure was also studied in which a chemically active layer was introduced at the top Metal-Insulator interface of the MIM devices. Cobalt phthalocyanine was used for the chemically active layer in this study. Devices modified in this way were shown to be sensitive to iodine and nitrogen dioxide. The chemical sensitivity of the modified structure was due to conductance changes in the active layer.

Khanna, S. K.↗

Comparison of laser models

Progress on the comparison of laser models is reported. Equations for an oscillatory model and a nonoscillatory model for the simulation of iodine laser operation are solved. Reaction rate coefficients used in both models are listed. Currently there are four models for the simulation of iodine laser operation are solved. Reaction rate coefficients used in both models are listed. Currently there are four models for the simulation of an iodine laser. They are: (1) a time dependent model; (2) a quasi-steady state model; (3) a noncompressible model; and (4) a compressible flow laser model. Current research is being directed toward: (1) parameter studies using the compressible flow laser model; (2) development of a two-pass amplifier model; and (3) solving a system of equations describing operation of the high powered iodine MOPA (master oscillator power amplifier).

Heinbockel, John H.↗

A 10-watt CW photodissociation laser with IODO perfluoro-tert-butane

NASA has been investigating the feasibility of direct solar-pumped laser systems for power beaming in space. Among the various gas, liquid, and solid laser systems being proposed as candidates for solar-pumped lasers, the iodine photodissociation gas laser has demonstrated its potential for space application. Of immediate attention is the determination of system requirements and the choice of lasants to improve the system efficiency. The development of an efficient iodine laser depends on the availability of a suitable iodide which has favorable laser kinetics, chemically reversibility, and solar energy utilization. Among the various alkyliodide lasants comparatively tested in a long-pulse system, perfluoro- tert-butyl iodide, T-C4F9I, was found to be the best. However, the operating conditions for the laser medium in a continuously pumped and continuous-flow iodine laser differ considerably from those in the pulsed regime. The results of the continuous wave (CW)) laser performance from t-C4F9I are reported. Perfluoro- n-propyl iodide, n-C3F7I is used for comparison because of its universal use in photodissociation iodine lasers.

Tabibi, Bagher↗

A Program to Detect and Characterize Extra-Solar Giant Planets

We initiated a significant hardware upgrade to the AFOE, to increase its efficiency for precise radial velocity studies to the level where we can continue to contribute usefully to extrasolar planet research on relatively bright stars. The AFOE, at a 1.5-m telescope, will of course not have the sensitivity of radial velocity instruments at larger telescopes, such as the HIRES on Keck or the Hectochelle on the MMT telescope (about to come on line). However, it has been possible to increase its efficiency for precise radial velocity studies by a factor of 4 to 5, which-combined with the large amount of telescope time available at the 1.5-m telescope-will permit us to do intensive follow-up observations of stars brighter than about 8 magnitude. The AFOE was originally designed primarily for asteroseismology using a ThAr reference. This provided useful wavelength stability over tens of minutes as required for asteroseismology, but we were unable to get a long-term (month-to-month) velocity precision better than about 15 m/s with that setup. Hence, we implemented an iodine cell as a wavelength reference for extrasolar planet studies. However, the optical design of the original AFOE did not completely span the wavelength range covered by the iodine absorption spectrum, and furthermore the optics suffered significant light loss through optical obscuration in the camera secondary. To remedy this, we replaced the AFOE grating with a new one that covered the entire iodine spectral range at somewhat lower spectral resolution, and replaced the camera with a transmitting lens. (The use of a lens was made possible by restricting the spectral range covered by the upgraded AFOE to only the iodine region.) These upgrades were successfully completed, and the instrument was tested for three nights in fall of 2002. The expected improvement in sensitivity by a factor of 4 to 5 was observed: that is, the same velocity precision as previously attained (of order 5 to 7 m/s) was now obtained on a stars that are about 4 to 5 times fainter. Unfortunately, just after installing the new AFOE optics, there was a catastrophic failure of the old Tektronix CCD. A careful investigation was made, and it was determined that the failure was probably due to too many thermal cyclings over the previous 8 years. The only solution was to purchase a new CCD. Internal funds of $16,000 were found for this purpose, and the new CCD (a thinned, back-illuminated Marconi 2K x 2K device with 13.5 micron pixels, and employing dual readout channels to keep the readout time as short as 20 seconds) was ordered, has now arrived, and is currently under test before 1 being installed in the AFOE liquid nitrogen dewar. At the same time, we expect to implement new CCD control electronics. This system should be better in many ways than the previous detector (including eliminating the need for UV flashing to maximize the quantum efficiency). We plan to install the detector on the telescope and begin operations again in April of this year.

Lindstrom, David↗

Self-Passivating Lithium/Solid Electrolyte/Iodine Cells

Robust lithium/solid electrolyte/iodine electrochemical cells that offer significant advantages over commercial lithium/ iodine cells have been developed. At room temperature, these cells can be discharged at current densities 10 to 30 times those of commercial lithium/iodine cells. Moreover, from room temperature up to 80 C, the maximum discharge-current densities of these cells exceed those of all other solid-electrolyte-based cells. A cell of this type includes a metallic lithium anode in contact with a commercial flexible solid electrolyte film that, in turn, is in contact with an iodine/ graphite cathode. The solid electrolyte (the chemical composition of which has not been reported) offers the high ionic conductivity needed for high cell performance. However, the solid electrolyte exhibits an undesirable chemical reactivity to lithium that, if not mitigated, would render the solid electrolyte unsuitable for use in a lithium cell. In this cell, such mitigation is affected by the formation of a thin passivating layer of lithium iodide at the anode/electrolyte interface. Test cells of this type were fabricated from iodine/graphite cathode pellets, free-standing solid-electrolyte films, and lithium-foil anodes. The cathode mixtures were made by grinding together blends of nominally 10 weight percent graphite and 90 weight percent iodine. The cathode mixtures were then pressed into pellets at 36 kpsi (248 MPa) and inserted into coin-shaped stainless-steel cell cases that were coated with graphite paste to minimize corrosion. The solid-electrolyte film material was stamped to form circular pieces to fit in the coin cell cases, inserted in the cases, and pressed against the cathode pellets with polyethylene gaskets. Lithium-foil anodes were placed directly onto the electrolyte films. The layers described thus far were pressed and held together by stainless- steel shims, wave springs, and coin cell caps. The assembled cells were then crimped to form hermetic seals. It was found that the solid electrolyte films became discolored within seconds after they were placed in contact with the cathodes - a result of facile diffusion of iodine through the solid electrolyte material (see figure).

Bugga, Ratnakumar↗

Madidrop for Passive Silver Dosing

Madidrop is a rectangular ceramic tablet originally designed to dose a 10-20-liter volume of water with silver to act as a biocide for remote communities with unreliable water sources. Silver as a biocide is a proposed method to control bacteria on the International Space Station or future Artemis missions. This would replace iodine currently used due to issues with a dual biocide system in place between Russian and US segments and the extra cost of iodine removal required before consumption. NASA has been reviewing this Madidrop technology and its potential application with a water reclamation system on orbit to dose silver after purifying the water. While there are a couple alternative methods to dosing silver on station, this method is like the existing passive dosing method used currently to dose iodine. Tests conducted characterize the manufacturer’s original intent to leave the tablet in a tank for a specified amount of time before removing and testing alternative passive flow-through methods. Passive flow testing involved two options: keeping the tablet intact or crushing the tablet into smaller particle sizes to increase the surface area while varying particle sizes. The results of these tests revealed a large amount of silver output at first that quickly reduced to a constant lower output within a reasonable dosing concentration range. The initial high concentration peaks after a couple days of quiescence and could be useful for shocking the initial tank water contents. Madidrop used as a passive particle doser could act as a stand-in replacement for iodine in future spaceflight water reclamation systems.

Ryan Ogilvie↗

Madidrop for Passive Silver Dosing

Madidrop is a rectangular ceramic tablet originally designed to dose a 10-20-liter volume of water with silver to act as a biocide for remote communities with unreliable water sources. Silver as a biocide is a proposed method to control bacteria on the International Space Station or future Artemis missions. This would replace iodine currently used due to issues with a dual biocide system in place between Russian and US segments and the extra cost of iodine removal required before consumption. NASA has been reviewing this Madidrop technology and its potential application with a water reclamation system on orbit to dose silver after purifying the water. While there are a couple alternative methods to dosing silver on station, this method is like the existing passive dosing method used currently to dose iodine. Tests conducted characterize the manufacturer’s original intent to leave the tablet in a tank for a specified amount of time before removing and testing alternative passive flow-through methods. Passive flow testing involved two options: keeping the tablet intact or crushing the tablet into smaller particle sizes to increase the surface area while varying particle sizes. The results of these tests revealed a large amount of silver output at first that quickly reduced to a constant lower output within a reasonable dosing concentration range. The initial high concentration peaks after a couple days of quiescence and could be useful for shocking the initial tank water contents. Madidrop used as a passive particle doser could act as a stand-in replacement for iodine in future spaceflight water reclamation systems.

Ryan Ogilvie↗

Proportional retention of I and radiogenic Xe-129 in preheated Allende

In order to study the effects of heat loss and redistribution of iodine and xenon on the I-Xe age, the iodine-xenon dating technique was applied to a bulk sample of the Allende chondrite and a similar sample preheated to 900 C prior to the irradiation. Little iodine or Xe-129 were lost from the high-temperature fractions of the preheated sample, and the high-temperature isochron was fully preserved. The amounts of I and radiogenic Xe-129 retained by the preheated sample were nearly proportional in those temperature fractions (900-1150 C) where most I and radiogenic X-129 were lost. However, the intermediate-temperature isochron was modified, resulting in an apparent isochron which would predate the high-temperature isochron by 6.7 + or - 1.1 m.y.

Rison, W.↗

Environmental stability of intercalated graphite fibers

Graphite fibers intercalated with bromine, iodine monochloride, ferric chloride, and cupric chloride were subjected to stability tests under four environments which are encountered by engineering materials in the aerospace industry: ambient laboratory conditions, as would be experienced during handling operations and terrestrial applications; high vacuum, as would be experienced in space applications; high humidity, as would be experienced in marine applications; and high temperature, as would be experienced in some processing steps and applications. Monitoring the resistance of the fibers at ambient laboratory conditions revealed that only the ferric chloride intercalated fibers were unstable, due to absorption of water from the air. All four types of intercalated fibers were unstable, due to absorption of water from the air. All four types of intercalated fibers were stable for long periods under high vacuum. Ferric chloride, cupric chloride, and iodine monochloride intercalated fibers were sensitive to high humidity conditions. All intercalated fibers began to degrade above 250 C. The order of their thermal stability, from lowest to highest, was cupric chloride, iodine monochloride, bromine, and ferric chloride. Of the four types of intercalated fibers tested, the bromine intercalated fibers appear to have the most potential for application, based on environmental stability.

Gaier, J. R.↗

Environmental stability of intercalated graphite fibers

Graphite fibers intercalated with bromine, iodine monochloride, ferric chloride, and cupric chloride were subjected to stability tests under four environments which are encountered by engineering materials in the aerospace industry: ambient laboratory conditions, as would be experienced during handling operations and terrestrial applications; high vacuum, as would be experienced in space applications; high humidity, as would be experienced in marine applications; and high temperature, as would be experienced in some processing steps and applications. Monitoring the resistance of the fibers at ambient laboratory conditions revealed that only the ferric chloride intercalated fibers were unstable, due to absorption of water from the air. All four types of intercalated fibers were unstable, due to absorption of water from the air. All four types of intercalated fibers were stable for long periods under high vacuum. Ferric chloride, cupric chloride, and iodine monochloride intercalated fibers were sensitive to high humidity conditions. All intercalated fibers began to degrade above 250 C. The order of their thermal stability, from lowest to highest, was cupric chloride, iodine monochloride, bromine, and ferric chloride. Of the four types of intercalated fibers tested, the bromine intercalated fibers appear to have the most potential for application, based on environmental stability.

Gaier, J. R.↗

I-129/I-127 variations among enstatite chondrites

The iodine isotopic compositions and corresponding I-Xe ages were obtained for eight enstatite chondrites, bringing the total number of enstatite chondrites examined by the I-Xe technique to 11. Iodine isotopic compositions of these 11 chondrites indicate a well-defined hiatus correlated with the hiatus in chemical composition defining the two distinct enstatite groups: EH(4,5) and EL(6). Judging by the I-129/I-127 ratios and assuming that both the EH and EL groups originated from a reservoir with a uniform initial iodine isotopic composition, the EH(4,5) chondrites were estimated to be about 4 mln older than the El chondrites.

Kennedy, B. M.↗

Model gases for the detailed study of microscopic chemical nonequilibrium in diatomic gas flows

It is shown that chlorine (Cl2) and iodine (I2) are suitable model diatomic gases to use in theoretical studies of chemical nonequilibrium that account for rotational and vibrational as well as electronic processes in a gas. Because of the low temperature at which significant dissociation can be achieved in iodine, it is a particularly attractive candidate for the study of relatively low temperature chemically reacting flows, permitting detailed knowledge of the nonequilibrium populations of translational, rotational, vibrational and electronic energy levels. A preliminary investigation indicates that a useful iodine flow facility can be constructed and that diagnostic techniques are available to validate in detail prediction techniques for nonequilibrium flows.

Kunc, Joseph A.↗

Microbial biofilm studies of the environmental control and life support system water recovery test for Space Station Freedom

NASA is developing a water recovery system (WRS) for Space Station Freedom to reclaim human waste water for reuse by astronauts as hygiene or potable water. A water recovery test (WRT) currently in progress investigates the performance of a prototype of the WRS. Analysis of biofilm accumulation, the potential for microbially influenced corrosion (MIC) in the WRT, and studies of iodine disinfection of biofilm are reported. Analysis of WRT components indicated the presence of organic deposits and biofilms in selected tubing. Water samples for the WRT contained acid-producing and sulfate-reducing organisms implicated in corrosion processes. Corrosion of an aluminum alloy was accelerated in the presence of these water samples; however, stainless steel corrosion rates were not accelerated. Biofilm iodine sensitivity tests using an experimental laboratory scale recycled water system containing a microbial check valve (MCV) demonstrated that an iodine concentration of 1 to 2 mg/L was ineffective in eliminating microbial biofilm. For complete disinfection, an initial concentration of 16 mg/L was required, which was gradually reduced by the MCV over 4 to 8 hours to 1 to 2 mg/L. This treatment may be useful in controlling biofilm formation.

Rodgers, E. B.↗

Regenerable biocide delivery unit, volume 1

The Microbial Check Valve (MCV), which is currently used aboard the Shuttle Orbiter for disinfection of the potable water supply, is an expendable flow-through canister containing iodinated ion exchange resin. Means for extension of MCV life are desirable to avoid resupply penalties. The Phase 1 Regenerable Biocide Delivery Unit program demonstrated the feasibility of regenerating an MCV in situ, using a strong aqueous elemental iodine solution resulting from diversion of the MCV influent to a packed bed containing iodine crystals. In small column tests, eight manual regenerations of an MCV resin were accomplished. The term Regenerative Microbial Check Valve (RMCV) was adopted describing this new technology. The Phase 2 program resulted in the development of a full scale and fully autonomous prototype RMCV, capable of maintaining residual I(sub 2) levels between 2.0 - 4.0 mg/L for prolonged periods. During six months of testing at the Space Station baseline flow rate of 120 cm(sup 3)/min, the prototype RMCV underwent nine regenerations. RMCV life cycle tests, using a variety of influent streams, were conducted over an eighteen month period to determine the useful lives of MCV's incorporating this new technology and to determine ultimate failure mechanisms. MCV life extensions of 130 fold were demonstrated, limited only by the Phase 2 performance period. Based upon this work, it is certain that RMCV units can be developed to provide unattended biocide addition for the thirty year life of Space Station Freedom, or for other longer duration applications such as a Lunar Base or Mars mission. RMCV technology was also demonstrated capable of delivering, on demand, a concentrated aqueous I(sub 2) solution for potential use as a disinfectant during transient episodes of microbial surface contamination, for the control of biofilm formation, or as a preventative measure in systems which are particularly susceptible to the growth of microorganisms.

Atwater, James E.↗