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At least 253 records · Page 14

First saturation correction in high energy proton-nucleus collisions. Part I. Time evolution of classical Yang-Mills fields beyond leading order

In high energy proton-nucleus collisions, the single- and double-inclusive soft gluon productions at the leading order have been calculated and phenomenologically studied in various approaches for many years. These studies do not take into account the saturation and multiple rescatterings in the field of the proton. The first saturation correction to these leading order results (the terms that are enhanced by the combination \( {\alpha}_s^2{\mu}^2 \) , where μ 2 is the proton’s color charge squared per unit transverse area) has not been completely derived despite recent attempts using a diagrammatic approach. This paper is the first in a series of papers towards analytically completing the first saturation correction to physical observables in high energy proton-nucleus collisions. Our approach is to analytically solve the classical Yang-Mills equations in the dilute-dense regime using the Color Glass Condensate effective theory and compute physical observables constructed from classical gluon fields. In the current paper, the Yang-Mills equations are solved perturbatively in the field of the dilute object (the proton). Next-to-leading order and next-to-next-to-leading order analytic solutions are explicitly constructed. A systematic way to obtain all higher order analytic solutions is outlined.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A vorticity-based criterion to characterise leading edge dynamic stall onset

We propose a more conservative, physically-intuitive criterion, namely, the boundary enstrophy flux ( BEF), to characterise leading-edge-type dynamic stall onset in incompressible flows. Our results are based on wall-resolved large-eddy simulations of pitching aerofoils, with fine spatial and temporal resolution around stall onset. We observe that |BEF| reaches a maximum within the stall onset regime identified. By decomposing the contribution to BEF from the flow field, we find that the dominant contribution arises from the laminar leading edge region, due to the combined effect of large clockwise vorticity and favourable pressure gradient. A relatively small contribution originates from the transitional/turbulent laminar separation bubble (LSB) region, due to LSB-induced counter-clockwise vorticity and adverse pressure gradient. This results in BEF being nearly independent of the integration length as long as the region very close to the leading edge is included. This characteristic of BEF yields a major advantage in that the effect of partial or complete inclusion of the noisy LSB region can be filtered out, without changing the BEF peak location in time significantly. Next, we analytically relate BEF to the net wall shear and show that its critical value (=max(|BEF|) ) corresponds to the instant of maximum net shear prevailing at the wall. Finally, we have also compared BEF with the leading edge suction parameter ( LESP) and find that the former reaches its maximum value between 0.3° and 0.8° of rotation earlier.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Bismuth in Lead–Tin Alloy Perovskites: Effect on Material Properties and Photovoltaic Device Performance

Metal halide perovskites (MHPs) have a strong potential for optoelectronic applications, especially photovoltaics. A significant advantage offered by MHPs is their bandgap tunability via chemical substitution and alloying, with lead–tin alloys producing the narrowest reported bandgaps of ~1.2 eV. Efforts to further narrow the bandgap of MHPs by alloying in other elements, such as bismuth, have largely been unsuccessful due to the introduction of defective electronic states, which severely diminish electronic quality. Here, in this study, we examine the effects of bismuth on a lead–tin alloyed MHP, motivated by the narrow bandgap of alloyed lead–tin MHPs. We find that the defect screening observed in lead–tin MHPs is not sufficient to screen the defect level introduced by bismuth, as evidenced by quenched photoluminescence, decreased mobility, and severely reduced performance in a photovoltaic device. Density functional theory calculations suggest that midgap states are introduced by bismuth addition over a range of chemical and compositional conditions. We further observe through wavelength-dependent photoconductivity that free carriers are generated out to ~0.9 eV in bismuth-containing samples, which could be of potential interest for NIR photodetection.

14 SOLAR ENERGY↗

Design of High-Performance Lead-Free Quaternary Antiperovskites for Photovoltaics via Ion Type Inversion and Anion Ordering

The emergence of halide double perovskites significantly increases the compositional space for lead-free and air-stable photovoltaic absorbers compared to halide perovskites. Nevertheless, most halide double perovskites exhibit oversized band gaps (>1.9 eV) or dipole-forbidden optical transition, which are unfavorable for efficient single-junction solar cell applications. The current device performance of halide double perovskite is still inferior to that of lead-based halide perovskites, such as CH 3 NH 3 PbI 3 (MAPbI 3 ). Here, by ion type inversion and anion ordering on perovskite lattice sites, two new classes of pnictogen-based quaternary antiperovskites with the formula of X 6 B 2 AA' and X 6 BB'A 2 are designed. Phase stability and tunable band gaps in these quaternary antiperovskites are demonstrated based on first-principles calculations. Further photovoltaic-functionality-directed screening of these materials leads to the discovery of 5 stable compounds (Ca 6 N 2 AsSb, Ca 6 N 2 PSb, Sr 6 N 2 AsSb, Sr 6 N 2 PSb, and Ca 6 NPSb 2 ) with suitable direct band gaps, small carrier effective masses and low exciton binding energies, and dipole-allowed strong optical absorption, which are favorable properties for a photovoltaic absorber material. The calculated theoretical maximum solar cell efficiencies based on these five compounds are all larger than 29%, comparable to or even higher than that of the MAPbI 3 based solar cell. Finally, our work reveals the huge potential of quaternary antiperovskites in the optoelectronic field and provides a new strategy to design lead-free and air-stable perovskite-based photovoltaic absorber materials.

three-dimensional electronic transport↗

Bromine Incorporation Affects Phase Transformations and Thermal Stability of Lead Halide Perovskites

Mixed-cation and mixed-halide lead halide perovskites show great potential for their application in photovoltaics. Many of the high-performance compositions are made of cesium, formamidinium, lead, iodine, and bromine. However, incorporating bromine in iodine-rich compositions and its effects on the thermal stability of the perovskite structure has not been thoroughly studied. In this work, we study how replacing iodine with bromine in the state-of-the-art Cs 0.17 FA 0.83 PbI 3 perovskite composition leads to different dynamics in the phase transformations as a function of temperature. Through a combination of structural characterization, cathodoluminescence mapping, X-ray photoelectron spectroscopy, and first-principles calculations, we reveal that the incorporation of bromine reduces the thermodynamic phase stability of the films and shifts the products of phase transformations. Our results suggest that bromine-driven vacancy formation during high temperature exposure leads to irreversible transformations into PbI 2 , whereas materials with only iodine go through transformations into hexagonal polytypes, such as the 4H-FAPbI 3 phase. This work sheds light on the structural impacts of adding bromine on thermodynamic phase stability and provides new insights into the importance of understanding the complexity of phase transformations and secondary phases in mixed-cation and mixed-halide systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Causes of Degradation of Organ Pipes with Very Low Lead Content

This study investigates the causes of degradation in organ pipes with low lead content. Using light This study investigates the causes of degradation in organ pipes with low lead content. Using light optical microscopy, SEM/EDS, and TEM/EDS, intermetallic Cu6Sn5, FeSn2, Sn4As3, and Pb particles were observed in the structure of SnPb alloys. Degradation of the low-Pb organ metal, which is primarily caused by the selective corrosion of lead occurring due to the effect of volatile organic compounds (VOCs). Another factor leading to degradation is the structural transformation of tin occurring at low temperatures (tin pest). TEM/EDS allowed the unique observation of α-tin particles found in a β-tin matrix at room temperature. The presence of particles of α‑tin in historical organ pipes has not previously been reported, and it is the first presented observation of all.

alloy SnPb↗

Recycling lead and transparent conductors from perovskite solar modules

Abstract Perovskite photovoltaics are gaining increasing common ground to partner with or compete with silicon photovoltaics to reduce cost of solar energy. However, a cost-effective waste management for toxic lead (Pb), which might determine the fate of this technology, has not been developed yet. Here, we report an end-of-life material management for perovskite solar modules to recycle toxic lead and valuable transparent conductors to protect the environment and create dramatic economic benefits from recycled materials. Lead is separated from decommissioned modules by weakly acidic cation exchange resin, which could be released as soluble Pb(NO 3 ) 2 followed by precipitation as PbI 2 for reuse, with a recycling efficiency of 99.2%. Thermal delamination disassembles the encapsulated modules with intact transparent conductors and cover glasses. The refabricated devices based on recycled lead iodide and recycled transparent conductors show comparable performance as devices based on fresh raw materials. Cost analysis shows this recycling technology is economically attractive.

14 SOLAR ENERGY↗

Order-disorder phase transition driven by interlayer sliding in lead iodides

A variety of phase transitions have been found in two-dimensional layered materials, but some of their atomic-scale mechanisms are hard to clearly understand. Here, we report the discovery of a phase transition whose mechanism is identified as interlayer sliding in lead iodides, a layered material widely used to synthesize lead halide perovskites. The low-temperature crystal structure of lead iodides is found not 2H polytype as known before, but non-centrosymmetric 4H polytype. This undergoes the order-disorder phase transition characterized by the abrupt spectral broadening of valence bands, taken by angle-resolved photoemission, at the critical temperature of 120 K. It is accompanied by drastic changes in simultaneously taken photocurrent and photoluminescence. The transmission electron microscopy is used to reveal that lead iodide layers stacked in the form of 4H polytype at low temperatures irregularly slide over each other above 120 K, which can be explained by the low energy barrier of only 10.6 meV/atom estimated by first principles calculations. Our findings suggest that interlayer sliding is a key mechanism of the phase transitions in layered materials, which can significantly affect optoelectronic and optical characteristics.

36 MATERIALS SCIENCE↗

Strain-induced lead-free morphotropic phase boundary

Enhanced susceptibilities in ferroelectrics often arise near phase boundaries between competing ground states. While chemically-induced phase boundaries have enabled ultrahigh electrical and electromechanical responses in lead-based ferroelectrics, precise chemical tuning in lead-free alternatives, such as (K,Na)NbO 3 thin films, remains challenging due to the high volatility of alkali metals. Here, we demonstrate strain-induced morphotropic phase boundary-like polymorphic nanodomain structures in chemically simple, lead-free, epitaxial NaNbO 3 thin films. Combining ab initio simulations, thin-film epitaxy, scanning probe microscopy, synchrotron X-ray diffraction, and electron ptychography, we reveal a labyrinthine structure comprising coexisting monoclinic and bridging triclinic phases near a strain-induced phase boundary. The coexistence of energetically competing phases facilitates field-driven polarization rotation and phase transitions, giving rise to a multi-state polarization switching pathway and large enhancements in dielectric susceptibility and tunability across a broad frequency range. Our results open new possibilities for engineering lead-free thin films with enhanced functionalities for next-generation applications.

Electronic properties and materials↗

Demonstration of collinear factorization breaking due to collinear-to-soft Glauber exchanges for a 2 → 3 exclusive process at leading twist

We exhibit an exclusive process, namely the photoproduction of a π 0 γ pair with large invariant mass, which violates collinear factorization. We explicitly demonstrate that this is due to the fact that there exists diagrams with gluon exchange in t channel, contributing at the leading power, for which are . This is caused by the pinching of the contour integration of the plus and minus light-cone components of the Glauber gluon momentum. We argue that this leads to the observed “end pointlike” divergence of the convolution integral at leading order and leading power when collinear factorization is naïvely assumed. Published by the American Physical Society 2025

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Metallization and spin fluctuations in Cu-doped lead apatite

An electronic structure and magnetic properties analysis of the recently proposed Cu-doped lead apatite is performed. Here, we show that electronic structures of differently Cu-substituted structures are characterized by localized molecular Cu-O bands at or near the Fermi level. The Cu substitutions can happen at both Pb1 and Pb2 sites, leading to metallic and semiconducting systems differently. The electronic systems in these bands are highly unstable magnetically and form clusters of rigidly ferromagnetically coupled magnetic moments on Cu and neighboring oxygen atoms with a total moment of about 1µ B . The ground state of uniformly Cu-doped lead apatite appears to be magnetic and semiconducting. The nonuniform distribution of two Cu atoms at the nearest Pb2 sites leads to an antiferromagnetic semiconducting state with formation energy close to uniformly distributed Cu configurations. The inclusion of quantum spin fluctuations confirms the stability of magnetic Cu-O clusters. Our calculations revealed the absence of the long-range magnetic order between uniformly distributed Cu-O clusters, creating the spin glass type of system.

36 MATERIALS SCIENCE↗

Update on the Benchmark Analysis of the Jupiter Experiments: Plutonium Moderated by Lead

The Jupiter experiment was a series of measurements in the summer of 2017 to analyze the effects of voids in lead moderated plutonium assemblies. This experiment was part of a larger campaign that took place at the National Criticality Experiments Research Center (NCERC) in collaboration with the Japan Atomic Energy Agency (JAEA) that also investigated assemblies with differing uranium enrichments. The purpose for this campaign was to provide data useful for a potential lead-bismuth cooled accelerator driven system. This data is needed due to the low number of benchmarks involving lead. Given the wide use of lead for shielding in addition to new reactor designs, there is a need for further benchmarking that this experiment could help fulfill. In addition, adding more benchmarks to the International Criticality Safety Benchmark Evaluation Project (ICSBEP) is helpful for further validation of simulation methods used for criticality safety. This summary is an update on the current progress of this analysis, and all results shown are preliminary.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Unexpected Breakdown of Collinear Factorisation at Leading Twist in Exclusive π 0 γ Photoproduction Due to Glauber Pinch

We demonstrate the breakdown of collinear factorisation for the exclusive photoproduction at leading twist of a pair, sensitive to both quark and gluon GPD channels. For the very first time in the case of an exclusive process, we demonstrate the breakdown of collinear factorisation through soft-to-collinear Glauber exchanges. We show that the amplitude fails to factorise due to the presence of a Glauber pinch, which has the same power counting as the standard collinear pinch. The Glauber pinch that occurs here is peculiar, since the mechanism that produces it involves two-loop integrals. This is corroborated by an explicit calculation of the gluon GPD channel to pair photoproduction, which leads to a divergent amplitude already at leading twist-2 and at leading order in . On the other hand, for processes where the gluon GPD channel is forbidden, for example when the outgoing meson is a charged pion or a rho meson, collinear factorisation works without any issues.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Effects of increased leading-edge thickness on performance of a transonic rotor blade

A single-stage transonic compressor was tested with two rotor blade leading-edge configurations to investigate the effect of increased leading-edge thickness on the performance of a transonic blade row. The original rotor blade configuration was modified by cutting back the leading edge sufficiently to double the blade leading-edge thickness and thus the blade gap blockage in the tip region. At design speed this modification resulted in a decrease in rotor overall peak efficiency of four points. The major portion of this decrement in rotor overall peak efficienty was attributed to the flow conditions in the outer 30 percent of the blade span. At 70 and 90 percent of design speed, the modification had very little effect on rotor overall performance.

Reid, L.↗

Effect of spanwise blowing on leading-edge vortex bursting of a highly swept aspect ratio 1.18 delta wing

An investigation was conducted in the Langley 1/8-scale V/STOL model tunnel on a semispan delta wing with a leading-edge sweep of 74 deg, to determine the effectiveness of various locations of upper surface and reflection plane blowing on leading-edge vortex bursting. Constant area nozzles were located on the wing upper surface along a ray swept 79 deg, which was beneath the leading-edge vortex core. The bursting and reformation of the leading-edge vortex was viewed by injecting helium into the vortex core, and employing a schlieren system.

Scantling, W. L.↗

Design fabrication, testing, and delivery of shuttle heat pipe leading edge test modules. Volume 1: Executive summary

The construction of two test modules is presented for a feasibility demonstration of a concept for reusable space shuttle wing leading edge surfaces. In this leading edge concept high temperature heat pipes were incorporated into the structure to cool the stagnation region, allowing the use of super-alloys in place of refractory metal, ablator protected, or carbon-carbon structures. The program included the analysis and design of the heat pipes, their integration into the test module structure, heat pipe development testing, construction of the test modules and a facility adapter, and formulation of recommended testing conditions. The results of the heat pipe and leading edge module thermal analyses indicate the test modules will meet the design goal; reducing the leading edge temperature at the stagnation line from 1315 C (2400 F) to less than 1010 C (1850 F). The development tests demonstrated that the module assembly could be brazed with active heat pipes, as was borne out by the subsequent successful brazing of both modules with active heat pipes loaded with sodium.

Source record↗

Laser using lead chloride vapor

By applying electric discharge, lead chloride vapor in tube is dissociated into lead and chlorine atoms. Population inversion of lead atoms is attained subsequently by second discharge, before chemical recombination of lead and chlorine has occurred. Optimum time interval between two discharges is required for maximum laser output.

Chen, C. J.↗

Water hyacinths and alligator weeds for removal of lead and mercury from polluted waters

Removal of lead and mercury by water hyacinths (Eichhornia crassipes) (Mart.) Solms and alligator weeds (Alternanthera philoxeroides) (Mart.) Griesb. was investigated. Water hyacinths demonstrated the ability to remove 0.176 mg of lead and 0.150 mg of mercury per gram of dry plant material from distilled water and river water in a 24-hour period. One acre of water hyacinths is potentially capable of removing 105.6 grams of lead and 90.0 grams of mercury per day. Alligator weeds removed 0.101 mg of lead per gram of dry plant material in a 24-hour period. This same plant also demonstrated the ability to remove a minimum of 0.153 mg of mercury per gram of dry plant material in a six hour period.

Wolverton, B. C.↗