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At least 253 records · Page 14

Velocity and Density of Low Energy Ions in High-Latitude Magnetosphere

This study examines the characteristics of low energy ions at the polar cap boundary and within the polar cap in relationship to the convection velocity. The source of low energy ions in the magnetosphere could be driven by solar wind/IMF (interplanetary magnetic fields) interactions affecting energization processes of ionospheric ions. The IMF also influences the convection pattern which is in part responsible for determining the path ions take as they leave the ionosphere and contribute to magnetospheric populations. The primary source of data for this study is the Thermal Ion Dynamics Experiment (TIDE) on board the Polar satellite. TIDE can measure 3-D velocities and covers an energy range ideal for examining the polar cap plasma (0-450 eV). Due to certain limitations, this study uses H+ measurements at apogee and O+ measurements at perigee. At apogee H+ is very field-aligned and outflowing, and at perigee O+ is often moving downward in the polar cap proper. The path highly field-aligned flows take across the polar cap are also affected by changes in the magnetic field line topology which varies with geophysical conditions. Convection near the polar cap boundary is of particular interest since often the convection there is highly structured, and convection reversals may play a role in causing ion outflow. This study will examine in particular the density structures of ions in relationship to the convection velocity. Examining such relationships may provide insight into understanding the consequences of the 3-D flow on the density of ions in the polar cap, and transport of ions across the polar cap.

Elliott, Heather A.↗

Consistency Between Sun-Induced Chlorophyll Fluorescence and Gross Primary Production of Vegetation in North America

Accurate estimation of the gross primary production (GPP) of terrestrial ecosystems is vital for a better understanding of the spatial-temporal patterns of the global carbon cycle. In this study,we estimate GPP in North America (NA) using the satellite-based Vegetation Photosynthesis Model (VPM), MODIS (Moderate Resolution Imaging Spectrometer) images at 8-day temporal and 500 meter spatial resolutions, and NCEP-NARR (National Center for Environmental Prediction-North America Regional Reanalysis) climate data. The simulated GPP (GPP (sub VPM)) agrees well with the flux tower derived GPP (GPPEC) at 39 AmeriFlux sites (155 site-years). The GPP (sub VPM) in 2010 is spatially aggregated to 0.5 by 0.5-degree grid cells and then compared with sun-induced chlorophyll fluorescence (SIF) data from Global Ozone Monitoring Instrument 2 (GOME-2), which is directly related to vegetation photosynthesis. Spatial distribution and seasonal dynamics of GPP (sub VPM) and GOME-2 SIF show good consistency. At the biome scale, GPP (sub VPM) and SIF shows strong linear relationships (R (sup 2) is greater than 0.95) and small variations in regression slopes ((4.60-5.55 grams Carbon per square meter per day) divided by (milliwatts per square meter per nanometer per square radian)). The total annual GPP (sub VPM) in NA in 2010 is approximately 13.53 petagrams Carbon per year, which accounts for approximately 11.0 percent of the global terrestrial GPP and is within the range of annual GPP estimates from six other process-based and data-driven models (11.35-22.23 petagrams Carbon per year). Among the seven models, some models did not capture the spatial pattern of GOME-2 SIF data at annual scale, especially in Midwest cropland region. The results from this study demonstrate the reliable performance of VPM at the continental scale, and the potential of SIF data being used as a benchmark to compare with GPP models.

photosynthesis model↗

DE 1 RIMS operational characteristics

The Retarding Ion Mass Spectrometer (RIMS) on the Dynamics Explorer 1 spacecraft observes both the thermal and superthermal (50 eV) ions of the ionosphere and inner magnetosphere. It is capable of measuring the detailed species distribution function of these ions in many cases. It was equipped with an integral electrometer to permit in-flight calibration of the detector sensitivities and variations thereof. A guide to understanding the RIMS data set is given. The reduction process from count rates to physical quantities is discussed in some detail. The procedure used to establish in-flight calibration is described, and results of a comparison with densities from plasma wave measurements are provided. Finally, a discussion is provided of various anomalies in the data set, including changes of channeltron efficiency with time, spin modulation of the axial sensor heads, apparent potential differences between the sensor heads, and failures of the radial head retarding potential sweep and of the -Z axial head aperture plane bias. Studies of the RIMS data set should be conducted only with a thorough awareness of the material presented here, or in collaboration with one of the scientists actively involved with RIMS data analysis.

Olsen, R. C.↗

Global Analysis, Interpretation and Modelling: An Earth Systems Modelling Program

The Goal of the GAIM is: To advance the study of the coupled dynamics of the Earth system using as tools both data and models; to develop a strategy for the rapid development, evaluation, and application of comprehensive prognostic models of the Global Biogeochemical Subsystem which could eventually be linked with models of the Physical-Climate Subsystem; to propose, promote, and facilitate experiments with existing models or by linking subcomponent models, especially those associated with IGBP Core Projects and with WCRP efforts. Such experiments would be focused upon resolving interface issues and questions associated with developing an understanding of the prognostic behavior of key processes; to clarify key scientific issues facing the development of Global Biogeochemical Models and the coupling of these models to General Circulation Models; to assist the Intergovernmental Panel on Climate Change (IPCC) process by conducting timely studies that focus upon elucidating important unresolved scientific issues associated with the changing biogeochemical cycles of the planet and upon the role of the biosphere in the physical-climate subsystem, particularly its role in the global hydrological cycle; and to advise the SC-IGBP on progress in developing comprehensive Global Biogeochemical Models and to maintain scientific liaison with the WCRP Steering Group on Global Climate Modelling.

Moore, Berrien, III↗

Study of Static Microchannel Plate Saturation Effects for the Fast Plasma Investigation Dual Electron Spectrometers on NASA's Magnetospheric MultiScale Mission

Imaging detecting systems based on microchannel plates (MCPs) are the most common for low energy plasma measurements for both space borne and ground applications. One of the key parameters of these detection systems is the dynamic range of the MCP's response to the input fluxes of charged particles. For most applications the dynamic range of the linear response should be as wide as possible. This is especially true for the Dual Electron Spectrometers (DESs) of the Fast Plasma Investigation (FPI) on NASA's Magnetospheric MultiScale (MMS) mission because a wide range of input fluxes are expected. To make use of the full available dynamic range, it is important to understand the MCP response behavior beyond the linear regime where the MCPs start to saturate. We have performed extensive studies of this during the characterization and calibration of the DES instruments and have identified several saturation effects of the detection system. The MCP itself exhibits saturation when the channels lack the ability to replenish charge sufficiently rapidly. It is found and will be shown that the ground system can significantly impact the correct measurement of this effect. As the MCP starts to saturate, the resulting pulse height distribution (PHD) changes shape and location (with less pulse height values), which leads to truncation of the PHD by the threshold set on the detection system discriminator. Finally, the detection system pulse amplifier exhibits saturation as the input flux drives pulse rates greater than its linear response speed. All of these effects effectively change the dead time of the overall detection system and as a result can affect the quality and interpretation of the flight data. We present results of detection system saturation effects and their interaction with special emphasis on the MCP related effects.

detecting system↗

Information for space radar designers: Required dynamic range vs resolution and antenna calibration using the Amazon rain forest

Calibration of the vertical pattern of the antennas for the SEASAT scatterometer was accomplished using the nearly-uniform radar return from the Amazon rain forest. A similar calibration will be attempted for the SIR-B antenna. Thick calibration is important to establish the radiometric calibration across the swath of the SIR-B, and the developed methodology will provide an important tool in the evaluation of future spaceborne imaging radars. This calibration was made by the very-wide-beam SEASAT scatterometer antennas because at 14.65 GHz the scattering coefficient of the rain forest is almost independent of angle of incidence. It is expected that the variation in scattering coefficient for the rain forest across the relatively narrow vertical beam of the SIR-B will be very small; even at L band the forest should be essentially impenetrable for radar signals, the volume scatter from the treetops will predominate as at higher frequencies. The basic research elements include: (1) examination of SIR-B images over the rain forest to establish the variability of the scattering coefficient at finer resolutions than that of the SEASAT scatterometer; (2) analysis of the variability of SIR-B data detected prior to processing for either azimuth compression or; possibly, range compression so that averages over relatively large footprints can be used; (3) processing of data of the form of (2) using algorithms that can recover the vertical pattern of the antenna.

Moore, R. K.↗

Evolution and use of combined mechanical and thermal codes for cryogenic turbopump bearings

Shaft bearing system analysis codes were developed, improved, and used to investigate Space Shuttle Main Engine (SSME) Liquid Oxygen (LOX) turbopump bearing problems, and to support the Marshall Space Flight Center Bearing and Seal Materials Test (BSMT) program. Thermal network modeling uses the SINDA thermal code, and the modeling of bearing quasi-dynamic characteristics uses the SHABERTH bearing/shaft code. These codes are solved concurrently for a bearing/shaft system using software developed for this purpose. Simulation of the SSME LOX turbopump turbine and pump end bearings and the MSFC BSMT operating in liquid nitrogen (LN sub 2) and LOX was done. The thermal network models include the bearing components, bearing carriers, shaft, housing, frictional heat, and viscous fluid energy. A cage model was included to account for heat generation between the cage and rolling elements. Since most bearing surfaces operate at temperatures well above the coolant saturation temperature, and move at high speed relative to the coolant, forced convection boiling is the dominant mechanism for heat removal. Improved modeling of forced convection film boiling was incorporated to take into account the local vapor generation at the high temperature surfaces. Rearing preloads in the pump and tester are provided by preload springs. As bearing operating clearances and contact angles change due to thermal effects and loading, the bearing preload changes with these varying conditions. These characteristics were modeled and are included in the overall system models. Results from these models indicate an operational limit which, if exceeded, predicts a thermal excursion.

Cody, Joe C.↗

More Macrospicule Jets in On-Disk Coronal Holes

We examine the magnetic structure and dynamics of multiple jets found in coronal holes close to or on disk center. All data are from the Atmospheric Imaging Assembly (AIA) and the Helioseismic and Magnetic Imager (HMI) of the Solar Dynamics Observatory (SDO). We report on observations of about ten jets in an equatorial coronal hole spanning 2011 February 27 and 28. We show the evolution of these jets in AIA 193 A, examine the magnetic field configuration and flux changes in the jet area, and discuss the probable trigger mechanism of these events. We reported on another jet in this same coronal hole on 2011 February 27, (is) approximately 13:04 UT (Adams et al 2014, ApJ, 783: 11). That jet is a previously-unrecognized variety of blowout jet, in which the base-edge bright point is a miniature filament-eruption flare arcade made by internal reconnection of the legs of the erupting field. In contrast, in the presently-accepted 'standard' picture for blowout jets, the base-edge bright point is made by interchange reconnection of initially-closed erupting jet-base field with ambient open field. This poster presents further evidence of the production of the base-edge bright point in blowout jets by internal reconnection. Our observations suggest that most of the bigger and brighter EUV jets in coronal holes are blowout jets of the new-found variety.

jets↗

Structural Dynamics Observations in Space Launch System Green Run Hot Fire Testing

The Space Launch System (SLS) Core Stage (CS) Thrust Vector Control (TVC) system is comprised of eight mechanical feedback Shuttle heritage Type III TVC actuators and four RS-25 engines, each attached to a Shuttle heritage gimbal block/bearing. Two actuators are used to move each engine in two planes perpendicular to one another (i.e., pitch and yaw). The TVC system design leverages hardware from the Space Shuttle program as well as new hardware designed specifically for the Core Stage. The Green Run Hot Fire (GRHF) of the SLS Core Stage provided a flight-like ground test environment for verification of integrated vehicle TVC performance. A TVC model coupled to a vehicle structural dynamic model has been developed previously and incrementally validated in subsystem tests and simulations. Still, some aspects of TVC performance in GRHF were not anticipated. The ensuing investigation demonstrated the need for well-instrumented test environments, various levels of modeling fidelity, test-representative structural models, and caution in reuse of legacy components. This paper is the sixth installment in a seven-paper series surveying the design, engineering, test validation, and flight performance of the Core Stage Thrust Vector Control system. It introduces the salient structural dynamic phenomena uncovered in ambient and hot fire testing. During the Green Run test campaign, a comparison of ambient and hot fire step responses showed a significant change in apparent damping due to the presence of friction, challenging long standing assumptions that friction could be neglected. Additionally, the characteristic response of the engine and thrust structure during GRHF proved to be more complex than anticipated, as evidenced by the available actuator, thrust structure, and engine measurements. While the string-potentiometer based test instrumentation was intended to allow for reconstruction of the engine angles along the two control axes, the geometric placement, location uncertainty, and responses in overlapping frequency spectra revealed additional phenomena requiring further analysis and post-processing. The observations from both modal and frequency response testing during the Green Run ambient and hot fire configurations led to Engine and Core Stage FEM (finite element model) updates. When evidence of unexpected engine motion was found in engine section accelerometer data, the authors pursued additional structural analysis leading to FEM updates associated with the TVC gimbal and thrust structure. Through collaboration between structures, TVC, and flight control disciplines, the test-informed models and root-cause analysis led to confident flight rationale for the first flight of the SLS launch vehicle.

Richard Moore↗

Aeroelastic Tailoring of the NASA Common Research Model via Novel Material and Structural Configurations

This work explores the use of tow steered composite laminates, functionally graded metals (FGM), thickness distributions, and curvilinear rib/spar/stringer topologies for aeroelastic tailoring. Parameterized models of the Common Research Model (CRM) wing box have been developed for passive aeroelastic tailoring trade studies. Metrics of interest include the wing weight, the onset of dynamic flutter, and the static aeroelastic stresses. Compared to a baseline structure, the lowest aggregate static wing stresses could be obtained with tow steered skins (47% improvement), and many of these designs could reduce weight as well (up to 14%). For these structures, the trade-off between flutter speed and weight is generally strong, although one case showed both a 100% flutter improvement and a 3.5% weight reduction. Material grading showed no benefit in the skins, but moderate flutter speed improvements (with no weight or stress increase) could be obtained by grading the spars (4.8%) or ribs (3.2%), where the best flutter results were obtained by grading both thickness and material. For the topology work, large weight reductions were obtained by removing an inner spar, and performance was maintained by shifting stringers forward and/or using curvilinear ribs: 5.6% weight reduction, a 13.9% improvement in flutter speed, but a 3.0% increase in stress levels. Flutter resistance was also maintained using straightrotated ribs although the design had a 4.2% lower flutter speed than the curved ribs of similar weight and stress levels were higher. These results will guide the development of a future design optimization scheme established to exploit and combine the individual attributes of these technologies.

Jutte, Christine V.↗

Structural Dynamics Observations in Space Launch System Green Run Hot Fire Testing

The Space Launch System (SLS) Core Stage (CS) Thrust Vector Control (TVC) system is comprised of eight mechanical feedback Shuttle heritage Type III TVC actuators and four RS-25 engines, each attached to a Shuttle heritage gimbal block/bearing. Two actuators are used to move each engine in two planes perpendicular to one another (i.e., pitch and yaw). The TVC system design leverages hardware from the Space Shuttle program as well as new hardware designed specifically for the Core Stage. The Green Run Hot Fire (GRHF) of the SLS Core Stage provided a flight-like ground test environment for verification of integrated vehicle TVC performance. A TVC model coupled to a vehicle structural dynamic model has been developed previously and incrementally validated in subsystem tests and simulations. Still, some aspects of TVC performance in GRHF were not anticipated. The ensuing investigation demonstrated the need for well-instrumented test environments, various levels of modeling fidelity, test-representative structural models, and caution in reuse of legacy components. This paper is the sixth installment in a seven-paper series surveying the design, engineering, test validation, and flight performance of the Core Stage Thrust Vector Control system. It introduces the salient structural dynamic phenomena uncovered in ambient and hot fire testing. During the Green Run test campaign, a comparison of ambient and hot fire step responses showed a significant change in apparent damping due to the presence of friction, challenging long standing assumptions that friction could be neglected. Additionally, the characteristic response of the engine and thrust structure during GRHF proved to be more complex than anticipated, as evidenced by the available actuator, thrust structure, and engine measurements. While the string-potentiometer based test instrumentation was intended to allow for reconstruction of the engine angles along the two control axes, the geometric placement, location uncertainty, and responses in overlapping frequency spectra revealed additional phenomena requiring further analysis and post-processing. The observations from both modal and frequency response testing during the Green Run ambient and hot fire configurations led to Engine and Core Stage FEM (finite element model) updates. When evidence of unexpected engine motion was found in engine section accelerometer data, the authors pursued additional structural analysis leading to FEM updates associated with the TVC gimbal and thrust structure. Through collaboration between structures, TVC, and flight control disciplines, the test-informed models and root-cause analysis led to confident flight rationale for the first flight of the SLS launch vehicle.

Richard K. Moore↗

Comparison Between THOR Anthropomorphic Test Device and THOR Finite Element Model

Extended time spent in reduced gravity can cause physiologic deconditioning of astronauts, reducing their ability to sustain excessive forces during dynamic phases of spaceflight such as landing. To make certain that the crew is safe during these phases, NASA must take caution when determining what types of landings are acceptable based on the accelerations applied to the astronaut. In order to test acceptable landings, various trials have been run accelerating humans, cadavers, and Anthropomorphic Test Devices (ATDs), or crash test dummies, at different acceleration and velocity rates on a sled testing platform. Using these tests, risks of injury will be created and metrics will be developed for the likelihood of injuries due to the acceleration. A finite element model (FEM) of the Test Device for Human Occupant Restraint (THOR) ATD has been developed that can simulate these test trials and others (Putnam, 2014), reducing the need for human and ATD testing. Additionally, this will give researchers a more effective way to test the accelerations and orientations encountered during spaceflight landings during design of new space vehicles for crewed missions. However, the FEM has not been proven and must be validated by comparing the forces, accelerations, and other measurements of all parts of the body between the physical tests already completed and computer simulated trials. The purpose of my research was to validate the FEM for the ATD using previously run trials with the physical THOR ATD.

Moore, Erik↗

Geologic Landforms and Processes on Icy Satellites

During the first reconaissence of the satellites of the outer solar system conducted by the Voyager missions (1979-1989), a surprising diversity of unusual geologic landforms were observed, in some cases with bewildering complexity (e.g., Triton). Impact features were certainly expected but the variety of volcanic, diapiric, tectonic, impact, and erosional landforms was only remotely suggested by some early theoretical works. These diagnostic features are manifestations of the internal composition, thermal history, and dynamical evolution of these bodies. It is the job of the geologist to interpret the morphology, stratigraphy, and composition of these deposits and structures to ascertain what materials were mobilized in the interior, in what amount, and the mechanism and cause of their mobilization. In this chapter, we review what is know about these features and what constraints can be placed on composition and thermal history. Particular emphasis is placed on volcanic features, as these are most directly related to satellite composition and thermal history. The surface spectra, high albedos, and low bulk densities of the satellites of the outer solar system indicate that water and other ices are abundant on these bodies, particularly on their surfaces. Ices, particularly water ice, are less dense than silicates and will tend to float and form crusts during differentiation or partial melting of the interior. Ices therefore take the place of silicates as 'crust-forming' minerals and dominate geologic processes on icy satellites. Melted ices form magma bodies, and sometimes are extruded as lavas, an unusual but still valid perspective for terrestrial geologists. The unusual properties of some ices, including their low melting temperatures, and low strengths (as well as the decrease in density on the freezing of water ice), will ultimately be very important in interpreting this record.

Schenk, Paul M.↗

Polar Observations of Properties of H+ and O+ Conics in the Cusp Near ~5300 km Altitude

Observations by the thermal ion dynamics experiment (TIDE) on POLAR are used to explore features of low-energy ionospheric ion conical distributions at approximately 5300 km altitude over the southern cusp under different interplanetary magnetic field (IMF) conditions with negative and positive B(sub z) components. The properties are summarized as follows: (1) At the edge upstream of the convection in the cusp, the energy of outflowing ion distributions abruptly increased from a few eV to approximately 100 eV; (2) The angular distributions also abruptly changed from rammed < approximately 5 eV polar wind distributions to approximately 10-100 eV conics; (3) These conic signatures gradually gave way again to polar wind components further downstream of the cusp; (4) The uppermost energy of the detected O+ was larger than that of H+, while the density and flux of O+ were lower than those of H+; (5) The cone angles for both light and heavy ion conics were largest for the upstream region of the convection; (6) Cone angles are wider for O+ than H+; (7) The cone angles as well as the conic energies gradually decreased in the convection direction; (8) The UFI beams and conics were sometimes observed alternately, particularly for H+, and (9) In some cases, the distinct ion conic bursts occurred multiple times during a single cusp crossing.

Hirahara, M.↗

Measurement report: Closure Analysis of Aerosol–cloud Composition in Tropical Maritime Warm Convection

Cloud droplet chemical composition is a key observable property that can aid understanding of how aerosols and clouds interact. As part of the Clouds, Aerosols and Monsoon Processes – Philippines Experiment (CAMP2Ex), three case studies were analyzed involving collocated airborne sampling of relevant clear and cloudy air masses associated with maritime warm convection. Two of the cases represented a polluted marine background, with signatures of transported East Asian regional pollution, aged over water for several days, while the third case comprised a major smoke transport event from Kalimantan fires. Sea salt was a dominant component of cloud droplet composition, in spite of fine particulate enhancement from regional anthropogenic sources. Furthermore, the proportion of sea salt was enhanced relative to sulfate in rainwater and may indicate both a propensity for sea salt to aid warm rain production and an increased collection efficiency of large sea salt particles by rain in subsaturated environments. Amongst cases, as precipitation became more significant, so too did the variability in the sea salt to (non-sea salt) sulfate ratio. Across cases, nitrate and ammonium were fractionally greater in cloud water than fine-mode aerosol particles; however, a strong covariability in cloud water nitrate and sea salt was suggestive of prior uptake of nitrate on large salt particles. A mass-based closure analysis of non-sea salt sulfate compared the cloud water air-equivalent mass concentration to the concentration of aerosol particles serving as cloud condensation nuclei for droplet activation. While sulfate found in cloud was generally constrained by the sub-cloud aerosol concentration, there was significant intra-cloud variability that was attributed to entrainment – causing evaporation of sulfate-containing droplets –and losses due to precipitation. In addition, precipitation tended to promote mesoscale variability in the sub-cloud aerosol through a combination of removal, convective downdrafts, and dynamically driven convergence. Physical mechanisms exerted such strong control over the cloud water compositional budget that it was not possible to isolate any signature of chemical production/loss using in-cloud observations. The cloud-free environment surrounding the non-precipitating smoke case indicated sulfate enhancement compared to convective mixing quantified by a stable gas tracer; however, this was not observed in the cloud water (either through use of ratios or the mass closure), perhaps implying that the warm convective cloud timescale was too short for chemical production to be a leading-order budgetary term and because precursors had already been predominantly exhausted. Closure of other species was truncated by incomplete characterization of coarse aerosol (e.g., it was found that only 10 %–50% of sea salt mass found in cloud was captured during clear-air sampling) and unmeasured gasphase abundances affecting closure of semi-volatile aerosol species (e.g., ammonium, nitrate and organic) and soluble volatile organic compound contributions to total organic carbon in cloud water.

Ewan Crosbie↗

Relationship of O(+) Field-Aligned Flows and Densities to Convection Speed in the Polar Cap at 5000 km Altitude

Measurements of thermal O(+) ion number fluxes, densities, field-aligned velocities, and convective velocities from the Thermal Ion Dynamics Experiment (TIDE) on POLAR obtained near 5000 km altitude over the Southern hemisphere are examined. We find that the O(+) parallel velocities and densities are strongly related to the convection speeds. The polar cap densities decrease rapidly with convection speed, with a linear least square fit formula to bin averaged data giving the relationship log(N(sub (sub _)O(+))) = -0.33* V(sub (sub _)conv)) + 0.07, with a linear regression coefficient of r = -0.96. The parallel bulk flow velocities are on average slightly downward (0 - 2 km/s) for V(sub (sub _)conv) < 2.5 km/s, but tend to be upward (0 - 4 km/s) for average V(sub (sub _)conv) > 2.5 km/s. We interpret these relationships in terms of the Cleft Ion Fountain paradigm [e.g., Horwitz and Lockwood, 1985]. The densities decline with convection speed owing to increased spreading and resulting dilution from the restricted cleft source over the polar cap area with convection speed. The parallel velocities tend to be downward for low convection speeds because they fall earthward after initial cleft injection at shorter distances into the polar cap for low convection speeds. At the higher convection speeds, the initially-upward flows are transported further into the polar cap and thus occupy a larger area of the polar cap.

Stevenson, B. A.↗

Prediction of nonlinear optical properties of organic materials. General theoretical considerations

The prediction of nonlinear optical properties of organic materials is geared to assist materials scientists in the selection of good candidate molecules. A brief summary of the quantum mechanical methods used for estimating hyperpolarizabilities will be presented. The advantages and limitations of each technique will be discussed. Particular attention will be given to the finite-field method for calculating first and second order hyperpolarizabilities, since this method is better suited for large molecules. Corrections for dynamic fields and bulk effects will be discussed in detail, focusing on solvent effects, conformational isomerization, core effects, dispersion, and hydrogen bonding. Several results will be compared with data obtained from third-harmonic-generation (THG) and dc-induced second harmonic generation (EFISH) measurements. These comparisons will demonstrate the qualitative ability of the method to predict the relative strengths of hyperpolarizabilities of a class of compounds. The future application of molecular mechanics, as well as other techniques, in the study of bulk properties and solid state defects will be addressed. The relationship between large values for nonlinear optical properties and large conjugation lengths is well known, and is particularly important for third-order processes. For this reason, the materials with the largest observed nonresonant third-order properties are conjugated polymers. An example of this type of polymer is polydiacetylene. One of the problems in dealing with polydiacetylene is that substituents which may enhance its nonlinear properties may ultimately prevent it from polymerizing. A model which attempts to predict the likelihood of solid-state polymerization is considered, along with the implications of the assumptions that are used. Calculations of the third-order optical properties and their relationship to first-order properties and energy gaps will be discussed. The relationship between monomeric and polymeric third-order optical properties will also be considered.

Cardelino, B.↗

Another Look at Erupting Minifilaments at the Base of Solar X-Ray Polar Coronal “Standard” and “Blowout” Jets

We examine 21 solar polar coronal jets that we identify in soft X-ray images obtained from the Hinode/X-ray telescope (XRT). We identify 11 of these jets as blowout jets and four as standard jets (with six uncertain), based on their X-ray-spire widths being respectively wide or narrow (compared to the jet’s base) in the XRT images. From corresponding Extreme Ultraviolet (EUV) images from the Solar Dynamics Observatory’s (SDO) Atmospheric Imaging Assembly (AIA), essentially all (at least 20 of 21) of the jets are made by minifilament eruptions,consistent with other recent studies. Here, we examine the detailed nature of the erupting minifilaments (EMFs) in the jet bases. Wide-spire (“blowout”) jets often have ejective EMFs, but sometimes they instead have an EMF that is mostly confined to the jet’s base rather than ejected. We also demonstrate that narrow-spire (“standard”) jets can have either a confined EMF, or a partially confined EMF where some of the cool minifilament leaks into the jet’s spire. Regarding EMF visibility: we find that in some cases the minifilament is apparent in as few as one of the four EUV channels we examined, being essentially invisible in the other channels; thus it is necessary to examine images from multiple EUV channels before concluding that a jet does not have an EMF at its base. The size of the EMFs, measured projected against the sky and early in their eruption, is 14′′ ± 7′′, which is within a factor of two of other measured sizes of coronal-jet EMFs. A full report on these results will be published in the Astrophysical Journal. This work was supported by NASA's HGI, HSR, and HSOC programs, and by the NASA/MSFC Hinode Project.

Alphonse C Sterling↗