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At least 253 records · Page 14

Pore architecture controls on mineral reactivity

Mineral dissolution rates measured in natural environments are much slower than those measured in laboratory settings. This project tested the hypothesis that the way fluid flows through rocks in natural systems creates areas where mineral dissolution is fast and areas where mineral dissolution is slow. This hypothesis was tested with a combination of laboratory experiments and numerical simulation. We demonstrated a separation of fluid flow pathways and rates of mineral dissolution in laboratory experiments for the first time using an experimental approach where we created synthetic rocks that have different ratios of connected and dead-end pathways for fluid flow. In laboratory experiments with higher proportions of dead-end pathways, the mineral dissolution rates were slower. We found that where fluid flows through connected pathways the continuous refreshing of fluid at the mineral surface creates conditions where dissolution is fast. In contrast, where fluid either flows slowly through poorly connected pathways or is stagnant in dead-end pathways, mineral dissolution is slow. The results from this project suggest that the overall slowing of rates of mineral dissolution is important when the proportion of dead-end pathways is greater than ~40%. This project informs our understanding of the way that fluids react with rocks in carbon dioxide sequestration and enhanced geothermal projects where fluids are purposefully injected into rocks for energy applications.

58 GEOSCIENCES↗

DECOVALEX-2023: Task F2 Salt Final Report

The subject of Task F of DECOVALEX-2023 concerns performance assessment modelling of radioactive waste disposal in deep mined repositories. The primary objectives of Task F are to build confidence in the models, methods, and software used for performance assessment (PA) of deep geologic nuclear waste repositories, and/or to bring to the fore additional research and development needed to improve PA methodologies. In Task F2- (salt), these objectives have been accomplished through staged development and comparison of the models and methods used by participating teams in their PA frameworks. Coupled-process submodels and deterministic simulations of the entire PA model for a reference scenario for waste disposal in domal salt have been conducted. The task specification has been updated continuously since the initiation of the project to reflect the staged development of the conceptual repository model and performance metrics. Thermal, hydrological, mechanical, and chemical properties of individual components of the engineered and natural system were chosen for relevance by participating teams. The salt reference case system was characterized using data and measurements collected at relevant underground research laboratories (URLs), field sites, and simulation results from teams with specialized modelling capability. Participating teams made a wide range of model assumptions from compartmentalized networks to full 3D models of the salt formation. No single contributed model includes full-fidelity representation of all the features, events, and processes (FEPs) detailed in the task specification, but almost all features and processes are represented in at least one model. Despite differences in the modelling strategies developed by participating teams, all models indicate that salt compaction and radionuclide diffusion are key processes in the repository, and for the FEPs and model scenario considered, little of the disposed radionuclides will migrate beyond the repository seal over the 100,000 year simulations. In general, the model output quantities have the largest differences over the short term and near the waste. The models tend to be more similar further from waste and at later time. Disparities between the models are believed to be due to differing simplifications from the task specification, some of which are chosen simplifications to reduce complexity, and some are restrictions imposed by the modelling tools. A second round of this task has been accepted for DECOVALEX-2027 in conjunction with Task F1 on crystalline PA modelling. The future round includes waste package heating, improved modelling of salt creep closure, additional comparisons of coupled-process sub-models, and the impact of repository engineering design on radionuclide migration in the repository. Participants will also propose and finalize a set of uncertain inputs for the reference case simulations, propagate these uncertainties in a set of realizations, and conduct sensitivity analyses on the simulation results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Citizen-Led Community Innovation for Food Energy Water Nexus Resilience

Food-energy-water (FEW) resources are necessary for the function of multiple socio-natural systems. Understanding the synergies and trade-offs in the FEW nexus, and how these interconnections impact earth’s systems, is critical to ensure adequate access to these resources in the future; an essential component for achieving the Sustainable Development Goals (Scanlon et al., 2017). Although, over the last decade, the identification of FEW nexus complexities has increased at a global (IPCC, 2018; D’Orodico et al., 2018), national (Lant et al., 2019), and city scale (Rushforth and Ruddell, 2018), these findings are yet to be adequately translated into ‘on the ground’ action due a lack of technical and political capacity (Weitz et al., 2017). Specifically, local FEW systems have been overlooked in these analyses (Scanlon et al., 2017; Lant et al., 2019), thus leaving small and medium towns vulnerable due to a lack of data and inadequate FEW system management. Building on three years of field-tested FEW nexus research in the Ruddell Lab, we argue that participatory citizen science projects, such as our FEWSION for Community Resilience initiative, can bridge the data-policy gaps that exist within local FEW system management by: 1) providing last mile data on the FEW system, and 2) translating local data into evidence-based solutions at a grassroots level. Thus, we present a broadly applicable framework and call to action for local scale participatory citizen science to solve complex FEW nexus issues at a local, regional, and national scale.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Niche Differentiation of Bacterial Versus Archaeal Soil Nitrifiers Induced by Ammonium Inhibition Along a Management Gradient

Soil nitrification, mediated mainly by ammonia oxidizing archaea (AOA) and bacteria (AOB), converts ammonium (NH 4 + ) to nitrite (NO 2 – ) and thence nitrate (NO 3 – ). To better understand ecological differences between AOA and AOB, we investigated the nitrification kinetics of AOA and AOB under eight replicated cropped and unmanaged ecosystems (including two fertilized natural systems) along a long-term management intensity gradient in the upper U.S. Midwest. For five of eight ecosystems, AOB but not AOA exhibited Haldane kinetics (inhibited by high NH 4 + additions), especially in perennial and successional systems. In contrast, AOA predominantly exhibited Michaelis-Menten kinetics, suggesting greater resistance to high nitrogen inputs than AOB. These responses suggest the potential for NH 4 + -induced niche differentiation between AOA and AOB. Additionally, long-term fertilization significantly enhanced maximum nitrification rates (V max ) in the early successional systems for both AOA and AOB, but not in the deciduous forest systems. This was likely due to pH suppression of nitrification in the acidic forest soils, corroborated by a positive correlation of V max with soil pH but not with amoA gene abundance. Results also demonstrated that soil nitrification potentials were relatively stable, as there were no seasonal differences. Overall, results suggest that (1) NH 4 + inhibition of AOB but not AOA could be another factor contributing to niche differentiation between AOA and AOB in soil, and (2) nitrification by both AOA and AOB can be significantly promoted by long-term nitrogen inputs.

59 BASIC BIOLOGICAL SCIENCES↗

Data from: Niche differentiation of bacterial versus archaeal soil nitrifiers induced by ammonium inhibition along a management gradient

Soil nitrification, mediated mainly by ammonia oxidizing archaea (AOA) and bacteria (AOB), converts ammonium (NH4+) to nitrite (NO2−) and thence nitrate (NO3−). To better understand ecological differences between AOA and AOB, we investigated the nitrification kinetics of AOA and AOB under eight replicated cropped and unmanaged ecosystems (including two fertilized natural systems) along a long-term management intensity gradient in the upper U.S. Midwest. For five of eight ecosystems, AOB but not AOA exhibited Haldane kinetics (inhibited by high NH4+ additions), especially in perennial and successional systems. In contrast, AOA predominantly exhibited Michaelis-Menten kinetics, suggesting greater resistance to high nitrogen inputs than AOB. These responses suggest the potential for NH4+-induced niche differentiation between AOA and AOB. Additionally, long-term fertilization significantly enhanced maximum nitrification rates (Vmax) in the early successional systems for both AOA and AOB, but not in the deciduous forest systems. This was likely due to pH suppression of nitrification in the acidic forest soils, corroborated by a positive correlation of Vmax with soil pH but not with amoA gene abundance. Results also demonstrated that soil nitrification potentials were relatively stable, as there were no seasonal differences. Overall, results suggest that (1) NH4+ inhibition of AOB but not AOA could be another factor contributing to niche differentiation between AOA and AOB in soil, and (2) nitrification by both AOA and AOB can be significantly promoted by long-term nitrogen inputs.

59 BASIC BIOLOGICAL SCIENCES↗

Data for Hadjimichael et al. - Multi-actor, multi-impact scenario discovery

Naming convention for each file is S[scenario_id]_[realization_id].parquet All realizations are generated as per the accompanying paper: Hadjimichael, A., Reed, P.M., Quinn, J.D, Vernon, C.R., Thurber, T., Multi-actor, multi-impact scenario discovery of consequential narrative storylines for human-natural systems planning. Earth's Future (In Review) Each .parquet file contains the following columns: 'structure_id' : StateMod structure ID data corresponds to 'year': simulation year 'month': simulation month 'demand': water demand in acre-feet 'shortage': water shortage in acre-feet 'river_outflow': streamflow in diversion location in acre-feet 'control_location': other structure or reason for shortage

Hadjimichael, Antonia↗

MultiSector Dynamics: 2023 Inaugural Workshop Report

Preface The MultiSector Dynamics (MSD) Community of Practice (CoP) hosted an inaugural workshop on October 3-5, 2023 at the University of California, Davis, to bring together members of the MSD community of practice to advance understanding of the co-evolution of human and natural systems, and to build the next generation of tools that bridge sectors, scales, and systems to realize a more resilient and equitable future. The theme of the workshop was "Advancing Complex Adaptive Human-Earth Systems Science in a World of Interconnected Risks". This document outlines the motivation for the workshop, its goals and objectives, the application process, the agenda, overviews of the training sessions offered to the workshop participants and a summary of each breakout session. The MSD workshop report further discusses the feedback from workshop participants and presents some reflections and next steps. The MSD Workshop organizers thank the DOE Office of Science, Earth and Environmental System Modeling, MultiSector Dynamics program area for financial support of its activities through the Integrated Multisector Multiscale Modeling (IM3) project. For more information related to the broader DOE MultiSector Dynamics Program please see https://climatemodeling.science.energy.gov/program-area/multisector-dynamics. D.L.M. and C.M.B. acknowledge support from the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory (ORNL), managed by UT-Battelle, LLC, for the US Department of Energy (DOE). Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither theUnited States Government nor any agency thereof, nor Battelle Memorial Institute, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, complete- ness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial products, process, or service by trade name,trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or Battelle Memorial Institute. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. Pacific Northwest National Laboratory operated by Battelle for the United States Department of Energy Available from:Office of Scientific and Technical Information http://www.OSTI.gov multisectordynamics.org This work is made available under the terms of the Creative Commons Attribution- NonCommercial 4.0 International (CC BY-NC 4.0) https://creativecommons.org/licenses/by-nc/4 Suggested citation: Monier, E., Reed, P.M., Vernon, C.R., Hadjimichael, A., Brelsford, C.M., Burleyson, C.B., Dyreson, A.R., Fletcher, S.M., Giang, A., Gupta, R.S., Jackson, N.D., Jones, A.D., Lamontagne, J.R., McCollum, D.L., Morris, J.F., Moss, R.H., Peng, W., Saari, R.K., Srikrishnan, V., Szinai, J.K., Yoon, J. (2024) MultiSector Dynamics: 2023 Inaugural Workshop Report. MSD-LIVE Data Repository. doi:10.57931/2371710.

Monier, Erwan↗

Space vehicle with artificial gravity and earth-like environment

A space vehicle adapted to provide an artificial gravity and earthlike atmospheric environment for occupants is disclosed. The vehicle comprises a cylindrically shaped, hollow pressure-tight body, one end of which is tapered from the largest diameter of the body, the other end is flat and transparent to sunlight. The vehicle is provided with thrust means which rotates the body about its longitudinal axis, generating an artificial gravity effect upon the interior walls of the body due to centrifugal forces. The walls of the tapered end of the body are maintained at a temperature below the dew point of water vapor in the body and lower than the temperature near the transparent end of the body. The controlled environment and sunlight permits an earth like environment to be maintained wherein the CO2/O2 is balanced, and food for the travelers is supplied through a natural system of plant life grown on spacecraft walls where soil is located.

Gray, V. H.↗

Geological survey of Maryland using EREP flight data

The author has identified the following significant results. Underflight photography has been used in the Baltimore County mined land inventory to determine areas of disturbed land where surface mining of sand and ground clay, or stone has taken place. Both active and abandoned pits and quarries were located. Aircraft data has been used to update cultural features of Calvert, Caroline, St. Mary's, Somerset, Talbot, and Wicomico Counties. Islands have been located and catalogued for comparison with older film and map data for erosion data. Strip mined areas are being mapped to obtain total area disturbed to aid in future mining and reclamation problems. Coastal estuarine and Atlantic Coast features are being studied to determine nearshore bedforms, sedimentary, and erosional patterns, and manmade influence on natural systems.

Weaver, K. N.↗

An analysis of the Dahl friction model and its effect on a CMG gimbal rate controller

The effects of friction, represented by the Dahl model, on a CMG rate control system was investigated by digital simulation. The conclusion from these simulation results is that gimbal pivot friction can be a significant effect on the gimbal rate control system. The magnitude of the problem this presents depends on the characteristics of the actual pivot. It would appear from this preliminary look that one solution is to insure that the control system natural frequency is higher by some prescribed amount than the natural frequency of the friction loop.

Nurre, G. S.↗

Water resources planning for rivers draining into mobile bay

A hydrodynamic model describing water movement and tidal elevation is formulated, computed, and used to provide basic data about water quality in natural systems. The hydrodynamic model is based on two-dimensional, unsteady flow equations. The water mass is considered to be reasonably mixed such that integration (averaging) in the depth direction is a valid restriction. Convective acceleration, the Coriolis force, wind and bottom interactions are included as contributing terms in the momentum equations. The solution of the equations is applied to Mobile Bay, and used to investigate the influence that river discharge rate, wind direction and speed, and tidal condition have on water circulation and holdup within the bay. Storm surge conditions, oil spill transport, artificial island construction, dredging, and areas subject to flooding are other topics which could be investigated using the mathematical modeling approach.

Ng, S.↗

On the use of attachment modes in substructure coupling for dynamic analysis

Substructure coupling or component-mode synthesis may be employed in the solution of dynamics problems for complex structures. Although numerous substructure-coupling methods have been devised, little attention has been devoted to methods employing attachment modes. In the present paper the various mode sets (normal modes, constraint modes, attachment modes) are defined. A generalized substructure-coupling procedure is described. Those substructure-coupling methods which employ attachment modes are described in detail. One of these methods is shown to lead to results (e.g., system natural frequencies) comparable to or better than those obtained by the Hurty (1965) method.

Craig, R. R., Jr.↗

Regional energetic coupling of man and his environment: Data requirements

An energy analysis methodology was developed to serve as a rational basis for evaluating alternative regional management/use schemes. Human and natural systems are coupled and can be interpreted, using a common base of energy-flow analysis to evaluate past, present, and future states of regional integrated systems in the coastal zone and to provide the capability for rational selection of alternative patterns of resource use. Energy flows (or flows of dollars or materials converted to energy equivalents) are believed to be the basic factor in the organizations of all types of systems. An analysis example is provided of an estuarine subsystem of the Chesapeake Bay, and tabular listings of regional data needs are given. Current remote sensing capabilities were used to provide some of the necessary information.

Mihursky, J. A.↗

Introduction to Systems Approach

Main aspects of systems theory are outlined. Emphasis is on the interface of between time and systems - natural or artificial.

Winkler, G. M. R.↗

Photovoltaic power system reliability considerations

An example of how modern engineering and safety techniques can be used to assure the reliable and safe operation of photovoltaic power systems is presented. This particular application is for a solar cell power system demonstration project designed to provide electric power requirements for remote villages. The techniques utilized involve a definition of the power system natural and operating environment, use of design criteria and analysis techniques, an awareness of potential problems via the inherent reliability and FMEA methods, and use of fail-safe and planned spare parts engineering philosophy.

Lalli, V. R.↗