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At least 253 records · Page 14

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NASA NTRS1972

Nonequilibrium shock wave structure, 1. Kinetics of nitric oxide formation and decomposition, 2

Theoretical and numerical aspects of molecular flow simulation focussed on the development of collision models for diatomic and triatomic gases undergoing rotational excitation and energy exchange. A laser absorption technique is proposed and analyzed as sufficiently sensitive for measuring rotational populations in a nonequilibrium shock wave. Also reported is a survey of available literature on NO chemical rate data in preparation for experiments on NO decompensation kinetics in atmospheric pollution.

Kruger, C. H.↗

NASA NTRS1972

Numerical solutions of several reflected shock-wave flow fields with nonequilibrium chemical reactions

The method of characteristics for a chemically reacting gas is used in the construction of the time-dependent, one-dimensional flow field resulting from the normal reflection of an incident shock wave at the end wall of a shock tube. Nonequilibrium chemical reactions are allowed behind both the incident and reflected shock waves. All the solutions are evaluated for oxygen, but the results are generally representative of any inviscid, nonconducting, and nonradiating diatomic gas. The solutions clearly show that: (1) both the incident- and reflected-shock chemical relaxation times are important in governing the time to attain steady state thermodynamic properties; and (2) adjacent to the end wall, an excess-entropy layer develops wherein the steady state values of all the thermodynamic variables except pressure differ significantly from their corresponding Rankine-Hugoniot equilibrium values.

Hanson, R. K.↗

NASA NTRS1972

A Numerical Analysis of the Transient Response of an Ablation System Including Effects of Thermal Nonequilibrium, Mass Transfer and Chemical Kinetics

The differential equations governing the transient response of a one-dimensional ablative thermal protection system undergoing stagnation ablation are derived. These equations are for thermal nonequilibrium effects between the pyrolysis gases and the char layer and kinetically controlled chemical reactions and mass transfer between the pyrolysis gases and the char layer. The boundary conditions are written for the particular case of stagnation heating with surface removal by oxidation or sublimation and pyrolysis of the uncharred layer occurring in a plane. The governing equations and boundary conditions are solved numerically using the modified implicit method (Crank-Nicolson method). Numerical results are compared with exact solutions for a number of simplified cases. The comparison is favorable in each instance.

Clark, R. K.↗

NASA NTRS1973

An analysis of a charring ablator with thermal nonequilibrium, chemical kinetics, and mass transfer

The differential equations governing the transient response of a one-dimensional ablative thermal protection system are presented for thermal nonequilibrium between the pyrolysis gases and the char layer and with finite rate chemical reactions occurring. The system consists of three layers (the char layer, the uncharred layer, and an optical insulation layer) with concentrated heat sinks at the back surface and between the second and third layers. The equations are solved numerically by using a modified implicit finite difference scheme to obtain solutions for the thickness of the charred and uncharred layers, surface recession and pyrolysis rates, solid temperatures, porosity profiles, and profiles of pyrolysis-gas temperature, pressure, composition, and flow rate. Good agreement is obtained between numerical results and exact solutions for a number of simplified cases. The complete numerical analysis is used to obtain solutions for an ablative system subjected to a constant heating environment. Effects of thermal, chemical, and mass transfer processes are shown.

Clark, R. K.↗

NASA NTRS1973

Nonequilibrium effects on shock-layer radiometry during earth entry.

Radiative enhancement factors for the CN violet and N2(+) first negative band systems caused by nonequilibrium thermochemistry in the shock layer of a blunt-nosed vehicle during earth entry are reported. The results are based on radiometric measurements obtained with the aid of a combustion-driven shock tube. The technique of converting the shock-tube measurements into predictions of the enhancement factors for the blunt-body case is described, showing it to be useful for similar applications of other shock-tube measurements.

Arnold, J. O.↗

NASA NTRS1973

Wall boundary equations with slip and catalysis for multicomponent, nonequilibrium gas flows

Boundary equations obtained for a low Reynolds number, high enthalpy gas flow in regions of velocity slip and temperature jump are presented. The formulation treats, through a first-order distribution function used to include multicomponent diffusion, a multicomponent gas mixture that may be in nonequilibrium with finite-rate catalytic recombination occurring on the wall. In the boundary equations, which are obtained for use in flow-field calculations applicable to low-density flow regimes, a simplified gas/wall interaction is assumed wherein individual atoms or molecules either reflect specularly off the wall or stick and are fully accommodated. Fluxes in terms of evaluated integrals over the distribution function and integrals necessary for determining fluxes are given.

Scott, C. D.↗

NASA NTRS1974

Similitude requirements for hypersonic, rarefied, nonequilibrium flow

Similitude requirements for hypersonic, rarefied flow with nonequilibrium chemistry and vibration are presented. The full Navier-Stokes equations with catalytic or noncatalytic walls and with or without slip conditions are nondimensionalized. The heat transfer coefficient is written in terms of fourteen dimensionless parameters and reduced to four by making the binary scaling assumption. Duplication of blunt and sharp nose heat transfer requires the use of air over a geometrically similar model with the same free stream velocity, wall temperature and product of free stream density and characteristic length. Estimates of this heat transfer coefficient are also presented.

Hendricks, W. L.↗

NASA NTRS1974

Recent developments on time-dependent calculation of nonequilibrium flows

It is shown that, in a time-dependent nonequilibrium flow analysis, erroneous and unstable solutions can result from the use of temperature equations and flow variables other than pressure in fitting the bow shock. A formulation is presented that has been critically evaluated by comparison with a previous one and found to yield steady and more accurate solutions in conserving total enthalpy.

Li, C. P.↗

NASA NTRS1973

Nonequilibrium distributions of molecular states in interstellar space

Current knowledge on the components of interstellar space and on interstellar dust clouds (which contain most of the molecules existing in interstellar space) is reviewed. The discovery of molecules by absorption of a microwave continuum or by emission from their own excited state is discussed in historical order, and the interpretation of their spectra is examined. The observed microwave resonances of interstellar molecules are tabulated. Another table shows the approximate column densities of molecules found in the directions of the Orion nebula and of Sagittarius. The various types of nonequilibrium encountered are demonstrated by examples.

Townes, C. H.↗

NASA NTRS1974

Nonequilibrium boundary layer at a stagnation point for a hydrogen-helium stream over ablating graphite

The nonequilibrium axisymmetric stagnation point boundary layer over an ablating graphite surface is considered. The external stream is a high temperature mixture of hydrogen and helium. Variable thermodynamic and transport properties are assumed. Lennard-Jones potential model is used to calculate the transport coefficients of each species. Although the mixture rules for viscosity of the gas mixture are used, the weighting functions are more sophisticated than those commonly employed. For the conductivity of the mixture, generalized Wassiljewa coefficients are used. Seven species with 28 dissociation/recombination reactions are considered. Hansen's model for the dissociation rate constants is employed. The recombination rate constants are obtained by invoking detailed balance principles assisted by the JANAF thermodynamic data and the Hansen-Pearson thermodynamic data for C3.

Liu, T.-M.↗

NASA NTRS1974

Slip conditions with wall catalysis and radiation for multicomponent, nonequilibrium gas flow

The slip conditions for a multicomponent mixture with diffusion, wall-catalyzed atom recombination and thermal radiation are derived, and simplified expressions for engineering applications are presented. The gas mixture may be in chemical nonequilibrium with finite-rate catalytic recombination occurring on the wall. These boundary conditions, which are used for rarefied flow regime flow field calculations, are shown to be necessary for accurate predictions of skin friction and heat transfer coefficients in the rarefied portion of the space shuttle trajectory.

Hendricks, W. L.↗

NASA NTRS1977

Design of closed-cycle MHD generator with nonequilibrium ionization and system

A method is developed to include the nonequilibrium ionization process in the MHD generator duct design equations, and these equations are coupled to the thermodynamic conditions of the closed cycle system. This is used to relate MHD generator size, configuration and gas conditions to the overall thermodynamic efficiency of the system. The system studied consists of an MHD loop (Ar + Cs or He + Cs) topping a steam bottoming plant.

Voshall, R. E.↗

NASA NTRS1978

A numerical solution of the Navier-Stokes equations for chemically nonequilibrium, merged stagnation shock layers on spheres and two-dimensional cylinders in air

Results of solving the Navier-Stokes equations for chemically nonequilibrium, merged stagnation shock layers on spheres and two-dimensional cylinders are presented. The effects of wall catalysis and slip are also examined. The thin shock layer assumption is not made, and the thick viscous shock is allowed to develop within the computational domain. The results show good comparison with existing data. Due to the more pronounced merging of shock layer and boundary layer for the sphere, the heating rates for spheres become higher than those for cylinders as the altitude is increased.

Johnston, K. D.↗

NASA NTRS1979

Incorporation of coupled nonequilibrium chemistry into a two-dimensional nozzle code (SEAGULL)

A two-dimensional multiple shock nozzle code (SEAGULL) was extended to include the effects of finite rate chemistry. The basic code that treats multiple shocks and contact surfaces was fully coupled with a generalized finite rate chemistry and vibrational energy exchange package. The modified code retains all of the original SEAGULL features plus the capability to treat chemical and vibrational nonequilibrium reactions. Any chemical and/or vibrational energy exchange mechanism can be handled as long as thermodynamic data and rate constants are available for all participating species.

Ratliff, A. W.↗

NASA NTRS1979

Nonequilibrium ionization in solar and stellar winds

Substantial and systematic departures from ionization equilibrium can occur in the solar transition region and corona when mass outflows are present. Modeling calculations illustrate the general characteristics of the ionization balance in such regions. The presence of nonequilibrium conditions suggests a natural explanation for the extended region of EUV line emission that is observed above the solar limb. Comparison with observations of a coronal hole on the disk indicates that outflow may not start until temperatures of about 250,000 K are reached. Additional consequences include a diminution of the density discrepancy between ultraviolet and radio observations of coronal holes, and potential effects on the energy balance in solar and stellar atmospheres undergoing mass loss.

Dupree, A. K.↗

NASA NTRS1979

Solution of Boltzmann equation for highly nonequilibrium diatomic gases rotational translational energy relaxation

The direct simulation Monte Carlo method is applied to solve the Boltzmann equation for collisions between internally excited diatomic gases in highly nonequilibrium states. The semiclassical transition probability is incorporated in the simulation for energy exchange between rotational and translational energy. The results provide details on the fundamental mechanisms of gas kinetics where analytical methods are impractical. The validity of the local Maxwellian assumption and relaxation time, rotational-translational energy transition, and a velocity analysis of the inelastic collision are discussed in detail.

Yoshikawa, K. K.↗

NASA NTRS1981

An overview of the nonequilibrium behavior of polymer glasses

It is pointed out that research efforts are at present being directed in two areas, one comprising experimental studies of this phenomenon in various glassy polymer systems and the other involving the development of a quantitative theory capable of satisfactorily predicting aging behavior for a variety of polymer materials under different conditions. Recent work in both these areas is surveyed. The basic principles of nonequilibrium behavior are outlined, with emphasis placed on changes in material properties with annealing below the glass transition temperature. Free volume theory and thermodynamic theory are discussed.

Tant, M. R.↗

NASA NTRS1981

Dielectric tensor of a weakly relativistic, nonequilibrium, and magnetized plasma

The dielectric tensor of a magnetized plasma is investigated in order to obtain analytic expressions which can be used to study wave-plasma interactions for the case of wave frequencies lying close to the cyclotron harmonics of ions or electrons. Work on this topic by Trubnikov (1959) and Shkarovsky (1966) is extended to the nonequilibrium cases, in which the particles may have drift motions, thermal anisotropy, and loss-cone-type distributions. Account is taken of these features, and a set of analytic expressions in terms of an integral is derived. The discussion presented is pertinent to the absorption and emission of radiation near the electron cyclotron harmonics.

Tsai, S. T.↗