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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Analysis of Smart Composite Structures Including Debonding

Smart composite structures with distributed sensors and actuators have the capability to actively respond to a changing environment while offering significant weight savings and additional passive controllability through ply tailoring. Piezoelectric sensing and actuation of composite laminates is the most promising concept due to the static and dynamic control capabilities. Essential to the implementation of these smart composites are the development of accurate and efficient modeling techniques and experimental validation. This research addresses each of these important topics. A refined higher order theory is developed to model composite structures with surface bonded or embedded piezoelectric transducers. These transducers are used as both sensors and actuators for closed loop control. The theory accurately captures the transverse shear deformation through the thickness of the smart composite laminate while satisfying stress free boundary conditions on the free surfaces. The theory is extended to include the effect of debonding at the actuator-laminate interface. The developed analytical model is implemented using the finite element method utilizing an induced strain approach for computational efficiency. This allows general laminate geometries and boundary conditions to be analyzed. The state space control equations are developed to allow flexibility in the design of the control system. Circuit concepts are also discussed. Static and dynamic results of smart composite structures, obtained using the higher order theory, are correlated with available analytical data. Comparisons, including debonded laminates, are also made with a general purpose finite element code and available experimental data. Overall, very good agreement is observed. Convergence of the finite element implementation of the higher order theory is shown with exact solutions. Additional results demonstrate the utility of the developed theory to study piezoelectric actuation of composite laminates with pre-existing debonding. Significant changes in the modes shapes and reductions in the control authority result due to partially debonded actuators. An experimental investigation addresses practical issues, such as circuit design and implementation, associated with piezoelectric sensing and actuation of composite laminates. Composite specimens with piezoelectric transducers were designed, constructed and tested to validate the higher order theory. These specimens were tested with various stacking sequences, debonding lengths and gains for both open and closed loop cases. Frequency changes of 15% and damping on the order of more than 20% of critical damping, via closed loop control, was achieved. Correlation with the higher order theory is very good. Debonding is shown to adversely affect the open and closed loop frequencies, damping ratios, settling time and control authority.

Chattopadhyay, Aditi↗
NASA NTRSDate not supplied

Modeling the Worst-Case-Scenario of Soil Drydown for Agricultural Drought Monitoring in Kansas Using NASA Earth Observations and In-situ Parameters

Climatologists in Kansas have observed rapid shifts from wet to dry conditions and rapid intensification of drought conditions for the state in recent years. As a leading state in agricultural production, drought events can lead to decreased crop yields and impact the state’s economy. The exponential decay of soil moisture content is a major consequence of drought and can exacerbate these impacts on agricultural production. This study examined the rate of soil moisture drydown in Kansas to understand and monitor the worst-case-scenario of short-term soil water shortage. Soil Moisture Active Passive (SMAP) L-band Radiometer rootzone soil moisture imagery from March 2015 to June 2019 was used to estimate the minimum and maximum soil moisture capacity throughout the state. In situ soil moisture parameters, such as the exponential decay constant, were approximated from the Kansas Mesonet system. These variables were inputs into an exponential decay model that forecasted gridded rootzone soil moisture in a scenario that assumed no precipitation for a user-identified period of time. The forecasts were output on the order of weeks to capture the rapid shifts in soil moisture content. Another model was used to identify areas in Kansas currently below a given percentage of the relative soil moisture saturation, measured as a function of minimum, maximum, and current soil moisture. This model forecasted the number of days until each cell in the soil moisture grid reached the input percentage of relative soil moisture saturation. The gridded model outputs and workflow were developed in partnership with the Kansas Water Office and Kansas Office of the State Climatologist at Kansas State University, as a part of their drought monitoring efforts.

NASA DEVELOP↗
NASA NTRS2006

Remote Sensing of Cloud Properties using Ground-based Measurements of Zenith Radiance

An extensive verification of cloud property retrievals has been conducted for two algorithms using zenith radiances measured by the Atmospheric Radiation Measurement (ARM) Program ground-based passive two-channel (673 and 870 nm) Narrow Field-Of-View Radiometer. The underlying principle of these algorithms is that clouds have nearly identical optical properties at these wavelengths, but corresponding spectral surface reflectances (for vegetated surfaces) differ significantly. The first algorithm, the RED vs. NIR, works for a fully three-dimensional cloud situation. It retrieves not only cloud optical depth, but also an effective radiative cloud fraction. Importantly, due to one-second time resolution of radiance measurements, we are able, for the first time, to capture detailed changes in cloud structure at the natural time scale of cloud evolution. The cloud optical depths tau retrieved by this algorithm are comparable to those inferred from both downward fluxes in overcast situations and microwave brightness temperatures for broken clouds. Moreover, it can retrieve tau for thin patchy clouds, where flux and microwave observations fail to detect them. The second algorithm, referred to as COUPLED, couples zenith radiances with simultaneous fluxes to infer 2. In general, the COUPLED and RED vs. NIR algorithms retrieve consistent values of tau. However, the COUPLED algorithm is more sensitive to the accuracies of measured radiance, flux, and surface reflectance than the RED vs. NIR algorithm. This is especially true for thick overcast clouds where it may substantially overestimate z.

Chiu, J. Christine↗
DOE OSTI2024

A near X-point charge exchange neutral spectroscopy (CENS) system for DIII-D

A 16 channel spectroscopy system has been installed on DIII-D to provide information about the energy distribution of the atomic neutrals using the Doppler shift and broadening of passive Balmer-α emission. Here, the lines of sight are dominantly in the toroidal direction, with tangencies near the lowest point on closed magnetic flux surfaces moving from the lower divertor upward into the confined plasma. This allows the system to provide details of the neutrals as they undergo various atomic physics processes while traveling upward from the lower divertor. The spectrally resolved measurements provide several advantages that complement typical optical filter based measurements of hydrogenic spectral lines. These include more direct measurements of the neutrals that fuel deeper in the plasma and capturing neutral velocity distribution information via the Doppler broadened and shifted line. In addition, the spectral separation of higher energy “thermal” neutrals and bright cold emission from the scrape-off layer allows for a more straightforward calculation of the underlying neutral densities based on the emission because of the dependence of the thermal emission on confined plasma properties that are approximately flux functions and well measured.

Atomic and molecular physics↗
DOE OSTI2019

Experimental and Computational Analysis of NEAMS Pebble Bed Reactors

The Advanced High-Temperature Pebble Bed Reactor concept leverages a particle-based fuel format consisting of discrete spherical graphite pebbles arrayed in a packed bed architecture. Thermal regulation achieved via flow of gas (e.g., helium) or liquid (e.g., molten salt) coolants through the void spaces between pebbles in the bed (characteristic pebble diameters: ~ 6 cm, gas cooled; ~ 3 cm, liquid cooled). This design is of interest owing to inherent advantages including passive safety features and highly efficient heat transfer characteristics that enable high power densities to be achieved. Fully leveraging these advantages requires a fundamental understanding of the complex coolant flow structure within the pebble-shaped fuel bed. Unfortunately, complexities associated with non-invasively probing the micro-scale flow phenomena within the complex network of void spaces between pebbles have hindered efforts to characterize the underlying transport phenomena. Without this fundamental foundation, it becomes challenging to rationally construct macroscopic transport models based upon volume averages of micro-scale parameters that accurately capture the observed flow behavior. Consequently, this lack of fundamental knowledge has limited previous work to coarse comparisons between theory and extremely limited experimental data. Moreover, these comparisons have been made only in terms of integral or macroscopic results. Therefore, multipoint measurements with a high level of spatial and temporal resolution are critically needed to fully map the complex flow patterns and to provide data at high spatial density to permit accurate volume averaging in the pebble bed. For this project, we performed a coordinated experimental and computational effort to quantitatively map the full-field velocity and temperature fields in the interstitial spaces within the pebble bed. The major accomplishments of this project included the important knowledge acquired for the flow mixing and heat transfer in the interstitial pore scales, the effects of flow mixing in the near-wall and far-wall regions, and the by-pass flows of pebble bed systems. The produced high-resolution experimental data (not broadly available in existing literature) were then used for the numerical studies enabling the refinement and validation of standard simulation tools (Nek5000).

42 ENGINEERING↗
DOE OSTI2020

Ubiquitous Power Electronics in Future Power Systems: Recommendations to fully utilize fast control capabilities

Power electronics is becoming ubiquitous in power systems because the rapid growth of variable renewable generation such as wind and solar, responsive load, electric vehicles, energy storage, as well as DC transmission. As a result, a high percentage of electricity will be generated, transmitted or consumed by power electronics in the future power system. Such a high penetration of power electronics is changing power system operation landscapes and dynamic characteristics. Two major kinds of impact are reduced system mechanical inertia by inverter-based resources displacing conventional generation and active participation of many distributed energy resources through inverters. This has caused significant reliability challenges for power system operation. The mitigation approach so far has mostly focused on accommodating power electronics inverters as passive devices or creating synthetic inertias to make inverter-based generation behaving as conventional generators. However, the high-speed control capabilities of power electronics present new opportunities for achieving an optimal performance beyond conventional power systems. A lower-inertia system can be more responsive for improving reliability, and distributed small resources can be more adaptive and scalable for better flexibility and resilience. Power electronic inverters are capable of multiple fast control functions. To fully utilized the ubiquitous power electronics in power systems requires technology advancements in the following areas: data and communications to capture the new dynamic behaviors introduced by power electronics; modeling and simulation to understand the behaviors of power electronics and its interactions with other components in the context of power systems; control and optimization methods for fully utilizing the capabilities of power electronics for a new paradigm of performance beyond the traditional inertia-heavy system; and significant upgrades in power electronics hardware to cater to the new control capabilities. If properly controlled and optimized, power electronics can help transform the power system to be responsive, adaptive, and scalable.

Huang, Zhenyu↗
NASA NTRS2012

RFI Risk Reduction Activities Using New Goddard Digital Radiometry Capabilities

The Goddard Radio-Frequency Explorer (GREX) is the latest fast-sampling radiometer digital back-end processor that will be used for radiometry and radio-frequency interference (RFI) surveying at Goddard Space Flight Center. The system is compact and deployable, with a mass of about 40 kilograms. It is intended to be flown on aircraft. GREX is compatible with almost any aircraft, including P-3, twin otter, C-23, C-130, G3, and G5 types. At a minimum, the system can function as a clone of the Soil Moisture Active Passive (SMAP) ground-based development unit [1], or can be a completely independent system that is interfaced to any radiometer, provided that frequency shifting to GREX's intermediate frequency is performed prior to sampling. If the radiometer RF is less than 200MHz, then the band can be sampled and acquired directly by the system. A key feature of GREX is its ability to simultaneously sample two polarization channels simultaneously at up to 400MSPS, 14-bit resolution each. The sampled signals can be recorded continuously to a 23 TB solid-state RAID storage array. Data captures can be analyzed offline using the supercomputing facilities at Goddard Space Flight Center. In addition, various Field Programmable Gate Array (FPGA) - amenable radiometer signal processing and RFI detection algorithms can be implemented directly on the GREX system because it includes a high-capacity Xilinx Virtex-5 FPGA prototyping system that is user customizable.

Bradley, Damon↗
NASA NTRSDate not supplied

NASA Capture, Containment, and Return System: Bringing Mars Samples to Earth

The Capture, Containment, and Return System (CCRS) project is NASA’s last step in bringing back Mars samples. CCRS will close a decades-long multi-mission and multi-agency effort to bring Mars surface samples back to Earth for scientific studies. CCRS will launch in 2027 on the European Earth Return Orbiter (ERO) spacecraft, which will provide communications relay for the Mars Sample Return ground missions, Perseverance rover and the Sample Retrieval Lander (SRL) (to be launched in 2028). The main mission for CCRS begins when the first-ever orbital planetary capture operation occurs with CCRS catching and securing the Orbiting Sample (OS)in low Mars orbit. From this point, the system will perform additional "firsts": it will autonomously contain the OS with heat-shrink-fit, sterilize the outside surface, and assemble the Earth entry capsule, named Earth Entry System (EES), in orbit around Mars using a gantry mechanism. At approximately 2.8 Lunar distances from Earth, or 3-days from entry into Earth’s atmosphere, CCRS will open its micrometeoroid shield and release the EES on a ballistic trajectory to Earth. The EES is designed to be a fully passive system that will enter the atmosphere and land without parachute at the Utah Test and Training Range (UTTR).

Mars mission, Sample return, Mission design↗
DOE OSTI2021

Ring Model Development and Validation for Prismatic HTGR Core Thermal-hydraulics and Safety Analysis

Because of the complex core geometry, prismatic high temperature gas-cooled reactors (prismatic HTGRs) often exhibit complex thermal fluid behaviors during both normal operating and transient conditions. Most HTGR designs rely on passive safety system for decay heat removal, such as the reactor cavity cooling system (RCCS). During postulated accidents like Pressurized Conduction Cooldown (PCC) event, the decay heat is first radially transferred from the core region to the reactor vessel outer surface, then to the RCCS cooling panels. The peak fuel temperature is controlled by heat transfer mechanisms with two distinctive characteristic length scales, i.e., the core-wise effective heat conduction and local heat conduction in the fuel pellet scale. As both length scales are essential to determine the fuel temperature, from the modeling perspective, computer codes must be able to capture heat transfer in both scales. This is challenging for both computational fluid dynamics (CFD) tools because of extremely large amount of computation resources required, and for system analysis codes because of the challenge to model the complex core geometry. Under the support of DOE-NE’s Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, efforts have been pursued to support HTGR technology development and its modeling and simulation needs. There is a particular need for advanced modeling and simulation tools to predict thermal-fluid behavior during safety-related transients. In our previous studies, the ring model was adopted in SAM and further developed to simulate the normal operating condition and a PCC event using the MHTGR-350 design of General Atomics as the reference design. This current work represents a continuation of these previous efforts, and the focus is to critically review and examine simplifications and assumptions made to develop the ring model, and to perform code validation using experimental data from an integral-effect test facility, the High Temperature Test Facility (HTTF) at the Oregon State University. In this study, the test PG-27 from the HTTF test suite was selected for code validation purpose. The test PG-27 is a transient test designed to simulate the PCC event of the MHTGR design. Very good agreements between SAM prediction and experimental measurements were found in both coolant and solid structure temperatures during the transient.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2022

Gaussian approximation potential for amorphous Si : H

Hydrogenation of amorphous silicon (a–Si : H) is critical for reducing defect densities, passivating midgap states and surfaces, and improving photoconductivity in silicon-based electro-optical devices. Modeling the atomic-scale structure of this material is critical to understanding these processes, which in turn is needed to describe c–Si/a–Si : H heterojunctions that are at the heart of modern solar cells with world-record efficiency. Density functional theory (DFT) studies achieve the required high accuracy but are limited to moderate system sizes of 100 atoms or so by their high computational cost. Simulations of amorphous materials have been hindered by this high cost because large structural models are required to capture the medium-range order that is characteristic of such materials. Empirical potential models are much faster, but their accuracy is not sufficient to correctly describe the frustrated local structure. Data-driven, machine-learned interatomic potentials have broken this impasse and have been highly successful in describing a variety of amorphous materials in their elemental phase. Here, we extend the Gaussian approximation potential (GAP) for silicon by incorporating the interaction with hydrogen, thereby significantly improving the degree of realism with which amorphous silicon can be modeled. We show that our Si : H GAP enables the simulation of hydrogenated silicon with an accuracy very close to DFT but with computational expense and run times reduced by several orders of magnitude for large structures. Here, we demonstrate the capabilities of the Si : H GAP by creating models of hydrogenated liquid and amorphous silicon and showing that their energies, forces, and stresses are in excellent agreement with DFT results, and their structure as captured by bond and angle distributions are in agreement with both DFT and experiments.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Screening analysis of enhanced weathering of igneous rocks and industrial waste materials

Enhanced weathering (EW) is a promising emerging carbon dioxide removal approach that involves harnessing and accelerating the natural weathering process by which atmospheric CO2 passively reacts with exposed alkaline minerals and is removed from the atmosphere. This manuscript reports on a screening level techno-economic analysis of EW. Two primary cases utilizing different sources of alkaline material are considered: (1) utilizing naturally occurring mined igneous rocks, and (2) utilizing industrial waste materials. The modeled EW process encompasses material purchase, comminution, transport, distribution of material on farmland, and measurement, reporting and verification of CO2 removal. Detailed sensitivities are performed to highlight promising scenarios for application. The analysis highlights that utilizing materials with high weathering potential in suitable locations may result in relatively low levelized cost of captured (less than $100 per total tonnes of CO2 captured from the atmosphere). NETL is publishing a detailed and transparent report titled “Enhanced Weathering: Techno-Economic and Life Cycle Screening Analysis” that includes more detail on the screening level techno-economic analysis and includes a life cycle analysis.

Leptinsky, Sarah [NETL Site Support Contractor, Na↗
NASA NTRS1992

Testing of FTS fingers and interface using a passive compliant robot manipulator

This report deals with testing of a pair of robot fingers designed for the Flight Telerobotic Servicer (FTS) to grasp a cylinder type of Orbital Replaceable Unit (ORU) interface. The report first describes the objectives of the study and then the testbed consisting of a Stewart Platform-based manipulator equipped with a passive compliant platform which also serves as a force/torque sensor. Kinematic analysis is then performed to provide a closed-form solution for the force inverse kinematics and iterative solution for the force forward kinematics using the Newton's Raphson Method. Mathematical expressions are then derived to compute force/torques applied to the FTS fingers during the mating/demating with the interface. The report then presents the three parts of the experimental study on the feasibility and characteristics of the fingers. The first part obtains data of forces applied by the fingers to the interface under various misalignments, the second part determines the maximum allowable capture angles for mating, and the third part processes and interprets the obtained force/torque data.

Nguyen, Charles C.↗
NASA NTRS2021

Surface Melting Over the Greenland Ice Sheet Derived From Enhanced Resolution Passive Microwave Brightness Temperatures (1979–2019)

Surface melting is a major component of the Greenland ice sheet surface mass balance, and it affects sea level rise through direct runoff and the modulation of ice dynamics and hydrological processes, supraglacially, englacially and subglacially. Passive microwave (PMW) brightness temperature observations are of paramount importance in studying the spatial and temporal evolution of surface melting due to their long temporal coverage (1979–present) and high temporal resolution (daily). However, a major limitation of PMW datasets has been the relatively coarse spatial resolution, which has historically been of the order of tens of kilometers. Here, we use a newly released PMW dataset (37 GHz, horizontal polarization) made available through a NASA “Making Earth System Data Records for Use in Research Environments” (MeASUREs) program to study the spatiotemporal evolution of surface melting over the Greenland ice sheet at an enhanced spatial resolution of 3.125 km. We assess the outputs of different detection algorithms using data collected by automatic weather stations (AWSs) and the outputs of the Modèle Atmosphérique Régional (MAR) regional climate model. We found that sporadic melting is well captured using a dynamic algorithm based on the outputs of the Microwave Emission Model of Layered Snowpack (MEMLS), whereas a fixed threshold of 245 K is capable of detecting persistent melt. Our results indicate that, during the reference period from 1979 to 2019 (from 1988 to 2019), surface melting over the ice sheet increased in terms of both duration, up to 4.5 (2.9) d per decade, and extension, up to 6.9 % (3.6 %) of the entire ice sheet surface extent per decade, according to the MEMLS algorithm. Furthermore, the melting season started up to 4.0 (2.5) d earlier and ended 7.0 (3.9) d later per decade. We also explored the information content of the enhanced-resolution dataset with respect to the one at 25 km and MAR outputs using a semi-variogram approach. We found that the enhanced product is more sensitive to local-scale processes, thereby confirming the potential of this new enhanced product for monitoring surface melting over Greenland at a higher spatial resolution than the historical products and for monitoring its impact on sea level rise. This offers the opportunity to improve our understanding of the processes driving melting, to validate modeled melt extent at high resolution and, potentially, to assimilate these data in climate models.

Surface melting↗
NASA NTRS2018

Assessing Global Surface Water Inundation Dynamics Using Combined Satellite Information from SMAP, AMSR2 and Landsat

A method to assess global land surface water (fw) inundation dynamics was developed by exploiting the enhanced fw sensitivity of L-band (1.4 GHz) passive microwave observations from the Soil Moisture Active Passive (SMAP) mission. The L-band fw (fw(sub LBand)) retrievals were derived using SMAP H-polarization brightness temperature (Tb) observations and predefined L-band reference microwave emissivities for water and land endmembers. Potential soil moisture and vegetation contributions to the microwave signal were represented from overlapping higher frequency (Tb) observations from AMSR2. The resulting (fw(sub LBand)) global record has high temporal sampling (1-3 days) and 36-km spatial resolution. The (fw(sub LBand)) annual averages corresponded favourably (R=0.84, p<0.001) with a 250-m resolution static global water map (MOD44W) aggregated at the same spatial scale, while capturing significant inundation variations worldwide. The monthly (fw(sub LBand)) averages also showed seasonal inundation changes consistent with river discharge records within six major US river basins. An uncertainty analysis indicated generally reliable (fw(sub LBand)) performance for major land cover areas and under low to moderate vegetation cover, but with lower accuracy for detecting water bodies covered by dense vegetation. Finer resolution (30-m) (fw(sub LBand)) results were obtained for three sub-regions in North America using an empirical downscaling approach and ancillary global Water Occurrence Dataset (WOD) derived from the historical Landsat record. The resulting 30-m (fw(sub LBand)) retrievals showed favourable spatial accuracy for water (70.71%) and land (98.99%) classifications and seasonal wet and dry periods when compared to independent water maps derived from Landsat-8 imagery. The new (fw(sub LBand)) algorithms and continuing SMAP and AMSR2 operations provide for near real-time, multi-scale monitoring of global surface water inundation dynamics and potential flood risk.

WOD↗
DOE OSTI2021

Modeling HIV-1 Within-Host Dynamics After Passive Infusion of the Broadly Neutralizing Antibody VRC01

VRC01 is a broadly neutralizing antibody that targets the CD4 binding site of HIV-1 gp120. Passive administration of VRC01 in humans has assessed the safety and the effect on plasma viremia of this monoclonal antibody (mAb) in a phase 1 clinical trial. After VRC01 infusion, the plasma viral load in most of the participants was reduced but had particular dynamics not observed during antiretroviral therapy. In this paper, we introduce different mathematical models to explain the observed dynamics and fit them to the plasma viral load data. Based on the fitting results we argue that a model containing reversible Ab binding to virions and clearance of virus-VRC01 complexes by a two-step process that includes (1) saturable capture followed by (2) internalization/degradation by phagocytes, best explains the data. This model predicts that VRC01 may enhance the clearance of Ab-virus complexes, explaining the initial viral decay observed immediately after antibody infusion in some participants. Because Ab-virus complexes are assumed to be unable to infect cells, i.e., contain neutralized virus, the model predicts a longer-term viral decay consistent with that observed in the VRC01 treated participants. By assuming a homogeneous viral population sensitive to VRC01, the model provides good fits to all of the participant data. However, the fits are improved by assuming that there were two populations of virus, one more susceptible to antibody-mediated neutralization than the other.

60 APPLIED LIFE SCIENCES↗
NASA NTRS2019

Evaluating Models' Response of Tropical Low Clouds to SST Forcings Using CALIPSO Observations

Recent studies have shown that, in response to a surface warming, the marine tropical low-cloud cover (LCC) as observed by passive-sensor satellites substantially decreases, therefore generating a smaller negative value of the top-of-the-atmosphere (TOA) cloud radiative effect (CRE). Here we study the LCC and CRE interannual changes in response to sea surface temperature (SST) forcings in the GISS model E2 climate model, a developmental version of the GISS model E3 climate model, and in 12 other climate models, as a function of their ability to represent the vertical structure of the cloud response to SST change against 10 years of CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) observations. The more realistic models (those that satisfy the observational constraint) capture the observed interannual LCC change quite well ([delta]LCC]/[delta]SST= -3.49±1.01%K [negative 1 superscript] vs. [delta]LCC/[delta]SST[subscript obs]= -3.59±0.28%K[negative 1 superscript]) while the others largely underestimate it ([delta]LCC/[delta]SST= -1.32±1.28%K[negative 1 superscript]). Consequently, the more realistic models simulate more positive shortwave (SW) feedback ([delta]CRE/[delta]SST=2.60±1.13Wm[negative 2 superscript] K[negative 1 superscript]) than the less realistic models (CRE/SST=0.87±2.63Wm2K1), in better agreement with the observations ([delta]CRE/[delta]SST[subscript obs]=3±0.26Wm[negative 2 superscript] K[negative 1 superscript] ), although slightly underestimated. The ability of the models to represent moist processes within the planetary boundary layer (PBL) and produce persistent stratocumulus (Sc) decks appears crucial to replicating the observed relationship between clouds, radiation and surface temperature. This relationship is different depending on the type of low clouds in the observations. Over stratocumulus regions, cloud-top height increases slightly with SST, accompanied by a large decrease in cloud fraction, whereas over trade cumulus (Cu) regions, cloud fraction decreases everywhere, to a smaller extent.

low clouds↗
NASA NTRS2016

A Quasi-Global Approach to Improve Day-Time Satellite Surface Soil Moisture Anomalies through the Land Surface Temperature Input

Passive microwave observations from various spaceborne sensors have been linked to the soil moisture of the Earth's surface layer. A new generation of passive microwave sensors are dedicated to retrieving this variable and make observations in the single theoretically optimal L-band frequency (1-2 GHz). Previous generations of passive microwave sensors made observations in a range of higher frequencies, allowing for simultaneous estimation of additional variables required for solving the radiative transfer equation. One of these additional variables is land surface temperature, which plays a unique role in the radiative transfer equation and has an influence on the final quality of retrieved soil moisture anomalies. This study presents an optimization procedure for soil moisture retrievals through a quasi-global precipitation-based verification technique, the so-called Rvalue metric. Various land surface temperature scenarios were evaluated in which biases were added to an existing linear regression, specifically focusing on improving the skills to capture the temporal variability of soil moisture. We focus on the relative quality of the day-time (01:30 pm) observations from the Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E), as these are theoretically most challenging due to the thermal equilibrium theory, and existing studies indicate that larger improvements are possible for these observations compared to their night-time (01:30 am) equivalent. Soil moisture data used in this study were retrieved through the Land Parameter Retrieval Model (LPRM), and in line with theory, both satellite paths show a unique and distinct degradation as a function of vegetation density. Both the ascending (01:30 pm) and descending (01:30 am) paths of the publicly available and widely used AMSR-E LPRM soil moisture products were used for benchmarking purposes. Several scenarios were employed in which the land surface temperature input for the radiative transfer was varied by imposing a bias on an existing regression. These scenarios were evaluated through the Rvalue technique, resulting in optimal bias values on top of this regression. In a next step, these optimal bias values were incorporated in order to re-calibrate the existing linear regression, resulting in a quasi-global uniform LST relation for day-time observations. In a final step, day-time soil moisture retrievals using the re-calibrated land surface temperature relation were again validated through the Rvalue technique. Results indicate an average increasing Rvalue of 16.5%, which indicates a better performance obtained through the re-calibration. This number was confirmed through an independent Triple Collocation verification over the same domain, demonstrating an average root mean square error reduction of 15.3%. Furthermore, a comparison against an extensive in situ database (679 stations) also indicates a generally higher quality for the re-calibrated dataset. Besides the improved day-time dataset, this study furthermore provides insights on the relative quality of soil moisture retrieved from AMSR-E's day- and night-time observations.

soil moisture↗
DOE OSTI2023

Design, construction, and validation of an in-situ groundwater trace element analyzer with applications in carbon storage

Abstract It is estimated that carbon emissions should reach net-zero by 2050 to meet important climate targets. Carbon capture is likely necessary to reach these targets, requiring a long-term storage solution such as geological carbon sequestration. However, as with any subsurface activity, leakage can occur, potentially impacting groundwater quality near the storage site. Rapid detection is essential to mitigate damage to this resource. Since CO 2 will acidify groundwater, the concentrations of acid soluble minerals and associated cations will increase. Thus, an in-situ, real-time element analysis system based on laser-induced breakdown spectroscopy (LIBS) is under development to monitor these elements. The system splits the traditional LIBS system into a miniature, all-optical sensor head built around a passively Q-switch laser fiber coupled to a control unit. Previous work has validated the LIBS technique for use at high pressure as well as the split system design. In this work, a fieldable prototype sensor is developed and tested in an onsite monitoring well where trace elements concentrations (approx. 0–3 ppm) were tracked over 20 days. These concentrations varied in response to local rainfall, diluting with increased rain, demonstrating the ability of a LIBS-based sensor to track trace elements under real-world conditions.

54 ENVIRONMENTAL SCIENCES↗