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At least 253 records · Page 14

Carboxylic acid induced restructuring of the Fe 3 O 4 (001) surface

The redox properties of Fe 3 O 4 surfaces are central to many catalytic processes and enable dynamic, reduction-induced morphological restructuring during reactions. Here, we investigate the structural changes of the Fe 3 O 4 (001) surface during the decomposition of formic and acetic acids using scanning tunneling microscopy, X-ray photoelectron spectroscopy, and density functional theory (DFT) calculations. Both acids readily deprotonate, forming ordered carboxylate overlayers on the surface. Product formation pathways involve the removal of lattice oxygen, resulting in extensive surface restructuring. For formic acid, only a modest level of surface oxygen removal (∼3%) is observed, resulting in elongated pits along the octahedral Fe rows and exhibiting an aspect ratio of ∼3. In contrast, acetic acid induces more extensive reduction, with the removal of ∼20% of surface oxygen, yielding significantly larger pits while maintaining a similar aspect ratio. Repeated exposure to acetic acid further enlarges the pits, indicating preferential etching at step edges. DFT calculations reveal a mechanistic sequence in which lattice oxygen removal destabilizes adjacent Fe atoms, promoting their migration into the bulk and subsequent pit propagation and step edge formation. Together, these findings provide atomistic insights into the coupling between carboxylic acid conversion and oxide surface restructuring, underscoring the strong interplay between redox chemistry and morphological changes on catalytically active Fe 3 O 4 surfaces.

Ortiz-Garcia, José J. [Pacific Northwest National ↗

Xylem network connectivity and embolism spread in grapevine( Vitis vinifera L.)

Abstract Xylem networks are vulnerable to the formation and spread of gas embolisms that reduce water transport. Embolisms spread through interconduit pits, but the three-dimensional (3D) complexity and scale of xylem networks means that the functional implications of intervessel connections are not well understood. Here, xylem networks of grapevine (Vitis vinifera L.) were reconstructed from 3D high-resolution X-ray micro-computed tomography (microCT) images. Xylem network performance was then modeled to simulate loss of hydraulic conductivity under increasingly negative xylem sap pressure simulating drought stress conditions. We also considered the sensitivity of xylem network performance to changes in key network parameters. We found that the mean pit area per intervessel connection was constant across 10 networks from three, 1.5-m stem segments, but short (0.5 cm) segments fail to capture complete network connectivity. Simulations showed that network organization imparted additional resistance to embolism spread beyond the air-seeding threshold of pit membranes. Xylem network vulnerability to embolism spread was most sensitive to variation in the number and location of vessels that were initially embolized and pit membrane vulnerability. Our results show that xylem network organization can increase stem resistance to embolism spread by 40% (0.66 MPa) and challenge the notion that a single embolism can spread rapidly throughout an entire xylem network.

Wason, Jay↗

Test Results of the CERN HL-LHC low- Quadrupole Short Models MQXFS3c and MQXFS4

For the High Luminosity Upgrade of the CERN Large Hadron Collider, lower * quadrupole magnets based on advanced Nb3Sn conductors will be installed on each side of the ATLAS and CMS experiment insertion zones. As part of the technological developments needed to achieve the required field gradient of 132.6 T/m within a 150-mm aperture, short length model magnets, named MQXFS, are tested both at the CERN SM18 and FERMI Lab test facilities. The model magnets rely on two types of Nb3Sn conductors (RRP and PIT) and on an innovative bladders and keys design to provide mechanical support against the Lorentz forces. In 2016 and 2017, the powering tests of the first two models MQXFS3 (RRP) and MQXFS5 (PIT) proved that nominal performance (16.5 kA) could be reached with excellent memory of the quench current after thermal cycle. However both magnets showed a slow training behavior with clear observations of voltage disturbances before the quench. Besides MQXFS5 only could reach ultimate current (17.9 kA) whereas erratic behavior was observed on MQXFS3 due to conductor local degradation at the head of one of the coil. In 2018, this limiting coil was changed and the applied azimuthal pre-stress increased. If ultimate current could then be reached, no stable current could be maintained due to identified defect on the outer layer of the new coil. Finally the outcome of the test of the new model MQXFS4, featuring the final RRP conductors that will be used for the series production and variation on the inner layer quench heater designs are here reported in details.

43 PARTICLE ACCELERATORS↗

Interference effects in laser-induced plasma emission from surface-bound metal micro-particles

Here, the light-matter interaction of an optical beam and metal micro-particulates at the vicinity of an optical substrate surface is critical to the many fields of applied optics. Examples of impacted fields are laser-induced damage in high power laser systems, sub-wavelength laser machining of transmissive materials, and laser-target interaction in directed energy applications. We present a full-wave-based model that predicts the laser-induced plasma pressure exerted on a substrate surface as a result of light absorption in surface-bound micron-scale metal particles. The model predictions agree with experimental observation of laser-induced shallow pits, formed by plasma emission and etching from surface-bound metal micro-particulates. It provides an explanation for the prototypical side lobes observed along the pit profile, as well as for the dependence of the pit shape on the incident laser and particle parameters. Furthermore, the model highlights the significance of the interference of the incident light in the open cavity geometry formed between the micro-particle and the substrate in the resulting pit shape.

42 ENGINEERING↗

Soil Carbon and Nitrogen Elemental Analysis and Middle Infrared Spectroscopy from the Kougarok Fire Complex, Seward Peninsula, Alaska, 2022

In September and October of 2022, soil samples were collected at the Kougarok Fire Complex near mile marker 86 of the Nome-Taylor Highway on the Seward Peninsula of Alaska. This study site was chosen due to its unique fire history, as the Kougarok Fire Complex has experienced multiple wildfires since 1971. As the Arctic warms, the risk of Arctic tundra fires continues to increase due to warmer summer temperatures and higher frequency of lightning. Burned soil carbon or pyrogenic carbon (PyC) is an important component of C cycling after wildfire, and one that is often overlooked in tundra systems where wildfires are historically rare. To better understand PyC signatures and quantify PyC presence in post-regeneration permafrost regions, soils were sampled from soil pits within the 1971, 2002, and 2019 burn sites, as well as two unburned control sites. At each site, three soil pits were dug to the permafrost table. Soil samples were collected with a trowel from the face of each pit at 10 cm increments down to the permafrost table. Thaw depth, maximum vegetation height, vegetation species composition, and O horizon depth were also collected at each soil pit. An HS2 Hydrosense II Handheld Soil Moisture Sensor was used to collect volumetric soil moisture content at each 10 cm sampling increment. This dataset includes one *.csv of middle infrared spectroscopy measurements of soil samples, one *.csv of field observations, one *.csv of carbon and nitrogen analysis of soil samples, and one *.kml of sampling locations.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic) was a 15-year research effort (2012-2027) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy’s Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy’s Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Moisture Monitoring at Area G, Technical Area 54, Los Alamos National Laboratory, 2016 Status Report

Hydrological characterization and moisture monitoring activities provide data required for evaluating the transport of subsurface contaminants in the unsaturated and saturated zones beneath Area G, and for the Area G Performance Assessment and Composite Analysis. These activities have been ongoing at Area G, Technical Area 54 of the Los Alamos National Laboratory since waste disposal operations began in 1957. This report summarizes the hydrological characterization and moisture monitoring activities conducted at Area G. It includes moisture monitoring data collected from 1986 through 2016 from numerous boreholes and access tubes with neutron moisture meters, as well as data collected by automated dataloggers for water content measurement sensors installed in a waste disposal pit cover, and buried beneath the floor of a waste disposal pit. This report is an update of a nearly identical report by Levitt et al., (2015) that summarized data collected through early 2015; this report includes additional moisture monitoring data collected at Pit 31 and the Pit 38 extension through December, 2016. It also includes information from the Jennings and French (2009) moisture monitoring report and includes all data from Jennings and French (2009) and the Draft 2010 Addendum moisture monitoring report (Jennings and French, 2010). For the 2015 version of this report, all neutron logging data, including neutron probe calibrations, were investigated for quality and pedigree. Some data were recalculated using more defensible calibration data. Therefore, some water content profiles are different from those in the Jennings and French (2009) report. All of that information is repeated in this report for completeness. Monitoring and characterization data generally indicate that some areas of the Area G vadose zone are consistent with undisturbed conditions, with water contents of less than five percent by volume in the top two layers of the Bandelier tuff at Area G. These data also indicate that other areas of the vadose zone are affected by waste disposal activities that have been ongoing at Area G since 1957, a period of nearly 60 years. In some areas, water content profiles indicate increases in water content to depths of tens of meters, especially in areas covered by asphalt and structures.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Evaluating Corrosion in SAVY Containers using Non-Destructive Techniques

Powerpoint presentation on Ultrasonic and Eddy Current NDT; UT Theory; Eddy current (ECA): How it works; Controlled Corrosion at NM Tech; Results – HCl Corrosion; Waveform Data for 10M HCl; Accuracy Statistics; Results – FeCl 3 Pitting; Waveforms for Anhydrous FeCl 3 ; Analyzing Corroded Stainless Steel 316L Plates; 316L Plate to Imitate Pitting; ECA Pit Depth Calibration Curve; C Scan Imaging; UT Pit Detection; SST Containers: Ultrasonic (UT) vs. CMM; UT Data Analysis; UT Conclusions and Observations; ECA Conclusions; Automated System Vision.

36 MATERIALS SCIENCE↗

Hanford Double Shell Waste Tank Corrosion Studies (Final Report FY2018)

For FY18, Savannah River National Laboratory (SRNL) focused on four main tasks in its study of corrosion of Hanford Double-Shell Tanks (DSTs). The New Limits task focused on the development of a pitting factor as a localized corrosion predictor. Electrochemical experiments were directed towards pitting factors between 1 and 2 (i.e., borderline conditions) and separating the effects of chloride and fluoride in the pitting factor equation. In addition, long term immersion testing experiments with partial and completely immersed coupons in solutions with a wide range of pitting factors were tested. Secondary liner studies continued this year with a new vapor corrosion inhibition (VCI) strategy in which ground water (GW) simulants at a specified concentration of commercial VCI were mixed. The specific concentrations were recommended by Cortec® and was compared with similar concentration of GW with calcium carbonate. The anodic drift task utilized a simulant corresponding to AN-107 waste tank chemistry. The chemistry was studied with three different surface conditions: mill-scale, partial mill-scale and ground to 600 grit to study the impact of different surfaces on the potential drift. The final task was focused on ammonia concentration determination of a vapor space corrosion (VSC) test vessel using Quartz-Enhanced Photoacoustic Spectroscopy (QEPAS) detector. A summary of each task is presented below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Transuranic Waste Volume Reduction Methods for Los Alamos National Laboratory

Los Alamos National Laboratory (LANL, or the Lab) is one of the United States’ (U.S.) weapons complex nuclear security laboratories; it is owned by the Department of Energy (DOE) and operated by Triad National Security, LLC. LANL’s mission is to solve national security challenges through scientific excellence, which includes nuclear deterrence and stockpile stewardship. Such activities generate a variety of radioactive waste types, including transuranic (TRU) waste. The National Nuclear Security Administration (NNSA) is under a congressional mandate to produce no fewer than 80 plutonium pits per year by 2030 to meet Department of Defense requirements and support the nuclear deterrent. LANL is responsible for producing at least 30 pits per year by 2026, while the Savannah River Site will produce 50 pits per year by 2030. As of August 2018, the NNSA TRU waste inventory at LANL was at 53% capacity. In order to ensure the nuclear material missions are able to continue uninterrupted, the storage of TRU waste needs to remain below 60% of total capacity. As LANL increases production and prepares to meet the 30 pits per year goal, waste generation will increase substantially. Thus, there is a need to rejuvenate current infrastructure and implement TRU waste reduction methods in the coming years.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Pulsed Thermal Tomography Nondestructive Examination of Additively Manufactured Reactor Materials and Components (Final Technical Report)

Metal Additive Manufacturing (AM) is a promising method for cost-efficient fabrication of complex shape structures for applications in harsh environment, such as in a nuclear reactor. However, internal defects (pores) occur in high-strength AM alloys, which are manufactured with Laser Powder Bed Fusion (LPBF) AM method. Pulsed Infrared Thermography (PIT) is an efficient nondestructive evaluation (NDE) method to examine actual structures, because this method offers one-sided non-contact measurements, and fast processing of large sample areas. However, imaging of material defects, particularly defects with sizes at microscopic level, is challenging. In this report, we benchmark the performance of several Unsupervised Learning (UL) algorithms designed to enhance imaging of microscopic defects in metals with PIT. UL aims to learn the latent principal patterns (dictionaries) in PIT data to detect defects with minimal human supervision. Performance of Independent Component Analysis (ICA), Sparse Coding (SC), Principal Component Analysis (PCA) and Exploratory Factor Analysis (EFA) was compared using F-score, UL model training time and defects reconstruction time. We obtained the average F-score of 0.75, and a highest F-score of 0.89 for the EFA algorithm. Overall, EFA outperforms other UL algorithms considered in this study. In another approach, we investigate Thermal Tomography (TT), which is a computational method for reconstruction of depth profile of internal material defects from PIT nondestructive evaluation (NDE). TT algorithm obtains depth reconstructions of thermal effusivity, which has been shown to provide visualization of subsurface internals defects in metals. In many applications, one needs to determine the defect shape and orientation from reconstructed effusivity images. Interpretation of TT images is non-trivial because of blurring, which increases with depth due to heat diffusion-based nature of image formation. We have developed a deep learning convolutional neural network (CNN) to classify size and orientation of subsurface material defects in TT images. CNN was trained with TT images produced with computer simulations of 2D metallic structures (thin plates) containing elliptical subsurface voids. Performance of CNN was investigated using test TT images developed with computer simulations of plates containing elliptical defects, and defects with shape imported from scanning electron microscopy (SEM) images. CNN demonstrated the ability to classify radii and angular orientation of elliptical defects in previously unseen test TT images. We have also demonstrated that CNN trained on TT images of elliptical defects is capable of classifying shape and orientation of irregular defects. Training the CNN on irregular defect shapes instead of on elliptical shapes would make the resulting classifications more descriptive of actual defect shapes. However, this requires a much higher volume of SEM images of material defects, which are difficult to obtain because of random occurrence of defects in LPBF. To address this challenge, we developed a generative adversarial network (GAN) to augment the existing dataset of SEM defect images. The GAN model is demonstrated to create novel yet realistic defect shapes that can be used as input for simulated PTT images to train CNN. We also investigate several approaches based on Gaussian Random Circle and Bezier Curves for constructing parametric models of irregular-shape defects.

36 MATERIALS SCIENCE↗

Digitally Optimized Autonomous Robotic System for Hanford Waste Tank Handling [Slides]

Idaho National Laboratory (INL) is developing a robotic system and digital twin to perform monitoring, inspection, and mapping of underground tank pits at the Hanford Site, operated by the U.S. Department of Energy (USDOE). The Autonomous Pit Exploration System (APES) will consist of four primary components: an electric vehicle truck with a robotic system developed by INL to deploy payloads into the tanks through small diameter preexisting risers, a robotic arm developed by Florida International University (FIU) for the purposes of deploying a variety of payloads into the tank pit environment, and a small robotic COTS crawler platform for examining the bottom of the pits.

42 - ENGINEERING↗

Lianas and Trees From a Seasonally Dry and a Wet Tropical Forest Did Not Differ in Embolism Resistance but Did Differ in Xylem Anatomical Traits in the Dry Forest

One of the most prominent changes in neotropical forests has been the increase in abundance and size of lianas. Studies suggest that lianas have more acquisitive strategies than trees, which could allow them to take advantage of water more effectively when it is available in water-limited forests, but few studies compared across growth form (i.e., lianas vs. trees) and forest type (i.e., wet vs. seasonally dry). We measured hydraulic and anatomical traits of co-occurring lianas and trees that convey drought resistance (xylem embolism resistance and intervessel pit membranes) and water transport capacity (xylem vessel diameter and density) in a seasonally dry and a wet evergreen tropical forest to address: (1) Are there differences between vulnerability to embolisms (P 50 —water potential at 50% loss of hydraulic conductivity) and hydraulic safety margins (HSM) across growth form and forest type? (2) How do vessel diameter and density vary across growth form and forest type? (3) Are there differences in xylem intervessel pit membrane thickness across growth form and forest type and does it predict xylem embolism vulnerability in trees and lianas? We examined hydraulic and xylem anatomical traits of 32 species—eight lianas and eight trees in each forest type. We found no difference in P 50 and HSMs between lianas and trees and between the wetter and drier forest. Dry forest lianas had 81% greater maximum vessel diameter and 125% greater range in vessel diameter sizes than dry forest trees but, there was no significant difference between life forms in the wet forest. Dry forest species had 50% greater vessel density and 30% greater maximum pit membrane thickness than wet forest ones. Maximum pit membrane thickness was correlated to P 50 and HSMs. The main difference between lianas and trees occurred in the dry forest, where lianas had larger maximum xylem vessel size than trees, implying that they have proportionally greater hydraulic conductive capacity than the trees in seasonal forests.

Smith-Martin, Chris M.↗

Determining Drying Conditions to Mitigate Hanford Transfer Line Corrosion

Radioactive waste is stored in underground, carbon-steel double-shell tanks at the Department of Energy Hanford site.1,2,3 The underground transfer lines are used to transfer the waste between the tanks and other assets at the Hanford tank farm facilities. The transfer lines constructed before 1990 are pipe-in-pipe design with most of the lines having carbon steel carrier pipe and carbon steel encasements. The lines constructed after 1990 have a stainless-steel carrier with a carbon steel encasement. The carrier lines, which are in contact with the waste, provide a critical confinement function, while the encasements provide secondary containment to reduce the risk of a release and contamination to the environment. In 2022, a visual inspection of the annulus between the encasement and the carrier for one of the pre-1990 transfer lines revealed standing liquid in contact with the carrier pipe. Additionally, a significant build-up of corrosion products on the exterior of the carrier pipe and the interior of the encasement pipe was observed. To assess the extent of condition, borescope inspections were performed in the encasement space of additional transfer lines in the facility to provide a baseline. The inspection revealed that of the lines inspected, 29 had either moisture present or evidence that moisture had been present in the past (e.g., waterline corrosion where the pipe had been exposed to standing water). Additional inspections indicated several instances of pitting corrosion on the interior of the encasement and exterior the carrier transfer lines. An image of the carrier pipe with several pits is presented in Figure 1(a) and the profiled image of the transfer line section along with the pit depths are presented Figure 1(b). As seen in the figure, the deepest pit was 73 mils on the pipe section. These lines were designated as “do-not-use” until further compensatory actions are implemented to return the lines to service.

Shukla, Pavan K. [Savannah River National Laborato↗

Composite Lithium Metal Structure to Mitigate Pulverization and Enable Long‐Life Batteries

In lithium metal batteries, non‐uniform stripping of lithium results in pit formation, which promotes subsequent non‐uniform, dendritic deposition. This viscous cycle leads to pulverization of lithium which promotes cell shorting or capacity degradation, symptoms further exaggerated by high electrode areal loading and lean electrolytes. Here, to address this challenge, a composite lithium metal anode is engineered that contains uniformly distributed, nanometer‐sized carbon particles. This composite lithium is shown to strip more uniformly since the growth of non‐uniform pits is intercepted by the carbon particles. This mechanism is corroborated by a continuum electrochemical model. Subsequent lithium deposition on carbon particles is also found to be more uniform than on the surface with irregular pits. Notably, the pulverization rate of composite lithium is 26 times slower than that of commercial lithium. Moreover, in a Li‐S battery with sulfurized polyacrylonitrile cathode, the use of the composite anode extends the cycle life by three times when the areal capacity is 8 mAh cm −2 . The approach of using an engineered lithium composite structure to address challenges during both stripping and plating can inform future designs of lithium metal anodes for high areal capacity operations.

high areal capacity↗

Microstructure and Corrosion Properties of Laser-Welded SAF 2507 Super Duplex Stainless Steel Joints

SAF 2507 super duplex stainless steel has been welded using laser beam (LB) welding and laser/gas metal arc hybrid (LGH) welding processes. The pitting and intergranular corrosion properties of the welding joints have been tested using electrochemical testing and microstructure observations. The volume fraction of the ferrite phase reaches 70% in the weld zone of the LB welding joint, while the volume fraction of the ferrite phase is 60% for the welding joint of LGH due to the introduction of Ni from welding wire. The pitting corrosion resistance of the welding joint for LB is better than that of LGH. The pitting corrosion is easily conceived in the heat-affected zone (HAZ) because of the formation of Cr{sub 2}N in the HAZ during welding.

36 MATERIALS SCIENCE↗

Corrosion Inhibition Study of Mg-Nd-Y High Strength Magnesium Alloy Using Organic Inhibitor

A study on corrosion inhibition mechanism has been performed on rare earth containing WE43 magnesium alloy in 3.5 wt.% NaCl containing 8-hydroxyquinoline (HQ). After an initial increase in corrosion rate due to the formation of sparingly soluble MgQ{sub 2} complex, it was found to decrease owing to inhibition effect of the complex. Scanning electrochemical microscopic analysis showed a decrease in corrosion currents and enhanced resistance to pitting corrosion was observed for WE43 samples in the presence of HQ after an exposure of 48 h. With time, the MgQ{sub 2} thus generated formed a protective layer on the Mg alloy surface to prevent further corrosion. The corrosion rate of WE43 samples decreased by ~ 50% in HQ containing medium after a constant exposure of 28 days (from ~ 0.22 mg/cm{sup 2} day in no HQ to ~ 0.11 mg/cm{sup 2} day in HQ). For the WE43 samples in the presence of HQ, formation of MgO and MgQ{sub 2} was detected by x-ray photoelectron spectroscopy and x-ray diffraction. Shallower and smaller pits appeared on the magnesium alloy with HQ in the solution as compared to deeper and larger pits on the samples with no HQ in the solution. The significance of metal-complexing organic agent, hydroxyquinoline, in initial acceleration and subsequent prevention of Mg corrosion via protective MgQ{sub 2} complex layer formation is demonstrated.

36 MATERIALS SCIENCE↗

The Electrochemical Corrosion Behavior of Plasma Electrolytic Oxidation Coatings Fabricated on Aluminum in Silicate Electrolyte

Plasma electrolytic oxidation (PEO) coatings were fabricated on the aluminum in silicate electrolyte. Microstructures and elemental compositions of these PEO coatings were examined by scanning electron microscopy (SEM) equipped with an energy-dispersive x-ray spectroscopy (EDS). Corrosion resistances of the coated samples were evaluated using the measurements of open-circuit potential (OCP), repetitive polarization and electrochemical impedance spectroscopy (EIS) in 3.5 wt.% NaCl solution. The results indicated that the PEO coatings not only act as a physical shield limiting the penetration of corrosive solution, but also establish an anodic location with high concentration of H{sup +} ions and other product ions as pitting corrosion begins. With the development of pitting corrosion, the accumulation of corrosion products inside the pits and pores of the coatings decreases the corrosion process effectively.

36 MATERIALS SCIENCE↗

Effect of Cobalt on the Microstructure and Corrosion Behavior of Martensitic Age-Hardened Stainless Steel

To evaluate the influence of cobalt on the microstructure and pitting behavior of martensitic age-hardened stainless steel (MASS), the microstructures and electrochemical behaviors were characterized by optical microscopy, scanning electron microscopy, transmission electron microscopy, x-ray photoelectron spectroscopy, potentiodynamic curve, electrochemical impedance spectroscopy, and Mott–Schottky analysis. Results indicated that adding cobalt reduced the grain size of the original austenite, refined the lath martensite, inhibited the precipitation of Cu-rich phases, and increased the content of reversed austenite. Compared with the cobalt-free steel, the cobalt-containing steel has a higher pitting potential, lower corrosion current density, and higher pitting resistance. The primary components of the passive film grown on the cobalt-free steel included (Cr, Fe) oxides, such as Cr{sub 2}O{sub 3}, Cr(OH){sub 3}, FeOOH, and Fe{sub 2}O{sub 3}. The cobalt-containing steel included the aforementioned components as well as Co, which was attributed to the formation of the passive film in the forms of CoFe{sub 2}O{sub 4}, Co(OH){sub 2}, and CoO. In addition, the synergy of the refined lath martensite and the precipitation of the Cu-rich phase induced an increase in corrosion resistance in MASS containing cobalt.

36 MATERIALS SCIENCE↗