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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Mixed mode stress field effect in adhesive fracture

Numerical or analytical analyses were performed on seven different test specimens including blister test, 90-degree peel test, torsion test, and various cone tests. These specimens are in general subjected to complex stress fields having various amounts of Mode I, Mode II, and Mode III loads. The specimens were then constructed using polymethyl methacrylate for the adherends and a transparent polyurethane elastomer (Solithane 113) for the adhesive. This combination permitted direct observation of the bondline as load was applied. Although initial debonds as well as bond end termination singularities were present in all specimens, in some cases the debond did not initiate at the singularity points as would normally have been expected. An explanation for this behavior is presented, as well as a comparison of loading mode effect on those specimens for which the debond did propagate from a bond terminus singular point.

Anderson, G. P.↗

Industrial and biomedical use of aerospace personal cooling garments

Liquid-cooled garments (LCG) have been developed which utilize liquid-cooled modules rather than the network of tygon tubing typical of Apollo LCG's. The ultra-thin, heat-sealed, polyurethane modules are situated over the body to cover 50 percent of the body surface area with special emphasis on the 'working' muscles and the head-neck area. These garments are being designed specifically for industrial and biomedical uses, such as: a head-neck cooling system which is being tested for race-car drivers, tractor drivers, truck drivers, or a head-neck cooling system tested for the reduction of the scalp hair loss which normally accompanies cancer treatments. A combined head-neck and thorax unit is being developed for use during mine distaster rescue operations, and for other hazardous hot applications. Finally applications for head-neck and partitional cooling are anticipated for military pilots, tank drivers, and heavy equipment operations.

Williams, B. A.↗

Experimental verification of turbulent skin friction reduction with compliant walls

Preliminary compliant wall skin friction test results obtained in a low-turbulence pressure tunnel are reported. Compliant surface skins consisted of 0.0025 cm thick mylar, stretched under tension and area-bonded or longitudinally strip-bonded with silicone rubber adhesive to polyurethane foam. Mean velocity and fluctuating survey data were obtained with a single slanted hot wire. Mean velocity profiles for the area-bonded mylar surface skins indicated up to a 20% reduction in boundary-layer thickness (and lower momentum thickness) over rigid surfaces. This reduction in boundary-layer thickness indicates that a drag reduction occurred. In addition, a 16% reduction in wall shear was evident for the mylar/compressor foam compliant surface.

Weinstein, L. M.↗

Relative toxicity of pyrolysis products of some foams and fabrics

A limited number of foams and fabrics was evaluated in the course of developing test procedures for determining the relative toxicity of materials. The principal variable studied, heating rate, did not affect the relative ranking of the materials tested. Two pyrolysis test procedures using the same basic approach but employing different sample weights, chamber volumes, laboratory animals, heating rates, and upper temperature limits, resulted in identical rankings of relative toxicity. The data obtained show that modification of conventional flexible polyurethane foams with flame retardants to comply with California upholstered furniture flammability regulations seems to consistently reduce toxicity under pyrolysis conditions.

Hilado, C. J.↗

Uniform spray coating for large tanks

System employs spray facility located within ventilated plastic booth to uniformly coat exterior of large cylindrical tanks with polyurethane foam insulation. Coating target is rotated on turntable while movable spray guns apply overlapping spirals of foam. Entire operation may be controlled by single operator from remote station.

Carter, J. M.↗

Development of a special purpose spacecraft interior coating. Phase 2

Numerous acrylic and epoxy modifiers for the fluorocarbon latex resin base were investigated. Optimum coatings were developed by modifying the fluorocarbon latex with an epoxy acrylic resin system. In addition, a number of other formulations, containing hard acrylics as modifiers, displayed attractive properties and potential for further improvements. The preferred formulations dried to touch in about one hour and were fully dried in about twenty four hours under normal room temperature and humidity conditions. In addition to physical and mechanical properties either comparable or superior to those of commercial solvent base polyurethane or polyester coatings, the preferred compositions meet the flammability and offgassing requirements specified by NASA.

Bartoszek, E. J.↗

Real time outdoor exposure testing of solar cell modules and component materials

Plastic samples, solar cell modules, and sub-modules were exposed at test sites in Florida, Arizona, Puerto Rico, and Cleveland, Ohio, in order to determine materials suitable for use in solar cell modules with a proposed 20-year lifetime. Various environments were encountered including subtropical, subtropical with a sea air atmosphere, desert, rain forest, normal urban, and urban-polluted. The samples were exposed for periods up to six months. Materials found not suitable were polyurethane, polyester, Kapton, Mylar, and UV-stabilized Lexan. Suitable materials were acrylic, FEP-A, and glass. The results of exposure of polyvinylidene fluoride were dependent on the specific formulation, but several types appear suitable. RTV silicone rubber (clear) appears to pick up and hold dirt both as a free film and as a potting medium for modules. The results indicate that dirt accumulation and cleanability are important factors in the selection of solar cell module covers and encapsulants.

Anagnostou, E.↗

Atmospheric analyzer, carbon monoxide monitor and toluene diisocyanate monitor

The purpose of the atmospheric analyzer and the carbon monoxide and toluene diisocyanate monitors is to analyze the atmospheric volatiles and to monitor carbon monoxide and toluene diisocyanate levels in the cabin atmosphere of Skylab. The carbon monoxide monitor was used on Skylab 2, 3, and 4 to detect any carbon monoxide levels above 25 ppm. Air samples were taken once each week. The toluene diisocyanate monitor was used only on Skylab 2. The loss of a micrometeoroid shield following the launch of Skylab 1 resulted in overheating of the interior walls of the Orbital Workshop. A potential hazard existed from outgassing of an isocyanate derivative resulting from heat-decomposition of the rigid polyurethane wall insulation. The toluene diisocyanate monitor was used to detect any polymer decomposition. The atmospheric analyzer was used on Skylab 4 because of a suspected leak in the Skylab cabin. An air sample was taken at the beginning, middle, and the end of the mission.

Shannon, A. V.↗

Relative toxicity of products of pyrolysis and combustion of polymeric materials using various test conditions

Relative toxicity data for a large number of natural and synthetic polymeric materials are presented which were obtained by 11 pyrolysis and three flaming-combustion test methods. The materials tested include flexible and rigid polyurethane foams, different kinds of fabrics and woods, and a variety of commodity polymers such as polyethylene. Animal exposure chambers of different volumes containing mice, rats, or rabbits were used in the tests, which were performed over the temperature range from ambient to 800 C with and without air flow or recirculation. The test results are found to be sensitive to such variables as exposure mode, temperature, air flow and dilution, material concentration, and animal species, but relative toxicity rankings appear to be similar for many methods and materials. It is concluded that times to incapacitance and to death provide a more suitable basis for relative toxicity rankings than percent mortality alone, that temperature is the most important variable in the tests reported, and that variables such as chamber volume and animal species may not significantly affect the rankings.

Hilado, C. J.↗

Relative toxicity of pyrolysis products of some aircraft seat materials

Eighteen samples of aircraft seat materials were evaluated for relative toxicity using the USF/NASA toxicity screening test method. Nine samples were upholstery fabrics and nine samples were cushioning foams. Under these particular conditions of test, the aromatic phenolic and aromatic polyamide fabrics exhibited less toxicity than the samples of wool and wool/nylon fabrics, and the samples of neoprene foams exhibited less toxicity than the samples of polyurethane foams. These relative toxicity rankings were obtained using both apparent lethal concentration for 50 percent of the test animals (ALC50), and time to death (Td) at a fixed weight of material.

Hilado, C. J.↗

Some possible reference materials for fire toxicity tests

Suitable reference materials need to be selected in order to standardize any test method. The evaluation of cotton, polyethylene, polyether sulfone, polycarbonate, polystyrene, and polyurethane flexible and rigid foams as possible reference materials for the University of San Francisco/NASA toxicity screening test method is discussed.

Hilado, C. J.↗

A simple laboratory method for determining flash fire propensity of materials

A simple laboratory method for determining flash fire propensity of materials is described. The apparatus consists of a tube furnace and a combustion tube. The ignition source can be a wooded match but the hot pyrolysis tube itself may be the most suitable ignition source. Test results are presented for various materials including polyethylene, polystyrene, polycarbonate, and polyurethane and polychloroprene flexible foams.

Hilado, C. J.↗

High-rise foam-in-place process

Large polyurethane parts are molded by sequential pouring without waiting for foam to cure. Joints between pours and tops of parts are free of voids and need no trimming.

Liskay, G. G.↗

Insulator for cryogenic joints

Semirigid polyurethane foam is firm enough not to collapse yet soft enough not to crack in extreme cold. Silicone cover retards flames and glass-fabric reinforcement protects foam against accidental damage from tools during installation and maintenance.

Hawkinson, E. L.↗

Dynamic response of some tentative compliant wall structures to convected turbulence fields

Some tentative compliant wall structures designed for possible skin friction drag reduction are investigated. Among the structural models considered is a ribbed membrane backed by polyurethane or PVS plastisol. This model is simplified as a beam placed on a viscoelastic foundation as well as on a set of evenly spaced supports. The total length of the beam may be either finite or infinite, and the supports may be either rigid or elastic. Another structural model considered is a membrane mounted over a series of pretensioned wires, also evenly spaced, and the entire membrane is backed by an air cavity. The forcing pressure field is idealized as a frozen random pattern convected downstream at a characteristic velocity. The results are given in terms of the frequency response functions of the system, the spectral density of the structural motion, and the spectral density of the boundary layer pressure including the effect of structural motion. These results are used in a parametric study of structural configurations capable of generating favorable wave lengths, wave amplitudes, and wave speeds in the structural motion for potential drag reduction.

Nijim, H. H.↗

The use of an ion-beam source to alter the surface morphology of biological implant materials

An electron bombardment, ion thruster was used as a neutralized-ion beam sputtering source to texture the surfaces of biological implant materials. Scanning electron microscopy was used to determine surface morphology changes of all materials after ion-texturing. Electron spectroscopy for chemical analysis was used to determine the effects of ion texturing on the surface chemical composition of some polymers. Liquid contact angle data were obtained for ion textured and untextured polymer samples. Results of tensile and fatigue tests of ion-textured metal alloys are presented. Preliminary data of tissue response to ion textured surfaces of some metals, polytetrafluoroethylene, alumina, and segmented polyurethane were obtained.

Weigand, A. J.↗

Sprayable low density ablator and application process

A sprayable, low density ablative composition is described consisting esentially of: (1) 100 parts by weight of a mixture of 25-65% by weight of phenolic microballoons, 0-20% by weight of glass microballoons, 4-10% by weight of glass fibers, 25-45% by weight of an epoxy-modified polyurethane resin, 2-4% by weight of a bentonite dispersing aid, and 1-2% by weight of an alcohol activator for the bentonite; (2) 1-10 parts by weight of an aromatic amine curing agent; and (3) 200-400 parts by weight of a solvent.

Sharpe, M. H.↗

Cryogenic foam insulation for LH2 fueled subsonic transports

Shortages of petroleum-based aircraft fuels are foreseen before the end of the century. To cope with such shortages, NASA is developing a commercial aircraft which can operate on liquid hydrogen. Various foam insulators for LH2 storage are considered in terms of thermal performance and service life. Of the cryogenic foams considered (plain foam, foam with flame retardants and fiberglass reinforcement, and foam with vapor barriers), polyurethane foams were found to be the best. Tests consisted of heating a 5 cm layer of insulation around an aluminum tank containing LH2 to 316 K, and then cooling it to 266 K, while the inner surface was maintained at LH2 temperature (20 K).

Sharpe, E. L.↗