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All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Thermal Constraints from Siderophile Trace Elements in Acapulcoite-Lodranite Metals

A fundamental process in the formation of differentiated bodies is the segregation of metal-sulfide and silicate phases, leading to the formation of a metallic core. The only known direct record of this process is preserved in some primitive achondrites, such as the acapulcoite-lodranites. Meteorites of this clan are the products of thermal metamorphism of a chondritic parent. Most acapulcoites have experienced significant partial melting of the metal-sulfide system but not of silicates, while lodranites have experienced partial melting and melt extraction of both. The clan has experienced a continuum of temperatures relevant to the onset of metal mobility in asteroidal bodies and thus could yield insight into the earliest stages of core formation. Acapulcoite GRA 98028 contains relict chondrules, high modal sulfide/metal, has the lowest 2-pyroxene closure temperature, and represents the least metamorphosed state of the parent body among the samples examined. Comparison of the metal-sulfide component of other clan members to GRA 98028 can give an idea of the effects of metamorphism.

Herrin, Jason S.↗
NASA NTRS1999

Mineralogy of the Solar System

The coming decade will witnesses the first sample return missions from solar system bodies in 30 years. These samples will all be very small, some missions return only a few milligrams of total mass. Fortunately, the capability of modem methods to characterize ultra-small samples is well established from analysis of interplanetary dust particles (IDPs), interstellar grains recovered from meteorites, and other materials requiring ultra-sensitive analytical capabilities. Powerful analytical techniques are available that require, under favorable circumstances, single particles of only a few nanograms for entire suites of fairly comprehensive characterizations. A returned sample of greater than 1,000 particles with total mass of just one microgram permits comprehensive quantitative geochemical measurements that are impractical to can-y out in situ by flight instruments. With the Galileo flybys of Gaspra and Ida, it is now recognized that even very small airless bodies have indeed developed a particulate regolith. Acquiring a sample of the bulk regolith, a simple sampling strategy, provides two critical pieces of information about the body. Regolith samples are excellent bulk samples since they normally contain all the key components of the local environment, albeit in particulate form. Furthermore, since this fine fraction dominates remote measurements, regolith samples also provide information about surface alteration processes and are a key link to remote sensing of other bodies. Studies indicate that a statistically significant number of nanogram-sized particles should be able to characterize the regolith of a primitive asteroid, although the presence of larger components within even primitive meteorites (e.g.. Murchison), e.g. chondrules, CAI, large crystal fragments, etc., points out the limitations of using data obtained from nanogram-sized samples to characterize entire primitive asteroids. However, most important asteroidal geological processes have left their mark on the matrix, since this is the finest-grained portion and therefore most sensitive to chemical and physical changes. Thus, the following information can be learned from this fine grain size fraction alone: (1) mineral paragenesis; (2) regolith processes, (3) bulk composition; (4) conditions of thermal and aqueous alteration (if any); (5) relationships to planets, comets, meteorites (via isotopic analyses, including oxygen; (6) abundance of water and hydrated material; (7) abundance of organics; (8) history of volatile mobility, (9) presence and origin of presolar and/or interstellar material.

Zolensky, Michael E.↗
NASA NTRS1984

The origin of the eukaryotic cell

The endosymbiotic hypothesis for the origin of the eukaryotic cell has been applied to the origin of the mitochondria and chloroplasts. However as has been pointed out by Mereschowsky in 1905, it should also be applied to the nucleus as well. If the nucleus, mitochondria and chloroplasts are endosymbionts, then it is likely that the organism that did the engulfing was not a DNA-based organism. In fact, it is useful to postulate that this organism was a primitive RNA-based organism. This hypothesis would explain the preponderance of RNA viruses found in eukaryotic cells. The centriole and basal body do not have a double membrane or DNA. Like all MTOCs (microtubule organising centres), they have a structural or morphic RNA implicated in their formation. This would argue for their origin in the early RNA-based organism rather than in an endosymbiotic event involving bacteria. Finally, the eukaryotic cell uses RNA in ways quite unlike bacteria, thus pointing to a greater emphasis of RNA in both control and structure in the cell. The origin of the eukaryotic cell may tell us why it rather than its prokaryotic relative evolved into the metazoans who are reading this paper.

Review↗
NASA NTRS2012

IDPs and Stardust

Interplanetary dust particles (IDPs) collected in the Earth s stratosphere and NASA Stardust mission samples constitute direct samples of diverse cometary bodies. These materials are among the least altered remnants of the original building blocks of the Solar System. Both cometary materials and primitive meteorites contain a broad diversity of organic compounds that appear to have formed in a range of environments, including the presolar cold molecular cloud, the solar nebula, asteroids and comet nuclei. Isotopic anomalies in H, C, and N are commonly observed in meteoritic organic matter, reflecting chemical processes at extremely low temperatures. These isotopic anomalies are also very heterogeneous on micrometer and even smaller spatial scales, suggesting that some presolar organic grains have survived the formation of the Solar System. Most recently, coordinated transmission electron microscopy and isotopic imaging studies have shown that isotopically anomalous organic globules having rounded and often hollow structures are abundant and widespread amongst the most primitive components of meteoritic materials. These studies suggest that such organic grains were among the most important primary building blocks of the Solar System.

Messenger, Scott R.↗
NASA NTRS2016

Coordinated Isotopic and Mineral Characterization of Highly Fractionated 18O-Rich Silicates in the Queen Alexandra Range 99177 CR3 Chondrite

Carbonaceous chondrites contain a mixture of solar system condensates, pre-solar grains, and primitive organic matter. Each of these materials record conditions and processes in different regions of the solar nebula, on the meteorite parent body, and beyond the solar system. Oxygen isotopic studies of meteorite components can trace interactions of distinct oxygen isotopic reservoirs in the early solar system and secondary alteration processes. The O isotopic compositions of the earliest solar system condensates fall along a carbonaceous chondrite anhydrous mineral (CCAM) line of slope approximately 1 in a plot of delta 17O against delta 18O. This trend is attributed to mixing of material from 16O-poor and 16O-rich reservoirs. Secondary processing can induce mass-dependent fractionation of the O isotopes, shifting these compositions along a line of slope approximately 0.52. Substantial mass-dependent fractionation of O isotopes has been observed in secondary minerals in CAIs, calcite, and FUN inclusions. These fractionations were caused by significant thermal or aqueous alteration. We recently reported the identification of four silicate grains with extremely fractionated O isotopic ratios (delta 18O equals 37 - 55 per mille) in the minimally altered CR3 chondrite QUE 99177. TEM analysis of one grain indicates it is a nebular condensate that did not experience substantial alteration. The history of these grains is thus distinct from those of the aforementioned fractionated materials. To constrain the origin of the silicate grains, we conducted further Mg and Fe isotopic studies and TEM analyses of two grains.

Nguyen, A. N.↗
NASA NTRS1992

Comets and the formation of biochemical compounds on the primitive earth - A review

Thirty years ago it was suggested that comets impacting on the primitive earth may have represented a significant source of terrestrial volatiles, including some important precursors for prebiotic synthesis (Oro, 1961). This possibility is strongly supported not only by models of the collisional history of the early earth, but also by astronomical evidence that suggests that frequent collisions of cometlike bodies from the circumstellar disk around the star Beta Pictoris are taking place. Although a significant fraction of the complex organic compounds that appear to be present in cometary nuclei were probably destroyed during impact, it is argued that cometary collisions with the primitive earth represented an important source of both free-energy and volatiles, and may have created transient, gaseous environments in which prebiotic synthesis may have taken place.

Oro, J.↗
NASA NTRS1980

Numerical solution of the Navier-Stokes equations for high Reynolds number incompressible turbulent flow

The full Navier-Stokes equations for incompressible turbulent flow must be solved to accurately represent all flow phenomena which occur in a high Reynolds number incompressible flow. A two layer algebraic eddy viscosity turbulence model is used to represent the Reynolds stress in the primitive variable formulation. The development of the boundary-fitted coordinate systems makes the numerical solution of these equations feasible for arbitrarily shaped bodies. The nondimensional time averaged Navier-Stokes equations, including the turbulence mode, are represented by finite difference approximations in the transformed plane. The resulting coupled system of nonlinear algebraic equations is solved using a point successive over relaxation iteration. The test case considered was a NACA 64A010 airfoil section at an angle of attack of two degrees and a Reynolds number of 2,000,000.

Thompson, D. S.↗
NASA NTRS2011

NASA's Dawn Mission to Asteroid 4 Vesta

NASA's Dawn Mission to asteroid 4 Vesta is part of a 13-year robotic space project designed to reveal the nature of two of the largest asteroids in the Main Asteroid Belt of our Solar System. Ceres and Vesta are two complementary terrestrial protoplanets whose accretion was probably terminated by the formation of Jupiter. They provide a bridge in our understanding between the rocky bodies of the inner solar system and the icy bodies of the outer solar system. Ceres appears to be undifferentiated Vesta has experienced significant heating and likely differentiation. Both formed very early in history of the solar system and while suffering many impacts have remained intact, thereby retaining a record of events and processes from the time of planet formation. Detailed study of the geophysics and geochemistry of these two bodies provides critical benchmarks for early solar system conditions and processes that shaped its subsequent evolution. Dawn provides the missing context for both primitive and evolved meteoritic data, thus playing a central role in understanding terrestrial planet formation and the evolution of the asteroid belt. Dawn is to he launched in 2006 arriving at Vesta in 20l0 and Ceres in 2014, stopping at each to make 11 months of orbital measurements. The spacecraft uses solar electric propulsion, both in cruise and in orbit, to make most efficient use of its xenon propellant. The spacecraft carries a framing camera, visible and infrared mapping spectrometer, gamma ray/neutron magnetometer, and radio science.

McFadden, Lucyann A.↗
NASA NTRSDate not supplied

Asteroid (142) Polana at 3 µM and Its Linkage to the Primitive Asteroid (101955) Bennu

The Polana family is a low-albedo family located at a low inclination and a semimajor axis of ~2.42 au in the inner main asteroid belt. This family is likely the source of primitive near-Earth asteroids, including the OSIRIS-REx mission target (101955) Bennu. The B-type asteroid 142 Polana is the largest remnant of the "New Polana" family, and it has been spectrally (~0.5-2.5 µm) and dynamically linked to Bennu. Here, we investigate the compositional linkage of asteroids Polana and Bennu using spectra measured at longer wavelengths (~1.6-4.0 µm), which cover the 3- µm band. Polana’s spectra were measured at NASA IRTF using the LXD mode of SpeX. Bennu’s spectra were measured by OSIRIS-REx’s OVIRS spectrometer and revealed that this primitive asteroid is hydrated consistent with CM, CI, or CR carbonaceous chondrites. Polana’s LXD spectra, on the hand, show that the parent body of the Polana family is not hydrated (i.e., no absorption band at ~ 3.0 µm). Additionally, Polana’s LXD spectra do not indicate the presence of organics and/or carbonates. Polana's lack of significant water, organic, and carbonate spectral features on its surface could be related to the degree of heating in the Polana family-forming event and the reaccretion of ejecta that contributed to additional heating. The Polana family-forming event could also expose the parent body's dehydrated, organic/carbonate-poor interior. These results will be placed in the context of other low-albedo families and background objects in the inner main belt. An approved JWST program to observe Polana (with both NIRSpec and MIRI) will be able to assess if there is a Ryugu-like band and should allow a comparison of the MIR spectrum to Bennu.

Driss Takir↗
NASA NTRS2003

Chemical Analysis of Primitive Objects Using a Slitless Ultraviolet Meteor Spectrometer (CAPO-SUMS)

Measure the elemental composition in both random meteors and in the bolides forming specific meteor streams (these are traceable to specific small bodies in the solar system). These will yield the average chemical composition and degree of chemical variability in a statistically significant number of planetesimals. CAPO-SUMS is functionally equivalent to a series of multiple, small-body sample analysis missions, but provides much more analytical capability than is possible on any orbital or flyby mission due to the vaporization, ionization and ultraviolet emission from the ablating bolide as it enters the atmosphere. CAPO-SUMS will provide a chemical context from which the detailed analytical studies provided by a cometary or asteroidal lander mission can be interpreted.

Nuth, J. A.↗
NASA NTRS2006

Turbulent Size Selection and Concentration of Chondrule-Sized Objects: Reynolds Number Invariance and Implications

It is generally agreed that individual chondrules formed as entities in a gaseous nebula prior to being accumulated into a meteorite parent body, within which they incur various forms of modification before arriving in our labs. While there are major unanswered questions about the properties of the nebula environment in which chondrules formed, the process by which the most primitive meteorites are formed overwhelmingly from chondrules must then be an aspect of "nebula processing". Textures in certain fragments of primitive meteorites might be summarized as being primarily chondrules and clastic, chondrule-sized, fragments of other minerals, each covered with a rim of fine dust with physical and chemical properties which are essentially independent of the composition and mineralogy of the underlying chondrule. This (unfortunately rather rare) texture was called "primary accretionary texture" to reflect their belief that it precedes subsequent stages in which fragmentation, comminution, mixing, heating, and other forms of alteration occur on the parent body(-ies). The size distribution of these chondrules and fragments, and the properties of their dusty rims, are key clues regarding the primary nebula accretion process. Even in the much more abundant meteorites which have clearly suffered internal mixing, abrasion, grinding, and even mineralogical alteration or replacement (due presumably to the collisional growth and heating process itself), key chondrule properties such as mean size and density remain relatively well defined, and well defined rims persist in many cases. It has been our goal to infer the key nebula processes indirectly from the properties of these very earliest primitive meteorites by making use of a theoretical framework in which the nebula possesses a plausible level of isotropic turbulence. We have shown that turbulence has the property of concentrating one particular particle size by orders of magnitude, where the preferentially concentrated size depends primarily on the intensity of the turbulent kinetic energy (represented by the Reynolds number of the nebula). Specifically, the preferentially concentrated particle is that which has a stopping time equal to the turnover time of the smallest eddy. The intensity level of turbulence implied by chondrule sizes can be maintained by even a small fraction of the energy released by the radially evolving disk (it must be noted that the details of how this transfer of energy actually occurs remain obscure, however).

Cuzzi, J. N.↗
NASA NTRS1978

Planet formation - Mechanism of early growth

Experiments in vacuum (approx. 0.5 to 1 mbar) and in air quantify mechanics of collisions, rebound, and fragmentation at low velocities (1-50 m/sec), under the conditions usually postulated for the preplanetary environment in the primitive solar nebula. Such collisions have been little studied experimentally. Contrary to widespread assumptions, accretionary growth of the largest meteoroid- and asteroid-sized bodies in a given swarm results spontaneously from the simple mechanics of these collisions, without other ad hoc sticking mechanisms. The smaller bodies in the swarm are less likely to grow. Granular surfaces form, either by gravitational collapse of dust swarms or by rapid formation of regolith surfaces on solid planetesimals; these surfaces strongly promote further growth by retarding rebound. Growth of large bodies increases modal collision velocities, causing fragmentation of smaller bodies and eventual production of interstellar dust as a by-product of planetesimal interactions.

Hartmann, W. K.↗
NASA NTRS2003

Dawn Mission: A Journey in Space and Time

By successively orbiting both 4 Vesta and 1 Ceres the Dawn mission directly addresses the longstanding goals of NASA and the planetary community to understand the origin and evolution of the solar system by obtaining geophysical and geochemical data on diverse main belt asteroids. Ceres and Vesta are two complementary terrestrial protoplanets (one apparently "wet" and one "dry"), whose accretion was terminated by the formation of Jupiter. Ceres is little changed since it formed in the early solar system, while Vesta has experienced significant heating and differentiation. Both have remained intact over the age of the solar system, thereby retaining a record of events and processes from the time of planet formation. Detailed study of the geophysics and geochemistry of these two bodies provides critical benchmarks for the early solar system conditions and processes that shaped its subsequent evolution. Dawn provides the missing context for both primitive and evolved meteoritic data, thus playing a central role in understanding terrestrial planet formation and the evolution of the asteroid belt. Dawn is to be launched in May 2006 arriving at Vesta in 2010 and Ceres in 2014, stopping at each to make 11 months of orbital measurements. The spacecraft uses solar electric propulsion both in cruise and in orbit to make most efficient use of its xenon propellant. The spacecraft carries a framing camera, visible and infrared mapping spectrometer, gamma ray/neutron spectrometer, a laser altimeter, magnetometer, and radio science.

Russell, C. T.↗
NASA NTRS2004

Chondrule Glass Alteration in Type IIA Chondrules in the CR2 Chondrites EET 87770 and EET 92105: Insights into Elemental Exchange Between Chondrules and Matrices

CR2 carbonaceous chondrites are a primitive group of meteorites that preserve evidence of a variety of processes that occurred in the solar nebula as well as on asteroidal parent bodies. CR2 chondrites are distinct from other carbonaceous chondrites by (among other properties) their relatively high abundance of chondrules (50-60 vol. %) and Fe,Ni metal (5-8 vol. %) [1]. Like the CM2 chondrites, the CRs have been affected by aqueous alteration and according to [2] show a range of degrees of alteration. In weakly- altered CR chondrites, fine-grained matrices and chondrule rims have been partially altered and chondrule mesostases show evidence of incipient aqueous alteration. In these meteorites, glassy mesostasis is still common. However, some CR chondrites, (e.g. Renazzo and Al Rais) show evidence of much more extensive alteration with complete replacement of chondrule mesostasis [2] by chlorite and serpentine. Although the general characteristics of alteration of the CR chondrites have been described, the details of alteration reactions in these meteorites remain unclear. In addition, the setting for aqueous alteration is poorly understood: both asteroidal and preaccretionary alteration scenarios have been proposed [2].

Burger, Paul V.↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 13

Contents include the following: A Fast, Non-Destructive Method for Classifying Ordinary Chondrite Falls Using Density and Magnetic Susceptibility. An Update on Results from the Magnetic Properties Experiments on the Mars Exploration Rovers, Spirit and Opportunity. Measurement Protocols for In Situ Analysis of Organic Compounds at Mars and Comets. Piping Structures on Earth and Possibly Mars: Astrobiological Implications. Uranium and Lead in the Early Planetary Core Formation: New Insights Given by High Pressure and Temperature Experiments. The Mast Cameras and Mars Descent Imager (MARDI) for the 2009 Mars Science Laboratory. MGS MOC: First Views of Mars at Sub-Meter Resolution from Orbit. Analysis of Candor Chasma Interior Layered Deposits from OMEGA/MEX Spectra. Analysis of Valley Networks on Valles Marineris Plateau Using HRSC/MEX Data. Solar Abundance of Elements from Neutron-Capture Cross Sections. Preliminary Evaluation of the Secondary Ion/Accelerator Mass Spectrometer, MegaSIMS. Equilibrium Landforms in the Dry Valleys of Antarctica: Implications for Landscape Evolution and Climate Change on Mars. Continued Study of Ba Isotopic Compositions of Presolar Silicon Carbide Grains from Supernovae. Paleoenviromental Evolution of the Holden-Uzboi Area. Stability of Magnesium Sulfate Minerals in Martian Environments. Tungsten Isotopic Constraints on the Formation and Evolution of Iron Meteorite Parent Bodies. Migration of Dust Particles and Volatiles Delivery to the Inner Planets. On the Sitting of Trapped Noble Gases in Insoluble Organic Matter of Primitive Meteorites. Trapping of Xenon Upon Evaporation-Condensation of Organic Matter Under UV Irradiation: Isotopic Fractionation and Electron Paramagnetic Resonance Analysis. Stability of Water on Mars. A Didactic Activity. Analysis of Coronae in the Parga Chasma Region, Venus. Photometric and Compositional Surface Properties of the Gusev Crater Region, Mars, as Derived from Multi-Angle, Multi-Spectral Investigation of Mars Express HRSC Data. Mapping Compositional Diversity on Mars: Spatial Distribution and Geological Implications. A New Simulation Chamber for Studying Planetary Environments. Folded Structure in Terra Sirenum. Mars. Nitrogen-Noble Gas Static Mass Spectrometry of Genesis Collector Materials. Neon Isotope Heterogeneity in the Terrestrial Mantle: Implication for the Acquisition of Volatile Elements in Terrestrial Planets. The Cosmic Clock, the Cycle of Terrestrial Mass Extinctions.

Source record↗
NASA NTRS1972

On the origins of trapped helium, neon and argon isotopic variations in meteorites. I - Gas-rich meteorites, lunar soil and breccia. II - Carbonaceous meteorites.

Data are presented from stepwise heating experiments and total extractions on five meteorites: Kapoeta, Fayetteville, Holman Island, Cee Vee, and Pultusk. These data reveal the presence of four isotopically distinct trapped neon components. A comparison of trapped neon with trapped helium and argon in bulk analyses indicates the existence of correlated helium, neon and argon isotopic structures. Component B is attributed primarily to direct implantation of rare gas ions by the present day solar wind. Component C is identified with directly implanted low energy (1-10 Mev/n) solar flare rare gases. Component D is associated with rare gas ions implanted in meteoritic material by the primitive, pre-main sequence, solar wind. A fourth component, observed only in Kapoeta and the lunar fines and breccia, is tentatively attributed to parent body 'atmospheric' ions implanted in surface material by a solar wind induced electric field.

Black, D. C.↗
NASA NTRS2013

Lessons Learned from the Stardust Sample Return Mission

These are science and mission design and operations lessons learned from the Stardust Mission, which returned grains from comet Wild-2 and fresh interstellar dust to Earth in 2006 [1]. Science Lessons: Major discoveries of the Stardust Wild-2 samples include the presence of numerous chondrules and CAI in a comet, which requires a much more dynamic early solar system than many had envisaged, and verified predictions made by models requiring outward flow of early solar system solids before the early nebular gas had dissipated [1-3]. No evidence has been found for the presence of live Al-26 in the comet, suggesting late accretion [4]. Carbonates and unusual sulfides were found which potentially require activity of liquid water within the comet, but to only a minor degree at best [5-6]. The presence of abundant thermally-metamorphosed silicates in Wild-2 appears to require assembly from an earlier generation of bodies [7]. The abundance of presolar grains in the Wild-2 samples appears to be below what has been found in most chondritic IDPs and primitive chondrites [1]. The bulk mineralogy of Wild-2 grains does not match the mineralogy from any single other known astromaterial [7], and is also strikingly unlike that inferred from Spitzer Telescope spectra of Comet Temple 1 dust [8]. Amino acids and other fragile organics have been detected among the Wild-2 samples [9], which highlights the critical importance of further developing techniques for organic analysis in small samples, and cleaning outbound spacecraft.

Zolensky, M. E.↗
NASA NTRSDate not supplied

The Nature of Extraterrestrial Amino Acids in Carbonaceous Chondrites and Links to Their Parent Bodies

Meteorites and samples returned from asteroids and comets provide an important record of the physical and chemical processes that occurred in the early solar system and represent some of the oldest solid materials currently available for laboratory analyses. The delivery of organic matter by extraterrestrial material to the early Earth could have been an important source of complex prebiotic organic molecules available for the emergence of life. Analyses of primitive carbonaceous chondrites over the last five decades have revealed a major insoluble organic component [1,2], as well as a complex and highly diverse suite of soluble organic molecules of prebiotic importance [3,4] that includes carboxylic acids, N-heterocycles, sugars, amino acids, amines, and many other organic molecules that have not yet been identified [5]. Amino acids continue to be a primary focus of many soluble organic analyses in carbonaceous chondrites because (1) these molecules are essential components of life (as the monomers of proteins), (2) they have structural diversity (multiple possible isomers) that can be used to help constrain formation mechanisms and parent body conditions, and (3) most amino acids identified in carbonaceous chondrites are chiral, a property that can be used to distinguish between amino acids of extraterrestrial and terrestrial origins. The degree of parent body hydrothermal alteration has been shown to have a major influence on the formation and destruction of amino acids in carbonaceous meteorites as observed in the measured abundances and molecular distributions [6]. Aqueous alteration in primitive asteroids could have also led to the preferential enrichment of some left-handed amino acids over their right-handed forms, an astounding discovery that suggests that the origin of life on Earth or elsewhere was biased toward left-handed amino acid homochirality [7,8]. This talk will give an overview of what is known about the amino acid composition of carbonaceous chondrites, present some key unanswered questions, and discuss how the analysis of samples returned from asteroids Ryugu and Bennu will further advance our understanding of parent body chemistry and potential contributions from carbonaceous asteroids to the origin of life on Earth or elsewhere.

Daniel P. Glavin↗