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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Elucidating Quintet-State Dynamics in Singlet Fission Oligomers and Polymers with Tetracene Pendants

To unlock the potential of molecular engineering for practical quantum sensing and computing, it is essential to create and control pure magnetic states in molecular systems. Singlet fission (SF) in organic materials offers a promising approach by generating pairs of triplet excited states from photoexcited singlets. Here, in this work, we investigate SF in a polymer with strategically positioned tetracene pendant groups along a polynorbornene backbone and its oligomeric counterparts, facilitating intrapolymer through-space coupling. Using continuous-wave and pulsed time-resolved electron paramagnetic resonance (EPR) spectroscopy, we elucidate the spin dynamics and identify key intermediates, including the quintet state, that emerge during SF. Our findings reveal that exciton translational motion along the pendant groups enhances the dissociation of triplet pairs, with oligomer length playing a critical role in modulating spin state interconversion and exciton transport. Our results provide key insights into the SF mechanism in polymeric materials and highlight the role of oligomer length in modulating spin state interconversion and exciton transport. This work advances our understanding of SF in polymers, paving the way for their application in quantum information science and energy conversion technologies.

Bindra, Jasleen K. [Argonne National Laboratory (A↗

Very high-energy gamma ray astronomy

Recent results in ground-based very high-energy (less than 10 to the eleventh power eV) gamma-ray astronomy are reviewed. The various modes of the atmospheric Cerenkov technique are described, and the importance of cosmic ray rejection methods is stressed. The positive detections (at approximately less than 10 to the 12th power eV) of the Crab pulsar that suggest a very flat spectrum and time-variable pulse phase are discussed. Observations of other pulsars (particularly Vela) suggest that these features may be general. The steady flux upper limits for the Crab Nebula are thus reconsidered, and a new value of the implied (Compton-synchrotron) magnetic field in the Nebula is reported. Evidence that a 4.8-hour modulated effect was detected at E sub gamma is less than 10 to the 12th power eV from Cyg X-3 is strengthened in that the exact period originally proposed agrees well with a recent determination of the X-ray period. The southern sky observations are reviewed, and the significance of the detection of an active galaxy (NGC 5128) is considered for source models and future observations.

Grindlay, J. E.↗

Shock position sensor for supersonic inlets

Static pressure taps or ports are provided in the throat of a supersonic inlet, and signals indicative of the pressure at each of the ports is fed to respective comparators. Means are also provided for directing a signal indicative of the total throat pressure to the comparators. A periodic signal is superimposed on the total throat pressure so that the signal from the static pressure tabs is compared to a varying scan signal rather than to total throat pressure only. This type of comparison causes each comparator to provide a pulse width modulated output which may vary from 0% 'time on' to 100% 'time on'. The pulse width modulated outputs of the comparators are summed, filtered, and directed to a controller which operates a bypass valve such as a door whereby air is dumped from the inlet to prevent the shock wave from being expelled out the front.

Dustin, M. O.↗

Efficient generation and extreme compression of multidimensional solitary states in molecular gas-filled hollow-core fibers driven by picosecond Yb lasers

We present an in-depth study on the impact of spatiotemporal Raman enhancement in molecular gas-filled hollow-core fibers (HCFs), demonstrating the efficient generation and post-compression of multidimensional solitary states (MDSS). Through different experimental scenarios—employing large-core HCFs filled with molecular gases (N 2 and N 2 O) and driven by high energy, sub-picosecond and picosecond Fourier transform-limited ytterbium laser pulses—this work leverages multimode propagation and enhanced spatiotemporal interactions to achieve significant spectral broadening and asymmetric redshift, contrasting sharply with self-phase modulation. Our findings reveal that, beyond the regime of maximum nonadiabatic molecular alignment, spatiotemporal nonlinear enhancement primarily governs spectral broadening for input pulse durations up to 1 ps. The process shows limited sensitivity to input pulse duration and the two investigated molecular gases (N 2 and N 2 O), with only subtle differences in broadening arising from their distinct Raman spectroscopic properties. Furthermore, post-compression of MDSS was achieved in various cases. Notably, using 7 mJ, 1 ps laser pulses, we generated 22 fs pulses with a 47% energy conversion efficiency of the input pulse energy. These results position MDSS as a powerful platform for generating high-energy, ultrashort pulses with tunable wavelengths, offering a robust solution for applications such as high harmonic generation.

47 OTHER INSTRUMENTATION↗

Nonlinear regenerative amplification using tunable intracavity cascaded quadratic nonlinearities

Conventional nonlinear regenerative amplification utilizes Kerr (i.e., self-focusing) nonlinearity to broaden the spectrum via self-phase modulation during the direct amplification of ultrashort pulses, which helps overcome spectral gain narrowing for high-energy, ultrashort-pulse generation. We introduce cascaded quadratic nonlinearities from a type-I second-harmonic generation crystal, which can be tuned in both magnitude and sign via the phase-mismatching condition, inside a regenerative amplifier to enable nonlinearity-tunable regenerative amplification. We demonstrate, both experimentally and numerically, a nonlinear Yb:YAG thin-disk regenerative amplifier with either positive or negative net nonlinearity that delivers 1-kHz, >0.4-mJ pulses as short as ∼200 fs and high-quality beams free of self-focusing. The laser’s average power can be scaled to >100 W when seeded and operated at a much higher repetition rate to benefit various applications.

47 OTHER INSTRUMENTATION↗

The Vacuum-Compacted Regolith Gripping Mechanism and Unmanned Flights via Quad-Rotors

During the course of the Kennedy Space Center Summer Internship, two main experiments were performed: The Vacuum-Compacted Regolith Gripping Mechanism and Unmanned Flights via Quad-copters. The objectives of the Vacuum-Compacted Regolith Gripping Mechanism, often abbreviated as the Granular Gripper, are to exhibit Space Technology, such as a soft robotic hand, lift different apparatuses used to excavate regolith, and conserve energy while executing its intended task. The project is being conducted to test how much weight the Granular Gripper can hold. With the use of an Animatronic Robotic Hand, Arduino Uno, and other components, the system was calibrated before actually conducting the intended weight test. The maximum weight each finger could hold with the servos running, in the order of pinky, ring, middle, and index fingers, are as follows: 1.340N, 1.456 N, 0.9579 N, and 1.358 N. Using the small vacuum pump system, the maximum weight each finger could hold, in the same order, was: 4.076 N, 6.159 N, 5.454 N, and 4.052 N. The maximum torques on each of the fingers when the servos were running, in the same respective order, was: 0.0777 Nm, 0.0533 Nm, 0.0648 Nm, and 0.0532 Nm. The maximum torques on the individual fingers, when the small vacuum pump was in effect, in the same order as above, was: 0.2318 Nm, 0.3032 Nm, 0.2741 Nm, and 0.1618 Nm. In testing all the fingers with the servos running, the total weight was 5.112 N and the maximum torque on the all the fingers was 0.2515 Nm. However, when the small vacuum pump system was used, the total weight was 19.741 N and the maximum torque on the all the fingers was 0.9713 Nm. The conclusion that was drawn stated that using the small vacuum pump system proved nearly 4 times more effective when testing how much weigh the hand could hold. The resistance provided by the compacted sand in the glove allowed more weight to be held by the hand and glove. Also, when the servos turned off and the hand still retaining its position, energy is being saved because the vacuum created the same resistance the running servos did without using power. The Unmanned Flights via Quad-rotors are built because multi-rotor dynamics are an important starting point and fair analog for space craft control systems and they make good terrestrial development platforms for various aspects of control for space crafts. The project is being conducted to see what the thrust response is going to be when a pulse width modulation command is sent to the control system since the quad-rotors are PWM controlled. A simulation environment in constructed so that one can quickly iterate and test different designs such as control systems, PID control vs. LDR control, and state estimation. Using two DIY Quad Kits, APM 2.6, testing apparatus (called a data acquisition system) to test the quad-rotors, and a simulation program such as Simulink, two quad-rotors are built and controlled via a simulation program, which is designed to be as realistic as possible and not idealistic. Due to the quad-rotors not being completely built nor ready for testing, there are no results or conclusions to report.

Granular Gripper↗

Loran-C digital word generator for use with a KIM-1 microprocessor system

The problem of translating the time of occurrence of received Loran-C pulses into a time, referenced to a particular period of occurrence is addressed and applied to the design of a digital word generator for a Loran-C sensor processor package. The digital information from this word generator is processed in a KIM-1 microprocessor system which is based on the MOS 6502 CPU. This final system will consist of a complete time difference sensor processor for determining position information using Loran-C charts. The system consists of the KIM-1 microprocessor module, a 4K RAM memory board, a user interface, and the Loran-C word generator.

Nickum, J. D.↗

Online and Offline Data Quality Monitoring for the Mu2e Calorimeter

This thesis presents the design, implementation, and validation of a calorimeter Data Quality Monitoring (DQM) toolchain for the Mu2e experiment at Fermilab. Mu2e searches for charged lepton flavor violation via coherent muon-to-electron conversion in the field of an aluminum nucleus, $\mu^- Al \rightarrow e^-Al$, a process whose observation would constitute clear evidence of physics beyond the Standard Model. Achieving target sensitivity requires stringent control of detector performance and data integrity during acquisition, as subtle issues in readout configuration, data formatting, or electronics behavior can compromise reconstruction and bias downstream analyzes. To address these challenges, this work develops a multi-layer DQM approach spanning both raw data validation and reconstructed digi-level diagnostics. At the low level, a fragment analysis component performs word- and bit-field decoding of calorimeter readout blocks, enabling sanity checks of the expected structure and producing detailed error and integrity statistics useful for commissioning and troubleshooting. At the digi level, the CaloDigiDQM analyzer is implemented within the art framework and transforms each CaloDigiCollection into a structured hierarchy of ROOT histograms designed for fast drill-down diagnostics. The module generates coherent monitoring views at global, disk, board, and channel granularity, including occupancy, waveform-derived features (baseline, RMS, peak amplitude and position), and left-right sensor consistency metrics. Detector-aware channel-to-electronics mapping is performed through the conditions system (CaloDAQMap), ensuring that diagnostics remain aligned with hardware identifiers used in operations. For end-to-end testing without reliance on live DAQ data, a synthetic CaloDigi producer is developed to generate realistic waveforms with controlled noise and pulse shapes. The resulting system supports both offline ROOT-file production and online operation, including optional histogram streaming through otsdaq via ots::HistoSender. This toolchain provides a practical and scalable foundation for calorimeter commissioning and stable data collection, enabling early detection of anomalies and reducing operational risk for Mu2e.

Vakulenko, Mark [Drew U.] (ORCID:0009000276197818)↗

Nonlinear Insolation Forcing: A Physical Mechanism for Climate Change

This paper focuses on recent advances in the understanding of nonlinear insolation forcing for climate change. The amplitude-frequency resonances in the insolation variations induced by the Earth's changing obliquity are emergent and may provide a physical mechanism to drive the glaciation cycles. To establish the criterion that nonlinear insolation forcing is responsible for major climate changes, the cooperative phenomena between the frequency and amplitude of the insolation are defined as insolation pulsation. Coupling of the insolation frequency and amplitude variations has established an especially new and interesting series of insolation pulses. These pulses would modulate the insolation in such a way that the mode of insolation variations could be locked to generate the 100-kyr ice age cycle which is a long-time geophysical puzzle. The nonlinear behavior of insolation forcing is tested by energy balance and ice sheet climate models and the physical mechanism behind this forcing is explained in terms of pulse duration in the incoming solar radiation. Calculations of the solar energy flux at the top of the atmosphere show that the duration of the negative and positive insolation pulses is about 2 thousand years which is long enough to prolong glaciation into deep ice ages and cause rapid melting of large ice sheets in the high latitudes of the northern hemisphere. We have performed numerical simulations of climate response to nonlinear insolation forcing for the past 2 million years. Our calculated results of temperature fluctuations are in good agreement with the climate cycles as seen in the terrestrial biogenic silica (BDP-96-2) data as well as in the marine oxygen isotope (delta(sup 18)O) records.

Liu, H. S.↗

The HEAO-A Scanning Modulation Collimator instrument

The Scanning Modulation Collimator X-ray instrument for the HEAO-A satellite was designed to measure celestial radiation in the range between 1 and 15 KeV and to resolve, and correlate, the position of X-ray sources with visible light sources on the celestial sphere to within 5 arc seconds. The positional accuracy is made possible by mechanical collimation of the X-ray sources viewed by the instrument. High sensitivity is provided from two systems each containing four gas filled proportional counters followed by preamplification, signal summing, pulse height analysis, pulse shape discrimination, X-ray event accumulators and telemetry processing electronics.

Roy, A.↗

Multimode-Guided-Wave Ultrasonic Scanning of Materials

Two documents discuss a method of characterizing advanced composite materials by use of multimode-guided ultrasonic waves. A transmitting transducer excites modulated (e.g., pulsed) ultrasonic waves at one location on a surface of a plate specimen. The waves interact with microstructure and flaws as they propagate through the specimen to a receiving transducer at a different location. The received signal is analyzed to determine the total (multimode) ultrasonic response of the specimen and utilize this response to evaluate microstructure and flaws. The analysis is performed by software that extracts parameters of signals in the time and frequency domains. Scanning is effected by using computer-controlled motorized translation stages to position the transducers at specified pairs of locations and repeating the measurement, data-acquisition, and data-analysis processes at the successive locations. One document presents results of a scan of a specimen containing a delamination.

Roth, Don↗

Ginga observation of an AM Herculis type source H0538 + 608

Results from a Ginga observation of the AM Her type object H0538 + 608 are presented. During the first half of the observation (pulsing state) the source showed periodic modulations caused by the white dwarf rotation, and the modulation profile was characterized by a flat top and a flat bottom. During the second half, the source was in a remarkable flaring state and the periodic modulation disappeared. The dramatic change of the X-ray light curve is interpreted in terms of a change of accretion pattern between an eclipsing spot and a noneclipsing spot. The spectrum is well described throughout by a thin thermal model including an iron K-line with equivalent width of some hundred eV, supporting the standard model for the hard X-ray emission region. The temperature in the pulsing state was found to change with the spin phase of the white dwarf. In the flaring state, the temperature showed a positive correlation with the source luminosity.

Ishida, M.↗

Implementation of Autonomous GPS Guidance and Control for Spacecraft Formation Flying

This paper presents the general relative orbit dynamics equations and GPS (Global Positioning System) orbit observational equations that have been developed for on-board control of spacecraft flying in formation. The approach to the implementation of the autonomous control for orbit acquisition and maintenance of spacecraft formation using GPS code pseudoranges are presented. As a practical application of the models and method provided in this paper, the orbit control of the Earth-Orbiter 1(EO-1) / Landsat 7 system has been designed, using the discrete-time linear optimal output feedback control. For the actuator of the on/off type reaction jets, the implementation problem of the pulse-amplitude modulation is also studied. Simulation results of autonomous orbit control and maintenance, for 3-dimensional initial orbit error, using optimal output feedback control are shown. These simulation results certified the feasibility of the implementation of the autonomous maintenance control for EO-1/Landsat 7 formation flying by means of the discrete-time linear optimal output feedback control.

Xing, Guang Q.↗

Studies of single-mode injection lasers and of quaternary materials. Volume 1: Single-mode constricted double-heterojunction AlGaAs diode lasers

Constricted double-heterojunction (CDH) lasers are presented as the class of single-mode nonplanar-substrate devices for which the lasing cavity is on the least resistive electrical path between the contact and the substrate. Various types of CDH structures are considered under three general topics: liquid-phase epitaxy over channeled substrates, lateral mode control, and current control in nonplanar-substrate devices. Ridge-guide CDH lasers have positive-index lateral-mode confinement and provide: single-mode CW operation to 7 mW/facet at room temperature and to 3 mW/facet at 150 C; light-current characteristics with second-harmonic distortion as low as -57 dB below the fundamental level; threshold-current temperature coefficients, as high as 375 C (pulsed) and 310 C (CW); constant external differential quantum efficiency to 100 C; and lasing operation to 170 C CW and 280 C pulsed. Semileakyguide CDH lasers have an asymmetric leaky cavity for lateral-mode confinement and provide single-mode operation to 15 to 20 mW/facet CW and to 50 mW/facet at 50% duty cycle. Modulation characteristics and preliminary reliability data are discussed.

Botez, D.↗

Precise time dissemination and applications development on the Bonneville Power Administration system

The Bonneville Power Administration (BPA) uses IRIG-B transmitted over microwave as its primary system time dissemination. Problems with accuracy and reliability have led to ongoing research into better methods. BPA has also developed and deployed a unique fault locator which uses precise clocks synchronized by a pulse over microwaves. It automatically transmits the data to a central computer for analysis. A proposed system could combine fault location timing and time dissemination into a Global Position System (GPS) timing receiver and close the verification loop through a master station at the Dittmer Control Center. Such a system would have many advantages, including lower cost, higher reliability, and wider industry support. Test results indicate the GPS has sufficient accuracy and reliability for this and other current timing requirements including synchronous phase angle measurements. A phasor measurement system which provides phase angle has recently been tested with excellent results. Phase angle is a key parameter in power system control applications including dynamic braking, DC modulation, remedial action schemes, and system state estimation. Further research is required to determine the applications which can most effectively use real-time phase angle measurements and the best method to apply them.

K. E. Martin↗

X-33 Integrated Test facility, Extended Range Simulation

In support of the X-33 Single Stage To Orbit program, NASA Dryden Flight Research Center was selected to provide continuous communications coverage of the X-33 vehicle from launch, through landing at Malmstrom Air Force Base, Montana and Michaels Army Air Field, Utah. An extensive real-time range simulation capability is being developed to ensure successful communications with the autonomous X-33 vehicle. This paper will provide an overview of the various levels of simulation being developed to support the X-33 extended range subsystems. These subsystems include the Flight Termination System, L-Band command uplink subsystem and the S-Band telemetry downlink subsystem. In addition, the radar model developed provides continuous azimuth, elevation and range information based on the flight trajectory. The Dynamic Ground Station Analysis model developed by NASA Goddard Space Flight Center, calculate the received signal strength at each ground station. This model takes into consideration Radio Frequency (RF) link parameters such as frequency, antenna gain, space loss, plasma effects and the vehicle's position and attitude at any point in time during the flight path. All three RF links are then attenuated based on this calculated level and the RF signals are sent into telemetry receivers to emulate remote sites, or the power incident on the vehicle from uplinked signals. The best source received telemetry data is then passed back to the Launch and Mission Control Monitoring System (LMCMS) resident in the Operations Control Center. The LMCMS also provides the range simulation system the uplink command combined with differential GPS corrections. Later stages will require the progressive integration of actual range hardware with this simulation effort, leading to communication between telemetry, uplink and FTS antennas at NASA Dryden Flight Research Center, with vehicle antennas mounted on the Walter C. Williams Research Aircraft Integration Facility (RAIF). Decommutated Pulse Code Modulated (PCM) data is displayed on one of the four monitors that comprise the Range Safety Officer's (RSO) station. Also displayed are instantaneous impact prediction models, and Federal Aviation Administration (FAA) data for notification of other traffic in the area. Aside from initiating the flight termination command and validating communication links, the RSO station with the range simulation will be used to provide both range control and range safety officers training. The training is necessary to perform their respective functions with greater levels of confidence prior to first flight.

Sharma, Ashley↗

Late Life Supplementation of 25‐Hydroxycholesterol Reduces Aortic Stiffness and Cellular Senescence in Mice

ABSTRACT Stiffening of the aorta is a key antecedent to cardiovascular diseases (CVD) with aging. Age‐related aortic stiffening is driven, in part, by cellular senescence—a hallmark of aging defined primarily by irreversible cell cycle arrest. In this study, we assessed the efficacy of 25‐hydroxycholesterol (25HC), an endogenous cholesterol metabolite, as a naturally occurring senolytic to reverse vascular cell senescence and reduce aortic stiffness in old mice. Old (22–26 months) p16‐3MR mice, a transgenic model allowing for genetic clearance of p16‐positive senescent cells with ganciclovir (GCV), were administered vehicle, 25HC, or GCV to compare the efficacy of the experimental 25HC senolytic versus genetic clearance of senescent cells. We found that short‐term (5d) treatment with 25HC reduced aortic stiffness in vivo, assessed via aortic pulse wave velocity (p = 0.002) to a similar extent as GCV. Ex vivo 25HC exposure of aorta rings from the old p16‐3MR GCV‐treated mice did not further reduce elastic modulus (measure of intrinsic mechanical stiffness), demonstrating that 25HC elicited its beneficial effects on aortic stiffness, in part, through the suppression of excess senescent cells. Improvements in aortic stiffness with 25HC were accompanied by favorable remodeling of structural components of the vascular wall (e.g., lower collagen‐1 abundance and higher α‐elastin content) to a similar extent as GCV. Moreover, 25HC suppressed its putative molecular target CRYAB, modulated CRYAB‐regulated senescent cell anti‐apoptotic pathways, and reduced markers of cellular senescence. The findings from this study identify 25HC as a potential therapy to target vascular cell senescence and reduce age‐related aortic stiffness.

Cell Biology↗

X-ray emission from PSR 0355+54

We have obtained a 20 ks observation of PSR 0355+54 using the ROSAT position sensitive proportional counter (PSPC). The pulsar is detected with a count rate of 4.2(+/- 1.3) x 10(exp -3)/s above the background. While the approximately 70 source counts are insufficient for spectral fitting, we have derived source parameters for specific cases of power law as well as blackbody spectra. For a Crab-like spectrum (photon index alpha = 2) we find L(sub x)(0.1-2.4 keV) = 1.0 x 10(exp 32) ergs/s, somewhat higher than upper limits reported from Einstein observations but consistent with typical L(sub x) versus E-dot values for other pulsars. For blackbody emission, we derive a temperature upper limit of approximately 9.5 x 10(exp 5) K for emission from the entire neutron star surface, which is consistent with standard models for cooling of the neutron star interior given a characteristic age 10(exp 5.75) yr. No evidence is present for modulation at the 156 ms pulsar period, setting a weak upper limit of approximately 75% for the pulsed fraction of the X-ray signal.

Slane, Patrick↗