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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

On the Propagation of Small Perturbations in Two Simple Aeroelastic Systems

In this paper we investigate the wave propagation patterns for two simple flow-structure problems. We focus on the study of the propagation speeds of the waves in the fluid and in the structure, as the rigidity of the structure and the Mach number of the undisturbed flow are changing. Some implications concerning the sound emission by inhomogeneities eventually present in the structure are discussed.

Iollo, Angelo↗

2D Crystal Engineering of Nanosheets Assembled from Helical Peptide Building Blocks

The successful integration of 2D nanomaterials into functional devices hinges on developing fabrication methods that afford hierarchical control across length scales of the entire assembly. We demonstrate structural control over a class of crystalline 2D nanosheets assembled from collagen triple helices. By lengthening the triple helix unit through sequential additions of Pro-Hyp-Gly triads, we achieved sub-angstrom tuning over the 2D lattice. These subtle changes influence the overall nanosheet size, which can be adjusted across the mesoscale size regime. The internal structure was observed by cryo-TEM with direct electron detection, which provides realspace high-resolution images, in which individual triple helices comprising the lattice can be clearly discerned. These results establish a general strategy for tuning the structural hierarchy of 2D nanomaterials that employ rigid, cylindrical structural units.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Using a fast Fourier method to model sound propagation in a stratified atmosphere over a stratified porous-elastic ground

Using a Fast Fourier integration method and a global matrix method for solution of the boundary condition equations at all interfaces simultaneously, a useful tool for predicting acoustic propagation in a stratified fluid over a stratified porous-elastic solid was developed. The model for the solid is a modified Biot-Stoll model incorporating four parameters describing the pore structure corresponding to the Rayleigh-Attenborough rigid-porous structure model. The method is also compared to another Fast Fourier code (CERL-FFP) which models the ground as an impedance surface under a horizontally stratified air. Agreement with the CERL FFP is good. The effects on sound propagation of a combination of ground elasticity, complex ground structure, and atmospheric conditions are demonstrated by theoretical results over a snow layer, and experimental results over a model ground surface.

Tooms, S.↗

Potential bio-medical and commercial applications of cold hibernated elastic memory (CHEM) self-deployable foam structures

A cold hibernated elastic memory (CHEM) foam structure is one of the most recent results of the quest for simple, reliable and low-cost expandable space structures. The CHEM technology utilizes shape memory polymers in open cellular (foam) structure or sandwich structures made of shape memory polymer foam cores and polymeric composite skins. It takes advantage of the polymer’s heat activated shape memory in addition to the foam’s elastic recovery to deploy a compacted structure. The glass transition temperature, Tg is tailored to rigidize the structure in the fully deployed configuration.

Sokolowski, Witold↗

Docking of a rigid spacecraft with unrestrained orbiting flexible structure

A methodology for producing simulations of the docking of a rigid spacecraft with any unrestrained flexible structure was studied. A detailed algorithm for the simulation of the docking of a rigid body with a nonuniform unrestrained beam was sought. The values acquired during docking by the variables characterizing the motions of the rigid body and the unrestrained beam were sought.

Kane, T. R.↗

Making Structural Members From Wire

Structural members of any size, consisting of wire gridwork, fabricated onsite. Rigid beam or column formed from intersecting helices and straight members of relatively flexible wire. Wires joined at their intersections: short wire sections between joints therefore approximate sides of rigid triangular structural subunits. Although originally intended for manufacturing large structures in space, technique has potential for use on Earth.

Dunn, T. J.↗

Curved vacuum cassette assembly for imaging applications

A curved vacuum cassette assembly including a rigid or semi-rigid curved structural backing that is porous or semi-porous to air flow such that one or more imaging detectors (e.g. film layers or CR plates), intensifying screens, and/or other layers may be affixed to the curved structural backing in a secure and conformal manner when a vacuum is applied to the structural backing. All of these structures are encapsulated within an airtight barrier and, optionally, another suitable rigid or semi-rigid housing.

36 MATERIALS SCIENCE↗

Rigid lightweight optical bench for a spaceborne FUV spatial heterodyne interferometer

Requirements for spaceflight optical instruments usually dictate that for the structures be rigid, lightweight, and thermally stable. In addition, for interferometric far ultraviolet (FUV) spectrometers, the requirements for torsional deflection are more severe than with conventional spectrometers. To meet the challenge for rigid and lightweight optical instruments, this paper explores the design of a high-stiffness structure for the support of an FUV spatial heterodyne interferometer where the torsional deflection of the instrument is on the order of 10 arc seconds. The structure is based on use of a thin, hollow section beam with weight-relieving between optical elements. The design also uses a modular and self-contained positioning mechanism that is removed after final optical alignment. Several specific material properties are presented as criteria for material selection. The parameters which affect the particular design requirements are identified with respect to the desired material properties and physical design features. Although large thin sections are susceptible to thermal gradients, this could be minimized by a trade-off for weight, where adequate margin exists. This paper describes the preliminary design for the structure and presents an analysis to verify compliance with the requirements.

Tom, James L.↗

Lifshitz Transition and Band Structure Evolution in Alkali Metal Intercalated 1T′-MoTe 2

In van der Waals materials, coupling between adjacent layers is weak, and consequently interlayer interactions are weakly screened. This opens the possibility to profoundly modify the electronic structure, e.g., by applying electric fields or with adsorbates. Here, in this study, we show for the case of the topologically trivial semimetal 1T′-MoTe 2 that potassium dosing at room temperature significantly transforms its band structure. With a combination of angle-resolved photoemission spectroscopy, scanning tunneling microscopy, X-ray photoemission spectroscopy, and density functional theory we show that (i) for small concentrations of K, 1T′-MoTe 2 undergoes a Lifshitz transition with the electronic structure shifting rigidly, and (ii) for larger K concentrations 1T′-MoTe 2 undergoes significant band structure transformation. Our results demonstrate that the origin of this electronic structure change stems from alkali metal intercalation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the relationship between wind profiles and the STS ascent structural loads

The response of STS ascent structural load indicators to the wind profile is analyzed. The load indicator values versus Mach numbers are calculated with algorithms using trajectory information. The ascent load minimum margin concept is used to show that the detailed wind profile structure measured by the Jimsphere wind system is not needed to assess the STS rigid body structural wind loads.

Smith, Orvel E.↗

Using ERF Devices to Control Deployments of Space Structures

A report proposes devices containing electrorheological fluids (ERFs) damper for controlling deployments of lightweight, flexible structures in outer space. The structures would include spring members that could be wound or compressed for compact stowage during transport. The ERF based damper would keep the structures compacted and/or regulate the speeds with which the structures would spring out for deployment. After deployment, ERF based dampening mechanism could be used to rigidize the structures or damp their vibrations. An experimental ERF deployment controlled structure described in the report comprised two metal carpenter s measuring tapes sandwiched together, held slightly apart by rubber-band spacers, and placed in a bag filled with an ERF. The viscosity of the ERF varied with the voltage applied to the tapes, such that it was possible to hold the tapes in the wound condition or slow the speed with which they sprung from the wound to the straight condition. The report describes several potential variations on the basic concept of an ERF-controlled structural member, including compartmentalization of the interior volume to prevent total loss of the ERF in case of a leak and the use of multiple, individually addressable electrode pairs to enable more localized control.

Bar-Cohen, Yoseph↗

Spin Qubits in Germanium Structures with Phononic Gap

We propose qubits based on shallow donor electron spins in germanium structures with phononic gap. We consider a phononic crystal formed by periodic holes in Ge plate or a rigid cover / Ge layer / rigid substrate structure with gaps approximately a few GHz. The spin relaxation is suppressed dramatically, if the Zeeman frequency omegaZ is in the phononic gap, but an effective coupling between the spins of remote donors via exchange of virtual phonons remains essential. If omegaZ approaches to a gap edge in these structures, a long-range (limited by detuning of omegaZ) resonant exchange interaction takes place. We estimate that ratio of the exchange integral to the longitudinal relaxation rate exceeds 10(exp 5) and lateral scale of resonant exchange 0.1 mm. The exchange contribution can be verified under microwave pumping through oscillations of spin echo signal or through the differential absorption measurements. Efficient manipulation of spins due to the Rabi oscillations opens a new way for quantum information applications.

Qubit↗

Advances in large inflatable reflectors

For most applications in space for which they were tried, inflatable structures show a significant weight reduction when compared to mechanical structures. Inflatables are unmatched when compared to mechanical structures when packaged volume is considered. The reliability of deployment of inflatable structures was known for years. When properly designed, such a system is inherently more reliable because it has very few points of failure. Fully inflatable vs. rigidized inflatable structures are discussed. The L'Garde solar concentrator experience is described. Reflector surface and cylinder rigidization, improvement in gore design tools, and expected advances in rigidization schemes with near future are examined.

Thomas, M.↗

Defect-Mediated Diffusion Pathways in Spodumene Accelerate Lithium Transport

Lithium extraction from naturally occurring α-spodumene is hindered by poor lithium diffusivity, necessitating high-temperature phase transformation to a low-density β polymorph. Although β spodumene exhibits up to 5 orders of magnitude higher lithium-ion diffusivity, both phases have diffusion activation energies between 0.8 and 1 eV, indicating that polymorph density is not the controlling factor over diffusivity. We show that aluminum vacancies facilitate lithium-ion diffusion in α-spodumene by reducing the migration barrier from 2.4 to 0.9 eV. Bond valence site energy and nudged elastic band calculations show a new lithium local minimum site which promotes a one-dimensional percolation network by reducing the lithium intersite distance from 4.5 Å to 2.9 Å. However, aluminum vacancies are energetically unfavorable to percolate through the whole structure, resulting in very low net lithium diffusivity and highlighting the critical role of nonstoichiometric defects in facilitating lithium transport in rigid aluminosilicate structures.

Chemical structure↗

Development of beryllium honeycomb sandwich composite for structural and other related applications

The feasibility of fabricating large beryllium honeycomb panels was demonstrated. Both flat and curved sandwich structures were manufactured using practical, braze bonding techniques. The processes developed prove that metallurgically assembled beryllium honeycomb panels show decided potential where rigid, lightweight structures are required. Three panels, each 10 square feet in surface area, were fabricated, and radiographically inspected to determine integrity. This examination revealed a 97 percent braze in the final panel. It is believed that ceramic dies for forming and brazing would facilitate the fabrication techniques for higher production rates. Ceramic dies would yield a lower thermal gradient in the panel during the braze cycle. This would eliminate the small amount of face sheet wrinkling present in the panels. Hot forming the various panel components demonstrated efficient manufacturing techniques for scaling up and producing large numbers of hot formed beryllium components and panels. The beryllium honeycomb panel demonstrated very good vibrational loading characteristics under test with desirable damping characteristics.

Vogan, J. W.↗

Collapsible Cryogenic Storage Vessel Project

Collapsible cryogenic storage vessels may be useful for future space exploration missions by providing long-term storage capability using a lightweight system that can be compactly packaged for launch. Previous development efforts have identified an 'inflatable' concept as most promising. In the inflatable tank concept, the cryogen is contained within a flexible pressure wall comprised of a flexible bladder to contain the cryogen and a fabric reinforcement layer for structural strength. A flexible, high-performance insulation jacket surrounds the vessel. The weight of the tank and the cryogen is supported by rigid support structures. This design concept is developed through physical testing of a scaled pressure wall, and through development of tests for a flexible Layered Composite Insulation (LCI) insulation jacket. A demonstration pressure wall is fabricated using Spectra fabric for reinforcement, and burst tested under noncryogenic conditions. An insulation test specimens is prepared to demonstrate the effectiveness of the insulation when subject to folding effects, and to examine the effect of compression of the insulation under compressive loading to simulate the pressure effect in a nonrigid insulation blanket under the action atmospheric pressure, such as would be seen in application on the surface of Mars. Although pressure testing did not meet the design goals, the concept shows promise for the design. The testing program provides direction for future development of the collapsible cryogenic vessel concept.

Fleming, David C.↗

Structural Certification of Human-Rated Inflatable Space Structures

This paper details the results of an initial study to develop a certification plan for human-rated inflatable space structures, including guidelines for qualification testing. Habitable softgoods inflatables are multi-layered shell structures that use high-strength webbing, cordage and broadcloth fabric to carry the skin loads of a variety of volumetric shapes and structural architectures. The primary objectives of this study are to define the key parameters that affect these structures and propose a statistically robust approach to defining safety and knockdown factors based on test and analysis. Current NASA standards for habitable inflatable space structures use a factor of safety of 4, which was inherited from airship design criteria. An updated approach to defining a design factor, taking into account material strength variability, load variability in the article, number of test samples, and damage and degradation effects is specified. Accurate analytical modeling of these structures is hindered by the difficulty of obtaining accurate and consistent material data due to load-history- dependent, nonlinear load versus strain behavior. A building block approach to certification is detailed that uses stochastic modeling and statistical test design and analysis to address the unique challenges these high-strength softgoods structures present. Human-rated inflatable modules are a transformative capability for launching much larger habitable volumes into space than is possible with rigid shell structures. This research aims to provide the framework for certifying these structures for future human space exploration missions.

Jones, Thomas C.↗

The carboxylation status of osteocalcin has important consequences for its structure and dynamics

The carboxylation status of Osteocalcin (Ocn) not only influences formation and structure in bones but also has important endocrine functions affecting energy metabolism and expenditure. In this study, the role of γ-carboxylation of the glutamate residues in the structure-dynamics-function relationship in Ocn is investigated. Three forms of Ocn, differentially carboxylated at the Glu-17, 21 and 24 residues, along with a mutated form of Ocn carrying Glu/Ala mutations, are modeled and simulated using molecular dynamics (MD) simulation in the presence of calcium ions. Characterization of the global conformational dynamics of Ocn, described in terms of the orientational variations within its 3-helical domain, highlights large structural variations in the non-carboxylated osteocalcin (nOcn). The bi-carboxylated Ocn (bOcn) and tri-carboxylated (tOcn) species, in contrast, display relatively rigid tertiary structures, with the dynamics of most regions strongly correlated. Radial distribution functions calculated for both bOcn and tOcn show long-range ordering of the calcium ion distribution around the carboxylated glutamate (γGlu) residues, likely playing an important role in promoting stability of these Ocns. Additionally, the same calcium ions are observed to coordinate with neighboring γGlu, better shielding their negative charges and in turn stabilizing these systems more than do the singly coordinating calcium ions observed in the case of nOcn. bOcn is also found to exhibit a more helical C-terminal structure, that has been shown to activate its cellular receptor GPRC6A, highlighting the allosteric role of Ocn carboxylation in modulating the stability and binding potential of the active C-terminal. Furthermore, the carboxylation status of Ocn as well and its calcium coordination appear to have a direct influence on Ocn structure and dynamics, possibly leading to the known differences in Ocn biological function.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗