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At least 253 records · Page 14

Kinetics Measurements in Resistive Electrolytes Using Ring-Disk Electrode: Ring as Current “Shield” Enables Uniform Disk Current Distribution

Rotating disk electrodes are commonly used for electrochemical kinetics measurements. A major disadvantage of these types of electrodes is their nonuniform secondary current distribution, especially when performing electroanalytical measurements in resistive electrolytes. Such nonuniform current distribution can render the values of kinetics constants extracted from the disk electrode to be highly inaccurate. Furthermore, one emerging class of electrolytes that suffer from low ionic conductivities is deep eutectic solvents (DES). DES are a promising class of electrolytes for various emerging applications; however, due to their resistive nature, the secondary current distribution when using them is typically highly nonuniform. For example, the Wagner number when measuring Cu²⁺/Cu⁺ kinetics in choline chloride–ethylene glycol DES (1:4 molar ratio of ChCl:EG) is very low (<0.1), indicating highly nonuniform current distribution over the disk electrode. We show here that the Cu²⁺/Cu⁺ exchange current density measured using disk electrodes is very inaccurate due to the aforementioned nonuniform current distribution. To obtain uniform disk current distribution, we employ here a coplanar concentric rotating ring-disk electrode (RRDE), where the ring serves the function of a current “shield.” Specifically, we show using modeling that the ring minimizes the current distribution nonuniformity at the disk by effectively shielding the disk against current spikes near the disk edge. This enables improved precision in electrode kinetics measurements for the Cu²⁺/Cu⁺ couple in resistive DES. To enable broad applicability of this technique, an analytical expression based on the Wagner number is integrated into an iterative algorithm to help users identify ring conditions to achieve uniform current distribution and thus improved electroanalytics at the disk.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Imaging the End-to-End Dynamics of the Global Solar Wind-Magnetosphere Interaction

Much of what we know about the solar wind’s interaction with the Earth’s magnetosphere has been gained from isolated in situ measurements by single or multiple spacecraft. Based on their observations, we know that reconnection, whether on the dayside magnetopause or deep within the Earth’s magnetotail, controls the flow of solar wind energy into and through the global system. We know that nightside activity provides the energized particles that power geomagnetic storms. But by their very nature these isolated in situ measurements cannot provide an instantaneous global view of the entire system or its cross-scale dynamics. As a result, we don’t know which mode of reconnection prevails on the dayside magnetopause or within the magnetotail as a function of solar wind and geomagnetic conditions. We don’t know which mode or modes of nightside activity supply the most energized particles to the ring current. Nor do we know the dominant loss mode for ring current decay: precipitation, magnetopause outflow, or charge exchange with neutrals. Nor do we know how processes deep within the magnetosphere provide feedback to those happening in the outer magnetosphere. The answers to these questions could have an impact far beyond magnetospheric physics, since magnetic reconnection, particle acceleration, and charge-exchange are fundamental plasma processes that operate at other planets and throughout the universe. Comprehensive end-to-end global imaging of the key micro, meso-, and macro-scale plasma structures that comprise the magnetosphere will provide the answers to these questions via observations with a spatial resolution that exceeds anything possible with in situ measurements. Each proposed interaction mechanism generates a diagnostic plasma structure or boundary signature. Global, end-to-end, imaging provides the pathway to understanding the system as a whole, its constituent parts, and its cross-scale processes on a continuous basis, as needed to quantify the flow of solar wind energy through the global magnetospheric system. The significance of each mechanism is the product of its amplitude and occurrence rate. This white paper describes how a comprehensively-instrumented single spacecraft in a high-latitude circular polar orbit can provide the essential observations needed to track and quantify the flow of solar wind energy through the magnetosphere, including the solar wind plasma and magnetic field input, the magnetopause location in soft X-rays, the auroral oval in far ultraviolet, the ring current in energetic neutrals, the plasmasphere in extreme ultraviolet, the exosphere in Lyman-, the microstructure of the nightside auroral oval in ground-based all sky cameras, and the magnetic perturbations of ionospheric current patterns seen by ground-based magnetometers.

D G Sibeck↗

Simulation and 'TWINS Observations of the 22 July 2009 Storm

TWINS is the first mission to perform stereo imaging of the Earth's ring current. The magnetic storm on 22 July 2009 is the largest storm observed since TWINS began routine stereo imaging in June 2008. On 22 July 2009, the Dst dropped to nearly -80nT at 7:00 and 10:00 UT. During the main phase and at the peak of the storm, TWINS 1 and 2 were near apogee and moving from pre-dawn to post-dawn local time. The energetic neutral atom (ENA) imagers on the 2 spacecraft captured the storm intensification and the formation of the partial ring current. The peak of the ENA emissions was seen in the midnight-to-dawn local-time sector. The development of this storm has been simulated using the Comprehensive Ring Current Model (CRCM) to understand and interpret the observed signatures. We perform CRCM runs with constant and time-varying magnetic field. The model calculations are validated by comparing the simulated ENA and ion flux intensities with TWINS ENA images and in-situ ion data from THEMIS satellites. Simulation with static magnetic field produces a strong shielding electric field that skews the ion drift trajectories toward dawn. The model's corresponding peak ENA emissions are always eastward than those in the observed TWINS images. On the other hand, simulation with a dynamic magnetic field gives better spatial agreements with both ENA and insitu particle data, suggesting that temporal variations of the geomagnetic field exert a significant influence upon global ring current ion dynamics.

Fok, Mei-Ching↗

Simulation and Twins Observations of the 22 July 2009 Storm

TWINS is the first mission to perform stereo imaging of the Earth's ring current. The magnetic storm on 22 July 2009 was at the time the largest storm observed since TWINS began routine stereo imaging in June 2008. On 22 July 2009, the Dst dropped to nearly .80 nT at 0700 and 1000 UT. During the main phase, and at the peak of the storm, TWINS 1 and 2 were near apogee and moving between predawn and postdawn local time. The energetic neutral atom (ENA) imagers on the two spacecraft captured the storm intensification and the formation of the partial ring current. The peak of the high-altitude ENA emissions was seen in the midnight-to-dawn local time sector. The development of this storm has been simulated using the comprehensive ring current model (CRCM) to understand and interpret the observed signatures. We perform CRCM runs with constant and time-varying magnetic field. The model calculations are validated by comparing the simulated ENA and ion flux intensities with TWINS ENA images and in situ ion data from a THEMIS satellite. Simulation with a static magnetic field produces a strong shielding electric field that skews the ion drift trajectories toward dawn. The model's corresponding peak ENA emissions are always more eastward than those in the observed TWINS images. On the other hand, the simulation with a dynamic magnetic field gives better spatial agreement with both ENA and in situ particle data, suggesting that temporal variations of the geomagnetic field exert a significant influence upon global ring current ion dynamics.

Fok, M.-C.↗

Wet model of Saturn's ionosphere: Water from the rings

Current theoretical models of Saturn's ionosphere are difficult to reconcile with the ionospheric electron density profiles obtained from the Pioneer and Voyager radio occultation observations and the large diurnal variation of maximum ionospheric electron density deduced from studies of Saturn lightning discharges. A model of Saturn's ionosphere is proposed in which water plays a major role as a minor constituent present by virtue of downward diffusion from an external source. This model of the Saturn ionosphere is a classical 'F2' type layer resulting from the photodissociative production of H(+) from H2 and rapid chemical loss due to a series of charge exchange reactions with water. A planet-wide influx of about 4x10 to the 7th power molecules/sec/sq cm of water from the rings is consistent with the observed ionospheric electron densities and estimates of influx due to micrometeoride bombardment of the rings. An enhanced influx of water occurs at latitudes (-38 deg, +44 deg) magnetically connected to the inner edge of Saturn's B ring which results from an electromagnetic erosion process contributing substantially to the (local) upper atmosphere water content. Present day influx at these latitudes is possibly as large as 2x10 to the 9th power molecules/sec/sq cm.

Connerney, J. E. P.↗

Inner Magnetospheric Physics

The inner magnetosphere extends from just above the topside ionosphere to approximately 8 RE geocentric distance. Magnetospheric physics is a young science that only started to be recognized as a region with the space observations by Explorer 1 in 1958. The region is mostly populated by ionized gas or plasma from Earth’s ionosphere. Plasma populations are differentiated by their energies primarily. From the least energetic to most are the plasmasphere, ring current, and radiation belts, extending from about 1 eV to 10 MeV in energy and from 1,000s cm-3 down to a few particles per cubic centimeter and less, respectively. The solar wind and solar erupted coronal mass ejections (CMEs) arriving and interacting with Earth’s magnetic field creates a dynamo effect that drives million ampere currents along magnetic field lines that close through the ionosphere. The solar wind dynamo also creates a 100s kV electric field across the magnetosphere that drives convective motion of the plasma within it. The solar wind driven currents compress Earth’s magnetic field on the sunward side and greatly extents the field on the nightside to form the magnetotail. The energy stored in the magnetotail is impulsively released when magnetic field lines there merge, releasing energy into the plasma trapped by the magnetic field. Those plasma become the ring current that loses plasma into the atmosphere to produce the aurora and at the same time ring current plasma can be further energized by wave-particle interactions to become the radiation belts. The presentation will review these topics and a few of the underlying physical processes that are involved in this highly coupled planetary system.

inner magnetosphere↗

Auroral electrojets and evening sector electron dropouts at synchronous orbit

Evidence is presented in support of the concept that, during magnetospheric substorms, ionospheric auroral electrojet currents are directly coupled to the proton partial ring current in the outer magnetosphere. It has been found that for sufficiently isolated substorms the timing of the start of the electron dropout and of its maximum depression is in good agreement with the start and maximum of electrojet activity as indicated by the auroral electrojet index. This correlation suggests a direct coupling between the electrojet currents and the proton partial ring current.

Erickson, K. N.↗

Magnetic Storms

This talk provides a brief summary of the first conference devoted entirely to magnetic storms. Topics cover the relevant phenomena at the Sun/corona, propogation of these structures through interplanetary space, the response of the magnetosphere to interaction with these interplanetary structures, the formation of the storm time ring current (in particular the oxygen content of the ring-current), and storm ionospheric effects and ground based effects.

magnetic storms magnetosphere storm time ring curr↗

Kinetic Simulation and Energetic Neutral Atom Imaging of the Magnetosphere

Advanced simulation tools and measurement techniques have been developed to study the dynamic magnetosphere and its response to drivers in the solar wind. The Comprehensive Ring Current Model (CRCM) is a kinetic code that solves the 3D distribution in space, energy and pitch-angle information of energetic ions and electrons. Energetic Neutral Atom (ENA) imagers have been carried in past and current satellite missions. Global morphology of energetic ions were revealed by the observed ENA images. We have combined simulation and ENA analysis techniques to study the development of ring current ions during magnetic storms and substorms. We identify the timing and location of particle injection and loss. We examine the evolution of ion energy and pitch-angle distribution during different phases of a storm. In this talk we will discuss the findings from our ring current studies and how our simulation and ENA analysis tools can be applied to the upcoming TRIO-CINAMA mission.

Fok, Mei-Ching H.↗

Magnetic Field Measurement on the C/NOFS Satellite: Geomagnetic Storm Effects in the Low Latitude Ionosphere

The Vector Electric Field Investigation (VEFI) suite onboard the Communications/Navigation Outage Forecasting System (C/NOFS) spacecraft includes a sensitive fluxgate magnetometer to measure DC and ULF magnetic fields in the low latitude ionosphere. The instrument includes a DC vector measurement at 1 sample/sec with a range of +/- 45,000 nT whose primary objective is to provide direct measurements of both V x B and E x B that are more accurate than those obtained using a simple magnetic field model. These data can also be used for scientific research to provide information of large-scale ionospheric and magnetospheric current systems, which, when analyzed in conjunction with the C/NOFS DC electric field measurements, promise to advance our understanding of the electrodynamics of the low latitude ionosphere. In this study, we use the magnetic field data to study the temporal and local time variations of the ring currents during geomagnetic storms. We first compare the in situ measurements with the POMME (the POtsdam Magnetic Model of the Earth) model in order to provide an in-flight "calibration" of the data as well as compute magnetic field residuals essential for revealing large scale external current systems. We then compare the magnetic field residuals observed both during quiet times and during geomagnetic storms at the same geographic locations to deduce the magnetic field signatures of the ring current. As will be shown, the low inclination of the C/NOFS satellite provides a unique opportunity to study the evolution of the ring current as a function of local time, which is particularly insightful during periods of magnetic storms. This paper will present the initial results of this study.

Le, Guan↗

Electrodynamics of the Inner Magnetosphere Observed in the Dusk Sector by CRRES and DMSP during the Magnetic Storm of June 4-6, 1991

We compare equatorward/earthward boundaries of convection electric fields and auroral/plasma sheet electrons detected by the DMSP F8 and CRRES satellites during the June 1991 magnetic storm. Measurements come from the dusk magnetic local time sector where the ring current penetrates closest to the Earth. The storm was triggered by a rapid increase in the solar wind dynamic pressure accompanied by a southward turning of the interplanetary magnetic field (IMF). Satellite data show the following: (1) all particle and field boundaries moved equatorward/earthward during the initial phase, probably in response to the strong southward IMF turning; (2) electric field boundaries were either at lower magnetic L shells or close to the inner edge of ring current ions throughout the main and early recovery phases. Penetration earthward of the ring current occurred twice as the polar cap potential increased rapidly; (3) electric potentials at subauroral latitudes were large fractions of the total potentials in the afternoon cell, twice exceeding 60 kV; and (4) the boundaries of auroral electron precipitation were more variable than those of electric fields and mapped to lower L shells than where CRRES encountered plasma sheet electrons. Observations qualitatively agree with predictions of empirical models for auroral electron and electric field boundaries.

Bruke, W. J.↗

Comment on Decay of the Dst Field of Geomagnetic Disturbance After Substorm Onset and its Implication to Storm-Substorm Relation

Over the past few years, there has been a considerable revival in the study of geomagnetic storms stimulated by an increasing knowledge of the energetic particles which comprise the ring current. It is only in recent years that the composition of the ring current has been thouroughly explored and the important role of the oxygen component of the near Earth plasma sheet has become recognized.

geomagnetic storms near Earth plasma sheet ring cu↗

Solar Wind Fluctuations and Their Consequences on the Magnetosphere

Efforts have been made to extract the physical meaning of each term in our prediction model of the Dst index using the solar wind as the only input. The work has been published Journal of Geophysical Research (Temerin and Li, 21002). We found different terms in the model representing different current in the magnetospheric system and each current has different rise and decay times, with the symmetric ring current the slowest, then the partial ring current, then the tail current. We also have been trying to understand the physical meaning of the diffusion coefficient used in our prediction model of relativistic electron fluxes at geostationary orbit. The model reproduced the observations of MeV electron flux variations well, the diffusion coefficient had be assumed only die to local magnetic field fluctuations, leading to its 10th power dependence on the L. We have studied the theoretical derivation of the diffusion coefficient and we believe that the effect electric field fluctuations at smaller L could become more significant. We have expanded our previous radiation belt electron prediction model, which predicted MeV electron geosynchronous orbit based on solar wind measurements, to predict MeV electrons inside geosynchronous orbit. The model results are compared with measurements from Polar/CEPPAD. Prediction efficiencies of 0.56 and 0.54, respectively, at L=6 and L=4, have been achieved over the entire year of 1998. This work wa reported at 2003 Fall AGU and has been accepted for publication in Space Weather (Barker et al., 2005). We also have used simultaneous measurements of the upstream solar wind and of energetic electrons at geosynchronous orbit to analyze the response of electrons over a very wide energy range, 50 keV-6MeV, to solar wind variations. Enhancements of energetic electron fluxes over this whole energy range are modulated by the solar wind speed and the polarity of the interplanetary magnetic field (IMF). The solar wind speed seems to be a dominant controlling parameter for electrons of all energy. This work has been published in Space Weather (Li et al., 2005).

Li, Xin-Lin↗

Minimal Joule dissipation models of magnetospheric convection

This paper gives a topical review of theoretical models of magnetospheric convection based on the concept of minimal Joule dissipation. A two-dimensional slab model of the ionosphere featuring an enhanced conductivity auroral oval is used to compute high-latitude electric fields and currents. Mathematical methods used in the modeling include Fourier analysis, fast Fourier transforms, and variational calculus. Also, conformal transformations are introduced in the analysis, which enable the auroral oval to be represented as a nonconcentric, crescent-shaped figure. Convection patterns appropriate to geomagnetic quiet and disturbed conditions are computed, the differentiating variable being the relative amount of power dissipated in the magnetospheric ring current. When ring current dissipation is small, the convection electric field is restricted to high latitudes (shielding regime), and when it is large, a significant penetration of the field to low latitudes occurs, accompanied by an increase in the ratio of the region I current to the region 2 current.

Barbosa, D. D.↗

C/NOFS Measurements of Stormtime Magnetic Perturbations in the Low-latitude Ionosphere

The Vector Electric Field Investigation suite on the C/NOFS satellite includes a fluxgate magnetometer to monitor the Earth's magnetic fields in the low-latitude ionosphere. Measurements yield full magnetic vectors every second over the range of +/- 45,000 nT with a one-bit resolution of 1.37 nT (16 bit AID) in each component. The sensor's primary responsibility is to support calculations of both VxB and ExB with greater accuracy than can be obtained using standard magnetic field models. The data also contain information about large-scale current systems, that, when analyzed in conjunction with electric field measurements, promise to significantly expand understanding of equatorial electrodynamics. We first compare in situ measurements with the POMME (POtsdam Magnetic Model of the Earth) model to establish in-flight sensor "calibrations" and to compute magnetic residuals. At low latitudes the residuals are predominately products of the stormtime ring current. Since C/NOFS provides a complete coverage of all local times every 97 minutes, magnetic field data allow studies of the temporal evolution and local-time variations of stormtime ring current. The analysis demonstrates the feasibility of using instrumented spacecraft in low-inclination orbits to extract a timely proxy for the provisional Dst index and to specify the ring current's evolution.

Le, Guan↗

C/NOFS Measurements of Magnetic Perturbations in the Low-Latitude Ionosphere During Magnetic Storms

The Vector Electric Field Investigation suite on the C/NOFS satellite includes a fluxgate magnetometer to monitor the Earth s magnetic fields in the low-latitude ionosphere. Measurements yield full magnetic vectors every second over the range of +/-45,000 nT with a one-bit resolution of 1.37 nT (16 bit A/D) in each component. The sensor s primary responsibility is to support calculations of both V x B and E x B with greater accuracy than can be obtained using standard magnetic field models. The data also contain information about large-scale current systems that, when analyzed in conjunction with electric field measurements, promise to significantly expand understanding of equatorial electrodynamics. We first compare in situ measurements with the POMME (Potsdam Magnetic Model of the Earth) model to establish in-flight sensor "calibrations" and to compute magnetic residuals. At low latitudes the residuals are predominately products of the storm time ring current. Since C/NOFS provides a complete coverage of all local times every 97 min, magnetic field data allow studies of the temporal evolution and local time variations of storm time ring current. The analysis demonstrates the feasibility of using instrumented spacecraft in low-inclination orbits to extract a timely proxy for the provisional Dst index and to specify the ring current s evolution.

Le, Guan↗