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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Results of wind tunnel tests at Mach 5 on the .004 scale model 2A configuration space shuttle to determine proximity effects and orbiter control effectiveness during orbiter/external tank abort separation (IAG)

Results from tests in the NASA/MSFC Trisonic Wind Tunnel on 0.004-Scale Orbiter and External Tank Force Models in Close Proximity (RTLS Abort Separation Conditions) are presented. The primary test objectives were to obtain data concerning proximity effects on the aerodynamic forces and moments experienced by Vehicle 2A Configuration Shuttle Orbiter and External Tank during an abort separation (Return to Launch Site) at a Mach number of 5. Additionally, data on orbiter control effectiveness during such an abort was obtained. Proximity effects were investigated for relative angles of incidence from minus 5 deg to plus 10 deg of the orbiter FRL with respect to the external tank centerline over a range of vertical and longitudinal displacements from the mated position to 2.5 tank diameters below and 3 tank diameters aft of the mated position.

Garton, W. P.↗

Theoretical Evaluation of the Pressures, Forces, and Moments at Hypersonic Speeds Acting on Arbitrary Bodies of Revolution Undergoing Separate and Combined Angle-of-attack and Pitching Motions

Equations based on Newtonian impact theory have been derived and a computational procedure developed with the aid of several design-type charts which enable the determination of the aerodynamic forces and moments acting on arbitrary bodies of revolution undergoing either separate or combined angle-of-attack and pitching motions. Bodies with axially increasing and decreasing cross-sectional area distributions are considered; nose shapes may be sharp, blunt, or flat faced. The analysis considers variations in angle of attack from -90 degrees to 90 degrees and allows for both positive and negative pitching rates of arbitrary magnitude. The results are also directly applicable to bodies in either separate or combined sideslip and yawing maneuvers.

Margolis, Kenneth↗

Customized atomic force microscopy probe by focused-ion-beam-assisted tip transfer

We present a technique for transferring separately fabricated tips onto tipless atomic force microscopy (AFM) cantilevers, performed using focused ion beam-assisted nanomanipulation. This method addresses the need in scanning probe microscopy for certain tip geometries that cannot be achieved by conventional lithography. For example, in probing complex layered materials or tall biological cells using AFM, a tall tip with a high-aspect-ratio is required to avoid artifacts caused by collisions of the tip's sides with the material being probed. We show experimentally that tall (18 μm) cantilever tips fabricated by this approach reduce squeeze-film damping, which fits predictions from hydrodynamic theory, and results in an increased quality factor (Q) of the fundamental flexural mode. We demonstrate that a customized tip's well-defined geometry, tall tip height, and aspect ratio enable improved measurement of elastic moduli by allowing access to low-laying portions of tall cells (T lymphocytes). This technique can be generally used to attach tips to any micromechanical device when conventional lithography of tips cannot be accomplished.

36 MATERIALS SCIENCE↗

Electronic and Polar Properties of Vanadate Compounds Stabilized by Epitaxial Strain

Recent experimental and computational studies have demonstrated pressure and epitaxial stabilization of polar PbVO 3 phases with perovskite-derivative crystal structures. In this study, we demonstrate, by density functional theory (DFT) calculations, the stability of similar perovskite-derivative structures in the KVO 3 and NaVO 3 systems when subjected to compressive biaxial strain. The electronic structure and polar properties of these compounds are computed as a function of biaxial strain, and the results are compared to those obtained for experimentally observed PbVO 3 structures. It is demonstrated that the substitution of Pb with monovalent K or Na cations increases the strength of the vanadyl bond due to the removal of the spatially extended Pb 6p states. Both KVO 3 and NaVO 3 exhibit epitaxially stabilized perovskite-derivative phases having large polarizations and only small total energy increases relative to their unstrained bulk structures. The calculated epitaxial phase diagram for KVO 3 predicts a strain-energy driving force for a phase separation from ~% to 1.5% misfit strain into a polar Cm phase, having square-pyramidal coordination of the B-site, and a paraelectric Pbcm phase, having tetrahedral coordination of the B-site. The results show that strain-stabilized polar vanadate compounds may occur for other compositions in addition to PbVO 3 and that changes in the A-site species can be used to tune bonding, structure, and functional properties in these systems.

36 MATERIALS SCIENCE↗

Direct Measure of Electrode Spatial Heterogeneity: Influence of Processing Conditions on Anode Architecture and Performance

The spatial (in)homogeneity of aqueous processed silicon electrodes using standard poly(acrylic acid)-based binders and slurry preparation conditions is demonstrated in this work. X-ray nanotomography shows segregation of materials into submicron-thick layers depending on the mixing method and starting binder molecular weights. Using a dispersant, or in situ production of dispersant from the cleavage of the binder into smaller molecular weight species, increases the resulting lateral homogeneity while drastically decreasing the vertical homogeneity as a result of sedimentation and separation due to gravitational forces. This data explains some of the variability in the literature with respect to silicon electrode performance and demonstrates two potential ways to improve slurry-based electrode fabrications.

36 MATERIALS SCIENCE↗

Grain-grain interaction in stationary dusty plasma

We present a particle-in-cell simulation study of the steady-state interaction between two stationary dust grains in uniform stationary plasma. Both the electrostatic force and the shadowing force on the grains are calculated explicitly. The electrostatic force is always repulsive. For two grains of the same size, the electrostatic force is very nearly equal to the shielded electric field due to a single isolated grain, acting on the charge of the other grain. For two grains of unequal size, the electrostatic force on the smaller grain is smaller than the isolated-grain field, and the force on the larger grain is larger than the isolated-grain field. In all cases, the attractive shadowing force exceeds the repulsive electrostatic force when the grain separation d is greater than an equilibrium separation d{sub 0}. d{sub 0} is found to be between 6λ{sub D} and 9λ{sub D} in all cases. The binding energy is estimated to be between 19 eV and 900 eV for various cases.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Lamination of organic solar cells and organic light emitting devices: Models and experiments

In this paper, a combined experimental, computational, and analytical approach is used to provide new insights into the lamination of organic solar cells and light emitting devices at macro- and micro-scales. First, the effects of applied lamination force (on contact between the laminated layers) are studied. The crack driving forces associated with the interfacial cracks (at the bi-material interfaces) are estimated along with the critical interfacial crack driving forces associated with the separation of thin films, after layer transfer. The conditions for successful lamination are predicted using a combination of experiments and computational models. Guidelines are developed for the lamination of low-cost organic electronic structures.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Axial magnetic flux amplification in Hall-magnetohydrodynamic simulations of externally magnetized z-pinches

It is shown that externally magnetized gas-puff z-pinches under compression can exhibit robust axial flux amplification under suitable axial boundary conditions. This effect relies upon the Hall term in the generalized Ohm's law to generate azimuthal currents in the presence of a driving axial electric field. Under dynamic compression, the total current tends to flow in a mostly force-free boundary layer, separating the predominately azimuthal field outside the layer and the predominately axial field inside the layer. The effect only appears to occur if the axial boundaries allow for outflow or absorption of electromagnetic energy. The effect is mitigated by imposing either periodic or conducting axial boundary conditions. A semi-analytic equilibrium analysis agrees with steady-state solutions of the time-dependent electron-magnetohydrodynamic equations and provides an estimate of the scaling of the boundary layer as well as suggesting a scenario for the formation of the boundary layer. When operative, the effect can significantly impede plasma compression due to the increase in axial flux that diffuses into the pre-compressed plasma or through the presence of conductors that inhibit movement of the generated axial flux. Several facilities have noted unusual implosion behavior in z-pinch experiments with applied axial fields that does not appear to be explainable within the standard magnetohydrodynamic model. In conclusion, it is suggested that these experiments can be explained by the axial flux amplification and concentration effect

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Role of Azimuthal Prestress in the Longitudinal Degradation of Nb 3 Sn Superconducting Magnets

Superconducting magnet coils are subject to enormous electro-magnetic forces which push the cables away from the winding pole, and against the surrounding structure. This structure is usually optimized trying to limit the overall motion and the strains experienced by the superconducting elements. To achieve this, preload forces are applied both in the coil cross-section and along its length. If the e.m. forces overcome these preloads, separation between the coil and the pole occurs, resulting in an overall loss of rigidity. During the magnet design process, it is often tempting to treat the optimization of the azimuthal and longitudinal preload systems separately. However, the two are inextricably related: as the cross-section preload increases, friction can prevent any motion in the longitudinal plane, and decreasing it can instead allow dangerous motions in the conductor ends. The latter can result in very high strains and, in Nb 3 Sn conductors, damage that can prevent the magnet to reach the desired performances. In an attempt to define design guidelines, in this paper we use simplified numerical models to compute, as a function of the in-plane prestress, the variation of the peak strains in the end region of the coils. Finally, we investigate the impact of the azimuthal prestress on a real magnet case, the High-Luminosity Nb 3 Sn Quadrupole MQXF.

Nb3Sn↗

Design and Testing of a Prototype Eddy Current Actuated Valve for the ITER Shattered Pellet Injection System

Reliably mitigating disruptions is essential for ITER to meet its long-term operational research plan without damage to the in-vessel components. Currently, the shattered pellet injection (SPI) technique is the most effective radiator of thermal energy and has been chosen for the baseline disruption mitigation system (DMS) for ITER. The SPI process uses cryogenic temperatures to desublimate material into the barrel of a pipe gun forming a solid cylindrical pellet. Pellets for ITER will initially be hydrogen and hydrogen-neon mixtures. Once formed, pellets are dislodged and accelerated using high-pressure gas (40-60 bar) delivered by a fast-opening valve. The solenoid valves currently used for SPI experiments will not operate in an ITER environment due to the large background magnetic field. An ITER prototype fast-opening valve, called a flyer plate valve (FPV), has been designed and has undergone a wide range of testing. The FPV operates by pulsing current through a pancake coil that is closely coupled with a ``flyer plate.'' The flyer plate is an aluminum plate in which eddy currents are generated creating a repulsive force from the pancake coil. The force generated in the flyer plate rapidly lifts the valve tip off the seat and delivers a pulse of gas to the rear of the pellet, breaking it free from the barrel and accelerating the pellet downstream to its intended target. The design of the valve has been iterated on over the lifetime of this project, as the DMS for ITER shifted from massive gas injection (MGI) to SPI. The most recent design has been tested, and operational ranges have been mapped. The valve must survive 3000+ cycles in an ITER-like magnetic field. The principal functional requirement of this valve is to reliably dislodge and accelerate hydrogen (or H-Ne mixture) pellets into ITER. The valve was mated with an ITER SPI test stand and has been shown to be capable of launching pellets reliably. The valve and power supply design will be discussed in this article, along with the various testing setups used to determine the feasibility of this valve for use on ITER.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Balancing Power Absorption and Fatigue Loads in Irregular Waves for an Oscillating Surge Wave Energy Converter

The aim of this paper is to describe how to control the power-to-load ratio of a novel wave energy converter (WEC) in irregular waves. The novel WEC that is being developed at the National Renewable Energy Laboratory combines an oscillating surge wave energy converter (OSWEC) with control surfaces as part of the structure; however, this work only considers one fixed geometric configuration. This work extends the optimal control problem so as to not solely maximize the time-averaged power, but to also consider the power-take-off (PTO) torque and foundation forces that arise because of WEC motion. The objective function of the controller will include competing terms that force the controller to balance power capture with structural loading. Separate penalty weights were placed on the surge-foundation force and PTO torque magnitude, which allows the controller to be tuned to emphasize either power absorption or load shedding. Results of this study found that, with proper selection of penalty weights, gains in time-averaged power would exceed the gains in structural loading while minimizing the reactive power requirement.

16 TIDAL AND WAVE POWER↗

Semiautomatic segmentation of aortic valve from sequenced ultrasound image using a novel shape-constraint GCV model

Purpose: Effective and accurate segmentation of the aortic valve (AV) from sequenced ultrasound (US) images remains a technical challenge because of intrinsic factors of ultrasound images that impact the quality and the continuous changes of shape and position of segmented objects. In this paper, a novel shape-constraint gradient Chan-Vese (GCV) model is proposed for segmenting the AV from time serial echocardiography. Methods: The GCV model is derived by incorporating the energy of the gradient vector flow into a CV model framework, where the gradient vector energy term is introduced by calculating the deviation angle between the inward normal force of the evolution contour and the gradient vector force. The flow force enlarges the capture range and enhances the blurred boundaries of objects. This is achieved by adding a circle-like contour (constructed using the AV structure region as a constraint shape) as an energy item to the GCV model through the shape comparison function. This shape-constrained energy can enhance the image constraint force by effectively connecting separate gaps of the object edge as well as driving the evolution contour to quickly approach the ideal object. Because of the slight movement of the AV in adjacent frames, the initial constraint shape is defined by users, with the other constraint shapes being derived from the segmentation results of adjacent sequence frames after morphological filtering. The AV is segmented from the US images by minimizing the proposed energy function. Results: To evaluate the performance of the proposed method, five assessment parameters were used to compare it with manual delineations performed by radiologists (gold standards). Three hundred and fifteen images acquired from nine groups were analyzed in the experiment. The area-metric overlap error rate was 6.89% ± 2.88%, the relative area difference rate 3.94% ± 2.63%, the average symmetric contour distance 1.08 ± 0.43 mm, the root mean square symmetric contour distance 1.37 ± 0.52 mm, and the maximum symmetric contour distance was 3.57 ± 1.72 mm. Conclusions: Compared with the CV model, as a result of the combination of the gradient vector and neighborhood shape information, this semiautomatic segmentation method significantly improves the accuracy and robustness of AV segmentation, making it feasible for improved segmentation of aortic valves from US images that have fuzzy boundaries.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

The origin and stability of nanostructural hierarchy in crystalline solids

The structural hierarchy exhibited by materials on more than one length scale can play a major part in determining bulk material properties. Understanding the hierarchical structure can lead to new materials with physical properties tailored for specific applications. We have used a combined experimental and phase-field modeling approach to explore such a hierarchical structure at nanoscale for enhanced coarsening resistance of ordered γ' precipitates in an experimental, multicomponent, high-refractory nickel-base superalloy. The hierarchical microstructure formed experimentally in this alloy is composed of a γ matrix with γ' precipitates that contain embedded, spherical γ precipitates, which do not directionally coarsen during high-temperature annealing but do delay coarsening of the larger γ' precipitates. Chemical mapping via atom probe tomography suggests that the supersaturation of Co, Ru, and Re in the γ' phase is the driving force for the phase separation, leading to the formation of this hierarchical microstructure. Representative phase-field modeling highlights the importance of larger γ' precipitates to promote stability of the embedded γ phase and to delay coarsening of the encompassing γ' precipitates. Our results suggest that the hierarchical material design has the potential to influence the high-temperature stability of precipitate strengthened metallic materials.

36 MATERIALS SCIENCE↗

Isotope Enrichment Using Microchannel Distillation Technology (Final Report)

The Pacific Northwest National Laboratory has successfully demonstrated isotopic enrichment with microchannel distillation (MCD) technology, a capability for process intensification of chemical boiling point separations (CBPS). Sixty separation stages were achieved in a single device, a new record for process intensification technologies. The minimum length of a separation stage was 0.41 cm, a factor of 5 smaller than the best commercial advanced structured packing. The reduced separation stage length dramatically shortens the column length, which is particularly important for isotopic enrichment that typically requires thousands of stages. A key advantage of MCD technology is scalability, which was demonstrated by increasing the length of the test device by a factor of 2.5 and doubling the number of channels while improving performance. Results were obtained for two separations, propane from propylene and isotopic enrichment of methane, which along with previous results with other separations, demonstrates the versatility and utility of MCD for difficult separations. By employing capillary forces, MCD devices can operated in a horizontal configuration that facilitates a lower equipment profile and compact systems. Compact systems are easier and cheaper to insulate and operate at cryogenic temperatures that are typical for isotopic enrichment. MCD devices have been operated as low as the normal boiling point of methane, -162°C, and as high as the boiling point of diesel fuel, ~300°C.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved anode design for metal-oxygen cells

Method for returning electrolyte to the anode compartment in metal-oxygen second battery cells eliminates the problem of the anode drying out during charge-discharge cycling. Electrolyte forced out of the separator is returned to the anode by a microporous insert and wicking material.

Arrance, F. C.↗

Assessment of potential buffet problems on the space shuttle vehicle

Buffet of the space shuttle launch and reentry configuration is an area requiring continued evaluation to produce a safe reliable vehicle of minimum weight. Buffet forces result from flow separation and therefore can not be predicted accurately. Buffet loads are highly sensitive to configuration, angle of attack, and Mach number and can be reliably determined only by wind tunnel tests of elastically scaled models.

Muhlstein, L., Jr.↗