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At least 253 records · Page 14

The effects of ion implantation on the tribology of perfluoropolyether-lubricated 440C stainless steel couples

The lubricating lifetime of thin films of a perfluoropolyether (PFPE) based on hexafluoropropene oxide in the presence of ion implanted 440C stainless steel is presented. Stainless steel discs, either unimplanted or implanted with N2, C, Ti, Ti + N2, or Ti + C had a thin film of PFPE (60-400 A) applied to them reproducibly (+/- 20 percent) and uniformly (+/- 15 percent) using a device developed for this study. The lifetimes of these films were quantified by measuring the number of sliding-wear cycles required to induce an increase in the friction coefficient from an initial value characteristic of the lubricated wear couple to a final, or failure value, characteristic of an unlubricated, unimplanted couple. The tests were performed in a dry nitrogen atmosphere (less than 1 percent RH) at room temperature using a 3 N normal load with a relative sliding speed of 0.05 m/s. The lubricated lifetime of the 440C couple was increased by an order of magnitude by implanting the disc with Ti. Ranked from most to least effective, the implanted species were: Ti; Ti+C; unimplanted; N2; C approximately equals Ti+N2. The mechanism postulated to explain these results involves the formation of a passivating or reactive layer which inhibits or facilitates the production of active sites. The corresponding surface microstructures induced by ion implantation, obtained using x-ray diffraction and conversion electron Mossbauer spectroscopy, ranked from most to least effective in enhancing lubricant lifetime were: amorphous Fe-Cr-Ti; amorphous Fe-Cr-Ti-C + TiC; unimplanted; epsilon-(Fe,Cr)(sub x)N, x = 2 or 3; amorphous Fe-Cr-C approximately equals amorphous Fe-Cr-Ti-N.

Shogrin, Bradley↗

Antimatter Production for Near-Term Propulsion Applications

This presentation discusses the use and potential of power generated from Proton-Antiproton Annihilation. The problem is that there is not enough production of anti-protons, and that the production methods are inefficient. The cost for 1 gram of antiprotons is estimated at 62.5 trillion dollars. Applications which require large quantities (i.e., about 1 kg) will require dramatic improvements in the efficiency of the production of the antiprotons. However, applications which involve small quantities (i.e., 1 to 10 micrograms may be practical with a relative expansion of capacities. There are four "conventional" antimatter propulsion concepts which are: (1) the solid core, (2) the gas core, (3) the plasma core, and the (4) beam core. These are compared in terms of specific impulse, propulsive energy utilization and vehicle structure/propellant mass ratio. Antimatter-catalyzed fusion propulsion is also evaluated. The improvements outlined in the presentation to the Fermilab production, and other sites. capability would result in worldwide capacity of several micrograms per year, by the middle of the next decade. The conclusions drawn are: (1) the Conventional antimatter propulsion IS not practical due to large p-bar requirement; (2) Antimatter-catalyzed systems can be reasonably considered this "solves" energy cost problem by employing substantially smaller quantities; (3) With current infrastructure, cost for 1 microgram of p-bars is $62.5 million, but with near-term improvements cost should drop; (4) Milligram-scale facility would require a $15 billion investment, but could produce 1 mg, at $0.1/kW-hr, for $6.25 million.

Gerrish, Harold P.↗

The IERS Special Bureau for Tides

The Global Geophysical Fluids Center of the International Earth Rotation Service (IERS) comprises 8 special bureaus, one of which is the Special Bureau for Tides. Its purpose is to facilitate studies related to tidal effects in earth rotation. To that end it collects various relevant datasets and distributes them, primarily through its website at bowie.gsfc.nasa.gov/ggfc/tides. Example datasets include tabulations of tidal variations in angular momentum and in earth rotation as estimated from numerical ocean tide models and from meteorological reanalysis products. The web site also features an interactive tidal prediction "machine" which generates tidal predictions (e.g., of UT1) from lists of harmonic constants. The Special Bureau relies on the tidal and earth-rotation communities to build and enlarge its datasets; further contributions from this community are most welcome.

Ray, Richard D.↗

Mars Surface System Common Capabilities and Challenges for Human Missions

NASA has begun a process to identify and evaluate candidate locations where humans could land, live and work on the martian surface. These locations are referred to as Exploration Zones (EZs). Given current mission concepts, an EZ is a collection of Regions of Interest (ROIs) that are located within approximately 100 kilometers of a centralized landing site. ROIs are areas that are relevant for scientific investigation and/or development/maturation of capabilities and resources necessary for a sustainable human presence. The EZ also contains a landing site and a habitation site that will be used by multiple human crews during missions to explore and utilize the ROIs within the EZ. In parallel with this process, NASA continues to make progress on the Evolvable Mars Campaign examining alternatives that can pioneer an extended human presence on Mars that is Earth independent. This involves ongoing assessments of surface systems and operations to enable a permanent, sustainable human presence. Because of the difficulty in getting equipment and supplies to the surface of Mars, part of these assessments involve identifying those systems and processes that can perform in multiple, sometimes completely unrelated, situations. These assessments have been performed in a very generic surface mission carried out at a very generic surface location. As specific candidate EZs are identified it becomes important to evaluate the current suite of surface systems and operations as they are likely to perform for the specific locations and for the types of operations - both scientific and development - that are proposed for these EZs. It is also important to evaluate the proposed EZs for their suitability to be explored or developed given the range of capabilities and constraints for the types of surface systems and operations being considered within the EMC. This means looking at setting up and operating a field station at a central location within the EZ as well as traversing to and exploring the scientific ROIs within the boundaries of the EZ. The proposed paper will describe the current status of common systems and operations as they can be applied to actual EZ locations on Mars. Initially these EZs will be the four locations identified MEPAG's Human Exploration of Mars Science Analysis Group (HEM‐SAG) that will be used as representative of the EZs that will emerge from the process that NASA has initiated. An example process that could be commonly applied is an approach for developing a field station site plan that would be demonstrated by applying this process to each of the four HEM‐SAG sites. Examples of common systems include (a) mobility systems that can be used to off‐load and move payloads to specific locations at the central field station location that could also be used to traverse long distances to reach some of the more remote ROIs or (b) robotic systems that can support various activities (such as system set up and maintenance) at the field station that could also be used to explore scientific ROIs and used to support site‐specific ISRU production activities.

Hoffman, Stephen J.↗

Effects of Simulated Spaceflight on Mitochondrial Oxidative Stress in Bone Remodelling

Microgravity and ionizing radiation may contribute to cellular stress; resulting in increased generation of reactive oxygen species (ROS), DNA damage, cell cycle arrest, and cell death. We hypothesized that suppression of excess ROS in osteoblasts and osteoclasts will improve bone microarchitecture. To test our hypothesis, we used irradiated transgenic mCAT mice overexpressing human anti-oxidant catalase gene targeted to the mitochondria (main site for ROS production). mCAT mice expressed the transgene and displayed elevated catalase activity in bone and ex vivo osteoblast and osteoclast cultures. Treated bone from wildtype mice showed elevated levels of oxidative damage whereas mCAT mice did not. Also, increased catalase activity correlated with decreased MDA levels and that increased oxidative damage correlated with decreased % bone volume. Ex-vivo osteoblast colony growth positively correlated with osteoblast catalase activity. mCAT mice displayed reduced % bone volume. Treatment caused significant bone loss in wildtype mice. Treatment also caused slight deficits in microarchitecture of mCAT mice. In conclusion, ROS signaling in both osteoblast and osteoclast lineage cells contribute to skeletal development and remodeling and quenching oxidative damage could play a role in bone loss prevention.

bone loss↗

Maximum Carbon Uptake Rate Dominates the Interannual Variability of Global Net Ecosystem Exchange

Terrestrial ecosystems contribute most of the interannual variability (IAV) in atmospheric carbon dioxide (CO2) concentrations, but processes driving the IAV of net ecosystem CO2 exchange (NEE) remain elusive. For a predictive understanding of the global C cycle, it is imperative to identify indicators associated with ecological processes that determine the IAV of NEE. Here, we decompose the annual NEE of global terrestrial ecosystems into their phenological and physiological components, namely maximum carbon uptake (MCU) and release (MCR), the carbon uptake period (CUP), and two parameters, α and β, that describe the ratio between actual versus hypothetical maximum C sink and source, respectively. Using long‐term observed NEE from 66 eddy covariance sites and global products derived from FLUXNET observations, we found that the IAV of NEE is determined predominately by MCU at the global scale, which explains 48% of the IAV of NEE on average while α, CUP, β, and MCR explain 14%, 25%, 2%, and 8%, respectively. These patterns differ in water‐limited ecosystems versus temperature‐ and radiation‐limited ecosystems; 31% of the IAV of NEE is determined by the IAV of CUP in water‐limited ecosystems, and 60% of the IAV of NEE is determined by the IAV of MCU in temperature‐ and radiation‐limited ecosystems. The Lund‐Potsdam‐Jena (LPJ) model and the Multi‐scale Synthesis and Terrestrial Model Inter‐comparison Project (MsTMIP) models underestimate the contribution of MCU to the IAV of NEE by about 18% on average, and overestimate the contribution of CUP by about 25%. This study provides a new perspective on the proximate causes of the IAV of NEE, which suggest that capturing the variability of MCU is critical for modeling the IAV of NEE across most of the global land surface.

Fu, Zheng↗

An AeroCom–AeroSat study: intercomparison of satellite AOD datasets for aerosol model evaluation

To better understand and characterize current uncertainties in the important observational constraint of climate models of aerosol optical depth (AOD), we evaluate and intercompare 14 satellite products, representing nine different retrieval algorithm families using observations from five different sensors on six different platforms. The satellite products (super-observations consisting of 1°×1° daily aggregated retrievals drawn from the years 2006, 2008 and 2010) are evaluated with AErosol RObotic NETwork (AERONET) and Maritime Aerosol Network (MAN) data. Results show that different products exhibit different regionally varying biases (both under- and overestimates) that may reach ±50 %, although a typical bias would be 15 %–25 % (depending on the product). In addition to these biases, the products exhibit random errors that can be 1.6 to 3 times as large. Most products show similar performance, although there are a few exceptions with either larger biases or larger random errors. The intercomparison of satellite products extends this analysis and provides spatial context to it. In particular, we show that aggregated satellite AOD agrees much better than the spatial coverage (often driven by cloud masks) within the 1°×1° grid cells. Up to ∼50 % of the difference between satellite AOD is attributed to cloud contamination. The diversity in AOD products shows clear spatial patterns and varies from 10 % (parts of the ocean) to 100 % (central Asia and Australia). More importantly, we show that the diversity may be used as an indication of AOD uncertainty, at least for the better performing products. This provides modellers with a global map of expected AOD uncertainty in satellite products, allows assessment of products away from AERONET sites, can provide guidance for future AERONET locations and offers suggestions for product improvements. We account for statistical and sampling noise in our analyses. Sampling noise, variations due to the evaluation of different subsets of the data, causes important changes in error metrics. The consequences of this noise term for product evaluation are discussed.

Aerosol↗

Intermountain West Wildland Fires: Mapping Tree Mortality and Burn Patches using NASA Earth Observations to Determine Fire Risk and Inform Fire Management Practices

Within the intermountain west, monitoring fuel loads is a major concern for wildland fire management efforts. To address this concern, we partnered with the U.S. Forest Service to inform the agency which forested areas should be prioritized for prescribed burning and fuel reduction near human communities in the Bridger-Teton National Forest, Wyoming. We created burn maps, fuel load maps, and a tutorial document to identify forest impact trends and provide the partner with the tools to replicate project methods for expansion to other wildfire crisis strategy sites. These end products were made using two NASA Earth observations: Landsat 8 Operational Land Imager and Shuttle Radar Topography Mission. Based on our random forest analysis, our maps identified 998 acres within the Wildland Urban Interface that are predicted to have high fuel loading and high burn severity within the Bridger-Teton National Forest. Forested areas closer to heavily populated areas such as Jackson, Kelly, Moran, New Forks Lake, and Star Valley Ranch should be prioritized for fuel reduction. However, our random forest model analysis was limited to using vegetation and topographical indices with no field data for model validation. Therefore, future studies should use field data for model validation to improve model accuracy and additionally incorporate Global Ecosystem Dynamics Investigation data into models to create better predictions of forested areas with high fuel load and high burn severity.

Remote Sensing↗

Effect of Mo precursors in Microwave-assisted Methane Dehydroaromatization over Mo/HZSM5 catalysts

Natural gas flaring occurs in remote shale regions due to limited pipeline takeaway capacity. The conversion of the associated natural gas into aromatics in modular microwave reactors is a viable alternative to monetize the wasted gas. Microwaves offer rapid, selective heating in compact reactor systems that can enable on-demand chemical production at the well-site. Mo-HZSM-5 catalysts are widely used for aromatic production, but the location and nature of the active sites are still under debate. This study focuses on the use of 6 different Mo precursors to elucidate insights into the Mo properties that are desirable for BTX production. The catalysts were characterized by different methods (XPS, TPR, Raman, etc) to determine differences in Mo catalytic properties that may affect performance and understand these differences through performance testing under microwave at 700C for methane dehydroaromatization. Metal precursors that enable a better distribution of Mo into the pores and over the surface lead to improved benzene yield, whereas those that limited Mo to primarily the surface suffer rapid deactivation and low benzene yields. Additionally, strong Lewis acidity that arises from the sodium containing precursor drastically shifts the product selectivity towards dehydrogenation, which produces more ethylene and carbon. This catalyst had the highest deactivation constant of all catalysts tested.

gas flaring reduction↗

Understanding Solar Photovoltaic System Performance: An Assessment of 75 Federal Photovoltaic Systems

This report presents a performance analysis of 75 photovoltaic systems based on PV system production data collected as part of a FEMP Federal PV Performance Assessment project combined with co-incident insolation, and ambient temperature to analyze how actual performance compares with a performance model. FEMP collaborated with 17 Federal agencies and sub-agencies to collect the information required to analyze the performance of each system. The systems represent a total capacity of 30,714 kW and range in size from 1 kW to 4,043 kW, with an average size of 410 kW, and were installed between 2011 and 2020. The data is analyzed for Key Performance Indicators, Availability, Performance Ratio and Energy Ratio by comparing the measured production data to model production data. The System Advisor Model (SAM) combines a description of the system (such as inverter capacity, de-rating for temperature, balance-of-system efficiency) with environmental parameters (coincident solar and temperature data) to calculate predicted performance. The performance metrics are calculated by lining up the measured production data with the model estimate on an hour-by-hour, day-by-day, or month-by-month basis (depending on the interval resolution of the production data). A report with system description, photo of the system, special assumptions made for the site, graph of measured production and model production, table of key performance indicators, and links to O&M resources that might improve performance was produced and delivered to site and agency staff with a short on-line briefing.

14 SOLAR ENERGY↗

Rainfall manipulation experiments as simulated by terrestrial biosphere models: Where do we stand?

Changes in rainfall amounts and patterns have been observed and are expected to continue in the near future with potentially significant ecological and societal consequences. Modelling vegetation responses to changes in rainfall is thus crucial to project water and carbon cycles in the future. In this study, we present the results of a new model-data intercomparison project, where we tested the ability of 10 terrestrial biosphere models to reproduce the observed sensitivity of ecosystem productivity to rainfall changes at 10 sites across the globe, in nine of which, rainfall exclusion and/or irrigation experiments had been performed. The key results are as follows: (a) Inter-model variation is generally large and model agreement varies with timescales. In severely water-limited sites, models only agree on the interannual variability of evapotranspiration and to a smaller extent on gross primary productivity. In more mesic sites, model agreement for both water and carbon fluxes is typically higher on fine (daily–monthly) timescales and reduces on longer (seasonal–annual) scales. (b) Models on average overestimate the relationship between ecosystem productivity and mean rainfall amounts across sites (in space) and have a low capacity in reproducing the temporal (interannual) sensitivity of vegetation productivity to annual rainfall at a given site, even though observation uncertainty is comparable to inter-model variability. (c) Most models reproduced the sign of the observed patterns in productivity changes in rainfall manipulation experiments but had a low capacity in reproducing the observed magnitude of productivity changes. Models better reproduced the observed productivity responses due to rainfall exclusion than addition. (d) All models attribute ecosystem productivity changes to the intensity of vegetation stress and peak leaf area, whereas the impact of the change in growing season length is negligible. Finally, the relative contribution of the peak leaf area and vegetation stress intensity was highly variable among models.

54 ENVIRONMENTAL SCIENCES↗

Unalakleet Climate: Analyzing Permafrost Degradation and Drainage Networks in Unalakleet, Alaska

The coastal community of Unalakleet is currently the 8th most at-risk community in Alaska due to the adverse effects of climate change that include permafrost degradation, severe coastal erosion, and sea-level rise-induced flood inundation caused by increasingly frequent storm surges. In response, the community has started a managed relocation with support from the Native Village of Unalakleet (NVU) and the National Renewable Energy Lab (NREL)’s Alaska campus in Fairbanks. The Unalakleet Climate NASA DEVELOP team partnered with NREL to provide remote sensing support and analysis for resilience planning in Unalakleet, supporting their ongoing relocation efforts and guiding future expansion. The team utilized Sentinel-1 C-Synthetic Aperture Radar (SAR), WorldView-2, and WorldView-3 datasets from 2017 – 2023 to analyze seasonal summer subsidence and utilized a 2014 Ancillary USGS 5 m Alaska DEM to conduct drainage network analyses that included watershed delineation and Height Above Nearest Drainage (HAND) analysis. The team also used high-resolution WorldView images to locate stable reference points that served as quality control for the team’s analyses. The team’s end products included maps containing subsidence and drainage zones information at and surrounding the relocation site. The team’s products provide NREL with valuable data that enables them to better assist Unalakleet’s managed relocation and assists Unalakleet with adapting to the catastrophic effects of climate change and build resilience in a community on the front lines of climate change.

Ian Lee↗

Hydrological Controls on Riverbed Methane Emissions: A Numerical Investigation of Hydrodynamic and Ebullitive Mechanisms from Site to Basin Scales

Methane production and emission from riverbed sediments constitute a significant yet underexplored component of the river methane budget. Despite their importance, a mechanistic and quantitative understanding of these processes under dynamic flow conditions remains elusive, particularly at the basin scale. In this study, we investigate the multiscale (site-to-basin) mechanisms governing methane emissions from riverbeds, focusing on the interplay between biogeochemical processes and hydrological dynamics. We developed a reactive transport model that integrates methane production with hydrodynamic and ebullitive pathways and coupled it with a basin-scale groundwater flow model to simulate methane emissions across scales. By incorporating key factors such as vertical hydrological exchange flow (VHEF), particulate organic carbon availability, sediment properties, and temperature sensitivity, our model captures the spatiotemporal variability of methane ebullition at both the site and basin scales. Our results reveal that methane ebullition is strongly modulated by VHEF, with lower flow rates promoting methane accumulation and subsequent ebullition. Sensitivity analyses underscore nonlinear responses of methane fluxes to environmental drivers. Furthermore, these findings emphasize the critical roles of sediment composition, hydrological exchange, and environmental conditions in shaping methane dynamics. Overall, this work advances our understanding of riverine methane emissions and offers insights for guiding climate models and mitigation strategies.

Fluxes↗

Carbidic Mo is the sole kinetically-relevant active site for catalytic methane dehydroaromatization on Mo/H-ZSM-5

Systematic variation of Mo/Al = {0.10, 0.25, 0.35} in Mo/H-ZSM-5 catalysts effects ~20× change of Mo-to-H + ratio during methane dehydroaromatization (DHA) reactions at steady state and on deactivating catalysts. Mo and Brønsted-acid site count, respectively enumerated by ethane hydrogenolysis probe reaction and dimethyl ether chemical titration, evolve disparately during DHA catalysis, indicating the two sites reduce in number by distinct mechanisms. Here, the deactivation of Mo/H-ZSM-5 catalytic activity is uniquely attributed to the loss of active, or accessible, Mo sites, evinced by (i) the non-selective nature of deactivation (i.e. that deactivation occurs without modification of residual active sites), (ii) invariance in product distribution from Mo/H + = 0.10–2.1, and (iii) linear correspondence between Mo-catalyzed ethane hydrogenolysis rate and active site count during DHA on deactivating samples. DHA forward rate – the intrinsic kinetic descriptor of catalyst activity – normalizes by Mo content at steady state and on deactivating catalysts with Mo/Al = 0.10–0.35 for Mo-based contact times in the range τ Mo = 0.79–44 mol Mo s mol –1 C , unequivocally establishing Mo aggregates as the sole kinetically-relevant active site on Mo/H-ZSM-5. Brønsted-acid site content over a ~40× range in τ H+ = 1.4–54 mol H+ s mol –1 C has no discernable correlation with or effect on DHA rate, methane conversion, or product distribution – demonstrating H + does not catalyze any rate- or selectivity-determining steps in the benzene formation pathway and suggesting that the benefits of zeolitic acid sites are only to disperse Mo during catalyst synthesis and, conceivably, to catalyze equilibrated reaction steps.

02 PETROLEUM↗

SNL Human Reliability Analysis (Capstone Final Report)

Sandia National Laboratories (SNL) requested a measure of possible human error for each state verification method for a safety mechanism performed at partnering production agencies. A team of three human factors individuals were tasked with conducting observations during site visits of both production agencies in order to complete a Human Reliability Analysis (HRA). A HRA will be used because it provides both qualitative and quantitative reports of human error. This report is the first phase of that effort, which will describe the methods which occur at one of the production agencies.

99 GENERAL AND MISCELLANEOUS↗

Stabilized open metal sites in bimetallic metal–organic framework catalysts for hydrogen production from alcohols

Liquid organic hydrogen carriers such as alcohols and polyols are a high-capacity means of transporting and reversibly storing hydrogen that demands effective catalysts to drive the (de)hydrogenation reactions under mild conditions. We employed a combined theory/experiment approach to develop MOF-74 catalysts for alcohol dehydrogenation and examine the performance of the open metal sites (OMS), which have properties analogous to the active sites in high-performance single-site catalysts and homogeneous catalysts. Methanol dehydrogenation was used as a model reaction system for assessing the performance of five monometallic M-MOF-74 variants (M = Co, Cu, Mg, Mn, Ni). Co-MOF-74 and Ni-MOF-74 give the highest H 2 productivity. However, Ni-MOF-74 is unstable under reaction conditions and forms metallic nickel particles. To improve catalyst activity and stability, bimetallic (NixMg 1-x )-MOF-74 catalysts were developed that stabilize the Ni OMS and promote the dehydrogenation reaction. An optimal composition exists at (Ni 0.32 Mg 0.68 )-MOF-74 that gives the greatest H2 productivity, up to 203 mL gcat -1 min -1 at 300 °C, and maintains 100% selectivity to CO and H 2 between 225–275 °C. The optimized catalyst is also active for the dehydrogenation of other alcohols. DFT calculations reveal that synergistic interactions between the open metal site and the organic linker lead to lower reaction barriers in the MOF catalysts compared to the open metal site alone. This work expands the suite of hydrogen-related reactions catalyzed by MOF-74 which includes recent work on hydroformulation and our earlier reports of aryl-ether hydrogenolysis. Moreover, it highlights the use of bimetallic frameworks as an effective strategy for stabilizing a high density of catalytically active open metal sites.

08 HYDROGEN↗

A low-latitude, high-elevation 10Be production-rate calibration from the Rwenzori Mountains, Uganda

Cosmogenic nuclide surface-exposure dating has become a key tool in geomorphology. Robust application of the technique relies on determination of local nuclide production rates using independently dated calibration sites. However, there are few existing calibration sites in certain regions, particularly in low-latitude, high-elevation regions where cosmogenic nuclide production is theoretically more sensitive to changes in Earth's magnetic field and atmospheric conditions. We present a new cosmogenic beryllium-10 (10Be) production-rate calibration from the equatorial Rwenzori Mountains in Uganda. The calibration is based on radiocarbon dating of basal lake sediments (∼21.3 kyr BP) from Lake Mahoma (2900 m asl) and measured 10Be concentrations from boulders on the crest of a moraine which dams the lake. Our results indicate a time-integrated 10Be production rate of 15.83 ± 0.81 at/g/yr at Lake Mahoma. We then use these calibration data and two public online calculators to calculate ages for moraines in a separate Rwenzori valley for which there exists a minimum-limiting radiocarbon age constraint (∼12 kyr BP) on surficial glacial sediments. This enables us to assess the performance of different parameters used to scale production rates spatially and temporally (e.g., scaling frameworks, geomagnetic field reconstructions, atmospheric models) for surface-exposure age calculation in the region. Our results highlight the sensitivity of low-latitude cosmogenic nuclide surface-exposure ages to discrete calculation parameters, such as scaling framework or reconstructions of Earth's magnetic field, and the utility of determining production rates at sites where limiting age data exists for other nearby landforms.

Anderson, N [Dartmouth College]↗