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At least 253 records · Page 14

Federal Facility Agreement and Consent Order Nevada National Security Site Use Restriction Management Plan, Revision 2

This Use Restriction Management Plan (URMP) provides the information needed to create, modify, and manage use restrictions (URs) for sites on the Nevada National Security Site (NNSS), and sites accessed through the NNSS main gate, that were closed using the corrective action alternative (CAA) of closure in place under the Federal Facility Agreement and Consent Order (FFACO). It addresses URs established under the FFACO for releases related to the development, testing, and production of nuclear weapons that are located on the NNSS and that are accessed through the NNSS main gate. FFACO URs are established at sites where contamination remains at levels exceeding final action levels (FALs) or is forecasted to exceed Safe Drinking Water Act (SDWA) maximum contaminant levels (CFR, 2025a) over the next 1,000 years following completion of corrective actions. Administrative URs are established at Industrial Sites and Soils sites where contamination remains at levels exceeding industrial action levels as defined in the Soils RBCA document. All URs stipulate restrictions sufficient to ensure the protection of human health, safety, and the environment.

54 ENVIRONMENTAL SCIENCES↗

Towards Spatial Control of Reaction Selectivity on Photocatalysts using Area Selective Atomic Layer Deposition on Model Dual Site Electrocatalyst Platform

Photocatalytic water splitting is a promising route to low-cost H2; however, this approach is currently limited by solar-to-hydrogen (STH) conversion efficiencies in the sub-10% range. Z-scheme water splitting, in which H2 and O2 evolving particles are operated in separate compartments and electronically coupled by a soluble redox mediator, offers improvements in STH efficiency but introduces high rates of undesired side and back reactions. Nanoscopic oxide coatings (e.g., CrOx, and SiOx) have previously been used to selectively block undesired reactants from reaching active sites; however, a coating encapsulating the entire photocatalyst particle limits activity as the particle can no longer facilitate both half reactions. In contrast to photodeposition, which may produce non-uniform overlayers due to the difficulty of controlling local electrochemical reactivity on the surface, area-selective atomic layer deposition (AS-ALD) can be used to deposit conformal ultrathin oxide coatings while preserving access to non-growth areas of a substrate surface. To develop this technique for Z-scheme photocatalysts, we performed AS-ALD of TiO2 on a dual site planar electrocatalyst based on interdigitated arrays of Pt and Au. Self-assembled monolayers of 1-octadecanethiol (ODT) were used to block growth on the Au array, resulting in a patterned surface in which only the Pt sites were encapsulated with TiO2. These electrocatalysts demonstrated localized reaction selectivity for hydrogen evolution reaction (HER) over the TiO2/Pt sites, while the uncoated Au sites retained activity towards Fe(II)/Fe(III) redox (FeRR). Under independent potential control, these microelectrodes showed that selectively deposited TiO2 coatings can suppress the rate of back reactions on neighboring active sites by an order of magnitude compared to uncoated control samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cooperative Support of the Fermilab Site’s Natural Areas and Related Programs (CRADA Final Report)

Under the prime contract with the Department of Energy, Fermi Research Alliance, LLC (FRA) is responsible for effective stewardship of the Fermi National Accelerator Laboratory (Fermilab) 6,800-acre site, to assure that Fermilab is renewed and enhanced to meet future mission needs. As the steward of the Fermilab site, FRA is responsible for maintaining the natural areas for the site (e.g., prairie restoration sites, woodlands, etc.), which are essential for protecting the health and safety of personnel working on or visiting the site, while supporting the scientific and educational missions of Fermilab. Fermilab Natural Areas (FNA) is a not-for-profit corporation organized and existing under the laws of the State of Illinois. FNA was founded in 2006 and incorporated in 2008 for the purposes of studying, conserving, and restoring the Fermilab Site’s natural areas in a manner consistent with the science mission of Fermilab and enhancing the awareness and visibility of the natural amenities of Fermilab to neighboring communities.

54 ENVIRONMENTAL SCIENCES↗

An Evaluation of AI Models’ Performance for Three Geothermal Sites

Current artificial intelligence (AI) applications in geothermal exploration are tailored to specific geothermal sites, limiting their transferability and broader applicability. This study aims to develop a globally applicable and transferable geothermal AI model to empower the exploration of geothermal resources. This study presents a methodology for adopting geothermal AI that utilizes known indicators of geothermal areas, including mineral markers, land surface temperature (LST), and faults. The proposed methodology involves a comparative analysis of three distinct geothermal sites—Brady, Desert Peak, and Coso. The research plan includes self-testing to understand the unique characteristics of each site, followed by dependent and independent tests to assess cross-compatibility and model transferability. The results indicate that Desert Peak and Coso geothermal sites are cross-compatible due to their similar geothermal characteristics, allowing the AI model to be transferable between these sites. However, Brady is found to be incompatible with both Desert Peak and Coso. The geothermal AI model developed in this study demonstrates the potential for transferability and applicability to other geothermal sites with similar characteristics, enhancing the efficiency and effectiveness of geothermal resource exploration. This advancement in geothermal AI modeling can significantly contribute to the global expansion of geothermal energy, supporting sustainable energy goals.

Energy & Fuels↗

Long-Range Allosteric Communication Modulated by Active Site Mn(II) Coordination Drives Catalysis in Xanthobacter autotrophicus Acetone Carboxylase

Acetone carboxylase (AC) from Xanthobacter autotrophicus is a 360 KDa α2β2γ2 heterohexamer that catalyzes the ATP-dependent formation of phosphorylated acetone and bicarbonate intermediates that react at Mn(II) metal active sites to form acetoacetate. Structural models of X. autotrophicus AC (XaAC) with and without nucleotides reveal that the binding and phosphorylation of the two substrates occurs ~40 Å from the Mn(II) active sites where acetoacetate is formed. Based on the crystal structures, a significant conformational change was proposed to open and close a tunnel that facilitates the passage of reaction intermediates between the sites for nucleotide binding and phosphorylation of substrates and Mn(II) sites of acetoacetate formation. We have employed electron paramagnetic resonance (EPR), kinetic assays, and hydrogen/deuterium exchange mass spectrometry (HDX-MS) of poised ligand-bound states and site-specific amino acid variants to complete an in-depth analysis of Mn(II) coordination and allosteric communication throughout the catalytic cycle. In contrast with the established paradigms for carboxylation, our analyses of XaAC suggested a carboxylate shift that couples both local and long-range structural transitions. Shifts in the coordination mode of a single carboxylic acid residue (αE89) mediate both catalysis proximal to a Mn(II) center and communication with an ATP active site in a separate subunit of a 180 kDa α2β2γ2 complex at a distance of 40 Å. This work demonstrates the power of combining structural models from X-ray crystallography with solution-phase spectroscopy and biophysical techniques to elucidate functional aspects of a multi-subunit enzyme.

Biochemistry & Molecular Biology↗

WRF Hindcasts of Cold Front Passages over the ARM Eastern North Atlantic Site: A Sensitivity Study

The present study explores the ability of the Weather Research and Forecasting (WRF) Model to accurately reproduce the passage of extratropical cold fronts at the DOE-ARM Eastern North Atlantic (ENA) observation site on the Azores Islands. An analysis of three case studies is performed in which the impact of the WRF domain size, position of the model boundary relative to the ENA site, grid spacing, and spectral nudging conditions are explored. The results from these case studies indicate that model biases in the timing and duration of cold front passages change with the distance between the model domain boundary and the ENA site. For these three cases, if the western model boundary is further than 1500 km from the site, the front becomes too meridional and fails to reach the site, making 1000 km or 1500 km the optimal distances. In contrast, integrations with small distances (e.g., 500 km) between the site and domain boundaries have inadequate spatial spin-up, i.e. the domain is too small for the model to properly stabilize. For all 3 cases, regardless of domain size, the model has biases in its upper-level circulation that impact the position and timing of the front. However, this issue is most serious for 4000 km2 domains and larger. For these domains, prolonged spectral nudging can correct cold front biases. As such, this analysis provides a framework to optimize the WRF model configuration necessary for a realistic hindcast of a cold front passage at a fixed location centered in a domain as large as computationally possible.

Faycal Lamraoui↗

Search for the Viking 2 landing site

The search for the landing site of Viking 2 is reviewed, emphasizing the characteristics of the various candidate sites and reasons for rejecting unsuitable sites. It is shown that the B3 site in Utopia Planitia was selected because the B latitude band (40 to 50 deg N) was of the highest scientific interest, the site appeared to be smoothed by uniform mantling, and the additional data analysis and acquisition required to land at any other site could have resulted in a landing delay and significant additional operational complexity. It is tentatively concluded that the Viking 2 lander rests in a deflation hollow.

Masursky, H.↗

Siting Issues for Solar Thermal Power Plants with Small Community Applications

Technologies for solar thermal plants are being developed to provide energy alternatives for the future. Implementation of these plants requires consideration of siting issues as well as power system technology. While many conventional siting considerations are applicable, there is also a set of unique siting issues for solar thermal plants. Early experimental plants will have special siting considerations. The siting issues associated with small, dispersed solar thermal power plants in the 1 to 10 MWe power range for utility/small community applications are considered. Some specific requirements refer to the first 1 MWe engineering experiment for the Small Power Systems Applications (SPSA) Project. The siting issues themselves are discussed in three categories: (1) system resource requirements, (2) environmental effects on the system, and (3) potential impact of the plant on the environment. Within these categories, specific issues are discussed in a qualitative manner. Examples of limiting factors for some issues are taken from studies of other solar systems.

Holbeck, J. J.↗

Assessing the representativeness of wind data for wind turbine site evaluation

Once potential wind turbine sites (either for single installations or clusters) are identified through siting procedures, actual evaluation of the sites must commence. This evaluation is needed to obtain estimates of wind turbine performance and to identify hazards to the machine from the turbulence component of the atmosphere. These estimates allow for more detailed project planning and for preliminary financing arrangements to be secured. The site evaluation process can occur in two stages: (1) utilizing existing nearby data, and (2) establishing and monitoring an onsite measurement program. Since step (2) requires a period of at least 1 yr or more from the time a potential site has been identified, step (1) is often an essential stage in the preliminary evaluation process. Both the methods that have been developed and the unknowns that still exist in assessing the representativeness of available data to a nearby wind turbine site are discussed. How the assessment of the representativeness of available data can be used to develop a more effective onsite meteorological measurement program is also discussed.

Renne, D. S.↗

Two Mars years of surface changes seen at the Viking Landing sites

An analysis of the spectrophotometric properties of the new dust deposited at the Viking Lander 1 site indicates that the new deposits are the same as the bright red material that only partially covered the site at the beginning of the mission. Certain areas of the Viking 1 site also showed an increase in contrast during the second year. The contrast increase is thought to be due to the partial removal of the recently deposited dust cover by high-velocity winds. What is more, a small soil slump occurred near the base of a boulder lying about 25 m from the lander. It is noted that whereas no obvious erosion has been detected at the Viking 2 site, periodic removal of the dust cover at this site is implied by the abundance of rocks at the site.

Guinness, E. A.↗

Geology of the Apollo 17 site

The Apollo 17 landing site was unique in several aspects: (1) it was the only site that was not selected from telescopic-based geologic interpretation--interest in the site was generated by the visual observations of Al Worden, Apollo 15 Command Module pilot, who interpreted dark-haloed craters as possible cinder cones; (2) instead of 20-m-resolution photographs, as was the norm for all earlier missions, this site had Apollo 15 panoramic camera photography coverage that had 2-m resolution; and (3) it had a geologist-astronaut aboard who was intimately involved in all stages of planning and mission operation, and was also instrumental in the design of a long-handled sample bag holder that eliminated the need for crew to dismount before collecting a sample, which then permitted sampling between major stations. Details of site geology, sample description, and geologic synthesis of the site as viewed from studies through 1976 are summarized.

Muehlberger, W. R.↗

Testing the Li-Strahler four-component canopy reflectance model in the HAPEX-Sahel shrub savanna sites using ground reflectance data

The rate at which a light field decays in water is characterized by the diffuse attenuation coefficient k. The Li-Strahler discrete-object canopy reflectance model was tested in two sites, a shrub grass savanna and a degraded shrub savanna on bare soil, in the proposed HAPEX (Hydrologic Atmospheric Pilot Experiment) II/Sahel study area in Niger, West Africa. Average site reflectance was predicted for each site from the reflectances and cover proportions of four components: shrub canopy, background (soil or grass and soil), shaded canopy, and shaded background. Component reflectances were sampled in the SPOT wavebands using a hand-held radiometer. Predicted reflectance was compared to average site reflectance measured using the same radiometer mounted on a backpack with measurements recorded every 5 m along two 1-km transects, also in the SPOT (Systeme Probatoire d'Observation de la Terre) bands. Measurements and predictions were made for each of the three days during the summer growing season, approximately two weeks apart. Red, near infrared reflectance, and the NDVI (normalized difference vegetation index) were all predicted with a high degree of accuracy for the shrub/grass site and with reasonable accuracy for the degraded shrub site.

Franklin, J.↗

Spectral bidirectional and hemispherical reflectance characteristics of selected sites in the Streletskaya steppe

Measurements of plant canopy bidirectional reflectance made by the PARABOLA (portable apparatus for rapid acquisition of bidirectional observations of the land and atmosphere) instrument in three spectral bands are analyzed for steppe grassland sites of differing productivity levels. The variation of spectral reflectance and the normalized difference vegetation index in the solar principal plane is presented. Comparisons are made with PARABOLA measurements from selected first ISLSCP field experiment (FIFE) grassland sites in the Konza prairie, Kansas. The Streletskaya steppe sites showed no strong hot spot reflectance, while this effect was present in some FIFE sites but absent in others. The hot spot effect seems to be dependent on canopy geometry and background reflectance characteristics of these sites. Spectral hemispherical reflectance was computed from the angular integration of the bidirectional measurements for the steppe sites. Total shortwave albedo was estimated from these hemispherical reflectance measurements and compared to albedo measured by pyranometers. The albedo estimates from PARABOLA were found to be approximately 12-17 percent higher than the pyranometer measurements.

Eck, Thomas F.↗

Site diversity for satellite earth terminals and measurements at 28 GHz

This paper reviews site diversity concepts and models and presents the results of a site diversity experiment, in which radiometers were used to measure attenuation on earth-space paths, performed at Columbus, Ohio, for a period of one year. Attenuation statistics are presented first in the form of the joint probability density function of attenuation at the two sites. From these are derived the cumulative two-dimensional distribution of attenuation at both sites, the cumulative distribution of attenuation at each site, the effective cumulative distribution of attenuation for a diversity system that always switches to the better of two signals, and the effective cumulative distribution of attenuation for a system with maximal-ratio signal combining. The switched-system diversity gain is compared with Hodge's predictive model, and the diversity improvement is compared with Boithias' model. Fade-duration and interfade-interval statistics are also presented for each site and for systems that employ switching and maximal-ratio combining. Rain-rate and interrainfall interval statistics are also included.

Lin, Kuan-Ting↗

GIS modeling of archaeological site locations: A low-tech approach

A Geographic Information System (GIS)-type analysis of archaeological site locations using a dBase III plus program and a desk top computer is presented. A previously developed model of site locations in the Sequatchie Valley of northeastern Alabama is tested against known site locations in another large survey area there. The model fails to account for site locations in the test area. A model is developed for the test area and indicates the site locations are indeed different. Whether this is due to differences in site locations on a sub-regional level, or to sample error in the original model is unknown.

Futato, Eugene M.↗

Highland crust at the Apollo 14 site: A review

Recent petrologic studies of pristine nonmare samples from the Apollo 14 site have demonstrated the unique character of the western highlands crust. Many of the lithologies which occur here are not found at other highland sites or represent unique variations of more common lithologies. Rare highland samples found at the Apollo 12 site have petrologic and geochemical affinities with the Apollo 14 highland suite and the two sites taken together constitute what can be called the Western Highland Province. Rocks of the Western Highland Province are geochemically distinct from similar lithologies found at eastern highland sites (Apollo 15, Apollo 16, Apollo 17, and the Luna sites) -- a fact which adds further complications to current petrogenetic models for the lunar crust. Nonetheless, an understanding of how the Western Highlands Province formed and why it differs from highland crust in the east is crucial to our overall understanding of primordial lunar differentiation and petrogenesis.

Shervais, John W.↗

The western highland province at the Apollo 14 site

Recent petrologic studies of pristine nonmare samples from the Apollo 14 site have demonstrated the unique character of the western highlands crust. Many of the lithologies which occur here are not found at other highland sites or represent unique variations of more common lithologies. Rare highland samples found at the Apollo 12 site have petrologic and geochemical affinities with the Apollo 14 highland suite, and the two sites taken together constitute what can be called the Western Highland Province. Rocks of the Western Highland Province are geochemically distinct from similar lithologies found at eastern highland sites (Apollo 15, Apollo 16, Apollo 17, and the Luna sites)--a fact which adds further complications to current petrogenetic models for the lunar crust. Nonetheless, and understanding of how the Western Highlands Province formed and why it differs from highland crust in the east is crucial to our overall understanding of primordial lunar differentiation and petrogenesis.

Shervais, John W.↗

Temporal Evolution of SL-9 Impact Sites on Jupiter and Global Maps of Jupiter from Multi-Observatory Visible and Infrared Images

The objective of this research was to investigate the temporal behavior of the impact features on Jupiter created by the fragments of the Shoemaker Levy-9 comet that collided with the planet in July 1994. The primary observations used in the study were ground based images of Jupiter acquired from the Swedish Solar Vacuum Tube on the island of La Palma in the Canary Islands. The measurement of position of the impact features in images acquired immediately after the impact over a period of a few days revealed that the apparent drift rates were too high and that a repetitive pattern could be seen in the longitude position on successive rotations. This could be explained only by the fact that the measured longitudes of the impact sites were being affected by parallax due to a significant elevation of the impact debris above the nominal cloud top altitude value used for image navigation. Once the apparent positions are analyzed as a function of the meridian angle, the parallax equation can be used to infer the height of the impact features above the cloud deck, once the true impact position (longitude) for the feature is known. Due to their inherent high spatial resolution, the HST measurements of the impact site locations have been accepted widely. However, these suffer from the parallax themselves since few of them were obtained at central meridian. Ground based imaging have the potential to improve this knowledge as they do observe most of the impact sites on either side of the central meridian, except for the degraded resolution. Measurements over a large number of images enables us to minimize the position error through regression and thus estimate both the actual impact site location devoid of parallax bias, and also of the altitude level of the impact debris above the cloud deck. With rapid imaging there is the potential to examine the time evolution of the altitude level. Several hundred ground based images were processed, navigated and subjected to the impact site location measurements. HST images were also acquired and used to calibrate the results and to improve the sample. The resources available enabled an in-depth study only of impact site A, however, many more images have since become available through the global network observations through Lowell Observatory.

Limaye, Sanjay S.↗