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At least 253 records · Page 14

Characterization of 244 Cm Neutron Sources

There is a need to find a replacement for the 252 Cf sources currently used in Standards-based performance testing of neutron instrumentation. This is a result of its relatively short half-life, concerns about future availability and recent increases in cost. A potential replacement source, 244 Cm is evaluated in this study where two commercially available sources have been acquired and their neutron emission spectra measured using a pair of spectrometers. Both instruments showed the 244 Cm spontaneous neutron spectrum to be fully consistent with a MCNP6®-calculated spectrum using published Watt fission parameters for 244 Cm. In addition, the emission rate of the weaker 244 Cm source was established through a direct count rate comparison against a calibrated and similarly encapsulated 252 Cf source. The 244 Cm source emission rate was found to be in excellent agreement with value stated on the manufacturer's source certificate. It is concluded that 244 Cm would be an ideal replacement for 252 Cf based on its longer half-life (18.1 y) and its essentially identical neutron emission spectrum. In addition, 244 Cm sources are commercially available at reasonable cost.

244Cm↗

Microwave-driven synthesis and modification of nanocarbons and hybrids in liquid and solid phases

Over the past 20 years, nanocarbons have become more significant as nanostructured fillers in composites and, more recently, as functional elements in a brand-new class of hybrid materials. Microwave-assisted synthesis and processing is a burgeoning subject matter in materials research with significant strides in the realm of nanocarbon during the last decade. Here, the review examines recent approaches to producing various nanocarbons using microwaves as energy sources, the characterization of such materials for various applications, and their results. The underlying factors supporting the increased performance of such materials or their composites are analyzed and reaction mechanisms are presented wherever necessary. In particular, the recently developed and verified approaches to produce porous carbon materials, CNTs and fibers, carbon nanospheres, carbon dots, CQDs, reduced graphene oxide, nanocarbon hybrid materials, and the purification and modification of CNTs are discussed. The reduction of graphene oxide and the preparation of graphene derivative hybrids using solid-state and liquid-state routes such as polyopl, mixed solvents, ionic liquids, and microwave-assisted hydrothermal/solvothermal methods are analyzed in detail. In addition, the principles of microwave heating in liquid and solid states, the use of metals particles as arcing agents or catalysts, and carbonaceous materials as internal or external susceptors during synthesis and modifications are presented in detail.

25 ENERGY STORAGE↗

Enriching OpenStreetMap network data for transportation applications: Insights into the impact of urban congestion on accessibility

OpenStreetMap (OSM) data is a valuable open-source resource for various transportation, traffic, and planning applications. However, OSM network data lack operating traffic speed information, which is critical for transport planning and operations. Addressing this shortcoming, this study leverages commercial vendor data (to serve as ground truth) with exogenous, open-source variables characterizing local transport infrastructure, land use, and demographic information to predict average congested traffic speeds on OSM networks. Three machine-learning models were tested and estimated for OSM links with and without speed limit information in the Denver metropolitan region. Among these, XGBoost performed best, with mean absolute errors of 3.27 and 3.62 mph for links with and without speed limits, respectively. The developed models accurately predicted traffic speeds for different hours and days of the week compared to ground truth data. Using these predicted speeds, drive accessibility scores were computed for the Denver region for different time periods using the Mobility Energy Productivity (MEP) metric to understand the impact of congestion on energy-efficient accessibility. Results show that congestion-adjusted drive accessibility can be significantly lower compared to accessibility calculated using free flow speeds. Specifically, weekday evening hours saw a 42 % drop in accessibility due to reduced speeds, particularly around downtown Denver. Across the Denver metro region, approximately half as many opportunities and jobs are accessible in under 20 min by car during the evening peak period relative to free flow conditions. These findings underscore the importance of using congestion-adjusted operating speeds rather than speed limits in accessibility calculations, as reliance on speed limits can substantially overestimate energy-efficient drive accessibility in large, car-centric cities susceptible to significant congestion. In conclusion, the methodology presented here could further enrich OSM network data, making them useful for an even broader range of transportation applications.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Experimental demonstration and modeling of a robotic neutron detector with spectral and directional sensitivity for treaty verification

International safeguards and arms control agreements often require labor-intensive, intrusive onsite inspections to perform verification tasks. The ability to localize a neutron source and/or characterize a neutron field may be imperative for identifying anomalies. We are interested in the role of autonomous mobile robots, which, if designed properly, may be more effective and efficient and less intrusive than their human counterparts. Toward developing such a capability, we, for this study, have constructed the N-SpecDir Bot, comprised of three boron-coated straw detectors azimuthally-distributed within a cylinder of high-density polyethylene, which is mounted on an omni-directional robotic platform. Our N-SpecDir Bot is specifically designed to provide spectral and directional sensitivity, in addition to gross counts, by utilizing the signals from the three detectors. The detection system has been extensively characterized by MCNP modeling, which has been benchmarked to experiments conducted at the Princeton Plasma Physics Laboratory. We demonstrate the spectral and directional sensitivity experimentally and in simulation, and provide a simple yet robust method for directional measurements.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Quaternary tephra from the Valles caldera in the volcanic field of the Jemez Mountains of New Mexico identified in western Canada

A fine-grained, up to 3-m-thick tephra bed in southwestern Saskatchewan, herein named Duncairn tephra (Dt), is derived from an early Pleistocene eruption in the Jemez Mountains volcanic field of New Mexico, requiring a trajectory of northward tephra dispersal of ~1500 km. An unusually low CaO content in its glass shards denies a source in the closer Yellowstone and Heise volcanic fields, whereas a Pleistocene tephra bed (LSMt) in the La Sal Mountains of Utah has a very similar glass chemistry to that of the Dt, supporting a more southerly source. Comprehensive characterization of these two distal tephra beds along with samples collected near the Valles caldera in New Mexico, including grain size, mineral assemblage, major- and trace-element composition of glass and minerals, paleomagnetism, and fission-track dating, justify this correlation. Two glass populations each exist in the Dt and LSMt. The proximal correlative of Dt1 is the plinian Tsankawi Pumice and co-ignimbritic ash of the first ignimbrite (Qbt1g) of the 1.24 Ma Tshirege Member of the Bandelier Tuff. Finally, the correlative of Dt2 and LSMt is the co-ignimbritic ash of Qbt2. Mixing of Dt1 and Dt2 probably occurred during northward transport in a jet stream.

58 GEOSCIENCES↗

Rapid biodegradation of microplastics generated from bio-based thermoplastic polyurethane

The accumulation of microplastics in various ecosystems has now been well documented and recent evidence suggests detrimental effects on various biological processes due to this pollution. Accumulation of microplastics in the natural environment is ultimately due to the chemical nature of widely used petroleum-based plastic polymers, which typically are inaccessible to biological processing. One way to mitigate this crisis is adoption of plastics that biodegrade if released into natural environments. In this work, we generated microplastic particles from a bio-based, biodegradable thermoplastic polyurethane (TPU-FC1) and demonstrated their rapid biodegradation via direct visualization and respirometry. Furthermore, we isolated multiple bacterial strains capable of using TPU-FC1 as a sole carbon source and characterized their depolymerization products. Finally, to visualize biodegradation of TPU materials as real-world products, we generated TPU-coated cotton fabric and an injection molded phone case and documented biodegradation by direct visualization and scanning electron microscopy (SEM), both of which indicated clear structural degradation of these materials and significant biofilm formation.

09 BIOMASS FUELS↗

No correlation of the Lyman continuum escape fraction with spectral hardness

The properties that govern the production and escape of hydrogen-ionizing photons (Lyman continuum, LyC; with energies > 13.6 eV) in star-forming galaxies are still poorly understood, but they are key to identifying and characterizing the sources that reionized the Universe. Here we empirically explore the relation between the hardness of ionizing radiation and the LyC leakage in a large sample of low- z star-forming galaxies from the recent Hubble Space Telescope Low- z Lyman Continuum Survey. Using Sloan Digital Sky Survey stacks and deep X-shooter observations, we investigate the hardness of the ionizing spectra ( Q He + / Q H ) between 54.4 eV (He + ) and 13.6 eV (H) from the optical recombination lines He II 4686 Å and Hβ 4861 Å for galaxies with LyC escape fractions spanning a wide range, f esc (LyC) ≃ 0–90%. We find that the observed intensity of He II/Hβ is primarily driven by variations in the metallicity, but is not correlated with LyC leakage. Both very strong (< f esc (LyC)> ≃ 0.5) and nonleakers (< f esc (LyC)> ≃ 0) present similar observed intensities of He II and Hβ at comparable metallicity, between ≃0.01 and ≃0.02 for 12 + log(O/H)> 8.0 and < 8.0, respectively. Our results demonstrate that Q He + / Q H does not correlate with f esc (LyC), which implies that strong LyC emitters do not show harder ionizing spectra than nonleakers at similar metallicity.

79 ASTRONOMY AND ASTROPHYSICS↗

Hydrodynamic conditions in laser irradiated buried layer experiments

The calculation of open shell ionization level and radiative properties of materials in Non-Local Thermal Equilibrium (NLTE) is currently still a major challenge for any atomic model. The predictions of various NLTE atomic codes at these conditions still differ significantly. In recent years, a new buried layer platform was developed at the Lawrence Livermore National Laboratory and the Laboratory for Laser Energetics. This platform is used to measure ionization distribution and emission of open L-shell, mid-Z ions and open M-shell, high-Z ions at NLTE conditions that are relevant in many laser plasma applications. These experiments offer a unique chance for benchmarking the atomic models. In order to perform these experiments, a uniform well characterized plasma source is required. In this work, we present one-dimensional (1D) and two-dimensional simulations of the experimental platform. These simulations were used for both the design and the analysis of the experiments. The simulations demonstrate the different phases of hydrodynamic evolution of the target and identify the time windows in which uniform conditions can be achieved. A 1D expansion of the target was found to be adequate to describe the target's evolution for most of the experiment duration. The fast 1D simulations were compared with recent experimental results from the Omega laser facility. The sensitivity of the results to several modeling parameters such as the electron flux limiter and laser resonant absorption is reported.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Development of planar P-type point contact germanium detectors for low-mass dark matter searches

The detection of low-energy deposition in the range of sub-eV through ionization using germanium (Ge) with a bandgap of ~ 0.7 eV requires internal amplification of the charge signal. This can be achieved through high electric field that accelerates charge carriers, which can then generate more charge carriers. The minimum electric field required to generate internal charge amplification is derived for different temperatures. We report the development of a planar point contact Ge detector in terms of its fabrication and the measurements of its leakage current and capacitance as a function of applied bias voltage. With the determination of the measured depletion voltage, the field distribution is calculated using GeFiCa, which predicts that the required electric field for internal charge amplification can be achieved in proximity to the point contact. The energy response to an Am-241 source is characterized and discussed. We conclude that such a detector with internal charge amplification can be used to search for low-mass dark matter.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Two-particle Bose–Einstein correlations in ${ pp }$ collisions at $\mathbf {\sqrt{s} = 13}$ TeV measured with the ATLAS detector at the LHC

This paper presents studies of Bose–Einstein correlations (BEC) in proton–proton collisions at a centre-of-mass energy of 13 TeV, using data from the ATLAS detector at the CERN Large Hadron Collider. Data were collected in a special low-luminosity configuration with a minimum-bias trigger and a high-multiplicity track trigger, accumulating integrated luminosities of 151 μb -1 and 8.4 nb -1 , respectively. The BEC are measured for pairs of like-sign charged particles, each with |η|<2.5, for two kinematic ranges: the first with particle p T >100 MeV and the second with particle p T >500 MeV. The BEC parameters, characterizing the source radius and particle correlation strength, are investigated as functions of charged-particle multiplicity (up to 300) and average transverse momentum of the pair (up to 1.5 GeV). The double-differential dependence on charged-particle multiplicity and average transverse momentum of the pair is also studied. The BEC radius is found to be independent of the charged-particle multiplicity for high charged-particle multiplicity (above 100), confirming a previous observation at lower energy. This saturation occurs independent of the transverse momentum of the pair.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Characterizing non-polarization-maintaining highly nonlinear fiber toward squeezed-light generation

Squeezed light, which is easily degraded by loss, could benefit from generation directly in optical fiber. Furthermore, highly nonlinear fiber could offer more efficient generation with lower pump power and shorter fiber lengths than standard single-mode fiber. We investigate non-polarization-maintaining highly nonlinear fiber (HNLF) for squeezed-light generation by characterizing possible sources of excess noise, including its zero-dispersion wavelength (ZDW) variation and polarization noise. We find significant ZDW variation and excess polarization noise. We believe the polarization noise is from non-linear polarization-mode dispersion. We model this polarization noise and find that it is likely to degrade Kerr squeezing but not squeezing from four-wave mixing.

47 OTHER INSTRUMENTATION↗

Insights into Slip-Rate Time Functions, Rupture Parameter Correlations, and Ground Motions from Validated Multicycle Earthquake Ruptures

Earthquake strong-motion predictions using kinematic source modeling require knowledge of the slip-rate functions (SRFs) along the rupture and their distinct characteristics in asperities, background (off-asperity) areas and near the surface. Here, in this study we analyzed SRFs from well-validated, self-consistent, and fully dynamic rupture models from earthquake cycles obeying a rate-and-state friction law, from our companion study (Galvez et al., 2021). The shapes of SRFs in asperities are well described by the regularized Yoffe function (RYF), which has only two parameters: rise time T r and smoothing time T s , which control the generation of long- and short-period ground motions, respectively. In background areas, we demonstrate that, in addition to the primary rupture, multiple secondary ruptures may also nucleate from rupture heterogeneities related to asperities, resulting in SRFs with multiple peaks. Because it is impossible to fit a multiple-peak SRF by the single-peak RYF, we describe SRFs in background areas in an effective way by fitting their amplitude spectra with the RYF spectra. Such spectrally effective RYFs capture salient aspects of seismic-wave generation and can be used in rupture generators for strong motion prediction. We found that small T s values correlate with small characteristic weakening distances, large peak slip rates (PSRs), and large rupture velocities. T r values are larger in background areas and smaller in asperities. Within the shallow aseismic zone, T s values approximately quadruple whereas T r values approximately double. Because of this dominant T s increase, PSR values decrease in the near-surface zone. These features indicate that the generation of strong motions by the near-surface portions of the rupture is negligible in the studied scenarios.

Geosciences↗

gamut: A Geospatial R Package to Analyze Multisectoral Urban Teleconnections

Most cities in the United States withdraw surface water to meet public water supply needs. The lands on which this water is generated are often developed for human activities -- such as agriculture, mining, and industry -- that may compete for water resources or contaminate water supplies. Cities are thereby connected to other sectors through their water supply catchments. This connection is an example of an multisectoral urban teleconnection. The Geospatial Analytics for Multisectoral Urban Teleconnections (``gamut``) package provides national-scale information on these teleconnections by combining land use data with hydrological analysis to characterize urban source watershed human interactions across the conterminous United States.

97 MATHEMATICS AND COMPUTING↗

Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) Science Implementation Plan

Boreal regions have experienced warming faster than the rest of the Earth, and the arctic ice cover has declined at a rate faster than predicted by most climate models. Uncertainties in climate projections for this region are large, in part due to the lack of observational guidance to constrain the treatment of aerosol-cloud-precipitation linkages in climate models. To remedy this shortfall, field campaigns have been conducted to collect integrated, comprehensive measurements under specific atmospheric regimes. While considerable efforts have been devoted to subtropical marine boundary-layer clouds, as well as to clouds in the stable arctic environment, very few targeted observations exist of convective boundary-layer clouds that form over open water when cold airmasses are advected off ice-covered regions or boreal continents. There is an urgent need to shed light on the dynamics and microphysical properties of clouds and precipitation in the high-latitude marine boundary layer during cold-air outbreaks. Despite the common occurrence of linear and cellular cloud patterns that typify cold-air outbreaks, little is known about the properties of these clouds; how they vary with surface, environmental, and aerosol conditions; the role of cold-air outbreaks in the global atmospheric and ocean circulation; and the accuracy of the treatment of this atmospheric regime in climate models. Thus, we proposed to conduct the Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE), to focus on marine boundary-layer clouds during cold-air outbreaks. COMBLE will deploy the first ARM Mobile Facility (AMF1) and an AMF “satellite” station in the far North Atlantic in January–May 2020. COMBLE will take advantage of the synergy with several coincident campaigns, notably MOSAIC, which will characterize the source airmasses of cold-air outbreaks over the arctic ice, and (AC) 3 , which will operate several aircraft between northern Scandinavia and the MOSAIC deployment to document evolution of these airmasses. COMBLE and its sister campaigns will compose a four-member array of supersites between northern Scandinavia and the Arctic, each with profiling and in situ cloud, precipitation, radiation, and aerosol measurements. COMBLE will be guided by six science themes. The first five deal with boundary-layer convection in cold-air outbreaks: (1) the fetch-dependent mesoscale organization of clouds and precipitation, including linear and cellular convection; (2) surface heat and momentum fluxes and vertical profiles of temperature, humidity, wind, and turbulence; (3) vertical structure of clouds and precipitation; (4) the sources and sinks of aerosol, including ice-nucleating particles, and the role of cloud-active aerosol on cloud processes and radiative fluxes; and (5) the influence of these four themes on polar cyclogenesis and polar low vertical structure. The overarching sixth theme is that COMBLE will provide integrated data sets of dynamical, thermodynamic, and cloud microphysical characteristics of marine boundary-layer convection in cold-air outbreaks, including cloud and aerosol properties, that will enable constraining high-resolution numerical simulations, developing process-level understanding, and, subsequently, evaluating and improving representations of shallow convection in weather and climate models.

54 ENVIRONMENTAL SCIENCES↗

SCALE Code System

The SCALE Code System is a widely used modeling and simulation suite for nuclear safety analysis and design that is developed, maintained, tested, and managed by the Reactor and Nuclear Systems Division (RNSD) of Oak Ridge National Laboratory (ORNL). SCALE provides a comprehensive, verified and validated, user-friendly tool set for criticality safety, reactor and lattice physics, radiation shielding, spent fuel and radioactive source term characterization, and sensitivity and uncertainty analysis. Since 1980, regulators, licensees, and research institutions around the world have used SCALE for safety analysis and design. SCALE provides an integrated framework with dozens of computational modules, including three deterministic and three Monte Carlo radiation transport solvers that are selected based on the desired solution strategy. SCALE includes current nuclear data libraries and problem-dependent processing tools for continuous-energy (CE) and multigroup (MG) neutronics and coupled neutron-gamma calculations, as well as activation, depletion, and decay calculations. SCALE includes unique capabilities for automated variance reduction for shielding calculations, as well as sensitivity and uncertainty analysis. SCALE’s graphical user interfaces assist with accurate system modeling, visualization of nuclear data, and convenient access to desired results.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Mixed Material Scintillator Systems Particle ID Modelling Report

AMixed-Material Scintillator System (MMSS) is a radiation detector using a scintillator made of a heterogeneous, structured mixture of two or more materials. MMSSs are designed so that the structured mixing of materials encodes properties of the radiation detected in the scintillator. This allows for new radiation detectors with advantages over detectors using traditional homogeneous scintillators. This report contains results from this project’s second task, to model and quantify the promise of the MMSSs invented earlier in the project. Those inventions have been divided into two categories, and this report focuses on the first category: MMSS inventions the use zones of differently-colored scintillators to detect and characterize neutron sources. We call this category particle-ID, or PID, detectors. Inventions using gradients designed to encode the position of radiation interactions using gradients will be discussed in a future report.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Report on the recovery of legacy 1997-1998 Depth-of-Burial / Tunnel-and-Hole-Closure explosion data from the Kazakhstan former Soviet nuclear test site, Semipalatinsk.

In 1996, negotiations between the National Nuclear Center of the Republic of Kazakhstan (NNC), the U.S. Defense Special Weapons Administration (DSWA) and the U.S. Department of Energy led to an agreement for a joint series of experiments at the former Soviet nuclear test site Semipalatinsk (STS). These experiments had a dual purpose: to close holes and tunnels originally created for the purpose of testing nuclear weapons, and to characterize explosive sources at a former nuclear test site. This report covers the recovery of legacy data from the experiments conduct in 1997 and 1998. Two teams collected data. Los Alamos National Laboratory (LANL), in collaboration with the NNC, collected the near-source (local) data out to approximately 20 km. Lamont-Doherty Earth Observatory (LDEO), with funding from Lawrence Livermore Laboratory (LLNL), also in collaboration with NNC, collected regional data, 200 – 1000 km distant, leveraging the KZ regional seismic network that LDEO had recently installed in collaboration with NNC. The two teams also worked together to some extent, regarding instrumentation and planning. This report primarily addresses the near-source data collected by the LANL/NNC team.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗