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At least 253 records · Page 14

Gaia and the colonization of Mars

The Gaia hypothesis states that the atmosphere, hydrosphere, surface sediments, and life on Earth behave dynamically as a single integrated physiological system. What has been traditionally viewed as the passive environment is a highly active, integral part of the gaian system. Aspects of the surface temperature and chemistry are regulated by the sum of life, the biota. Formulated first by James E. Lovelock, in the late 1960s, the Gaia hypothesis has been in the scientific literature for more than 25 years. Because of its properties of exponential growth and propagation, life is a powerful geologic force. A useful aspect of the Gaia idea is that it requires integration of scientific disciplines for the study of Earth. The recently touted Earth system science is broadly parallel with the gaian concept of the physiochemical regulation of Earth's surface. We discuss here, in a gaian context, the colonization of Mars by Earth organisms. Although colonizing Mars may be impossible, its accomplishment would be exactly equivalent to "the reproduction of Gaia by budding.".

NASA Discipline Exobiology↗

Dynamical and Chemical Behavior of the Lower Stratosphere and Interactions with the Troposphere

Equivalent-barotropic calculations, in tandem with Lagrangian analyses, reveal how changes of total ozone follow from vertical and horizontal transport by planetary waves. Those calculations also throw light on how diabatic motions comprising the Brewer-Dobson circulation develop from quasi-horizontal advection by planetary waves. Potential temperature along a material surface indicates organized subsidence inside the polar-night vortex, resembling tracer observations from UARS. Lagrangian histories illustrate that this sinking motion follows in large part from parcels being driven out of thermodynamic equilibrium by planetary waves, especially at high latitudes. Irreversible heat transfer then produces a net drift of air across isentropic surfaces as parcels orbit about the displaced vortex. By driving mean-meridional overturning in the stratosphere, this downward drift is ultimately responsible for transferring ozone from the tropics to the extratropical lower stratosphere. It also introduces horizontal structure into the distribution of total ozone, which surfaces clearly in ozone trends. High-resolution global cloud imagery constructed from 6 satellites simultaneously observing the Earth was used to investigate the spectrum of equatorial waves generated by tropical convection and propagating vertically into the stratosphere. The results indicate that temperature variability is dominated by planetary-scale equatorial waves like the Kelvin mode, which agrees with satellite observations of the tropical stratosphere. However, the Kelvin mode accounts for only about 30 - 50% of the eastward momentum flux radiating into the stratosphere, the remainder coming from gravity waves. An algorithm was developed to determine 3-dimensional atmospheric motion from satellite tracer measurements. Based on Lagrangian constraints, the algorithm circumvents limitations of the traditional scheme for inferring motion from temperature measurements and determines the circulation in the tropics as reliably as elsewhere. A study of deep convection revealed that the highest towers (those penetrating into stratospheric air and controlling tropopause height and composition through convective mixing) occur in close association with the diurnal cycle of convection. Clouds colder than 220 K develop almost entirely in association with the diurnal cycle of convection over tropical landmasses and substantially in association with it even over maritime regions.

Salby, Murry L.↗

Ignition of confined gaseous mixtures by hot surfaces and hot wires

Ignition times and spatial and temporal variations of temperature and concentration in gaseous mixtures confined between two infinite parallel walls or two infinite cylinders have been obtained by numerical integration of the appropriate conservation equations written in Lagrangian coordinates. Ignition times and ignition energies are presented for the case of an isothermal wall in terms of the initial mixture pressure and equivalence ratio for both one and two-step chemical reaction mechanisms. The numerical results indicate that there is a critical mixture pressure for which the ignition time is minimum. The values of this critical pressure are larger (smaller) than 1 atm for the one- (two-) step reaction mechanism. The critical pressure for the ignition time is not equal to the critical pressure for the ignition energy. The ignition time and energy decrease with the equivalence ratio within a certain range and then remain constant.

Ramos, J. I.↗

Utilization of surface cover composition to improve the microwave determination of snow water equivalent in a mountain basin

Satellite microwave data have been used to derive areal snow water equivalent in flat homogeneous areas. Over heterogeneous mountainous areas different algorithms are needed to retrieve the water equivalent of the snow cover. A mixed pixel model based on the percentage of vegetation cover within a pixel has been developed to simulate the microwave brightness temperatures for the Rio Grande basin in southwestern Colorado. A relationship between the difference in microwave-brightness temperature at two different frequencies (37- and 18-GHz horizontal polarization), and the basin-wide average snow water equivalent was obtained. The areal snow-water equivalent values derived from the model were consistent with values generated by a reliable snowmelt run-off model using snow-cover extent data.

Chang, A. T. C.↗

Performance of the Mechanically Pumped Fluid Loop Rover Heat Rejection System Used for Thermal Control of the Mars Science Laboratory Curiosity Rover on the Surface of Mars

The challenging range of landing sites for which the Mars Science Laboratory Rover was designed, required a rover thermal management system that is capable of keeping temperatures controlled across a wide variety of environmental conditions. On the Martian surface where temperatures can be as cold as -123 C and as warm as 38 C, the Rover relies upon a Mechanically Pumped Fluid Loop (MPFL) Rover Heat Rejection System (RHRS) and external radiators to maintain the temperature of sensitive electronics and science instruments within a -40 C to +50 C range. The RHRS harnesses some of the waste heat generated from the Rover power source, known as the Multi Mission Radioisotope Thermoelectric Generator (MMRTG), for use as survival heat for the rover during cold conditions. The MMRTG produces 110 Watts of electrical power while generating waste heat equivalent to approximately 2000 Watts. Heat exchanger plates (hot plates) positioned close to the MMRTG pick up this survival heat from it by radiative heat transfer and supply it to the rover. This design is the first instance of use of a RHRS for thermal control of a rover or lander on the surface of a planet. After an extremely successful landing on Mars (August 5), the rover and the RHRS have performed flawlessly for close to an earth year (half the nominal mission life). This paper will share the performance of the RHRS on the Martian surface as well as compare it to its predictions.

Mars↗

Experimental evaluation of catalytic combustion with heat removal at near stoichiometric conditions

Two concentric tube configurations were tested. Tests were conducted at an inlet pressure of 150,000 Pa, inlet fuel air mixture temperatures from 780 to 960 K, combustion air flow rates from 0.78 to 1.5 g/s, equivalence ratios up to 0.90, and a range of cooling air flow rates. Propane and propylene fuels were used. Both configurations used air flowing through the center tube for cooling and combustion in the annulus on the catalytic surface. One configuration had the catalyst applied to the outside surface of the inner tube. Conversion of the fuel was very low for this configuration. The other configuration had the catalyst applied to the inside surface of the outer tube. Conversion of the fuel was considerably better in this configuration.

Bulzan, D. L.↗

The influence of atmospheric stratification on scatterometer winds

Scatterometers measure surface roughness which is empirically related either to surface stress or to the equivalent neutral stability wind. The importance of atmospheric stability effects for the analysis of these data is studied. For low wind speeds and neutral to slightly stable conditions, neutral stability wind is quite sensitive to stability. A variational analysis procedure for the scatterometer data, which adjusts both the near-surface velocity and temperature, is developed. In simulation tests, temperature analysis increments are found to be small. Also, the differences in the wind analyses due to differences in the temperature background field are small. However, if stability effects are not accounted for, there will be small systematic errors in the wind analysis.

Hoffman, Ross N.↗

Influence of penetrating solar radiation on the heat budget of the equatorial Pacific Ocean

Recent satellite observations of ocean transparency, coupled with climatological surface heat fluxes and ocean density profiles, are used here to show that solar radiation in visible frequencies, usually assumed to be absorbed at the sea surface, in fact penetrates to a significant degree to below the upper mixed layer of the ocean which interacts actively with the atmosphere. The net effect is a reduction of the heat input into the upper layer; for a 20 m-thick mixed layer this is equivalent to an annual reduction in temperature of about 5-10 K. The results provide a natural explanation for the discrepancy between the SSTs predicted by models and those observed.

Lewis, Marlon R.↗

Techno-Economic Analysis of Green Hydrogen Energy Storage in a Cryogenic Flux Capacitor

Abstract The Cryogenic Flux Capacitor (CFC) is a cold, dense energy storage core that is being studied in the cryo-compressed, about 300 bar and 80K, region of gaseous hydrogen (GH2) storage and liquid hydrogen (LH2) region near the normal boiling point. Hydrogen storage is improved by physically bonding the molecules within the nanoscale pores of the aerogel composite blanket material. The process of bonding or debonding is governed by principles of physical adsorption (physisorption) and thermodynamics. The large surface area afforded by the nanoporous aerogel (∼1,000 m2/g) allows its storage performance to easily exceed capacities of high-pressure GH2 storage for an equivalent volume. With the integrated aerogel, subscale tests have shown that storage is increased by about 36% over a simple tank filled with GH2 at the same operating temperature and pressure. For LH2 conditions, the CFC is shown to operate at improved densities, but testing is ongoing. For the techno-economic analysis (TEA), the source of hydrogen is compared between onsite steam methane reforming (SMR) and onsite solar photovoltaic (PV) panels providing power to electrolyzers to produce green GH2. The TEA compares pure hydrogen produced at a small scale for a 25 MW power system and at a large scale in a 500 MW power system. The system allowed for hydrogen imports and exports at a set price with a tank sized for 10 hours of power production. The two power producing technologies are a combined cycle gas turbine (CCGT) and hydrogen fuel cells. The SMR system uses natural gas as an input and includes a carbon capture and storage (CCS) system. The levelized cost of electricity (LCOE), levelized cost of hydrogen (LCOH), and levelized cost of storage (LCOS) are developed based on the capital cost and operating cost of the systems. The results are shown for current costs using a 2021 benchmark and DOE projections for cost improvements by 2030. The TEA showed that onsite hydrogen generation from SMR has an LCOH of about 1.4 to 2 USD per kg over the life of the plant and the PV hydrogen production LCOH is about 5.2 to 5.5 USD per kg. The LCOS of conventional GH2 systems is estimated to be $210/MWh and cost of storage for LH2 systems is $205/MWh for fuel cell systems and $249/MWh for CCGT systems. CFC improved the LCOS of all these systems to $198/MWh, $191/MWh and $233/MWh respectively. The LCOE also improved with conventional systems between $171/MWh and $228/MWh improved by CFC to between $167/MWh and $212/MWh. Using projections for improvement in costs following DOE’s goals by 2030, green hydrogen improved to as low as $78/MWh LCOS and LCOE for conventional cases. CFC improved over conventional storage with the lowest LCOS being $62/MWh and the lowest LCOE being $73/MWh. These results correspond to an LCOH of $2/kg. Finally, the TEA shows how LCOE is improved for hydrogen conditioning and storage over conventional systems and caverns in the 10 to 50 hour range.

08 HYDROGEN↗

Summertime Post-Cold-Frontal Marine Stratocumulus Transition Processes over the Eastern North Atlantic

Abstract Marine boundary layer (MBL) cloud morphology associated with two summertime cold fronts over the eastern North Atlantic (ENA) is investigated using high-resolution simulations from the Weather Research and Forecasting (WRF) Model and observations from the Atmospheric Radiation Measurement (ARM) ENA Climate Research Facility. Lagrangian trajectories are used to study the evolution of post-cold-frontal MBL clouds from solid stratocumulus to broken cumulus. Clouds within specified domains in the vicinity of transitions are classified according to their degree of decoupling, and cloud-base and cloud-top breakup processes are evaluated. The Lagrangian derivative of the surface latent heat flux is found to be strongly correlated with that of the cloud fraction at cloud base in the simulations. Cloud-top entrainment instability (CTEI) is shown to operate only in the decoupled MBL. A new indicator of inversion strength at cloud top that employs the vertical gradients of equivalent potential temperature and saturation equivalent potential temperature, which can be computed directly from soundings, is proposed as an alternative to CTEI. Overall, results suggest that the deepening–warming hypothesis suggested by Bretherton and Wyant explains many of the characteristics of the summertime postfrontal MBL evolution of cloud structure over the ENA, thereby widening the phase space over which the hypothesis may be applied. A subset of the deepening–warming hypothesis involving warming initially dominating over moistening is proposed. It is postulated that changes in climate change–induced modifications in cold-frontal structure over the ENA may be accompanied by coincident changes in the location and timing of MBL cloud transitions in the post-cold-frontal environment.

54 ENVIRONMENTAL SCIENCES↗

Techno-economic Analysis of the Cryogenic Flux Capacitor Compared to Other forms of Hydrogen Production and Storage

The Cryogenic Flux Capacitor (CFC) is a cold, dense energy storage core that is being studied in the cryo-compressed, about 300 bar and 80K, region of gaseous hydrogen (GH2) storage and liquid hydrogen (LH2) region near the normal boiling point. The hydrogens storage is improved by physically bonding the molecules within the nanoscale pores of the aerogel composite blanket material. The process of bonding or debonding is governed by principles of physical adsorption (physisorption) and thermodynamics. The large surface area afforded by the nanoporous aerogel (~1,000 m2/g) allows its storage performance to easily exceed capacities of high-pressure GH2 storage for an equivalent volume. With the integrated aerogel, subscale tests have shown that storage is increased by about 49% over a simple tank filled with GH2 at the same operating temperature and pressure. For LH2 conditions, the CFC is shown to operate at equivalent densities. For the techno-economic analysis (TEA), the source of hydrogen is compared between onsite steam methane reforming (SMR) and onsite solar photovoltaic (PV) panels providing power to electrolyzers to produce GH2. The TEA compares pure hydrogen burning in a combined cycle gas turbine (CCGT) to hydrogen fuel cells with an overall net power output of 650 MW. The SMR system uses natural gas as an input and includes a carbon capture and storage (CCS) system. The levelized cost of electricity is developed based on the capital cost and operating cost of the systems. Sensitivities are discussed around the cost of natural gas, ranging from 1.93 USD per MMBTU to 6.75 USD per MMBTU, and carbon dioxide disposal, ranging from 7 USD per tonne to 10 USD per tonne. For comparison to the conventional CCGT baseline, a baseload scenario is adopted with 85% capacity factor. The results of the study show that onsite hydrogen generation from SMR is about 1 to 3 USD per kg over the life of the plant and the PV hydrogen production produces at 4 to 5 USD per kg. The cost of storage for CFC is compared to other systems, including high-pressure GH2 and atmospheric LH2. The system is shown to provide the lowest costs for all these options at the grid scale, due to its higher capacity than high-pressure GH2 and ability to operate at 80K, receiving refrigeration from liquid nitrogen systems reducing capital and operating costs when compared LH2 storage systems. SMR is competitive with CCGT at the gas prices, both of which have lower LCOE than the PV system. When accounting for variability in gas prices, the PV and electrolyzer system is less sensitive to these changes and provides the lowest LCOE across the whole range.

08 HYDROGEN↗

Magnetic fields and diffusion processes in peculiar A stars

The detailed effects of a magnetic field on the equilibrium surface abundances of Ap stars as well as on the diffusion velocity are considered. The equivalent widths of the magnetic null lines are shown to be functions of the magnetic field strength. Furthermore, null lines can be used to help distinguish between inhomogeneities in abundance and in magnetic field strength and to determine ionization temperatures. The results of the diffusion mechanism with magnetic fields are used to interpret the phenomenon of spectrum variability. A review of the observational aspects of null lines in the magnetic Ap stars is presented.

Shore, S. N.↗

Mechanism of lubrication by tricresylphosphate (TCP)

The coefficient of friction was measured as a function of temperature on a pin-on-disk tribometer. Pins and disks of 440C and 52100 steels were lubricated with tricresylphosphate (TCP), 3.45 percent TCP in squalene, and pure squalene. The M-50 pins and disks were lubricated with 3.45 percent TCP in squalene and pure squalene. Experiments were conducted under limited lubrication conditions in dry ( 100 ppm H2O) air and dry ( pp H2O) nitrogen at 50 rpm (equivalent to a sliding velocity of 13 cm sec) and a constant load of 9.8 N (1 kg). Characteristic temperatures T sub r were identified for TCP on 52100 steel and for squalene on M-50 and 52100 steels, where the friction decreased because of a chemical reaction between the lubricant and the metal surface. The behavior of squalene obscured the influence of 3.45 percent TCP solute on the friction of the system. Wear volume measurements demonstrated that wear was lowest at temperatures just above T sub r. Comparing the behavior of TCP on M-50, 440C, and 52100 steels revealed that the TCP either reacted to give T sub r behavior or produced initial failure in the temperature range 223 + or - 5 C.

Faut, O. D.↗

CFD Analysis for Assessing the Effect of Wind on the Thermal Control of the Mars Science Laboratory Curiosity Rover

The challenging range of landing sites for which the Mars Science Laboratory Rover was designed, requires a rover thermal management system that is capable of keeping temperatures controlled across a wide variety of environmental conditions. On the Martian surface where temperatures can be as cold as -123 C and as warm as 38 C, the rover relies upon a Mechanically Pumped Fluid Loop (MPFL) Rover Heat Rejection System (RHRS) and external radiators to maintain the temperature of sensitive electronics and science instruments within a -40 C to 50 C range. The RHRS harnesses some of the waste heat generated from the rover power source, known as the Multi Mission Radioisotope Thermoelectric Generator (MMRTG), for use as survival heat for the rover during cold conditions. The MMRTG produces 110 W of electrical power while generating waste heat equivalent to approximately 2000 W. Heat exchanger plates (hot plates) positioned close to the MMRTG pick up this survival heat from it by radiative heat transfer. Winds on Mars can be as fast as 15 m/s for extended periods. They can lead to significant heat loss from the MMRTG and the hot plates due to convective heat pick up from these surfaces. Estimation of this convective heat loss cannot be accurately and adequately achieved by simple textbook based calculations because of the very complicated flow fields around these surfaces, which are a function of wind direction and speed. Accurate calculations necessitated the employment of sophisticated Computational Fluid Dynamics (CFD) computer codes. This paper describes the methodology and results of these CFD calculations. Additionally, these results are compared to simple textbook based calculations that served as benchmarks and sanity checks for them. And finally, the overall RHRS system performance predictions will be shared to show how these results affected the overall rover thermal performance.

wind↗

Surface chemistry on a polarizable surface: Coupling of CO with KTaO 3 (001)

Polarizable materials attract attention in catalysis because they have a free parameter for tuning chemical reactivity. Their surfaces entangle the dielectric polarization with surface polarity, excess charge, and orbital hybridization. How this affects individual adsorbed molecules is shown for the incipient ferroelectric perovskite KTaO 3 . This intrinsically polar material cleaves along (001) into KO- and TaO 2 -terminated surface domains. At TaO 2 terraces, the polarity-compensating excess electrons form a two-dimensional electron gas and can also localize by coupling to ferroelectric distortions. TaO 2 terraces host two distinct types of CO molecules, adsorbed at equivalent lattice sites but charged differently as seen in atomic force microscopy/scanning tunneling microscopy. Temperature-programmed desorption shows substantially stronger binding of the charged CO; in density functional theory calculations, the excess charge favors a bipolaronic configuration coupled to the CO. These results pinpoint how adsorption states couple to ferroelectric polarization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High efficiency thermionic converter studies

The objective is to improve thermionic converter performance by means of reduced interelectrode losses, greater emitter capabilities, and lower collector work functions until the converter performance level is suitable for out-of-core space reactors and radioisotope generators. Electrode screening experiments have identified several promising collector materials. Back emission work function measurements of a ZnO collector in a thermionic diode have given values less than 1.3 eV. Diode tests were conducted over the range of temperatures of interest for space power applications. Enhanced mode converter experiments have included triodes operated in both the surface ionization and plasmatron modes. Pulsed triodes were studied as a function of pulse length, pulse potential, inert gas fill pressure, cesium pressure, spacing, emitter temperature and collector temperature. Current amplifications (i.e., mean output current/mean grid current) of several hundred were observed up to output current densities of one amp/sq cm. These data correspond to an equivalent arc drop less than 0.1 eV.

Huffman, F. N.↗

Cumulus convection as observed from an airborne infrared radiometer

The implementation of high resolution passive radiative remote sensing of the cloudiness volume in the atmospheric window between 10.5-12.5 microns is described. Airborne radiometers, the NASA/Cloud Top Scanner, were used to obtain radiances during several passages over two merging cumulus clouds, with the data being converted into equivalent blackbody temperatures. Data were also gathered in the 0.55-0.70 micron visible bands as part of the SESAME-79 experiment. The number of points observed in the IR channel were adjusted to account for the viewing angle and areal extents were calculated. A relationship was assumed to exist between the brightness temperatures of the cloud surface and the level of cloudiness at a given atmospheric altitude. Further measurements with lidar scans are indicated in order to reduce the error levels associated with the method.

Szejwach, G.↗

Reanalysis of X-ray emission from M87. 1: The single-phase medium

We reanalyze the density and temperature profiles of the X-ray-emitting gas around M87, assuming a spherically symmetric, single-phase model. For given assumed density and temperature profiles, we predict Einstein High Resolution Imager (HRI) and Imaging Proportional Counter (IPC) surface brightness distribution as well as Focal Point Crystal Spectrometer (FPCS) line fluxes, which we compare with the data. We find that a good fit to these data can be obtained and that, with a suitable adjustment of the abundances, the equivalent width of the iron complex at 7 keV as observed by wide-beam instruments can also be explained. In contrast to this, the Einstein Solid State Spectrometer (SSS) spectrum and optically determined mass profiles cannot be accounted for simultaneously with the previous X-ray data. We show that the disagreement of the Solid State Spectrometer with our models is due to an inconsistency of the Solid State Spectrometer data with that of the other X-ray instruments. Because of this, we find no evidence for the existence of absorption above the Galactic value, contrary to an earlier claim based on Solid State Spectrometer data. The disagreement of our models with optical mass data is due either to the assumption of a single-phase model, thus rendering the model unacceptable, or possibly to maximal systematic errors in the FPCS data. We also show that thermal conduction at the Spitzer rate is important in our models, although this conclusion is of limited importance in view of the poor fit of our models to the data.

Tsai, John C.↗