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At least 253 records · Page 14

Aubrite and Enstatite Chondrite Impact Melt Meteorites: Analogs to Mercury?

New data obtained during the MESSENGER mission has allowed us to better contrain the composition and mineralogy of the mercurian surface. One unique feature of Mercury is its extremely low oxygen fugacity (ƒO2) (Iron Wustite (IW) -7.3 to IW-2.6). At such extreme conditions, elements that exhibit lithophile behavior on Earth can exhibit chalcophile or siderophile behavior, leading to the formation of exotic sulfides and metals. As no samples have been returned from Mercury, it is critical to study meteorite analogs to better under-stand the formation conditions of the minerals present at the mercurian surface, as well as mercurian magmatic processes. Given the low fO2 on Mercury, we have selected to investigate potential meteoritic analogs for Mercury among the most reduced meteorite types, including the aubrites and enstatite chondrite impact melts. The aubrites are differentiated meteorites that show varying degrees of brecciation, have a similar ƒO2 to the mercurian surface and interior, and contain exotic sulfides that have been inferred to be present on the mercurian surface. The enstatite chondrite impact melts are from undifferentiated parent bodies, have a similar ƒO2 to the mercurian surface and interior, and contain exotic sulfides that have been inferred to be present on the mercurian surface. In this study, we present a comprehensive analysis of a representative suite of aubrites and enstatite chondrite impact melts and assess their relevance to under-standing magmatic processes on Mercury.

Wilbur, Z. E.↗

Collecting Samples from the Máaz Formation of Jezero Crater with the Mars 2020 Perseverance Rover

Collection of samples that could be returned to Earth from the floor of Jezero,a Noachian crater characterized by a delta–lake system with high potential for habitability, is a major goal of the Mars 2020 mission. The Mars 2020 Perseverancerover iscurrently exploringthe Máaz and Séítahformationsto the southeastof the delta. Here wefocus on thecrater-retainingMáaz formation, a widespread, rough and fractured terrain with lobatemarginsmapped in orbital images, e.g.[1]. Outcrop morphology and texture, as well as the appearance, composition and mineralogy of abraded rock surfaces observed by Perseverance suggest that theMáazformation consists of asequence of maficigneous units, likely lavas flows. These rocks have experienced variable interaction with aqueous fluids. Type localities of the lower Roubion and the more resistant Rochette members of the Máazformation have been targeted and their abraded surfaces characterized prior to sample collection. In thispresentation we will summarize these sampling activities and potential future sampling of theheavily crateredupperCh’ałmember that is indicative of the Máazformationfrom orbit.

Justin Ibrahim Simon↗

Rover mounted ground penetrating radar as a tool for investigating the near-surface of Mars and beyong

In spite of the highly successful nature of recent planetary missions to the terrestrial planets and outer satellites a number of questions concerning the evolution of their surfaces remain unresolved. For example, knowledge of many characteristics of the stratigraphy and soils comprising the near-surface on Mars remains largely unknown, but is crucial in order to accurately define the history of surface processes and near-surface sedimentary record. Similar statements can be made regarding our understanding of near-surface stratigraphy and processes on other extraterrestrial planetary bodies. Ground penetrating radar (GPR) is a proven and standard instrument capable of imaging the subsurface at high resolution to 10's of meters depth in a variety of terrestrial environments. Moreover, GPR is portable and easily modified for rover deployment. Data collected with a rover mounted GPR could resolve a number of issues related to planetary surface evolution by defining shallow stratigraphic records and would provide context for interpreting results of other surface analyses (e.g. elemental or mineralogical). A discussion of existing GPR capabilities is followed first by examples of how GPR might be used to better define surface evolution on Mars and then by a brief description of possible GPR applications to the Moon and other planetary surfaces.

Grant, J. A.↗

Lunar Mare Basalts as Analogues for Martian Volcanic Compositions: Evidence from Visible, Near-IR, and Thermal Emission Spectroscopy

The lunar mare basalts potentially provide a unique sample suite for understanding the nature of basalts on the martian surface. Our current knowledge of the mineralogical and chemical composition of the basaltic material on Mars comes from studies of the basaltic martian meteorites and from orbital and surface remote sensing observations. Petrographic observations of basaltic martian meteorites (e.g., Shergotty, Zagami, and EETA79001) show that the dominant phases are pyroxene (primarily pigeonite and augite), maskelynite (a diaplectic glass formed from plagioclase by shock), and olivine [1,2]. Pigeonite, a low calcium pyroxene, is generally not found in abundance in terrestrial basalts, but does often occur on the Moon [3]. Lunar samples thus provide a means to examine a variety of pigeonite-rich basalts that also have bulk elemental compositions (particularly low-Ti Apollo 15 mare basalts) that are comparable to basaltic SNC meteorites [4,5]. Furthermore, lunar basalts may be mineralogically better suited as analogues of the martian surface basalts than the basaltic martian meteorites because the plagioclase feldspar in the basaltic Martian meteorites, but not in the lunar surface basalts, is largely present as maskelynite [1,2]. Analysis of lunar mare basalts my also lead to additional endmember spectra for spectral libraries. This is particularly important analysis of martian thermal emission spectra, because the spectral library apparently contains a single pigeonite spectrum derived from a synthetic sample [6].

Graff, T. G.↗

Definition of exobiology experiments for future Mars missions

During the past year we have concentrated on two objectives. The first objective is ongoing and is to define the experimental parameters that are necessary to conduct autonomously a mineralogical analysis of the Martian surface in situ using differential thermal analysis coupled with gas chromatography (DTA/GC). The rationale in support of this objective is that proper interpretation of the mineralogical data from the DTA/GC can be used to better describe the present and past environments of Mars, leading to a better assessment of the probability of life evolving on Mars. To meet these objectives we have analyzed a number of samples collected from nature using the DTA/GC. One of the more significant findings was that in samples of desert varnish we detected magnetite and maghemite that may serve as potential biomarkers applicable to DTA/GC analyses of Martian surface material during landed missions. The second objective follows from the first and is to better understand microbe-environment interactions by determining the response of microbes to changes in their environment, including extreme desiccation and solar UV-radiation. The rationale behind this is to develop hypotheses regarding what may have happened to life that may have arose on Mars, and microbial life that may get to the surface of Mars via spacecraft, or meteors from Earth. To accomplish this objective we have exposed microbes, collected from NaCl and gypsum-halite crystals, to the space environment aboard the ESA-German Biopan facility for 15 days. The most significant finding was that these microbes survived the exposure better than others.

Mancinelli, Rocco L.↗

Long-Lived Venus Lander Conceptual Design: How To Keep It Cool

Surprisingly little is known about Venus, our neighboring sister planet in the solar system, due to the challenges of operating in its extremely hot, corrosive, and dense environment. For example, after over two dozen missions to the planet, the longest-lived lander was the Soviet Venera 13, and it only survived two hours on the surface. Several conceptual Venus mission studies have been formulated in the past two decades proposing lander architectures that potentially extend lander lifetime. Most recently, the Venus Science and Technology Definition Team (STDT) was commissioned by NASA to study a Venus Flagship Mission potentially launching in the 2020- 2025 time-frame; the reference lander of this study is designed to survive for only a few hours more than Venera 13 launched back in 1981! Since Cytherean mission planners lack a viable approach to a long-lived surface architecture, specific scientific objectives outlined in the National Science Foundation Decadal Survey and Venus Exploration Advisory Group final report cannot be completed. These include: mapping the mineralogy and composition of the surface on a planetary scale determining the age of various rock samples on Venus, searching for evidence of changes in interior dynamics (seismometry) and its impact on climate and many other key observations that benefit with time scales of at least a full Venus day (Le. daylight/night cycle). This report reviews those studies and recommends a hybrid lander architecture that can survive for at least one Venus day (243 Earth days) by incorporating selective Stirling multi-stage active cooling and hybrid thermoacoustic power.

Dyson, Ridger W.↗

Spectral Characterization of Bright Materials on Vesta

The surface of Vesta, as observed by the camera and imaging spectrometer onboard the Dawn spacecraft, displays large surface diversity in terms of its geology and mineralogy with noticeably dark and bright areas on the surface often associated with various geological features and showing remarkably different forms. Here we report our initial attempt to spectrally characterize the areas that are distinctively brighter than their surroundings.

Capaccioni, Fabrizio↗

Mineralogy of Rock Flour in Glaciated Volcanic Terrains: An Analog for a Cold and Icy Early Mars

Geomorphological and mineralogical data from early Martian surfaces indicate liquid water was present on ancient Mars. The relative surface temperatures, however, remain a subject of debate. Was early Mars warm and wet or cold and icy with punctuated periods of warmth and ice melt? By characterizing the mineralogy and geochemistry of modern icy mafic terrains on Earth, we can search for these characteristics in early Martian terrains to better constrain the early Martian climate. Here, we describe the mineralogy of glacial flour in a modern glaciated volcanic terrain in Oregon, USA. We are particularly interested in secondary phases that form in these environments, and we hypothesize that poorly crystalline phases may preferentially form in these terrains because of the low temperatures and the seasonality of melt water production. A description of the mineralogy of the moraines, the composition of the amorphous materials, and the geochemistry of the glacial melt waters are presented elsewhere. Glacial flour is made up of silt- and clay-sized particles that form from the physical weathering of rock underlying a wet-based glacier as the glacier slides over it. Flour is usually transported from underneath a glacier by melt water streams. The geochemistry of glacial melt water streams has been studied extensively and has been used to infer weathering reactions within glacial systems. However, the mineralogy of these environments, especially on mafic volcanic terrains, is not well studied. Rock flour is a ubiquitous physical weathering product in glaciated terrains and, therefore, affects microbial habitats, stream and lake chemistry, and chemical weathering processes. and by studying the mineralogy of glacial flour, we can better understand geochemical and microbiological processes in subglacial and proglacial terrains.

Rampe, E. B.↗

Rotational spectral variations of asteroid (8) Flora Implications for the nature of the S-type asteroids and for the parent bodies of the ordinary chondrites

The surface material and the surface material heterogeneities of the asteroid Flora are characterized using the best available data sets and the most sophisticated interpretive calibrations. Five spectrally derived mineralogic and patrologic properties of the surface assemblage of Flora which are relevant to whether this body is a differentiated or undifferentiated object are considered: bulk mineralogy, mafic mineral assemblage, metallic phase, pyroxene composition and structural type, and mineralogic variation. All of these properties indicate that Flora is a differentiated body. Flora is probably the residual core of an intensely heated, thermally evolved, and magnetically differentiated planetesimal which was subsequently disrupted. The present surface sample layers formed at or near the core-mantle boundary in the parent body.

Gaffey, M. J.↗

Composition of the Moon as Determined from Orbit by Gamma-Ray Spectroscopy

A spacecraft placed in a planetary orbit of suitably high inclination will pass over all or most of the planet's surface in a matter of several weeks to months. The quite prodigious scientific potential of planetary orbiters lies in coupling this comprehensive coverage with observing systems capable of gathering data on properties that include elemental and mineralogic composition, exogenic and endogenic surface alterations, thermal balance, gravity, topography, stratigraphy, albedo and magnetism.

gramma-ray spectroscopy↗

Spatial and temporal variability of soil temperature, moisture and surface soil properties

The overall objectives of this research were to: (l) Relate in-situ measured soil-water content and temperature profiles to remotely sensed surface soil-water and temperature conditions; to model simultaneous heat and water movement for spatially and temporally changing soil conditions; (2) Determine the spatial and temporal variability of surface soil properties affecting emissivity, reflectance, and material and energy flux across the soil surface. This will include physical, chemical, and mineralogical characteristics of primary soil components and aggregate systems; and (3) Develop surface soil classes of naturally occurring and distributed soil property assemblages and group classes to be tested with respect to water content, emissivity and reflectivity. This document is a report of studies conducted during the period funded by NASA grants. The project was designed to be conducted over a five year period. Since funding was discontinued after three years, some of the research started was not completed. Additional publications are planned whenever funding can be obtained to finalize data analysis for both the arid and humid locations.

Hajek, B. F.↗

Classification and Distribution of Mars Pathfinder Rocks Using Quantitative Morphologic Indices

The Mars Pathfinder (MPF) landing site was predicted to contain a broad sampling of rock types varying in mineralogical, physical, mechanical and geochemical characteristics. Although rocks have been divided into several spectral categories based on Imager for Mars Pathfinder visible/near-infrared spectra, it has not been fully determined which of these stem from intrinsic mineralogical differences between rocks or rock surfaces, and which result from factors such as physical or chemical weathering. This has made isolation of unique mineralogy's difficult. Efforts in isolating and classifying spectral units among MPF rocks and soils have met with varying degrees of success, and the current understanding is such that many factors influencing spectral signatures cannot be quantified to a sufficient level so they may be removed. The result is that fundamental questions regarding information needed to reveal the present and past interactions between the rocks and rock surfaces and the Martian environment remain unanswered. But it is possible to approach the issue of identifying distinct rock and rock surface types from a different angle.

Yingst, R. A.↗

Possible temperature variation effects on the interpretation of spatially resolved reflectance observations of asteroid surfaces

In virtue of the extent to which the visible and near-IR spectral reflectance of minerals that may be encountered on asteroid surfaces is a function of temperature, surface temperature distributions must be taken into account in the mineralogical evaluation of spectral reflectance data obtained from a spatially resolved asteroid surface. Possible errors of this type are presently illustrated for the case of a silicate mineral assemblage measured at the various temperatures that may be encountered over an asteroid surface, in order to allow optimal mineralogical data extraction.

Roush, Ted L.↗

Estimated Refractive Indices of Calcite, Dolomite, and Magnesite: ~0.3-500 M.

Carbonate minerals are germane to questions involving volatile and climate history on Mars [e.g., 1-2]. In particular, the abundance of carbonate-bearing minerals can provide broad useful bounds on the amount of CO2 out-gassed into the atmosphere over its history and their spatial distribution and mineralogy can yield constraints on the environments in which they were produced. Earth-based, orbital, and landed spectral observations provide evidence for the presence of carbonates in the Martian environment [3-6]. Infrared observations made from spacecraft near Mars were interpreted to indicate the presence of carbonates. [6] associated the carbonates with the surface dust and interpreted the mineralogy as being consistent with magnesite (MgCO3). Near- infrared observations from Mars orbit have been interpreted to suggest magnesite outcrops in restricted locations [7-9]. Quantitative estimates of the abundance of carbonates on Mars range from 0-3% [3], 2-5% [6], less than a few percent [10], and <10% [8]. With the growing evidence for magnesite on Mars additional quantitative estimates can be provided via theoretical modeling of the reflectance from the Martian surface. Calcite (CaCO3) and dolomite ((Ca,Mg)CO3) are identified in Asian dust [2-17%], [10] and calcite in Saharan dust [~8-10% [12-15]. The importance of op- tical constants at visible and near-infrared wavelengths as proxies for estimating the effects at infrared wave- lengths, has been investigated [15]. The growing evidence for Mg-carbonates on Mars, the presence of calcite and dolomite in terrestrial aero- sols, and general lack of optical constants for these materials in the visible- to mid-infrared (VMIR, ~0.3-6 ❍m) has motivated the current effort to estimate the optical constants of calcite, dolomite, and magnesite in the VMIR.

Roush, T. L.↗

Correlation of Rock Spectra with Quantitative Morphologic Indices: Evidence for a Single Rock Type at the Mars Pathfinder Landing Site

The Mars Pathfinder (MPF) landing site was predicted to contain a broad sampling of rock types varying in mineralogical, physical, mechanical and geochemical characteristics. Although rocks have been divided into several spectral categories based on Imager for Mars Pathfinder (IMP) visible/near-infrared data, efforts in isolating and classifying spectral units among MPF rocks and soils have met with varying degrees of success, as many factors influencing spectral signatures cannot be quantified to a sufficient level to be removed. It has not been fully determined which spectral categories stem from intrinsic mineralogical differences between rocks or rock surfaces, and which result from factors such as physical or chemical weathering. This has made isolation of unique rock mineralogies difficult. Morphology, like composition, is a characteristic tied to the intrinsic properties and geologic and weathering history of rocks. Rock morphologies can be assessed quantitatively and compared with spectral data, to identify and classify rock types at the MPF landing site. They can also isolate actual rock spectra from spectral types that are surficial in origin, as compositions associated with mantling dust or chemical coatings would presumably not influence rock morphology during weathering events. We previously reported on an initial classification of rocks using the quantitative morphologic indices of size, roundness, sphericity and elongation. Here, we compare this database of rock characteristics with associated rock surface spectra to improve our ability to discriminate between spectra associated with rock types and those from other sources.

Yingst, R. A.↗

Sulfur Mineralogy at the Mars Phoenix Landing Site

The Mars Phoenix Scout mission landed at the northernmost location (approx.68deg N) of any lander or rover on the martian surface. This paper compares the S mineralogy at the Phoenix landing site with S mineralogy of soils studied by previous Mars landers. S-bearing phases were not directly detected by the payload onboard the Phoenix spacecraft. Our objective is to derive the possible mineralogy of S-bearing phases at the Phoenix landing site based upon Phoenix measurements in combination with orbital measurements, terrestrial analog and Martian meteorite studies, and telescopic observations.

Ming, Douglas W.↗

Fundamental Mvssbauer Parameters of Hydrous Iron Sulfates

Hydrous iron sulfates, which form as alteration products of sulfides, are rare on Earth. On Mars, the low temperature and pH found in the martian permafrost create ideal conditions for the formation of this group of minerals [1], which includes such phases as coquimbite (Fe2(SO4) 9H2O) and amarantite (FeSO4(OH) 3H2O). Viking, Mars Pathfinder, MER and OMEGA data [e.g., [2]] have all indicated the presence of high sulfur contents on the surface of Mars, but the mineralogy of the sulfur-rich phases has not been well constrained. Recent work by [3] suggests that hydrous iron sulfates might satisfy the Martian thermal emission, vis-near IR, and M ssbauer spectra. These data suggest that sulfide and sulfate minerals might be significant contributors to all types of spectra acquired on the Martian surface.

Rothstein, Y.↗

Mineralogical diversity (spectral reflectance and Moessbauer data) in compositionally similar impact melt rocks from Manicouagan Crater, Canada

Meteoritic impacts under oxidizing surface conditions occur on both earth and Mars. Oxidative alteration of impact melt sheets is reported at several terrestrial impact structures including Manicouagan, West Clearwater Lake, and the Ries Basin. A number of studies have advocated that a significant fraction of Martian soil may consist of erosional products of oxidatively altered impact melt sheets. If so, the signature of the Fe-bearing mineralogies formed by the process may be present in visible and near infrared reflectivity data for the Martian surface. Of concern is what mineral assemblages form in impact melt sheets produced under oxidizing conditions and what their spectral signatures are. Spectral and Moessbauer data for 19 powder samples of impact melt rock from Manicouagan Crater are reported. Results show for naturally occurring materials that composite hematite-pyroxene bands have minima in the 910-nm region. Thus many of the anomalous Phobos-2 spectra, characterized by a shallow band minimum in the near-IR whose position varies between approximately 850 and 1000 nm, can be explained by assemblages whose endmembers (hematite and pyroxene) are accepted to be present on Mars. Furthermore, results show that a mineralogically diverse suite of rocks can be generated at essentially constant composition, which implies that variations in Martian surface mineralogy do not necessarily imply variations in chemical composition.

Morris, R. V.↗