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Results for “surface optimization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Realizing tunable Fermi level in SnTe by defect control

The tuning of the Fermi level in tin telluride, a topological crystalline insulator, is essential for accessing its unique surface states and optimizing its electronic properties for applications such as spintronics and quantum computing. In this study, we demonstrate that the Fermi level in tin telluride can be effectively modulated by controlling the tin concentration during chemical vapor deposition synthesis. By introducing tin-rich conditions, we observed a blue shift in the x-ray photoelectron spectroscopy core-level peaks of both tin and tellurium, indicating an upward shift in the Fermi level. Further, this shift is corroborated by a decrease in work function values measured via ultraviolet photoelectron spectroscopy, confirming the suppression of Sn vacancies. Our findings provide a low-cost, scalable method to achieve tunable Fermi levels in tin telluride, offering a significant advancement in the development of materials with tailored electronic properties for next-generation technological applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Effect of activation temperature on quantum efficiency and lifetime of NEA truncated nanocone array GaAs photocathode

This study investigates the quantum efficiency (QE) and operational lifetime of a negative electron affinity GaAs truncated nanocone array (TNCA) photocathode benchmarked against a conventional flat GaAs photocathode under varying activation temperatures. The TNCA structure demonstrated a QE of up to 13.6% at 590 nm with room temperature (RT) activation—approximately 1.5 times higher than its flat counterpart. This enhancement is due to Mie resonance effects within the nanostructure, as confirmed by finite-difference time-domain simulations. Moreover, the TNCA photocathode exhibits significantly extended charge lifetime, with enhancement factors of ∼6.1 and ∼19.8 under RT and 50 °C activations, respectively. These gains are primarily attributed to increased effective surface area and optimized dipole layer formation at elevated temperatures. In addition, shorter excitation wavelengths further contribute to lifetime improvements. These findings underscore the TNCA GaAs photocathode’s potential as a high QE, long lifetime electron source for many large-scale electron accelerators.

Cs-NF3 activation↗
DOE OSTI2026

Replication of x-ray blazed gratings by nano-inscribing.

A nano-inscribing technique was tested as a method of cost-effective replication of blazed diffraction gratings for x-rays. A saw-tooth mold for the nano-inscribing was fabricated by a double-replication process from a master blazed grating. The nano-inscribing was performed using a UV-curable resist of low viscosity to provide a small thickness of the resist replicas, required for a following transfer process. The nano-inscribing process was optimized to minimize surface relaxation and preserve the saw-tooth shape of the grooves, required for high diffraction efficiency. The quality of the replica gratings was evaluated via diffraction efficiency simulations. The simulations demonstrated that near theoretical efficiency can be achieved for the x-ray gratings made by the nano-inscribing approach.

blazed grating↗
DOE OSTI2024

Enhanced nucleation mechanism in ruthenium atomic layer deposition: Exploring surface termination and precursor ligand effects with RuCpEt(CO)2

Miniaturization of microelectronic devices necessitates atomic precision in manufacturing techniques, particularly in the deposition of thin films. Atomic layer deposition (ALD) is recognized for its precision in controlling film thickness and composition on intricate three-dimensional structures. This study focuses on the ALD nucleation and growth mechanisms of ruthenium (Ru), a metal that has significant future implications for microelectronics. Despite its advantages, the deposition of a high surface-free energy material like Ru on a low surface-free energy material such as an oxide often faces challenges of large nucleation delays and non-uniform growth. To address these challenges, we explored the effectiveness of organometallic surface pretreatments using trimethylaluminum (TMA) or diethylzinc (DEZ) to enhance Ru film nucleation and growth. Our study employed a less-studied Ru precursor, cyclopentadienylethyl(dicarbonyl)ruthenium [RuCpEt(CO)2], which demonstrated promising results in terms of reduced nucleation delay and increased film continuity. Ru ALD was performed on silicon substrates with native oxide, using RuCpEt(CO)2 and O2 as coreactants. Our findings reveal that surface pretreatment significantly improves nucleation density and film thickness within the initial 60 ALD cycles, achieving up to a 3.2-fold increase in Ru surface coverage compared to nonpretreated substrates. Supported by density functional theory calculations, we propose that the enhanced nucleation observed with RuCpEt(CO)2 compared to previously-studied Ru(Cp)2 is due to two key mechanisms: the facilitated removal of CO ligands during deposition, which enhances the reactivity of the precursor, and a hydrogen-abstraction reaction involving the ethyl ligand of RuCpEt(CO)2 and the metal-alkyl groups on the surface. This study not only advances our understanding of Ru ALD processes but also highlights the significant impact of precursor chemistry and surface treatments in optimizing ALD for advanced microelectronic applications.

Materials Science↗
DOE OSTI2024

Tuning Catalytically Active Single Sites in Nonstoichiometric, Mixed Metal Oxides for Oxygen Electrocatalysis (Final Technical Report)

The objective of the proposed work is to employ controlled synthesis, advanced characterization, detailed electrochemical testing and theoretical calculations to develop a framework that would guide the design of robust, non-stoichiometric mixed metal oxides for oxygen electrocatalysis. In this research plan, we focus around the idea of tuning the metal ion composition and environment to create single atom centers with the utmost electrocatalytic activity. We hypothesized that tuning the cationic sites in nonstoichiometric mixed metal oxides will lead to single 4d/5d metal surface sites with optimal catalytic activity for low temperature oxygen reduction (ORR) and oxygen evolution (OER) at solid/liquid interfaces. We will focus on different crystal structures of these oxides including Ruddlesden-Popper (R-P) oxides, simple perovskites and pyrochlores due to their flexibility in accommodating different metal cation dopants, and the fact that they represent variations in the cationic arrangements in non-stoichiometric mixed metal oxide structures, which will lead to an understanding of how bulk crystal structure effects catalytic activity and stability of these systems.

08 HYDROGEN↗
NASA NTRS1980

Computational aerodynamics on large computers

Three examples of advances in computational aerodynamics; (1) three-dimensional inviscid transonic analysis, (2) design calculations for wings, and (3) the computation of viscous-induced aileron buzz, are reviewed. Attention is given to wing surface pressures, design optimization, computer memory, speed and advanced solution methods on parallel computer architecture. It is determined that many implicit approximate-factorization schemes, that have been developed for Navier-Stokes equations, can be coded to run efficiently on microprocessors.

Ballhaus, W. F.↗
NASA NTRS1981

Application of laser annealing to solar cell junction formation

The possibility of using high-energy Q-switched Nd:glass lasers to form pn junctions in solar cells by annealing ion-implanted substrates is investigated. The properties of laser annealed cells are analyzed by electrical, transmission electron microscopy, Rutherford backscattering and secondary ion mass spectrometry techniques. Tests indicate the laser annealed substrates to be damage-free and electrically active. Similar reference analysis of ion-implanted furnace-annealed substrates reveals the presence of residual defects in the form of dislocation lines and loops with substantial impurity redistribution evident for some anneal temperature/time regimes. Fabricated laser annealed cells exhibit excellent conversion efficiency. It is noted that additional improvements are anticipated once the anneal parameters for a back surface field are optimized.

Katzeff, J. S.↗
NASA NTRS1984

An analytical design procedure for the determination of effective leading edge extensions on thick delta wings

An analytical design procedure for leading edge extensions (LEE) was developed for thick delta wings. This LEE device is designed to be mounted to a wing along the pseudo-stagnation stream surface associated with the attached flow design lift coefficient of greater than zero. The intended purpose of this device is to improve the aerodynamic performance of high subsonic and low supersonic aircraft at incidences above that of attached flow design lift coefficient, by using a vortex system emanating along the leading edges of the device. The low pressure associated with these vortices would act on the LEE upper surface and the forward facing area at the wing leading edges, providing an additional lift and effective leading edge thrust recovery. The first application of this technique was to a thick, round edged, twisted and cambered wing of approximately triangular planform having a sweep of 58 deg and aspect ratio of 2.30. The panel aerodynamics and vortex lattice method with suction analogy computer codes were employed to determine the pseudo-stagnation stream surface and an optimized LEE planform shape.

Farhad Ghaffari↗
NASA NTRS1985

Further research on high open circuit voltage in silicon solar cells

The results of a new research on the use of controlled dopant profiles and oxide passivation to achieve high open circuit voltage V sub oc in silicon solar cells is presented. Ion implantation has been used to obtain nearly optimal values of surface dopant concentration. The concentrations are selected so as to minimize heavy doping effects and thereby provide both high blue response and high V sub oc ion implantation technique has been successfully applied to fabrication of both n-type and p-type emitters. V sub oc of up to 660 mV is reported and AMO efficiency of 16.1% has been obtained.

Spitzer, M. B.↗
NASA NTRS1989

Adjusting Surfaces Of Large Antenna Reflectors

New approach more effective than traditional rms-surface-distortion approach. Optimization procedure for control of shape of reflector of large space antenna (LSA). Main feature is shape-controlling mathematical mechanism driven by need to satisfy explicit EM design requirements. Uses standard finite-element structural analysis, aperture-integration EM analysis, and constrained optimization techniques to predict set of actuator inputs that improves performance of antenna while minimizing applied control effort. Procedure applicable to wide variety of LSA concepts.

Padula, Sharon L.↗
NASA NTRS1991

Forming YBa2Cu3O7-x Superconductors On Copper Substrates

Experimental process forms layer of high-critical-temperature ceramic superconductor YBa2Cu3O7-x on surface of copper substrate. Offers possible solution to problem of finishing ceramic superconductors to required final sizes and shapes (difficult problem because these materials brittle and cannot be machined or bent). Further research necessary to evaluate superconducting qualities of surface layers and optimize process.

Mackenzie, J. Devin↗
NASA NTRS1992

Optimal recovery from microburst wind shear

The flight path of a twin-jet transport aircraft is optimized in a microburst encounter during approach to landing. The objective is to execute an escape maneuver that maintains safe ground clearance and an adequate stall margin during the climb-out portion of the trajectory. A cost function penalizing rate of climb deviations from a nominal value and rate of elevator deflection produces qualitatively good results in a variety of microburst encounters. The optimal maneuver is a gradual pitch-up that ceases near the core of the microburst, followed by a slight reduction in pitch attitude in the tailwind area of the microburst. A minimum airspeed constraint in the optimization prevents excessive airspeed loss in very severe microbursts. The aircraft equations of motion include short-period dynamics, so that the optimization solves directly for the control surface deflections required to achieve the optimal flight paths.

Mulgund, Sandeep S.↗
NASA NTRS1993

Surface passivation of InP solar cells with InAlAs layers

The efficiency of indium phosphide solar cells is limited by high values of surface recombination. The effect of a lattice-matched In(0.52)Al(0.48)As window layer material for InP solar cells, using the numerical code PC-1D is investigated. It was found that the use of InAlAs layer significantly enhances the p(+)n cell efficiency, while no appreciable improvement is seen for n(+)p cells. The conduction band energy discontinuity at the heterojunction helps in improving the surface recombination. An optimally designed InP cell efficiency improves from 15.4 percent to 23 percent AMO for a 10 nm thick InAlAs layer. The efficiency improvement reduces with increase in InAlAs layer thickness, due to light absorption in the window layer.

Jain, Raj K.↗
NASA NTRS1993

TOPEX/Poseidon mission early results

The joint U.S./France TOPEX/Poseidon mission launched on August 10, 1992 and aimed at optimizing the sea surface height measurements is described. Results of the first six months of the mission intended to calibrate and validate the missions measurements are presented. The verification results show that almost all measurements have exceeded performance requirements. The root-mean-square accuracy of the sea surface height measurement is estimated to be about 5.7 cm, which is significantly less than the specification of 13.4 cm.

Fu, Lee-Lueng↗
NASA NTRS1999

An Assessment of the Impact of the 1997-98 El Nino on the Asian-Australian Monsoon

Using state-of-the-art satellite-gauge monthly rainfall estimate and optimally interpolated sea surface temperature (SST) data, we have assessed the 1997-98 AA-monsoon anomalies in terms of three basic causal factors: basin-scale SST, regional coupling, and internal variability. Singular Value Decomposition analyses of rainfall and SST are carried out globally over the entire tropics and regionally over the AA-monsoon domain. Contributions to monsoon rainfall predictability by various factors are evaluated from cumulative anomaly correlation with dominant regional SVD modes. Results reveal a dominant, large-scale monsoon-El Nino coupled mode with well-defined centers of action in the near-equatorial monsoon regions during the boreal summer and winter respectively. The observed 1997-98 AA-monsoon anomalies are found to be very complex with approximately 34% of the anomalies of the Asian (boreal) summer monsoon and 74% of the Australia (austral) monsoon attributable to basin-scale SST influence associated with El Nino. Regional coupled processes contribute an additional 19% and 10%, leaving about 47% and 16% due to internal dynamics for the boreal and austral monsoon respectively. For the boreal summer monsoon, it is noted that the highest monsoon predictability is not necessary associated with major El Nino events (e.g. 1997, 1982) but rather in non-El Nino years (e.g. 1980, 1988) when contributions from the regional coupled modes far exceed those from the basin-scale SST. The results suggest that in order to improve monsoon seasonal-to-interannual predictability, there is a need to exploit not only monsoon-El Nino relationship, but also intrinsic monsoon regional coupled processes.

Lau, K.-M.↗
NASA NTRS1999

Assessment of the 1997-1998 Asian Monsoon Anomalies

Using State-of-the-art satellite-gauge monthly rainfall estimate and optimally interpolated sea surface temperature (SST) data, we have assessed the 1997-98 Asian monsoon anomalies in terms of three basic causal factors: basin-scale SST, regional coupling, and internal variability. Singular Value Decomposition analysis of rainfall and SST are carried out globally over the entire tropics and regionally over the Asian monsoon domain. Contributions to monsoon rainfall predictability by various factors are evaluated from cumulative anomaly correlation with dominant regional SVD modes. Results reveal a dominant, large-scale monsoon-El Nino coupled mode with well-defined centers of action in the near-equatorial monsoon regions. it is noted that some subcontinental regions such as all-India, or arbitrarily chosen land regions over East Asia, while important socio-economically, are not near the centers of influence from El Nino, hence are not necessarily representative of the response of the entire monsoon region to El Nino. The observed 1997-98 Asian monsoon anomalies are found to be very complex with approximately 34% of the anomalies attributable to basin- scale SST influence associated with El Nino. Regional coupled processes contribute an additional 19%, leaving about 47% due to internal dynamics. Also noted is that the highest monsoon predictability is not necessary associated with major El Nino events (e.g. 1997, 1982) but rather in non-El Nino years (e.g. 1980, 1988) when contributions from the regional coupled modes far exceed those from the basin-scale SST. The results suggest that in order to improve monsoon seasonal-to-interannual predictability, there is a need to exploit not only monsoon-El Nino relationship, but also monsoon regional coupled processes and their modulation by long-term climate change.

Lau, William K.-M.↗
NASA NTRS1995

Grid Sensitivity and Aerodynamic Optimization of Generic Airfoils

An algorithm is developed to obtain the grid sensitivity with respect to design parameters for aerodynamic optimization. The procedure is advocating a novel (geometrical) parameterization using spline functions such as NURBS (Non-Uniform Rational B- Splines) for defining the airfoil geometry. An interactive algebraic grid generation technique is employed to generate C-type grids around airfoils. The grid sensitivity of the domain with respect to geometric design parameters has been obtained by direct differentiation of the grid equations. A hybrid approach is proposed for more geometrically complex configurations such as a wing or fuselage. The aerodynamic sensitivity coefficients are obtained by direct differentiation of the compressible two-dimensional thin-layer Navier-Stokes equations. An optimization package has been introduced into the algorithm in order to optimize the airfoil surface. Results demonstrate a substantially improved design due to maximized lift/drag ratio of the airfoil.

Sadrehaghighi, Ideen↗
NASA NTRS2006

Development of a 32 Inch Diameter Levitated Ducted Fan Conceptual Design

The NASA John H. Glenn Research Center has developed a revolutionary 32 in. diameter Levitated Ducted Fan (LDF) conceptual design. The objective of this work is to develop a viable non-contact propulsion system utilizing Halbach arrays for all-electric flight, and many other applications. This concept will help to reduce harmful emissions, reduce the Nation s dependence on fossil fuels, and mitigate many of the concerns and limitations encountered in conventional aircraft propulsors. The physical layout consists of a ducted fan drum rotor with blades attached at the outer diameter and supported by a stress tuner ring at the inner diameter. The rotor is contained within a stator. This concept exploits the unique physical dimensions and large available surface area to optimize a custom, integrated, electromagnetic system that provides both the levitation and propulsion functions. The rotor is driven by modulated electromagnetic fields between the rotor and the stator. When set in motion, the time varying magnetic fields interact with passive coils in the stator assembly to produce repulsive forces between the stator and the rotor providing magnetic suspension. LDF can provide significant improvements in aviation efficiency, reliability, and safety, and has potential application in ultra-efficient motors, computers, and space power systems.

Eichenberg, Dennis J.↗