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At least 253 records · Page 14

Estimating 11-year solar UV variations using 27-day response as a guide to isolate trends in total column ozone

The total column ozone response to 11-year solar ultraviolet (UV) variations is estimated here from the observed response to 27-day solar variations adjusted for the theoretical difference between the 27-day response and 11-year response. The estimate is tested by comparing two data sets where long-term drifts have been removed, the Nimbus 7 TOMS Version 6 total column ozone and the 280 nm core-to-wing ratio (a proxy for solar UV variations). The 365-day running means of data area-weighted between 40 deg N to 40 deg S latitude give a 1.9% ozone variation related to the 11-year solar cycle compared with the estimate of 1.8%. Estimates of linear trends were reduced by a factor of 2 by including solar effects. The standard deviation from the empirical model was reduced from 1.0 to 0.6 Dobson Units, by including the quasi-biennial oscillation (QBO), but the QBO did not significantly alter trend estimates. Both the ozone responses to 27-day and 11-year solar variations were considerably stronger than predicted by a 2-D theoretical model.

Keating, G. M.↗

Interhemispheric survey of minor upper atmospheric constituents during October - November 1976

The CV-990 aircraft coordinated several flights with a NASA U-2 aircraft, NOAA ground station measurements in Alaska, Hawaii, and American Samoa, and with Australian and New Zealand ground stations, aircraft, and a balloon experiment in the Southern hemisphere. Data were obtained for species including ozone, total ozone, the oxides of nitrogen, the chlorofluoromethanes, water vapor, nitric acid, carbon monoxide, carbon dioxide, hydrogen chloride, Aitken nuclei, ammonia, aerosols, temperatures, and winds. Individual experiment results and selected analyses are presented. The experimental data include total column densities, latitude variations, interhemisphere differences, and vertical profiles.

Gauntner, D. J.↗

Reconciliation of Halogen-Induced Ozone Loss with the Total-Column Ozone Record

The observed depletion of the ozone layer from the 1980s onwards is attributed to halogen source gases emitted by human activities. However, the precision of this attribution is complicated by year-to-year variations in meteorology, that is, dynamical variability, and by changes in tropospheric ozone concentrations. As such, key aspects of the total-column ozone record, which combines changes in both tropospheric and stratospheric ozone, remain unexplained, such as the apparent absence of a decline in total-column ozone levels before 1980, and of any long-term decline in total-column ozone levels in the tropics. Here we use a chemistry-climate model to estimate changes in halogen-induced ozone loss between 1960 and 2010; the model is constrained by observed meteorology to remove the eects of dynamical variability, and driven by emissions of tropospheric ozone precursors to separate out changes in tropospheric ozone. We show that halogen-induced ozone loss closely followed stratospheric halogen loading over the studied period. Pronounced enhancements in ozone loss were apparent in both hemispheres following the volcanic eruptions of El Chichon and, in particular, Mount Pinatubo, which significantly enhanced stratospheric aerosol loads. We further show that approximately 40% of the long-term non-volcanic ozone loss occurred before 1980, and that long-term ozone loss also occurred in the tropical stratosphere. Finally, we show that halogeninduced ozone loss has declined by over 10% since stratospheric halogen loading peaked in the late 1990s, indicating that the recovery of the ozone layer is well underway.

Shepherd, T. G.↗

Assimilation of Satellite Ozone Observations

This talk will discuss assimilation of ozone data from satellite-borne instruments. Satellite observations of ozone total columns and profiles have been measured by a series of Total Ozone Mapping Spectrometer (TOMS), Solar Backscatter Ultraviolet (SBUV) instruments, and more recently by the Global Ozone Monitoring Experiment. Additional profile data are provided by instruments on NASA's Upper Atmosphere Research Satellite and by occultation instruments on other platforms. Instruments on Envisat' and future EOS Aura satellite will supply even more comprehensive data about the ozone distribution. Satellite data contain a wealth of information, but they do not provide synoptic global maps of ozone fields. These maps can be obtained through assimilation of satellite data into global chemistry and transport models. In the ozone system at NASA's Data Assimilation Office (DAO) any combination of TOMS, SBUV, and Microwave Limb sounder (MLS) data can be assimilated. We found that the addition of MLS to SBUV and TOMS data in the system helps to constrain the ozone distribution, especially in the polar night region and in the tropics. The assimilated ozone distribution in the troposphere and lower stratosphere is sensitive also to finer changes in the SBUV and TOMS data selection and to changes in error covariance models. All results are established by comparisons of assimilated ozone with independent profiles from ozone sondes and occultation instruments.

Stajner, I.↗

Spectral analyses, climatology, and interannual variability of Nimbus-7 TOMS version 6 total column ozone

This reference publication presents selected results from space-time spectral analyses of 13 years of version 6 daily global ozone fields from the Total Ozone Mapping Spectrometer (TOMS). One purpose is to illustrate more quantitatively the well-known richness of structure and variation in total ozone. A second purpose is to provide, for use by modelers and for comparison with other analysts' work, quantitative measures of zonal waves 1, 2, 3, and medium-scale waves 4-7 in total ozone. Their variations throughout the year and at a variety of latitudes are presented, from equatorial to polar regions. The 13-year averages are given, along with selected individual years which illustrate year-to-year variability. The largest long wave amplitudes occur in the polar winters and early springs of each hemisphere, and are related to strong wave amplification during major warning events. In low attitudes total ozone wave amplitudes are an order of magnitude smaller than at high latitudes. However, TOMS fields contain a number of equatorial dynamical features, including Rossby-gravity and Kelvin waves.

Stanford, J. L.↗

TOMS: The Antarctic ozone hole and ozone trends

The Total Ozone Mapping Spectrometer (TOMS) instrument aboard Nimbus 7 has proved invaluable for the investigation of the recent rapid decline in the springtime total ozone over the Antarctic. The principle problem discussed is that of observing the atmosphere over long periods of time to determine whether or not trends and/or slow oscillations are taking place. Total ozone is an excellent summary parameter for the state of the stratosphere. It responds to temperature changes, and in the long term, is expected to respond to chemical changes. Thus, when changes take place in total ozone, such as the springtime Antarctic decrease it is a clear indication of an important problem, both because of environmental potential and scientific importance. TOMS is actually an overkill for this problem. Significantly more data is taken than is necessary. Tests have shown that maps produced on a 2 by 4 degree grid are essentially equivalent to those produced from the entire gridded data set. Because the critical aspect of the search for changes in ozone is continuous data, reflight of a polar orbiting TOMS is important. Included in the flight should be a stratospheric temperature sensor and, if possible, a modification to obtain some ozone altitude information. A critical aspect of the problem is timeliness of the data. This is the only drawback of the existing TOMS. It is expected that in the very near future the processing will be done within two weeks of real time. This is critical to the process of discovery of phenomena such as the Antarctic ozone hole.

Stolarski, Richard S.↗

Near-real-time TOMS, telecommunications and meteorological support for the 1987 Airborne Antarctic Ozone Experiment

The goal of the 1987 Airborne Antarctic Ozone Experiment was to improve the understanding of the mechanisms involved in the formation of the Antarctic ozone hole. Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the experiment. During the experiment, the near-real-time TOMS total ozone observations were supplied within hours of real time to the operations center in Punta Arenas, Chile. The final report summarizes the role which Research and Data Systems (RDS) Corporation played in the support of the experiment. The RDS provided telecommunications to support the science and operations efforts for the Airborne Antarctic Ozone Experiment, and supplied near real-time weather information to ensure flight and crew safety; designed and installed the telecommunications network to link NASA-GSFC, the United Kingdom Meteorological Office (UKMO), Palmer Station, the European Center for Medium-Range Weather Forecasts (ECMWF) to the operation at Punta Arenas; engineered and installed stations and other stand-alone systems to collect data from designated low-orbiting polar satellites and beacons; provided analyses of Nimbus-7 TOMS data and backup data products to Punta Arenas; and provided synoptic meteorological data analysis and reduction.

Ardanuy, P.↗

Trends in total column ozone measurements

It is important to ensure the best available data are used in any determination of possible trends in total ozone in order to have the most accurate estimates of any trends and the associated uncertainties. Accordingly, the existing total ozone records were examined in considerable detail. Once the best data set has been produced, the statistical analysis must examine the data for any effects that might indicate changes in the behavior of global total ozone. The changes at any individual measuring station could be local in nature, and herein, particular attention was paid to the seasonal and latitudinal variations of total ozone, because two dimensional photochemical models indicate that any changes in total ozone would be most pronounced at high latitudes during the winter months. The conclusions derived from this detailed examination of available total ozone can be split into two categories, one concerning the quality and the other the statistical analysis of the total ozone record.

Rowland, F. S.↗

Tropopause adjustment to tropical cyclones as inferred from satellite ozone observations

Data from the Total Ozone Mapping Spectrometer on the Nimbus-7 are used to map the climatological total ozone within and around tropical cyclones. A tropical cyclone numerical model is used to interpret total ozone patterns. The total ozone maps are used to diagnose storm intensity and to differentiate between intesifying and weakening tropical cyclones. The tropical cyclone intensity versus total ozone anomaly distribution is examined and examples of mapping the total ozone of tropical cyclones in the period 1979-1982 are presented.

Rodgers, Edward B.↗

Improving Total Column Ozone Retrievals by Using Cloud Pressures Derived from Raman Scattering in the UV

The higher spectral resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals, including estimates of tropospheric ozone. By default, the TOMS-like OMI total column ozone algorithm uses climatological cloud-top pressures based on infrared (IR) measurements to estimate the column ozone below the clouds. Alternatively, cloud pressure can be retrieved using atmospheric rotational Raman scattering with OMI. The retrieved cloud pressures should be more consistent with assumptions made in the total ozone algorithm. Here, we use data from the global ozone monitoring experiment (GOME) to estimate total ozone using both the IR-climatological and retrieved cloud pressures. The exceed approximately 15 DU. Use of the UV cloud pressure retrievals leads to a smoother distribution of ozone along a satellite track by reducing small spatial irregularities presumably caused by errors in the climatological cloud pressures.

Vasilkov, A.↗

A Comparison of TOMS Version 8 Total Column Ozone Data with Data from Groundstations

The Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) data have been reprocessed with a new retrieval algorithm, (Version 8) and an updated calibration procedure. These data have been systematically compared to total ozone data from Brewer and Dobson spectrophotometers for 73 individual ground stations. The comparisons were made as a function of latitude, solar zenith angle, reflectivity and total ozone. Results show that the accuracy of the TOMS retrieval'is much improved when aerosols are present in the atmosphere, when snow/ice and sea glint are present, and when ozone in the northern hemisphere is extremely low. TOMS overpass data are derived from the single TOMS best match measurement, almost always located within one degree of the ground station and usually made within an hour of local noon. The version 8 Earth Probe TOMS ozone values have decreased by an average of about 1% due to a much better understanding of the calibration of the instrument. The remaining differences between TOMS and ground stations suggest that there are still small errors in the TOMS retrievals. But if TOMS is used as a transfer standard to compare ground stations, the large station-to-station differences suggest the possibility of significant instrument errors at some ground stations.

Labow, G. J.↗

Satellite Mapping of the Earth's Ozone and Sulfur Dioxide

The Total Ozone Mapping Spectrometer (TOMS) instruments are spatially-scanning UV spectrometers that have produced daily global images of total ozone over the last 21 years since the launch of the Nimbus 7 satellite. The instruments use a total ozone retrieval algorithm pioneered by J.V. Dave and C. L. Mateer for the Nimbus 4 Backscatter Ultraviolet (BUV) instrument, designed by D.F. Heath. The TOMS ozone maps have revealed the relations between total ozone and atmospheric dynamics, and shown the dramatic losses of ozone in the Antarctic ozone hole and the Northern hemisphere. The accepted long-term trends in global, regional, and local ozone are derived from data from the Nimbus 7 TOMS and three successive TOMS flights on Russian, Japanese, and American satellites. The next TOMS flight will be launched in 2000. The contiguous mapping design and fortuitous choice of TOMS wavelengths bands also permitted imaging of a second atmospheric gas, sulfur dioxide, which is transient due to its short lifetime. The importance of this measurement was first realized after the eruption of El Chichon volcano in 1982. The extreme range of sizes of volcanic eruptions and the 'associated danger require observations from a distant observing platform. The first quantitative time series of the input of sulfur dioxide by explosive volcanic eruptions into the atmosphere thus was developed from the TOMS missions. Finally, the Rayleigh and aerosol scattering spectral characteristic and reflectivity complete the four dominant pieces of information in the near UV albedo of the Earth. The four parameters are derived with a linear algorithm, the absorption coefficients of the gases, and effective paths computed from radiative transfer tables. Absorbing aerosol clouds (smoke, dust, volcanic ash) are readily identified by their deviation from a Rayleigh signature. The greatest shortcoming of the TOMS dataset is the 24 hour time resolution that is produced by the polar orbit of the satellite. Dynamic phenomena, such as upper air fronts that modulate total ozone and volcanic eruptions of sulfur dioxide and ash, cannot be adequately resolved. It is hoped that UV observations from geostationary satellites will soon be made to test the value of this unique information in weather forecasting and aviation safety.

Krueger, Arlin↗

Satellite Mapping of the Earth's Ozone and Sulfur Dioxide

The Total Ozone Mapping Spectrometer (TOMS) instruments are spatially-scanning UV spectrometers that have produced daily global images of total ozone over the last 21 years since the launch of the Nimbus 7 satellite. The instruments use a total ozone retrieval algorithm pioneered by J.V. Dave and C. L. Mateer for the Nimbus 4 Backscatter Ultraviolet (BUV) instrument, designed by D.F. Heath. The TOMS ozone maps have revealed the relations between total ozone and atmospheric dynamics, and shown the dramatic losses of ozone in the Antarctic ozone hole and the Northern hemisphere. The accepted long-term trends in global, regional, and local ozone are derived from data from the Nimbus 7 TOMS and three successive TOMS flights on Russian, Japanese, and American satellites. The next TOMS flight will be launched in 2000. The contiguous mapping design and fortuitous choice of TOMS wavelengths bands also permitted imaging of a second atmospheric gas, sulfur dioxide, which is transient due to its short lifetime. The importance of this measurement was first realized after the eruption of El Chichon volcano in 1982. The extreme range of sizes of volcanic eruptions and the associated danger require observations from a distant observing platform. The first quantitative time series of the input of sulfur dioxide by explosive volcanic eruptions into the atmosphere thus was developed from the TOMS missions. Finally, the Rayleigh and aerosol scattering spectral characteristic and reflectivity complete the four dominant pieces of information in the near UV albedo of the Earth. The four parameters are derived with a linear algorithm, the absorption coefficients of the gases, and effective paths computed from radiative transfer tables. Absorbing aerosol clouds (smoke, dust, volcanic ash) are readily identified by their deviation from a Rayleigh signature. The greatest shortcoming of the TOMS dataset is the 24 hour time resolution that is produced by the polar orbit of the satellite. Dynamic phenomena, such as upper air fronts that modulate total ozone and volcanic eruptions of sulfur dioxide and ash, cannot be adequately resolved. It is hoped that UV observations from geostationary satellites will soon be made to test the value of this unique information in weather forecasting and aviation safety.

Krueger, Arlin↗

Using Cloud Top Pressures Derived from Raman Scattering in the UV for the OMI Total Column Ozone Retrievals

The OMI cloud pressure product is necessary for accounting for cloud effects on the mission- critical total ozone product. One of the OM1 cloud pressure algorithms uses UV measurements to derive cloud pressures from the high frequency structure of top- of-atmosphere reflectance caused by rotational Raman scattering (RRS) in the atmosphere. RRS results in filling-in of Fraunhofer lines in the backscatter UV spectra (also known as the Ring effect). The magnitude of filling-in of the Fraunhofer lines is roughly proportional to the average number of solar photon scatterings in the atmosphere above the clouds. This property of RRS is used to deduce an effective cloud pressure. The cloud pressure algorithm retrieves the cloud pressure and cloud fraction using a concept of the Mixed Lambert Equivalent Reflectivity (MLER) also used for the TOMS-V8 OM1 total column ozone algorithm. Currently, this OMI total column ozone algorithm utilizes information about cloud top pressures from a climatology based on IR measurements. The IR-derived cloud top pressure is known to be lower than UV-derived cloud top pressure because UV radiation penetrates clouds deeper than IR radiation. That is why the UV-derived cloud pressure may be more consistent withthe total ozone algorithm. We estimate total column ozone differences caused by replacing the cloud pressure climatology with cloud pressures retrieved from GOME data same as used for retrieval of ozone.

Joiner, J.↗

A geostationary imaging spectrometer TOMS instrument

One design for a geostationary Total Ozone Mapping Spectrometer (TOMS) with many desirable features is an imaging spectrometer. A preliminary study makes use of a 0.25 m Czerny-Turner spectrometer with which the Earth is imaged on a charge-coupled device (CCD) in dispersed light. The wavelength is determined by a movable grating which can be set arbitrarily by ground control. The signal integration time depends on wavelength but this system allows arbitrary timing by command. Special circumstances such as a requirement to track a low-lying sulfur dioxide cloud or a need to discriminate high level ozone from total ozone at midlatitudes could be obtained by adding a particular wavelength to the normally pre-programmed time sequence. The incident solar irradiance is measured by deploying a diffuser plate in the field of view. Individual detector elements correspond to scene elements in which the several wavelengths are serially sampled and the Earth radiance is compared to the incident sunlight. Thus the problem of uncorrelated drift of multiple detectors is removed.

Krueger, Arlin J.↗

A new self-calibration method applied to TOMS and SBUV backscattered ultraviolet data to determine long-term global ozone change

The currently archived (1989) total ozone mapping spectrometer (TOMS) and solar backscattered ultraviolet (SBUV) total ozone data (version 5) show a global average decrease of about 9.0 percent from November 1978 to November 1988. This large decrease disagrees with an approximate 3.5-percent decrease estimated from the ground-based Dobson network. The primary source of disagreement was found to arise from an overestimate of reflectivity change and its incorrect wavelengths dependence for the diffuse plate used when measuring solar irradiance. Both of these factors have led to an overestimate of the rate of atmospheric ozone depletion by SBUV and TOMS. For total ozone measured by TOMS, a means has been found to use the measured radiance-irradiance ratio from several wavelengths pairs to construct an internally self-consistent calibration. The method uses the wavelength dependence of the sensitivity to calibration errors and the requirement that albedo ratios for each wavelength pair yield the same total ozone amounts. Smaller errors in determining spacecraft attitude, synchronization problems with the photon counting electronics, and sea-glint contamination of boundary reflectivity data have been corrected or minimized. New climatological low-ozone profiles have been incorporated into the TOMS algorithm that are appropriate for Antarctic ozone hole conditions and other low ozone cases. The combined corrections have led to a new determination of the global average total ozone trend (version 6) as a 2.9 + or - 1.3 percent decrease over 11 years (October 1978 to November 1989).

Herman, J. R.↗

The 1987 Airborne Antarctic Ozone Experiment: the Nimbus-7 TOMS Data Atlas

Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the 1987 Airborne Antarctic Ozone Experiment. The near-real-time TOMS total ozone observations were suppled within hours of real time to the operations center in Punta Arenas, Chile, over a telecommunications network designed specifically for this purpose. The TOMS data preparation and method of transfer over the telecommunications links are reviewed. This atlas includes a complete set of the near-real-time TOMS orbital overpass data over regions around the Palmer Peninsula of Antarctica for the period of August 8 through September 29, 1987. Also provided are daily polar orthographic projections of TOMS total ozone measurements over the Southern Hemisphere from August through November 1987. In addition, a chronology of the salient points of the experiment, along with some latitudinal cross sections and time series at locations of interest of the TOMS total ozone observations are presented. The TOMS total ozone measurements are evaluated along the flight tracks of each of the ER-2 and DC-8 missions during the experiment. The ozone hole is shown here to develop in a monotonic progression throughout late August and September. The minimum total ozone amount was found on 5 October, when its all-time lowest value of 109 DU is recorded. The hole remains well defined, but fills gradually from mid-October through mid-November. The hole's dissolution is observed here to begin in mid-November, when it elongates and begins to rotate. By the end of November, the south pole is no longer located within the ozone hole.

Krueger, Arlin J.↗

Implications of Version 8 TOMS and SBUV Data for Long-Term Trend Analysis

Total ozone data from the Total Ozone Mapping Spectrometer (TOMS) and profile/total ozone data from the Solar Backscatter Ultraviolet (SBUV; SBW/2) series of instruments have recently been reprocessed using new retrieval algorithms (referred to as Version 8 for both) and updated calibrations. In this paper, we incorporate the Version 8 data into a TOMS/SBW merged total ozone data set and an S B W merged profile ozone data set. The Total Merged Ozone Data (Total MOD) combines data from multiple TOMS and SBW instruments to form an internally consistent global data set with virtually complete time coverage from October 1978 through December 2003. Calibration differences between instruments are accounted for using external adjustments based on instrument intercomparisons during overlap periods. Previous results showed errors due to aerosol loading and sea glint are significantly reduced in the V8 TOMS retrievals. Using SBW as a transfer standard, calibration differences between V8 Nimbus 7 and Earth Probe TOMS data are approx. 1.3%, suggesting small errors in calibration remain. We will present updated total ozone long-term trends based on the Version 8 data. The Profile Merged Ozone Data (Profile MOD) data set is constructed using data from the SBUV series of instruments. In previous versions, SAGE data were used to establish the long-term external calibration of the combined data set. The SBW Version 8 we assess the V8 profile data through comparisons with SAGE and between SBW instruments in overlap periods. We then construct a consistently-calibrated long term time series. Updated zonal mean trends as a function of altitude and season from the new profile data set will be shown, and uncertainties in determining the best long-term calibration will be discussed.

Frith, Stacey M.↗