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At least 253 records · Page 14

Trace element studies of rocks and soils from Oceanus Procellarum and Mare Tranquillitatis

Neutron activation data on Zn, Ga, Ge, Cd, In and Ir are reported for six rocks and two soils from the Apollo 12 mission. Comparison of these and similar data for Apollo 11 samples indicates extralunar components in the 12070 and 10084 soils of about 1.0 and 1.1% expressed in terms of an assumed composition which is the same as the water-free portion of C1 chondrites. A relationship between the integrated flux of extralunar material and the increase in concentration of such material in the fines of the lunar regolith is derived. Apollo 12 rocks have concentrations of Zn, Ge, Cd, In and possibly Ir which are lower by factors of 60 or more, relative to terrestrial basalts. A mechanism is proposed for the late accretion of volatile-rich materials, including comets, in which a primitive terrestrial atmosphere is invoked to explain the significantly higher concentrations of such substances on the earth.

Baedecker, P. A.↗

Bulk, rare earth and other trace elements in Apollo 14 and 15 and Luna 16 samples

The chemical abundances were measured by instrumental and radiochemical neutron activation analysis in a variety of lunar specimens. Apollo 14 soils are characterized by significant enrichments of Al2O3, Na2O and K2O and depletions of TiO2, FeO, MnO and Cr2O3 relative to Apollo 11 and to most of Apollo 12 soils. The uniform abundances in 14230 core tube soils and three other Apollo 14 soils indicate that the regolith is uniform to at least 22 cm depth and within approximately 200 m from the lunar module. Two Luna 16 breccias are similar in composition to Luna 16 soils. Four Apollo 15 soils (LM, STA 4, 9, and 9a) have variable compositions. Interelement correlations between MnO-FeO, Sc-FeO, V-Cr2O3 and K2O-Hf negate the hypothesis that howardite achondrites may be primitive lunar matter, argue against the fission hypothesis for the origin of the moon, and precludes any selective large scale volatilization of alkalies during lunar magmatic events.

Laul, J. C.↗

Meteoritic and non-meteoritic trace elements in Luna 16 samples.

Two Luna 16 soils have been analyzed for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, Ge, In, Ur, Ni, Rb, Re, Sb, Se, Te, Tl, and Zn. A meteoritic component similar to that in Apollo 11 and 12 soils seems to be present, corresponding to about 1.5 to 2% Cl chondrites or equivalent. It probably consists largely of micrometeorites. Three elements show strong enrichments compared to Apollo 11 and 12 soils: Cd (5 x to 200 x), Ag (5 x to 10 x), and Bi (3 x). Presumably these elements were brought in by Cd-Ag-Bi rich material, similar to that in Unit VI of Apollo core 12028.

Laul, J. C.↗

Trace elements profiles, notably Hg, from a preliminary study of the Apollo 15 deep-drill core.

The possible thermal gradient near the surface during a lunation is considered together with the heat flow from the interior, the physical process of Hg migration, the results from core and trench samples from previous missions, and other temperature sensitive phenomena that may help understand the processes. U, Os, and Ru concentrations in the deep drill core samples are of potential interest and are summarized in a table. The Os tends to parallel the Hg profile with depth.

Jovanovic, S.↗

Trace elements in fines from the Apollo 15 deep drill.

Samples of fines from the bottom of the Apollo 15 deep drill core and from each junction between the six 42.5-cm long segments of the drill stem were analyzed for Ag, Co, Cr, Cs, Cu, Ga, Hf, Rb, Sc, and Zn by neutron activation. The most striking feature of the results is the absence of significant variations in concentration for any element throughout the depth of the drill sample and despite the considerable stratigraphy of the cored material. The presence of a significant amount of KREEP material is indicated.

Helmke, P. A.↗

Rare earths, other trace elements and iron in Luna 20 samples.

The results of the analysis by neutron activation of six samples from the Luna 20 mission and one sample of less than 1 mm fines from Apollo 16 are reported. The concentrations of the rare-earth elements (REE) in the samples of fines from Luna 20 and Apollo 16 are less than those found for corresponding materials from the mare areas but a negative Eu anomaly is still present. The concentrations of the REE in fines from Luna 20 are only about two-thirds as great as in the sample of Apollo 16 fines, but the concentration of Co, Sc and Cr are greater by factors ranging from 1.5 to 2.3.

Helmke, P. A.↗

Luna 20 soil - Abundance of 17 trace elements.

Review of the results of radiochemical neutron activation analysis of two Luna 20 fine soil and breccia samples for the abundance of 17 mainly siderophile and volatile elements that are strongly depleted in lunar surface rocks and hence represent sensitive indicators of meteoritic materials. These results are compared with those previously obtained for Apollo 16 soils. Some of the source rocks of Luna 20 regolith are identified.

Morgan, J. W.↗

Lunar bulk sample trace element contents and KREEP.

The geochemical coherence of KREEP-related labile (Cl) and refractory (F, K, P, and REE) elements in lunar soils is shown to provide some insights into the evolution of the lunar samples studied. Thus, this coherence may help define the physical conditions under which the samples evolved. These conditions range from high temperatures and relatively open systems for mare basalts to moderate temperatures and closed systems for KREEP-related material. The water leachable Cl may be the residuum of the Cl-containing phase with which mare and KREEP source material equilibrated.

Reed, G. W., Jr.↗

A survey of the selenochemistry of major, minor and trace elements.

Average data for igneous and/or metaigneous rocks and soils from seven lunar sites are presented. There are compositional similarities between Apollo 11 and Luna 16 eastern maria, Ap 12 and 15 western maria, and between Ap 16 and L 20 highlands. Subtle differences do exist between the paired mare sites and the two highland sites and striking differences between the eastern and western maria. Chondritic normalized REE (rare earth element) patterns for igneous rocks and soils from all sites range from 7-350 generally with negative Eu anomalies. Anorthositic gabbroes to anorthosites, presumably highland material, exhibit a positive Eu anomaly. The REE patterns or Sr isotopic ratios suggest two lava flows each for the L 16 and Ap 14 sites, at least four lava flows for the Ap 11 and 12 site and about six for the Ap 15 site.

Schmitt, R. A.↗