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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1964

Vehicle Walks on Varied Terrain, Can Assist Handicapped Persons

The problem: Designing a vehicle capable of traversing varied terrain at moderate speeds (up to 4 miles per hour). Development of such a vehicle was originally undertaken to meet NASA requirements for a remotely controlled instrument carrier to be used for unmanned exploration of lunar and planetary surfaces. The solution: A battery-powered motorized vehicle with three pairs of legs that are connected to push rods and a series of linkages. How it's done: Locomotion of the basic vehicle is accomplished by three pairs of legs, one pair in the front and two pairs in the rear. Each leg consists of an upper horizontal portion, a middle vertical portion, and a foot. Two cams connected to the drive mechanism (a small motor, gearbox, and push rods) control the motion of the legs. The two outer rear legs move in unison with the right front leg, and the two inner rear legs move in unison with the left front leg. Each set of three legs is lifted to clear or rest on any expected obstacle on the terrain to be traversed by the vehicle and advanced a fixed distance for the succeeding step. A system of spring-loaded vertical-motion linkages permits obstacles (within design limitations) to be traversed with a minimum disturbance of the vehicle's axes. The linkages are arranged to permit the legs to be folded when the vehicle is stored. Steering is accomplished by a small motor, which swings the front pair of legs to the desired angle. The rear legs are connected by a differential linkage to compensate for the required variation in step length or speed between the right and left pairs of rear legs when turns are made.

Source record↗

DOE OSTI2026

Generating a stratocumulus-like cloud top in a convection-cloud chamber

Stratocumulus-topped boundary layers play a crucial role in influencing daily weather and earth energy balance. Entrainment at the stratocumulus cloud top affects the cloud’s lifetime, precipitation, and radiative properties, but our understanding remains limited due to the lack of resolution in both field observations and numerical simulations. A recently proposed convection-cloud chamber with detailed control of sidewall temperatures can provide a unique opportunity to explore this mechanism in a laboratory setting. In this work, we use numerical simulations to demonstrate that this design can produce a cloud top that mimics the entrainment interfacial layer in a stratocumulus cloud. Our results show that a steady-state cloud can be formed by cooling the lower portions of the sidewalls and warming the bottom surface, while a temperature inversion at the cloud top can be generated by keeping the upper sidewalls and top surface warmer than the bottom. The turbulent kinetic energy profile and budget are similar to those found in a convective boundary layer, and inhomogeneous mixing near the cloud top can be observed. These findings significantly enhance the scientific value of constructing the tall convection-cloud chamber.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1999

Thermal Control Replacement Materials Evaluated for Durability and Selected for the Hubble Space Telescope

During the Hubble Space Telescope (HST) second servicing mission, astronauts noticed that the outer layer of the multilayer insulation (MLI) was cracked in many locations around the telescope. The insulation s outer layer is composed of 5-mil (0.127 mm) Teflon FEP (DuPont; fluorinated ethylene propylene) with vapor-deposited aluminum (VDA) on the backside. The MLI blankets, which are used on over 80 percent of the external surface of the telescope, provide passive thermal control for equipment. Two large cracks were observed on the light shield directly above the high gain antenna. The upper light shield crack propagated from a cut placed in the blanket during installation around a handrail standoff. Two cracks propagated almost normal to each other, with the outer layer curling tightly as the cracks propagated. A second much larger vertical crack had started to curl and lift away from the telescope, as seen in the figure. MLI on the equipment bays was cracked extensively also, and in some areas it had pulled away from the bay. Continued degradation of the equipment bay insulation would potentially cause limited observations because of housekeeping boxes; for example, the data interface unit could overheat during some portions of the year, in certain sun angles.

deGroh, Kim K.↗

NASA NTRS1976

Chemical vapor deposition growth

A laboratory type CVD reactor system with a vertical deposition chamber and sample pedestal heated by an external RF coil has been extensively modified by installation of mass flow controllers, automatic process sequence timers, and special bellows-sealed air-operated valves for overall improved performance. Various film characterization procedures, including classical metallography, SEM analyses, X ray diffraction analyses, surface profilometry, and electrical measurements (resistivity, carrier concentration, mobility, spreading resistance profiles, and minority-carrier lifetime by the C-V-t method) area used to correlate Si sheet properties with CVD parameters and substrate properties. Evaluation procedures and measurements are given. Experimental solar cell structures were made both in epitaxial Si sheet (on sapphire substrates) and in polycrystalline material on alumina substrates, the former to provide an indication of what might be an upper limit on performance of the latter. Preliminary results are given, as obtained in cell structures not specially designed to allow for the unique properties of the sheet material, and fabricated in material known to be far from optimum for photovoltaic performance. Low power conversion efficiencies have been obtained in the epitaxial as well as the polycrystalline Si sheet.

Ruth, R. P.↗

NASA NTRS2004

Recent Climate Variability in Antarctica from Satellite-derived Temperature Data

Recent Antarctic climate variability on month-to-month to interannual time scales is assessed through joint analysis of surface temperatures from satellite thermal infrared observations (T(sub IR)) and passive microwave brightness temperatures (T(sub B)). Although Tw data are limited to clear-sky conditions and T(sub B) data are a product of the temperature and emissivity of the upper approx. 1m of snow, the two data sets share significant covariance. This covariance is largely explained by three empirical modes, which illustrate the spatial and temporal variability of Antarctic surface temperatures. T(sub B) variations are damped compared to TIR variations, as determined by the period of the temperature forcing and the microwave emission depth; however, microwave emissivity does not vary significantly in time. Comparison of the temperature modes with Southern Hemisphere (SH) 500-hPa geopotential height anomalies demonstrates that Antarctic temperature anomalies are predominantly controlled by the principal patterns of SH atmospheric circulation. The leading surface temperature mode strongly correlates with the Southern Annular Mode (SAM) in geopotential height. The second temperature mode reflects the combined influences of the zonal wavenumber-3 and Pacific South American (PSA) patterns in 500-hPa height on month-to-month timescales. ENSO variability projects onto this mode on interannual timescales, but is not by itself a good predictor of Antarctic temperature anomalies. The third temperature mode explains winter warming trends, which may be caused by blocking events, over a large region of the East Antarctic plateau. These results help to place recent climate changes in the context of Antarctica's background climate variability and will aid in the interpretation of ice core paleoclimate records.

Schneider, David P.↗

DOE OSTI2026

Witnessing Spin-Orbital Entanglement Using Resonant Inelastic X-Ray Scattering

Entanglement plays a central role in quantum technologies, yet its characterization and control in materials remain challenging. Recent developments in spectrum-based entanglement witnesses have enabled new strategies for quantifying many-body entanglement in macroscopic materials. Here, in this work, we develop a protocol for detecting spin-orbital entanglement using experiment-accessible resonant inelastic x-ray scattering. Central to our approach is the construction of a Hermitian generator from measurable spectra, which allows us to compute the quantum Fisher information (QFI) available in spin-orbital systems. The resulting QFI provides upper bounds for 𝑘-producible states and thus serves as a robust witness of spin-orbital entanglement. To account for realistic experimental limitations, we further extend our framework to include relaxed QFI bounds applicable to measurements lacking full polarization resolution.

entanglement detection↗

NASA NTRS1993

Subsonic aerodynamic characteristics of the HL-20 lifting-body configuration

The HL-20 is proposed as a possible future manned spacecraft. The configuration consists of a low-aspect-ratio body with a flat undersurface. Three fins (a small centerline fin and two outboard (tip) fins set at a dihedral angle of 50 deg) are mounted on the aft body. The control system consists of elevon surfaces on the outboard fins, a set of four body flaps on the upper and lower aft body, and an all-movable center fin. Both the elevons and body flaps were capable of trimming the model to angles of attack from -2 deg to above 20 deg. The maximum trimmed lift-drag ratio was 3.6. Replacing the flat-plate tip fins with airfoil tip fins increased the maximum trimmed lift-drag ratio to 4.2. The elevons were effective as a roll control, but they produced about as much yawing moment as rolling moment because of the tip-fin dihedral angle. The body flaps produced less rolling moment than the elevons and only small values of yawing moment. A limited investigation of the effect of varying tip-fin dihedral angle indicated that a dihedral angle of 50 deg was a reasonable compromise for longitudinal and lateral stability, longitudinal trim, and performance at subsonic speeds.

Ware, George M.↗

NASA NTRS1993

Telescience capability for the Sondre Stromfjord, Greenland, incoherent-scatter radar facility

SRI International (SRI) operates an upper-atmospheric research facility in Sondre Stromfjord (Sondrestrom), Greenland. In the past, the facility's remote location and limited logistical support imposed constraints on the research that could be carried out at the site. Campaigns involving multiple instruments were often constrained due to limited space, and experiments requiring coordination with other geographically separated facilities, though possible, were difficult. To provide greater access to the facility, an electronic connection between Sondrestrom and the mainland U.S.A. was established, providing access to the National Science Internet. SRI developed telescience software that sends data from the incoherent scatter radar at the Sondrestrom facility to SRI's offices in Menlo Park, California. This software uses the transmission control protocol (TCP/IP) to transmit the data in near real time between the two locations and the X window system to generate displays of the data in Menlo Park. This is in contrast to using the X window system to display data remotely across a wide-area network. Using CP to transport data over the long distance network has resulted in significantly improved network throughput and latency. While currently used to transport radar data, the telescience software is designed and intended for simultaneous use with other instruments at Sondrestrom and other facilities. Work incorporating additional instruments is currently in progress.

Zambre, Yadunath B.↗

DOE OSTI2024

Influence of Nb alloying on Nb recrystallization and the upper critical field of Nb 3 ⁢Sn

Nb 3 Sn conductors are important candidates for high-field magnets for particle accelerators, and they continue to be widely used for many laboratory and NMR magnets. However, the critical current density, J c , of present Nb 3 Sn conductors declines swiftly above 12-15 T. State-of-the-art Ta- and Ti-doped strands exhibit upper critical field, H c2 , values of ~ 24-26.5 T (4.2 K) and do not reach the FCC target J c , which serves as the present stretch target for Nb 3 Sn development. As recently demonstrated, to meet this goal requires enhanced vortex pinning but an independent and supplementary approach is to significantly enhance H c2 . In this study, we have arc-melted multiple Nb alloys with added Hf, Zr, Ta and Ti and drawn them successfully into monofilament wires to investigate the possibilities of H c2 enhancement through alloying. H c2 (T) was measured for all samples in fields up to 16 T and some up to 31 T. We have found that all alloys show good agreement with the standard Werthamer, Helfand, and Hohenberg (WHH) fitting procedure without the need to adjust the paramagnetic limitation parameter (α) and spin-orbit scattering parameter (λ so ). The evaluation of dH c2 /dT near T c , which is proportional to the electronic specific heat coefficient γ and the normal state resistivity ρn, allows a better understanding of the induced disorder introduced by alloying in the A15 phase. So far, we have observed that Hf alloying of pure Nb can enhance H c2 (0) by 3-4 T to ~28 T, while adding just 1 at. %Hf or Zr into a Nb4Ta base alloy can raise H c2 (0) to ~31 T. Very importantly we find that Hf and Zr raise the alloy recrystallization temperature above the usual A15 reaction temperature range of 650°C – 750°C, thus ensuring denser A15 phase nucleation in the Nb alloy grain boundaries, possibly leading to a more homogeneous A15 phase Sn content and refined A15 grain size. Furthermore, the potential for further advancements in Nb 3 Sn properties is explored in relation to the recrystallization of the Nb alloy and the factors controlling the upper critical field.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS2017

Mind the Gap: Exploring the Underground of the NASA Space Cancer Risk Model

The REID quantifies the lifetime risk of death from radiation-induced cancer in an exposed astronaut. The NASA Space Cancer Risk (NSCR) 2012 mode incorporates elements from physics, biology, epidemiology, and statistics to generate the REID distribution. The current model quantifies the space radiation environment, radiation quality, and dose-rate effects to estimate a NASA-weighted dose. This weighted dose is mapped to the excess risk of radiation-induced cancer mortality from acute exposures to gamma rays and then transferred to an astronaut population. Finally, the REID is determined by integrating this risk over the individual's lifetime. The calculated upper 95% confidence limit of the REID is used to restrict an astronaut's permissible mission duration (PMD) for a proposed mission. As a statistical quantity characterized by broad, subjective uncertainties, REID estimates for space missions result in wide distributions. Currently, the upper 95% confidence level is over 350% larger than the mean REID value, which can severely limit an astronaut's PMD. The model incorporates inputs from multiple scientific disciplines in the risk estimation process. Physics and particle transport models calculate how radiation moves through space, penetrates spacecraft, and makes its way to the human beings onboard. Epidemiological studies of exposures from atomic bombings, medical treatments, and power plants are used to quantify health risks from acute and chronic low linear energy transfer (LET) ionizing radiation. Biological studies in cellular and animal models using radiation at various LETs and energies inform quality metrics for ions present in space radiation. Statistical methodologies unite these elements, controlling for mathematical and scientific uncertainty and variability. Despite current progress, these research platforms contain knowledge gaps contributing to the large uncertainties still present in the model. The NASA Space Radiation Program Element (SRPE) defines the knowledge gaps that impact our understanding of the cancer risks. These gaps are outlined in NASA's Human Research Roadmap [4], which identifies the research questions and actions recommended for reducing the uncertainty in the current NSCR model and for formulation of future models. The greatest contributors to uncertainty in the current model include radiation quality, dose rate effects, and the transfer of exposure-based risk from other populations to an astronaut population. Future formulations of the risk model may benefit from including other potential sources of uncertainty such as space dosimetry, errors in human epidemiology data, and the impact of microgravity and other spaceflight stressors. Here, we discuss the current capabilities of the NSCR-2012 model and several immediate research needs, highlighting areas expected to have an operational impact on the current model schema. The following subway-style route map outlines the NSCR-2012 model (Green Line), emphasizing the research gaps in the Human Research Roadmap for risk of radiation-induced carcinogenesis (Stops on Dashed Lines). The map diagrams how these research gaps feed specific portions of the model.

Chappell, L. J.↗

DOE OSTI2020

Transport of coexisting Ni-Cu sulfide liquid and silicate melt in partially molten peridotite

Transport of coexisting sulfide and silicate melts in partially molten peridotite contributes to the redistribution of chalcophile elements within the upper mantle as well as the genesis of magmatic Ni-Cu sulfide deposits, but has not been investigated systematically. Using laboratory experiments, theoretical calculations, and X-ray synchrotron microtomography, this study documents the topology and considers controls on the extraction of two immiscible liquids during partial melting of mantle peridotite. Under hydrostatic conditions, the measured dihedral angle at silicate melt-mineral-mineral junctions is 13.7–21.3°. Silicate melt is distributed along grain edges forming incompletely interconnected melt channels that disconnected by some dead ends at melt fractions ~7–9 vol%. Application of theoretically predicted permeability (k ~10 -14 -10 -16 m 2 ) permits estimation of the extraction velocity of silicate melt of 0.7-11.1 μm/day within a single interconnected melt channel. In the absence of silicate melt, isolated sulfide droplets (3.77 vol%) show a sulfide-olivine-olivine dihedral angle of 91.5–101.3°. However, in the presence of silicate melt, sulfide droplets (average size ~2.53±2.14μm, 1σ) are partially surrounded by silicate melt and stranded in triple junctions or melt pockets due to the limitation of the smallest dimension (0.3μm) of melt channels. Thus, the extraction of sulfide liquid is highly restricted by these dead ends and the smallest dimension of melt channels during porous flow of silicate melt. In contrast, during large-strain shear deformation (strain ~1.6–2.5), initially stranded sulfide droplets were elongated and extracted with silicate melt into liquid-rich sheets with a length of several hundred microns, constantly oriented at 14.3±4.5°to the shear plane and antithetic to the shear direction. The angle is lower than that (18-30°) of those sheets containing sulfide liquid only, indicating that silicate melt dominates liquid-rich sheets. Driven by stress, silicate melt-dominated liquid-rich sheets open the appropriately oriented grain boundaries between silicate minerals, thus providing an efficient pathway for the extraction of sulfide liquid during deformation. When such sheet-like channels remain open, sulfide droplets (> millimeter-scale) can be potentially mobile through high strain domains of the upper mantle, contributing to the addition of chalcophile elements and the fertilization of the lithospheric mantle.

high P-T experiment↗

DOE OSTI2026

Networks of electrochemical oxidation of common lithium-ion Battery solvents revealed by NMR spectroscopy

Raising the upper cutoff voltage of lithium-ion batteries (LIBs) to increase energy density often exceeds the electrolyte’s anodic stability limit, accelerating degradation and creating a major durability tradeoff. Designing electrolytes that can sustain long-term high-voltage cycling requires a clearer understanding of the fundamental mechanisms occurring when commercial carbonate solvents oxidize. Here, to this end, simplified single-salt, single-solvent formulations of LiClO 4 and LiPF 6 in dimethyl carbonate (DMC), ethylene carbonate (EC), or ethyl methyl carbonate (EMC) were anodically electrolyzed on inert electrodes and monitored for extended periods of time using 1 H, 13 C, 19 F, and 35 Cl nuclear magnetic resonance (NMR) spectroscopy. The controlled environment of the experiments, coupled to the unique sensitivity of NMR, unveiled novel metastable intermediates and the formation of branching networks of products with temporal evolution. Oxidation of the pristine solvent primarily proceeds through a radical pathway that also produces highly reactive protons but faces competition from a second pathway involving a radical carbocation intermediate. In all cases, the intermediates follow a variety of downstream pathways that can intersect with each other. The concomitant network of reactions represents a significant increase in complexity compared to common descriptions in the literature, yet, critically, it helps explain the wide range of products typically identified in electrolyte oxidation in complete cells. The results highlight the need for refocusing fundamental research on anodic stability to analysis of the hierarchy of reaction networks to better inform efforts to mitigate the detrimental effects on battery performance, including prevention and harvesting of proton and radical products.

Electrolytes↗

NASA NTRS1987

Self-regulating heater application to Shuttle/Centaur hydrazine fuel line thermal control

The Shuttle/Centaur high energy upper stage vehicle thermal environments were more severe than previous Centaur vehicle thermal environments, creating need for a new hydrazine fuel line thermal control technique. Constant power heaters did not satisfy power dissipation requirements, because the power required to maintain fuel line thermal control during cold conditions exceeded the maximum power allowable during hot conditions. Therefore, a Raychem Thermolimit self-regulating heater was selected for this application, and was attached to the hydrazine fuel line with Kapton and aluminum foil tapes. Fuel line/heater thermal modeling and subsequent thermal vacuum chamber testing simulated heater thermal performance during all worst-case Shuttle/Centaur thermal environmental conditions. Fuel line temperatures were maintained between the 4C to 71C limits during all analytical and test cases. Finally, the thermal model predictions were correlated with the test data, thereby ensuring that the model would provide satisfactory predictions for future missions and/or vehicles.

Unkrich, David B.↗

DOE OSTI2023

Nuclear-Level Effective Theory of 𝜇 → 𝑒 Conversion

The Mu2e and COMET 𝜇 → 𝑒 conversion experiments are expected to significantly advance limits on new sources of charged lepton flavor violation. Almost all theoretical work in the field has focused on just two operators. However, general symmetry arguments lead to a 𝜇 → 𝑒 conversion rate with six response functions, each of which, in principle, is observable by varying nuclear properties of targets. We construct a nucleon-level nonrelativistic effective theory (NRET) to clarify the microscopic origin of these response functions and to relate rate measurements in different targets. This exercise identifies three operators and their small parameters that control the NRET operator expansion. We note inconsistencies in past treatments of these parameters. The NRET is technically challenging, involving 16 operators, several distorted electron partial waves, bound muon upper and lower components, and an exclusive nuclear matrix element. We introduce a trick for treating the electron Coulomb effects accurately, which enables us to include all of these effects while producing transition densities whose one-body matrix elements can be evaluated analytically, greatly simplifying the nuclear physics. We derive bounds on operator coefficients from existing and anticipated 𝜇 → 𝑒 conversion experiments. We discuss how similar NRET formulations have impacted dark matter phenomenology, noting that the tools this community has developed could be adapted for charged lepton flavor violation studies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS2015

Robonaut 2 - Building a Robot on the International Space Station

In 2010, the Robonaut Project embarked on a multi‐phase mission to perform technology demonstrations on‐board the International Space Station (ISS), showcasing state of the art robotics technologies through the use of Robonaut 2 (R2). This phased approach implements a strategy that allows for the use of ISS as a test bed during early development to both demonstrate capability and test technology while still making advancements in the earth based laboratories for future testing and operations in space. While R2 was performing experimental trials onboard the ISS during the first phase, engineers were actively designing for Phase 2, Intra‐Vehicular Activity (IVA) Mobility, that utilizes a set of zero‐g climbing legs outfitted with grippers to grasp handrails and seat tracks. In addition to affixing the new climbing legs to the existing R2 torso, it became clear that upgrades to the torso to both physically accommodate the climbing legs and to expand processing power and capabilities of the robot were required. In addition to these upgrades, a new safety architecture was also implemented in order to account for the expanded capabilities of the robot. The IVA climbing legs not only needed to attach structurally to the R2 torso on ISS, but also required power and data connections that did not exist in the upper body. The climbing legs were outfitted with a blind mate adapter and coarse alignment guides for easy installation, but the upper body required extensive rewiring to accommodate the power and data connections. This was achieved by mounting a custom adapter plate to the torso and routing the additional wiring through the waist joint to connect to the new set of processors. In addition to the power and data channels, the integrated unit also required updated electronics boards, additional sensors and updated processors to accommodate a new operating system, software platform, and custom control system. In order to perform the unprecedented task of building a robot in space, extensive practice sessions and meticulous procedures were required. Since crew training time is at a premium, the R2 team took a skills‐based training approach to ensure the astronauts were proficient with a basic skill set while refining the detailed procedures over several practice sessions and simulations. In addition to the crew activities, meticulous ground procedures were required in order to upgrade firmware on the upper body motor drivers. The new firmware for the IVA mobility unit needed to be deployed using the old software system. This also provided an opportunity to upgrade the upper body joints with new software and allowed for limited insight into the success of the updates. Complete verification that the updated firmware was successfully loaded was not confirmed until the rewiring of the upper body torso was complete.

Diftler, Myron↗

NASA NTRS1979

Application of the relative energy release criteria to enclosure fire testing

The five relative energy release criteria (RERC) which are a first step towards formulating a unified concept that can be applied to the development of fires in enclosures, place upper bounds on the rate and amount of energy released during a fire. They are independent, calculated readily, and may be applied generally to any enclosure regardless of size. They are useful in pretest planning and for interpreting experimental data. Data from several specific fire test programs were examined to evaluate the potential use of RERC to provide test planning guidelines. The RERC were compared with experimental data obtained in full-scale enclosures. These results confirm that in general the RERC do identify the proper limiting constraints on enclosure fire development and determine the bounds of the fire development envelope. Plotting actual fire data against the RERC reveals new valid insights into fire behavior and reveals the controlling constraints in fire development. The RERC were calculated and plotted for several descrpitions of full-scale fires in various aircraft compartments.

Roschke, E. J.↗

NASA NTRS1998

A Plasma Drag Hypervelocity Particle Accelerator (HYPER)

Current debris models are able to predict the growth of the space debris problem and suggest that spacecraft must employ armor or bumper shields for some orbital altitudes now and that the problem will become worse as a function of time. The practical upper limit to the velocity distribution is on the order of 40 km/s and is associated with the natural environment. The velocity distribution of the man-made component peaks at 9-10 km/s with maximum velocity in the 14-16 km/s range. Experience in space has verified that the "high probability of impact" particles are in the microgram to milligram range. These particles can have very significant effects on coatings, insulators, and thin metallic layers. The surface of thick materials becomes pitted and the local debris component is enhanced by ejecta from the impact events. In this paper, the HYPER facility is described which produces a reasonable simulation of the man-made space debris spectrum in a controlled environment. The facility capability is discussed in terms of drive geometry, energetics, velocity distribution, diagnostics, and projectile/debris loading. The facility has been used to study impact phenomena on Space Station Freedom's solar array structure, the calibration of space debris collectors, other solar array materials, potential structural materials for use in space, electrical breakdown in the space environment, and as a means of clarifying or duplicating the impact phenomena on surfaces which have been exposed in space.

Best, Steve R.↗

NASA NTRS2006

Chemical Characterization and Thermal Stressing Studies of Perfluorohexane Fluids for Space-Based Applications

Perfluorohexane (PFH), C6F14, is a perfluorocarbon fluid. Several PFH fluids with different isomer concentrations were evaluated for use in an upcoming NASA space experiment. Samples tested included two commercially obtained high-purity n-perfluorohexane (n-PFH) fluids and a technical grade mixture of C6F14 branched and linear isomers (FC-72(TradeMark)). These fluids were evaluated for exact chemical composition, impurity purity and high temperature degradation behavior (pyrolysis). Our investigation involved simulated thermal stressing studies of PFH fluids under conditions likely to occur in the event of an atmospheric breach within the International Space Station (ISS) and subsequent exposure of the vapors to the high temperature and catalyst present in its Trace Contaminant Control Subsystem (TCCS). Exposure to temperatures in the temperature range of 200-450 C in an inert or oxidizing atmosphere, with and without the presence of catalyst was investigated. The most aggressive conditions studied were exposure of PFH vapors to 450 C in air and in the presence of TCCS (palladium) catalyst. Gas chromatography-mass spectrometry (GC-MS) and gas chromatography (GC) analyses were conducted on the perfluorohexane samples before and after pyrolysis. The FC-72 and n-PFH samples showed no significant degradation following pyrolysis even under the most aggressive study conditions. Some trace level impurities associated with the PFH samples such as linear perfluorocarbon monohydrides or monoiodides were destroyed by pyrolysis at the upper limit. Other trace level impurities such as olefinic or cycloolefinic perfluorocarbons were converted into oxidation products by pyrolysis. The purity of PFH following pyrolysis actually increased slightly as a consequence since these trace contaminants were effectively scrubbed from the samples. However, since the initial concentrations of the thermally-impacted impurities were so low, the net effect was trivial. A potential byproduct of exposure of perfluorohexane fluids to high temperatures is the production of perfluoroisobutene (PFiB), which is extremely toxic. An ultra-high sensitivity PFiB-specific analysis based on GC-MS with negative ion chemical ionization (NICI) detection was used to evaluate the samples following thermal stressing. The perfluorohexanes examined here under conditions reflective of the ISS TCCS environment showed no signs of PFiB production with an analytical detection limit of 10 part per billion (ppb v/v).

Arnold, William A.↗