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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

The ISOCAM field-of-view distortion correction

We describe results from new re-analysis of the ISOCAM field-of-view distortion. In this contribution we describe the procedure for determining the distortion, the implentation and resulting effects on the ISOCAM astrometric measurements, mosaicking and flux calibration.

ISOCAM field-of-view distortion 2MASS↗

Optimal 3D Viewing with Adaptive Stereo Displays for Advanced Telemanipulation

A method of optimal 3D viewing based on adaptive displays of stereo images is presented for advanced telemanipulation. The method provides the viewer with the capability of accurately observing a virtual 3D object or local scene of his/her choice with minimum distortion.

3D viewing advanced telemanipulation telemanipulat↗

The Earth Viewed as a Deforming Polyhedron: Method and Results

GPS is quite unlike any other geodetic technique, because we can use it to look at the Earth with high spatial and temporal resolution. For example, the GPS global network provides us with a daily snapshot of the Earth, allowing us to look with high temporal resolution at the motion of sites before, during, and after a large earthquake.The main focus of this paper is to view the Earth as an evolving polyhedron, whose vertices are defined by the GPS sites.

GPS global network GPS GPS sites deforming polyhed↗

MISR CMVs and Multiangular Views of Tropical Cyclone Inner-Core Dynamics

Multi-camera stereo imaging of cloud features from the MISR (Multiangle Imaging SpectroRadiometer) instrument on NASA's Terra satellite provides accurate and precise measurements of cloud top heights (CTH) and cloud motion vector (CMV) winds. MISR observes each cloudy scene from nine viewing angles (Nadir, +/-26(sup o), +/-46(sup o), +/-60(sup o), +/-70(sup o)) with approximatel 275-m pixel resolution. This paper provides an update on MISR CMV and CTH algorithm improvements, and explores a high-resolution retrieval of tangential winds inside the eyewall of tropical cyclones (TC). The MISR CMV and CTH retrievals from the updated algorithm are significantly improved in terms of spatial coverage and systematic errors. A new product, the 1.1-km cross-track wind, provides high accuracy and precision in measuring convective outflows. Preliminary results obtained from the 1.1-km tangential wind retrieval inside the TC eyewall show that the inner-core rotation is often faster near the eyewall, and this faster rotation appears to be related linearly to cyclone intensity.

hurricanes↗

SNPP and N20 VIIRS Solar Vector Orientation Knowledge Error Detected by SDSM Sun Views

The Visible Infrared Imaging Radiometer Suite (VIIRS) is a passive scanning Earth observing satellite radiometer. The VIIRS has 22 spectral bands with design center wavelengths from 0.41 to 12.01 μm, providing data to generate more than 20 Earth’s biogeophysical parameters. Fourteen of the 22 VIIRS bands are the reflective solar bands (RSBs), detecting Earth reflected sunlight. To ensure data quality, regular on-orbit radiometric calibrations of the RSBs are performed, mainly through observations of an onboard solar diffuser (SD). The spectral radiance provided by the sunlit SD depends on the SD screen transmittance which is a function of the solar vector orientation. Additionally, on orbit the SD’s bidirectional reflectance distribution function (BRDF) changes its value due to solar bombardment. The BRDF change is derived from the SD stability monitor (SDSM) measurements. The SDSM views the Sun through a screen with through holes (the SDSM screen) and the SD at almost the same time. The time series of the ratio of the signal strengths is a measure of the SD BRDF on-orbit change. Hence the measurements of the on-orbit SD BRDF change depends on the SDSM screen relative transmittance which is also solar vector orientation dependent. In this paper for both the SNPP and the NOAA-20 VIIRS instruments we examine the solar vector orientation knowledge error through matching the SDSM screen relative effective transmittances derived from the calibration data collected on the yaw maneuver and the regular orbits.

SNPP↗

Single Field-of-View Sounding Atmospheric Products

The Single Field-of-view Sounder Atmospheric Products (SiFSAP) answer the need for a novel high spatial resolution atmospheric data product for major hyper-spectral infrared (IR) sounder missions. SiFSAP include a complete set of atmospheric vertical profiles, cloud, and surface properties, which are physically retrieved from top-of-atmosphere (TOA) spectral radiances under all-sky conditions via a rigorously defined radiative transfer relationship. By using a state-of-art fast radiative transfer model and a carefully designed optimal estimation based physical retrieval scheme, the SiFSAP algorithm ensures both an ultra-fast data processing speed needed for operational weather applications and the radiometric consistency desired by long-term climate studies. SiFSAP supplement existing operational products by providing data at the native spatial resolution of the sounder instruments, the direct and accurate retrieval of cloud scattering properties, and the establishment of ‘radiance closure.’

single-field-of-view, retrieval, hyperspectral sou↗

Observation of Deep Convective Cloud-Top Height and Vertical Temperature Structure of Hurricane Using Hyperspectral Infrared Sounder and its Single-Field-View Retrieval Products

A new method utilizing hyperspectral infrared sounders is developed to estimate cloud top height (CTH) for deep convective clouds from hurricane, or tropical cyclone (TC). By analyzing measurements from the Cross-track Infrared Sounder (CrIS), and further validating with radiative transfer simulations, we identified an inverted-V spectral feature in the ozone (O3) band near 9.6 μm, which correlates with deep convective clouds. The depth of this feature can be used to estimate the CTH of a TC's eyewall and surrounding rain bands. This approach effectively captures the cloud structure of the TC. Additionally, a new single Field of View sounder products (SiFSAP), derived from CrIS and the Advanced Technology Microwave Sounder (ATMS), will be used to analyze the vertical temperature and water vapor structure, offering more insights into TC dynamics.

Single-field-view retrieval↗

Comparison of Machine Learning and Deep Learning for View Identification from Cardiac Magnetic Resonance Images

Background: Artificial intelligence is increasingly utilized to aid in the interpretation of cardiac magnetic resonance (CMR) studies. One of the first steps is the identification of the imaging plane depicted, which can be achieved by both deep learning (DL) and classical machine learning (ML) techniques without user input. We aimed to compare the accuracy of ML and DL for CMR view classification and to identify potential pitfalls during training and testing of the algorithms. Methods: To train our DL and ML algorithms, we first established datasets by retrospectively selecting 200 CMR cases. The models were trained using two different cohorts (passively and actively curated) and applied data augmentation to enhance training. Once trained, the models were validated on an external dataset, consisting of 20 cases acquired at another center. We then compared accuracy metrics and applied class activation mapping (CAM) to visualize DL model performance. Results: The DL and ML models trained with the passively-curated CMR cohort were 99.1% and 99.3% accurate on the validation set, respectively. However, when tested on the CMR cases with complex anatomy, both models performed poorly. After training and testing our models again on all 200 cases (active cohort), validation on the external dataset resulted in 95% and 90% accuracy, respectively. The CAM analysis depicted heat maps that demonstrated the importance of carefully curating the datasets to be used for training. Conclusions: Both DL and ML models can accurately classify CMR images, but DL outperformed ML when classifying images with complex heart anatomy.

artificial intelligence↗

Importance of viewing angle: Hotspot effect improves the ability of satellites to track terrestrial photosynthesis

The product of near-infrared reflectance of vegetation and photosynthetic active radiation (NIRvP) is a new tool for monitoring gross primary productivity (GPP) dynamics in terrestrial ecosystems, due to the discovered linear correlation between NIRvP and GPP. While remote sensing-based NIRvP is considerably influenced by sensor geometry, such geometry impacts on the NIRvP-GPP relationship remain underexplored. In this study, we calculate NIRvP using observations from the Deep Space Climate Observatory (DSCOVR) that provide unique hotspot observation geometry in which the sensor viewing angle coincides with the sun direction. We evaluated the linear correlation between NIRvP and GPP in both the common nadir direction and the special hotspot direction. The results indicate that NIRvP in the hotspot direction significantly outperforms that in the nadir direction for tracking GPP variations across different ecosystems from diurnal to daily scales. This conclusion is further supported by data from the MODerate resolution Imaging Spectroradiometer (MODIS) and simulations using the Soil Canopy Observation Photosynthesis Energy (SCOPE) model. Finally, our research highlights the value of using the unconventional hotspot-based sun-tracking satellite observations for a more accurate characterization of GPP dynamics in terrestrial ecosystems.

54 ENVIRONMENTAL SCIENCES↗

Atomic-Scale View of Redox Induced Changes for Monolayer MoO x on α-TiO 2 (110) with Chemical-State Sensitivity

Supported molybdenum oxide (MoO x ) plays an important role in catalytic transformations from alcohol dehydrogenation to transesterification. During these reactions, Mo and oxygen surface species undergo structural and chemical changes. A detailed, chemical-state specific, atomic-scale structural analysis of the catalyst under redox conditions is important for improving catalytic properties. In this study, monolayer of MoO x grown on α-TiO 2 (110) by atomic-layer deposition is analyzed by X-ray standing wave (XSW) excited X-ray photoelectron spectroscopy (XPS). The chemical shifts for Mo 2p 3/2 and O 1s peaks are used to distinguish Mo 6+ from Mo 4+ and surface O from bulk O. Excitation of XPS by XSW allows pin-pointing the location of these surface species relative to the underlying substrate lattice. Finally, measured 3D composite atomic density maps for the oxidized and reduced interfaces compare well with our density functional theory models, and collectively create a unique view of the redoxdriven dynamics for this complex catalytic structure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Molecular View of Methane Activation on Ni(111) through Enhanced Sampling and Machine Learning

A combination of machine learned interatomic potentials (MLIPs) and enhanced sampling simulations is used to investigate the activation of methane on a Ni(111) surface. The work entails the development and iterative refinement of MLIPs, initially trained on a dataset constructed via ab initio molecular dynamics (AIMD) simulations, supplemented by adaptive biasing forces, to enrich the sampling of catalytically relevant configurations. Our results reveal that by incorporating collective variables that capture the behavior of the reactant molecule, as well as additional frames that describe the dynamic response of the catalytic surface, it is possible to enhance considerably the accuracy of predicted energies and forces. By employing enhanced sampling schemes in the refinement of the MLIP, we systematically explore the potential energy surface, leading to a refined MLIP capable of predicting DFT-level energies and forces and replicating key geometric characteristics of the catalytic system. The resulting free energy landscapes at several temperatures provide a detailed view of the thermodynamics and dynamics of methane activation. Specifically, as methane approaches and dissociates on the catalytic surface, the process involves the dynamic interplay of CH 4 and the Ni catalyst that includes both enthalpic and entropic contributions. The progression towards the transition state involves an CH 4 moiety that is increasingly restrained in its ability to rotate or translate, while the stage following the transition state is characterized by a notable rise of the Ni atom that interacts with the cleaved C–H bond. Furthermore, this leads to an increase in the mobility of the adsorbed species, a feature that becomes more pronounced at higher temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nanoscale View of Engineered Massive Dirac Quasiparticles in Lithographic Superstructures

Massive Dirac fermions are low-energy electronic excitations characterized by a hyperbolic band dispersion. They play a central role in several emerging physical phenomena such as topological phase transitions, anomalous Hall effects, and superconductivity. This work demonstrates that massive Dirac fermions can be controllably induced by lithographically patterning superstructures of nanoscale holes in a graphene device. Their band dispersion is systematically visualized using angle-resolved photoemission spectroscopy with nanoscale spatial resolution. A linear scaling of effective mass with feature sizes is reported, underlining the Dirac nature of the superstructures. In situ electrostatic doping dramatically enhances the effective hole mass and leads to the direct observation of an electronic band gap that results in a peak-to-peak band separation of 0.64 ± 0.03 eV, which is shown via first-principles calculations to be strongly renormalized by carrier-induced screening. The methodology demonstrates band structure engineering guided by directly viewing structurally and electrically tunable massive Dirac quasiparticles in lithographic superstructures at the nanoscale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Surface Terminations of LaAlO 3 Perovskite Nanoparticles as Viewed by Solid-State Nuclear Magnetic Resonance

Nanocrystal surfaces generally undergo reconstructions that differentiate them from the bulk structures, often in nontrivial ways. Understanding these terminations is critical across diverse fields, from heterogeneous catalysis to the formation of topological states and the synthesis of semiconductor nanomaterials. Determining surface structures is currently an interdisciplinary task, most often involving high-resolution electron microscopy and surface electron diffraction. These methods, however, do not provide a global view of the ensemble of structures present in a sample. Here, we show how surface-sensitive solid-state nuclear magnetic resonance (SSNMR) spectroscopy methods can bridge this gap. In this context, we investigated the surface structure of lanthanum aluminate (LaAlO 3 ) perovskite nanoparticles. Four distinct surface terminations have previously been observed for this material, but their relative abundances were unknown. Using an array of double- and triple-resonance SSNMR methods probing the relative proximities of surface 1 H, 27 Al, 17 O, and 139 La nuclei, we conclude the surface to be majority terminated (80%) by AlO x with substantial (20%) LaO x terminated regions.

Materials↗

Epidural anesthesia needle guidance by forward-view endoscopic optical coherence tomography and deep learning

Epidural anesthesia requires injection of anesthetic into the epidural space in the spine. Accurate placement of the epidural needle is a major challenge. To address this, we developed a forward-view endoscopic optical coherence tomography (OCT) system for real-time imaging of the tissue in front of the needle tip during the puncture. We tested this OCT system in porcine backbones and developed a set of deep learning models to automatically process the imaging data for needle localization. A series of binary classification models were developed to recognize the five layers of the backbone, including fat, interspinous ligament, ligamentum flavum, epidural space, and spinal cord. The classification models provided an average classification accuracy of 96.65%. During puncture, it is important to maintain a safe distance between the needle tip and the dura mater. Regression models were developed to estimate that distance based on the OCT imaging data. Based on the Inception architecture, our models achieved a mean absolute percentage error of 3.05% ± 0.55%. Overall, our results validated the technical feasibility of using this novel imaging strategy to automatically recognize different tissue structures and measure the distances ahead of the needle tip during the epidural needle placement.

60 APPLIED LIFE SCIENCES↗