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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Residual strength of repaired graphite/epoxy laminates after 5 years of outdoor exposure

The NASA Langley Research Center has sponsored research to develop generic repair techniques and processes for advanced graphite/epoxy (Gr/Ep) composites applicable to secondary structures for commercial transport aircraft. The long-term durability of such repairs is being addressed in a 10-year outdoor exposure program at the Langley Research Center. Details of the program and results of residual strength tests after 5 years of outdoor exposure are presented. Four repair methods are being evaluated. These include: (1) externally bolted aluminum-plus adhesive; (2) precured, bonded external Gr/Ep; (3) cure-in-place external Gr/Ep; and (4) cure-in-place flush Gr/Ep. Repaired specimens as well as undamaged and damaged unrepaired controls are being exposed outdoors for 1, 3, 5, 7, and 10 years. The residual tensile strength of stressed, unstressed, and fatigue specimens from each group is reported and compared with the tensile strength of baseline specimens which received no outdoor exposure. Identification of the commercial products and companies is used to describe adequately the test materials. The identification of these commercial products does not constitute endorsement, expressed or implied, of such products by the National Aeronautics and Space Administration.

Deaton, Jerry W.↗
NASA NTRS1991

Cloud screening Coastal Zone Color Scanner images using channel 5

Clouds are removed from Coastal Zone Color Scanner (CZCS) data using channel 5. Instrumentation problems require pre-processing of channel 5 before an intelligent cloud-screening algorithm can be used. For example, at intervals of about 16 lines, the sensor records anomalously low radiances. Moreover, the calibration equation yields negative radiances when the sensor records zero counts, and pixels corrupted by electronic overshoot must also be excluded. The remaining pixels may then be used in conjunction with the procedure of Simpson and Humphrey to determine the CZCS cloud mask. These results plus in situ observations of phytoplankton pigment concentration show that pre-processing and proper cloud-screening of CZCS data are necessary for accurate satellite-derived pigment concentrations. This is especially true in the coastal margins, where pigment content is high and image distortion associated with electronic overshoot is also present. The pre-processing algorithm is critical to obtaining accurate global estimates of pigment from spacecraft data.

Eckstein, B. A.↗
NASA NTRS1992

An experimental/computational study of sharp fin induced shock wave/turbulent boundary layer interactions at Mach 5 - Experimental results

A combined experimental/computational study has been performed of sharp fin induced shock wave/turbulent boundary layer interactions at Mach 5. The current paper focuses on the experiments and analysis of the results. The experimental data include mean surface heat transfer, mean surface pressure distributions and surface flow visualization for fin angles of attack of 6, 8, 10, 12, 14 and 16-degrees at Mach 5 under a moderately cooled wall condition. Comparisons between the results and correlations developed earlier show that Scuderi's correlation for the upstream influence angle (recast in a conical form) is superior to other such correlations in predicting the current results, that normal Mach number based correlations for peak pressure heat transfer are adequate and that the initial heat transfer peak can be predicted using pressure-interaction theory.

Rodi, Patrick E.↗
NASA NTRS1992

The molecular hydrogen emission around L1551 IRS 5 - Shock-heated molecular gas at the base of the molecular outflow

Spatially resolved observations of the v = 1-0 S(1) molecular hydrogen emission toward L1551 IRS 5 using the grating spectrometer at KPNO are presented. The S(1) emission consists of a ridge component extending toward west along the optical jet from its peak on IRS 5 and a diffuse component which traces the innermost region of the cavity enclosed by the molecular outflow. The ridge component represents shock-heated molecular gas at the root of the optical jet. The diffuse component is too bright to be of scattered origin; it most likely arises from shock-heated gas within the cavity and could represent an acceleration process of the molecular outflow.

Yamashita, Takuya↗
NASA NTRS1992

Radiative lifetime of the 3s3p exp 3(exp 5 S sub 2 exp 0) metastable level of P(+)

The present experimental and theoretical results for the radiative lifetime of the 3s3p exp 3(exp 5 S sub 2 exp 0) metastable level of P(+) encompass an experimental determination of the (exp 5 S sub 2 exp 0) lifetime which represents the first measured lifetime of a low charge-state ion in the Si I sequence. This constitutes a fundamental test of the theoretical methods used to determine transition possibilities for intercombination lines involving this level, and suggests that theoretical techniques used to determine such transition probabilities in low-Z species of the Si I isoelectronic sequence should be reevaluated.

Calamai, Anthony G.↗
NASA NTRS1987

Hard x ray (soft gamma ray) bursts and the 1979 March 5 transient

A series of transients from the galactic bulge direction was observed to have energies intermediate between the x-ray burst and the gamma-ray burst domain. The events are distinct from the 'classical' gamma-ray bursts both in their repeating nature and in their characteristic energy; they are also very brief in duration. This brings to possibly four the historic total number of observed transient series of this type, including the 1979 March 5 event and its sequels, from the direction of N49 in the Large Magellanic Cloud (LMC), and Mazets' B1900+14 series and Babushkina's decade-old observation, both from the galactic disk. It is suggested that these repeaters, unlike the classical bursts with an isotropically distributed source pattern, have sources specifically in high-density galactic and the LMC regions. The evident similarity to the source distributions of x-ray binaries, infrared objects, and visible stars is discussed. The relative intensities and size spectra, the relationship to the anomalous 1979 March 5 event, and other considerations are outlined.

Cline, T. L.↗
NASA NTRS1992

The structure and energetics of Cr(CO)6 and Cr(CO)5

The geometric structure of Cr(CO)6 is optimized at the modified coupled pair functional (MCPF), single and double excitation coupled-cluster (CCSD) and CCSD(T) levels of theory (including a perturbational estimate for connected triple excitations), and the force constants for the totally symmetric representation are determined. The geometry of Cr(CO)5 is partially optimized at the MCPF, CCSD, and CCSD(T) levels of theory. Comparison with experimental data shows that the CCSD(T) method gives the best results for the structures and force constants, and that remaining errors are probably due to deficiencies in the one-particle basis sets used for CO. The total binding energies of Cr(CO)6 and Cr(CO)5 are also determined at the MCPF, CCSD, and CCSD(T) levels of theory. The CCSD(T) method gives a much larger total binding energy than either the MCPF or CCSD methods. An analysis of the basis set superposition error (BSSE) at the MCPF level of treatment points out limitations in the one-particle basis used. Calculations using larger basis sets reduce the BSSE, but the total binding energy of Cr(CO)6 is still significantly smaller than the experimental value, although the first CO bond dissociation energy of Cr(CO)6 is well described. An investigation of 3s3p correlation reveals only a small effect. In the largest basis set, the total CO binding energy of Cr(CO)6 is estimated to be 140 kcal/mol at the CCSD(T) level of theory, or about 86 percent of the experimental value. The remaining discrepancy between the experimental and theoretical value is probably due to limitations in the one-particle basis, rather than limitations in the correlation treatment. In particular an additional d function and an f function on each C and O are needed to obtain quantitative results. This is underscored by the fact that even using a very large primitive set (1042 primitive functions contracted to 300 basis functions), the superposition error for the total binding energy of Cr(CO)6 is 22 kcal/mol at the MCPF level of treatment.

Barnes, Leslie A.↗
NASA NTRS1992

Oligomerization reactions of ribonucleotides - The reaction of the 5'-phosphorimidazolide of nucleosides on montmorillonite and other minerals

The reaction of ImpA in the presence of Na(+)-montmorillonite 22A or Na(+)-Volclay in aqueous, pH 8 solution gives a 50-60 percent yield of dimers and trimers (pA)2 and (pA)3. The ratio of 3',5'-phosphodiester bond formation is twice as great as 2',5'-bond formation. The reaction requires the presence of Mg2+ and is inhibited by 0.4 M imidazole. N-methylimidazole enhances the rate of the reaction but does not cause major changes in yield or product composition. Higher yields were obtained when Li+- or Ca2+-montmorillonites were used in place of Na+-montmorillonite. Little or no phosphodiester bond formation was observed with Mg2+- or Al3+-montmorillonite. Montmorillonites other than 22A and Volclay exhibited litle or no catalysis. In addittion, little or no catalysis was exhibited in ferrugenous smectite, nontronite, allophane, imogolite or sepiolite. Oligomers were also formed by the reaction of ImpG, 2-methylImpG, ImpC and ImpU in the presence of Na+-montmorillonite. The pyrimidine nucleotides gave significantly lower yields of oligomers.

Ferris, James P.↗
NASA NTRS1991

Unexpectedly facile synthesis of symmetrical P1,P2-dinucleoside-5'pyrophosphates

Symmetrical dinucleoside 5'-pyrophosphates have been synthesized from the corresponding nucleoside 5'-phosphate free acid in high yield. The one-pot procedure is carried out in DMF or DMSO using triphenylphosphine and 2,2'-dipyridyldisulfide as the coupling agents, and 1-methylimidazole as the catalyst.

Kanavarioti, Anastassia↗
NASA NTRS1991

5-year lifetime hybrid superfluid helium dewar for the AXAF X-Ray Spectrometer (XRS)

The focal plane of the AXAF X-Ray Spectrometer requires an operating temperature of 0.1 K with a mission lifetime of 5 yrs. This demanding task is accomplished with a hybrid cryogenic subsystem consisting of mechanical coolers, a superfluid helium dewar and an adiabatic demagnetization refrigerator. By using mechanical coolers to remove heat from the dewar outer vapor-cooled shield, a 5-yr lifetime is achievable with only a 483-liter tank. This approach takes advantage of flight-proven, high-performance dewar technology and recent success in the development of split, Stirling-cycle mechanical coolers. Although the dewar design principles are similar to those used previously, parasitic heat flow is reduced to a new level by an optimized tension strap support system and careful attention to insulation system details. The benefit of the mechanical coolers is maximized by dewar interface design features that minimize parasitic heating and thermal impedance of the coupling. The dewar design and thermal performance analysis are discussed. Helium lifetime sensitivities and the effects of mechanical cooler failures are predicted.

Nieczkoski, Stephen J.↗
NASA NTRS1993

In-stream measurements of combustion during Mach 5 to 7 tests of the Hypersonic Research Engine (HRE)

Results of in-stream combustion measurements taken during Mach 5 to 7 true simulation testing of the Hypersonic Research Engine/Aerothermodynamic Integration Model (HRE/AIM) are presented. These results, the instrumentation techniques, and configuration changes to the engine installation that were required to test this model are described. In test runs at facility Mach numbers of 5 to 7, an exhaust instrumentation ring which formed an extension of the engine exhaust nozzle shroud provided diagnostic measurements at 10 circumferential locations in the HRE combustor exit plane. The measurements included static and pitot pressures using conventional conical probes, combustion gas temperatures from cooled-gas pyrometer probes, and species concentration from analysis of combustion gas samples. Results showed considerable circumferential variation, indicating that efficiency losses were due to nonuniform fuel distribution or incomplete mixing. Results using the Mach 7 facility nozzle but with Mach 6 temperature simulation, 1590 to 1670 K, showed indications of incomplete combustion. Nitric oxide measurements at the combustor exit peaked at 2000 ppmv for stoichiometric combustion at Mach 6.

Lezberg, Erwin A.↗
NASA NTRS1993

Mode of emplacement of lunar mare volcanic deposits: Graben formation due to near surface deformation accompanying dike emplacement at Rima Parry 5

Theoretical analyses, together with the observed style of emplacement of lunar mare volcanic deposits, strongly suggest that mare volcanic eruptions are fed by dikes from source regions at the base of the crust or deeper in the lunar mantle. Some dikes intrude into the lower crust, while others penetrate to the surface and are the sources for voluminous outpourings of lava. Still others stall near the surface generating a near-surface extensional stress field. We have investigated the hypothesis that some lunar linear rilles (graben) are the near-surface manifestations of dikes intruded to shallow depths. For a specific example (Rima Parry 5), we show that the geometry of the faults implies a mean dike width of about 150 m and depth to the dike top of about 500 m, values consistent with other theoretical and observational data on lunar dike geometry. Localized pyroclastic deposits along Rima Parry 5 are evidence for the presence of near-surface magma, and are interpreted to be the result of degassing and pyroclastic eruption subsequent to the emplacement of the dike.

Head, J. W.↗
NASA NTRS1993

Theoretical reaction pathways for the formation of (Si(OH)5)(1-) and the deprotonation of orthosilicic acid in basic solution

The stability of (Si(OH)5)(1-) is predicted by means of molecular orbital calculations. Si is predicted to be as stable in basic aqueous solutions as hydrated (/OH/3SiO)(1-) and more stable than Si(OH)4 + (OH)(1-). Vibrational analysis of (Si(OH)5)(1-) predicts Raman and IR spectra that are not compatible with the presence of Si in some silicate glasses under ambient temperature compression.

Kubicki, J. D.↗
NASA NTRS1994

X-ray sources in regions of star formation. 5: The low mass stars of the Upper Scorpius association

We report followup investigations of Einstein x-ray observations of the Upper Scorpius OB association. We identify 28 low mass pre-main sequence stars as counterparts of x-ray sources in the approximately = 7 square degrees of the OB association observed. Based on kinematics and lithium abundances, these stars are low mass members of the OB association. We use optical spectra and optical and near-IR photometry to determine the stellar luminosities, effective temperatures, masses, and ages. We show that the bolometric corrections and effective temperatures of the G and K stars are consistent with those of subgiants. The low mass stars have isochronal ages of 1-2 Myr, depending on the choice of evolutionary models, with very small dispersion (sigma approximately = 1 Myr). This age is significantly younger than the 5-6 Myr found for the more massive B stars. The small dispersion in stellar ages, less than 10% the sound-crossing time of the association, suggests that star formation was triggered. We present two scenarios for star formation in this association. In the two-episode scenario, formation of the low mass stars was triggered by a supernova explosion, and the low mass stars form quickly, with high efficiency. Alternatively, high and low mass star formation was all initiated at the same time, some 5-6 Myr ago, and the apparent systematic age difference is an artifact of how the isochrones are dated. The effect of the supernova is to terminate mass accretion and yield an apparently coeval population. We show that the incompleteness in the x-ray sampling is about 65%, and is strongly dependent on stellar mass. After correction for incompleteness, we estimate there are about 2000 low mass members (stellar mass less than 2 solar mass) of this association. The mass function in this association is indistinguishable from that of the field. The ratio of naked to classical T Tauri stars is much larger than in Tau-Aur, and may be attributable to the local environment. We also present observations of eight ROX sources associated with the rho Oph cloud, and observations of non-pre-main sequence (PMS) stars in our fields.

Walter, Frederick M.↗
NASA NTRS1995

Thermal emission measurements 2000-400/cm (5-25 micrometers) of Hawaiian palagonitic soils and their implications for Mars

The thermal emision of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 micrometers (2000 to 400/cm) for several partical size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approximately 20% in the short wavelength region (5 to 6.5 mirometers, 2000 to 1500/cm), and is more subdued, less than 4%, at longer wavelengths. The strengths of features present in the infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorptions(s).

Roush, Ted L.↗
NASA NTRS1996

Mach 5 to 7 RBCC Propulsion System Testing at NASA-LeRC HTF

A series of Mach 5 to 7 freejet tests of a Rocket Based Combined Cycle (RBCC) engine were cnducted at the NASA Lewis Research Center (LERC) Hypersonic Tunnel Facility (HTF). This paper describes the configuration and operation of the HTF and the RBCC engine during these tests. A number of facility support systems are described which were added or modified to enhance the HTF test capability for conducting this experiment. The unfueled aerodynamic perfor- mance of the RBCC engine flowpath is also presented and compared to sub-scale test results previously obtained in the NASA LERC I x I Supersonic Wind Tunnel (SWT) and to Computational Fluid Dynamic (CFD) analysis results. This test program demonstrated a successful configuration of the HTF for facility starting and operation with a generic RBCC type engine and an increased range of facility operating conditions. The ability of sub-scale testing and CFD analysis to predict flowpath performance was also shown. The HTF is a freejet, blowdown propulsion test facility that can simulate up to Mach 7 flight conditions with true air composition. Mach 5, 6, and 7 facility nozzles are available, each with an exit diameter of 42 in. This combination of clean air, large scale, and Mach 7 capabilities is unique to the HTF. This RBCC engine study is the first engine test program conducted at the HTF since 1974.

Perkins, H. Douglas↗
NASA NTRS1993

The Natural Thermoluminescence of Meteorites: Ordinary Chondrites at the Allan Hills Ice Fields - Part 5

Natural thermoluminescence (TL) data have been obtained for 167 ordinary chondrites from the ice fields in the vicinity of the Allan Hills in Victoria Land, Antarctica, in order to investigate their thermal and radiation history, pairing, terrestrial age, and concentration mechanisms. Using fairly conservative criteria (including natural and induced TL, find location, and petrographic data), the 167 meteorite fragments are thought to represent a maximum of 129 separate meteorites. Natural TL values for meteorites from the Main ice field are fairly low (typically 5-30 krad, indicative of terrestrial ages of approx. 400 ka), while the Far western field shows a spread with many values 30-80 krad, suggestive of less then 150-ka terrestrial ages. There appear to be trends in TL levels within individual ice fields which are suggestive of directions of ice movement at these sites during the period of meteorite concentration. These directions seem to be confirmed by the orientations of elongation preserved in meteorite pairing groups. The proportion of meteorites with very low natural TL levels (less then 5 krad) at each field is comparable to that observed at the Lewis Cliff site and for modern non-Antarctic falls and is also similar to the fraction of small perihelia (less then 0.85 AU) orbits calculated from fireball and fall observations. Induced TL data for meteorites from the Allan Hills confirm trends observed for meteorites collected during the 1977/1978 and 1978/1979 field seasons which show that a select group of H chondrites from the Antarctic experienced a different extraterrestrial thermal history to that of non-Antarctic H chondrites.

Benoit, Paul H.↗
NASA NTRS1997

Near Infrared Luminescence Properties of Mn(5+): Ca5(PO4)3F

We report a spectroscopic investigation of Mn(5+) doped Ca5(PO4)(sub 3)F or FAP. Mn(5+) doped crystals have recently attracted world wide attention for potential solid-state laser applications. Following optical excitation of Mn: FAP with the 600 nm output of a Nd: YAG OPO laser system, we observed a strong near infrared luminescence centered at around 1150 nm. The room temperature luminescence decay time was measured to be approximately 635 microseconds. We attribute the infrared luminescence to the(1)E yields (3)A2 transition of tetrahedrally coordinated Mn5+ ions located in a strong crystal field environment. Absorption, luminescence and lifetime data of Mn: FAP will be presented and discussed.

Davis, Valetta R.↗