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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
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NASA NTRS1988

Theoretical spectroscopy of comets

Theoretical spectra of various emitting species in cometary comae were calculated both to investigate physical parameters that are measureable with cometary spectra and to provide fluorescence efficiencies for the derivation of abundances from fluxes. NH was found to be much further from nucleus than proviously thought and, because previous fluorescence efficiencies were much too high, NH is 5 times more abundant than previously thought. The spectrum of S sub 2 in comet I-A-A was analyzed. Despite its short lifetime, S sub 2 reaches fluorescent equlibrium. The equilibrium spectrum matches the relative band strengths in IUE spectra much better than does single cycle fluorescence. Equilibrium (but not single-cylce) flurescence also predicts strong optical emission bands which are seen in ground-based spectra of comet I-A-A. Equilibrium fluorescence efficiencies are much higher than single-cycle fluorescence efficiencies implying S sub 2 is only half as abundant as previously estimated. Fluorescence spectrum of SO was calculated and compared with several IUE spectra including those in which Wallis and Krishna Swamy claim SO to be present. Relative intensities and shapes of bands are inconsistent with any real identification.

Ahearn, Michael F.↗
NASA NTRS1993

Electronic and vibrational spectra of matrix isolated anthracene radical cations - Experimental and theoretical aspects

The IR vibrational and visible/UV electronic absorption spectra of the anthracene cation, An(+), were studied experimentally, in argon matrices at 12 K, as well as theoretically, using ab initio calculations for the vibrational modes and enhanced semiempirical methods with configuration interaction for the electronic spectra. It was found that both approaches predicted well the observed photoelectron spectrum. The theoretical IR intensities showed some remarkable differences between neutral and ionized species (for example, the CH in-plane bending modes and CC in-plane stretching vibrations were predicted to increase by several orders of magnitude upon ionization). Likewise, estimated experimental IR intensities showed a significant increase in the cation band intensities over the neutrals. The implication of these findings for the hypothesis that polycyclic aromatic hydrocarbon cations are responsible for the unidentified IR emission bands from interstellar space is discussed.

Szczepanski, Jan↗
NASA NTRS1982

A broad-band VLF-burst associated with ring-current electrons

Frequency band broadening takes place just outside of the nighttime plasmasphere, where the density of cold plasma is known to be very low during the later phase of a geomagnetic storm. Instead of the gradual broadening of several hours duration, a burst type broadening of VLF emission lasting less than ten minutes was observed by Explorer 45 in a similar location. The magnetic field component of this emission is very weak and the frequency spreads below the local half electron cyclotron frequency. Corresponding enhancement of the anisotropic ring current electrons is also very sudden and limited below the order of 10 keV without significant velocity dispersion, in contrast to the gradual broadening events. The cause of this type of emission band spreading can be attributed to the generation of the quasielectrostatic whistler mode emission of short wavelength by hot bimaxwellian electrons surging into the domain of relatively low density magnetized cold plasma. The lack of energy dispersion in the enhanced electrons indicates that the inner edge of the plasma sheet, the source of these hot electrons, is not far from the location of this event.

Maeda, K.↗
NASA NTRS1987

Photometric observations of comet P/Giacobini-Zinner

Narrow-band filter photometry of comet P/Giacobini-Zinner was obtained on 15 nights at Lowell Observatory in the interval from June 15 to Nov. 20, 1985. The emission bands of OH, NH, CN, C3, and C2 were isolated, along with continuum points at 3650 A and 4845 A. All observed species showed pronounced asymmetry about perihelion, with preperihelion abundances being greater by more than a factor of 2 than postperihelion abundances over the heliocentric distance range of 1.0-1.5 AU. The characteristics of the asymmetry were significantly different than observed in previous apparitions, with the peak production rates occurring in late July/early August. The unusually low C2/CN abundance ratio seen in previous apparitions is confirmed by the present observations. Furthermore, the QH data demonstrate that the C2 in Giacobini-Zinner (along with C3 and NH) is depleted when compared to water (the dominant species), rather than CN being unusually over abundant.

Schleicher, D. G.↗
NASA NTRS2015

Soil Moisture Active Passive (SMAP) Microwave Radiometer Radio-Frequency Interference (RFI) Mitigation: Initial On-Orbit Results

The Soil Moisture Active Passive (SMAP) mission, launched in January 2015, provides global measurements of soil moisture using a microwave radiometer. SMAPs radiometer passband lies within the passive frequency allocation. However, both unauthorized in-band transmitters as well as out-of-band emissions from transmitters operating at frequencies adjacent to this allocated spectrum have been documented as sources of radio frequency interference (RFI) to the L-band radiometers on SMOS and Aquarius. The spectral environment consists of high RFI levels as well as significant occurrences of low level RFI equivalent to 0.1 to 10 K. The SMAP ground processor reports the antenna temperature both before and after RFI mitigation is applied. The difference between these quantities represents the detected RFI level. The presentation will review the SMAP RFI detection and mitigation procedure and discuss early on-orbit RFI measurements from the SMAP radiometer. Assessments of global RFI properties and source types will be provided, as well as the implications of these results for SMAP soil moisture measurements.

radiometers↗
NASA NTRS2006

Is the Linear Mode Conversion Theory Viable for Generating Kilometric Continuum?

Kilometric Continuum (KC) usually exhibits a complicated banded radiation pattern observed in frequency time spectrograms. Can the number of bands, the frequency range over which the bands are observed, and their time variation be explained with Linear Mode Conversion Theory (LMCT) using realistic plasmapause models and Extreme Ultraviolet (EUV) plasmaspheric observations? In this paper we compare KC observations with simulated frequency emission bands based on LMCT for a number of cases. In LMCT the allowed frequency range across the equatorial plasmapause is restricted to frequencies much greater than the electron cyclotron frequency (fce) and less than the maximum plasma frequency in this region. Fce also determines the number of allowed bands in this range. Is the observed frequency range and number of bands consistent with the predications of LMCT? Can irregularities in the shape of plasmaspheric structures like notches be observed in the time variations of KC emissions? We will investigate these and other questions. Simulated radiation patterns will be generated by ray tracing calculations in the L-O mode from the radio window at the near equatorial plasmapause. The KC observations used in this study are from the Plasma Wave Instrument on the Geotail spacecraft and from the Radio Plasma Imager on the IMAGE spacecraft. The plasmasphere and plasmapause will be derived either from plasmasphere simulations, from images by the EUV imager on the IMAGE spacecraft, and by using empirical models. In situ plasma density measurements from a number of spacecraft will also be used in order to reconstruct the plasmasphere for these case studies.

Boardsen, Scott A.↗
NASA NTRS2005

PAHs and the Diffuse Interstellar Bands. What have we Learned from the New Generation of Laboratory and Observational Studies?

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. PAHs are the best-known candidates to account for the IR emission bands (UIR bands) and PAH spectral features are now being used as new probes of the ISM. PAHs are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). In the model dealing with the interstellar spectral features, PAHs are present as a mixture of radicals, ions and neutral species. PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge for laboratory astrophysics is to reproduce (in a realistic way) the physical conditions that exist in the emission and/or absorption interstellar zones, An extensive laboratory program has been developed at NASA Ames to characterize the physical and chemical properties of PAHs in astrophysical environments and to describe how they influence the radiation and energy balance in space and the interstellar chemistry. In particular, laboratory experiments provide measurements of the spectral characteristics of interstellar PAH analogs from the ultraviolet and visible range to the infrared range for comparison with astronomical data. This paper will focus on the recent progress made in the laboratory to measure the direct absorption spectra of neutral and ionized PAHs in the gas phase in the near-W and visible range in astrophysically relevant environments. These measurements provide data on PAHs and nanometer-sized particles that can now be directly compared to astronomical observations. The harsh physical conditions of the IS medium - characterized by a low temperature, an absence of collisions and strong V W radiation fields - are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions are formed from the neutral precursors in an isolated environment at low temperature (of the order of 100 K). The spectra of neutral and ionized PAHs are measured using the high sensitivity methods of cavity ring down spectroscopy (CRDS). These experiments provide unique information on the spectra of free, cold large carbon molecules and ions in the gas phase. Intrinsic band profiles and band positions of cold gas-phase PAHs can now be measured with high- sensitivity spectroscopy and directly compared to the astronomical data. The electronic bands measured for ionized PAH are found to be intrinsically broad (about 20/cm) while the bands associated with the neutral precursors are narrower (of the order of 2 - 10/cm).

Salama, Farid↗
NASA NTRS1992

Narrow band photometry of selected asteroids

The CCD photometry of selected asteroids was carried out to check for possible cometary activity in them. To distinguish the asteroids with possible cometary activity from those of the main belt, each object of interest was observed in two filters; one centered on the C2 emission band at 5140A (90A bandpass) and the other centered on the nearby continuum at 4845A (65A bandpass). None of the observed asteroids appear to have any C2 emission.

Rajamohan, R.↗
NASA NTRS2003

Seasonal/Diurnal Mapping of Ozone and Water in the Martian Atmosphere

Ozone and water are key species for understanding the stability and evolution of Mars atmosphere; they are closely linked (along with CO, H, OH, and O) through photochemistry. Photolysis of water produces the OH radical (thought to catalyze reformation of CO2 from CO and O2) and atomic hydrogen (which reacts with O3 forming OH and O2). Atomic hydrogen also reacts with O2 (forming HO2), thereby reducing the amount of O2 available to reform O3 from collisions between O and O2. Hence ozone and water should be anti-correlated on Mars. Photolysis of O3 produces O2(a(sup 1) delta g) with 90% efficiency, and the resulting emission band system near 1.27 mm traces the presence and abundance of ozone. This approach was initially used to study ozone on Earth and then applied to Mars. In 1997, we measured several lines of the O2(a(sup 1) delta g) emission using CSHELL at the NASA IRTF; the O2(a(sup 1) delta g) state is also quenched by collisions with CO2. This quenching dominates at lower altitudes so that the detected emissions are used to detect ozone column densities above ~20 km. The slit was positioned N-S along Mars' central meridian resulting in a one-dimensional map of ozone. Nearly simultaneous maps may be made of water using CSHELL by detecting the v1 fundamental band of HDO near 3.67 microns and using the D/H ratio for Mars. This technique was used by DiSanti and Mumma. With CSHELL, measurements for both O2(a(sup 1) delta g) emissions and HDO absorptions can be made during the day or night. Since January, 1997, we have repeated these measurements at different times during the Martian year. For all of these dates, we have positioned the slit N-S along the central meridian; for some of these dates, we have also stepped the slit across the planet at 1 arc-sec intervals generating a 2-dimensional map. We have also positioned the slit E-W on Mars thus providing diurnal variations of ozone and water along the slit.

Novak, R. E.↗
NASA NTRS1983

Sensitivity of ozone retrievals in limb-viewing experiments to errors in line-width parameters

The variance of atmospheric ozone concentration profiles retrieved in i.r. limb-viewing experiments is examined over the range of published ozone halfwidth values. Simulated retrievals are performed for a typical satellite-based high-resolution absorption experiment and a broad-band emission experiment. The results indicate that, for limb-viewing experiments, inaccurate collision-broadened linewidth values can lead to significant errors in retrieved profiles for broad-band radiometric data or for isolated strong lines in high-resolution spectra.

Smith, M. A. H.↗
NASA NTRS1990

From interstellar dust to comets - A unification of observational constraints

The interstellar dust model of comets is numerically worked out to satisfy simultaneously several basic constraints provided by observations of Comet Halley, and to derive the porosity of coma dust. The observational constraints are (1) the strengths of the 3.4 and 9.7 micron emission bands, (2) the shape of the 9.7 micron band, (3) the amount of silicates relative to organic materials, and (4) the mass distribution of the dust. The method used involves precise calculations of temperatures and the emission characteristics of porous aggregates of interstellar dust as a function of their mass, porosity, and distance to the sun and the wavelength. The results indicate that coma dust has a porosity in the range 0.93-0.975, i.e., a packing factor of 0.07 or less, consistent with independent observations of comet densities of 0.6 to 0.26 g/cu cm and meteor densities of less than 0.2 g/cu cm.

Greenberg, J. Mayo↗
NASA NTRS2020

Assessment of MODIS and VIIRS Calibration Consistency for Reflective Solar Bands Using Vicarious Approaches

The Moderate-Resolution Imaging Spectroradiometer (MODIS) is the key instrument of the NASA’s Earth Observing System (EOS) Terra and Aqua missions, launched in December 1999 and May 2002, respectively. The Visible Infrared Imaging Radiometer Suite (VIIRS) expands the MODIS legacy, launched onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite in October 2011 and NOAA20 satellite in November 2017, respectively. The MODIS and VIIRS sensors have a similar design with spectrally matched reflective solar spectral bands (RSB). Their on-board calibration components include a solar diffuser and a solar diffuser stability monitor for RSB, a V-grooved blackbody for the thermal emissive bands (TEB), and a space view as a background reference. This study evaluates the calibration consistency of the Terra and Aqua MODIS RSB based on the current Collection 6.1 L1B data products generated by the NASA MODAPS, which have used consistent calibration coefficient look up tables (LUT) for the entire data-record. In the case of SNPP and NOAA20 VIIRS, the latest L1B data produced by NASA Land SIPS are used. Several independent vicarious approaches are used to examine the stability and consistency of the at-sensor reflectance among MODIS and VIIRS instruments. Vicarious approaches include observations from simultaneous nadir overpasses (SNO), the Libya-4 desert and Dome C snow sites, as well as deep convective clouds (DCC). Impact of existing band spectral difference on the reflectance is corrected using hyperspectral observations provided by Europe Space Agency’s SCIAMACHY sensor. Results of this study provide comprehensive assessments of calibration performance, radiometric agreement and associated uncertainties.

MODIS↗
NASA NTRS1977

Statistical equilibrium in cometary C2. I

Swan-band emission from the C2 molecule provides important information for a study of the physical processes occurring in comets. It is, therefore, a disturbing factor that many quantitative Swan-band observations are in clear contradiction of predictions of resonance fluorescence excitation of the Swan bands. A description is presented of an investigation involving an application of resonance fluorescence theory to C2. The investigation takes into account all important electronic transitions which determine the population distribution of the lowest energy states. It is found that the previous discrepancy for the brighter band sequences disappears.

Swamy, K. S. K.↗
NASA NTRS2012

Characterization of Mineralogy Across Vesta

Dawn VIR spectra are characterized by pyroxene absorptions and no clear evidence for abundant other minerals are observed at the scale of the present measurements. Even though Vesta spectra are dominated by pyroxenes, spectral variation at regional and local scales are evident and distinct color units are identified. Although almost all of the surface materials exhibit spectra like those of howardites, some large units can be interpreted to be material richer in diogenite (based on pyroxenes band depths and band centers) and some others like eucrite-rich howardite units. VIR data strongly indicate that the south polar region (Rheasilvia) has its own spectral characteristics, indicating the presence of Mg-pyroxene-rich terrains (diogenite-like), while the equatorial areas have swallower band depths and average band centers at slightly longer wavelengths, consistent with more eucrite rich materials. Vesta surface shows considerable diversity at smaller scales (tens of km), in terms of spectral reflectance and emission, band depths and slopes. Many bright and dark spots are present on Vesta. Dark spots have low reflectance at visible wavelengths and are spectrally characterized by shallower 1 and 2 micron bands with respect the surrounding terrains. Bright materials have high reflectance and are often spectrally characterized by deep pyroxenes absorption bands. Vesta presents complex geology/topography and the mineral distribution is often correlated with geological and topographical structures. Ejecta from large craters have distinct spectral behaviors, and materials exposed in the craters show distinct spectra on floors and rims. VIR reveals the mineralogical variation of Vesta s crustal stratigraphy on local and global scales. Maps of spectral parameters show surface and subsurface unit compositions in their stratigraphic context. The hypothesis that Vesta is the HED parent body is consistent with, and strengthened by, the geologic and spectral context for pyroxene distribution provided by Dawn.

De Sanctis, M. C.↗
NASA NTRS1979

The ultraviolet spectrum of Comet Seargent 1978m

UV spectrograms of Comet Seargent (1978m) have been obtained with the IUE satellite in the low- (1.8-nm) and high- (0.1-nm) dispersion modes. In the long-wavelength region (189-340 nm) emission bands of OH, CS, CO2(+), NH, and CO(+) can be identified, and the rotational structure of OH could clearly be resolved. In the short-wavelength region (119-192 nm) emission lines of H(Lyman-alpha), O I, C I, and S I appear. These observations demonstrate that the IUE observatory can effectively be used to obtain high-quality spectra of comets as faint as ninth magnitude.

Jackson, M. W.↗
NASA NTRS2009

Using Dome C for Moderate Resolution Imaging Spectroradiometer Calibration Stability and Consistency

Currently, there are two nearly identical moderate resolution imaging spectroradiometer (MODIS) instruments operated in space: one on the Terra spacecraft launched in December 1999 and another on the Aqua spacecraft launched in May 2002. MODIS has 36 spectral bands with wavelengths covering from visible (VIS) to long-wave infrared (LWIR). Since launch, M0DIS observations and data products have significantly enabled studies of changes in the Earth system of land, oceans, and atmosphere. In order to maintain its on-orbit calibration and data product quality, MODIS was built with a comprehensive set of on-board calibrators. MODIS reflective solar bands (RSB) are calibrated on-orbit by a system that consists of a solar diffuser (SD) and a solar diffuser stability monitor(SDSM) on a regular basis. Its thermal emissive bands (TEB) calibration is executed on a scan-by-scan basis using an on-board blackbody (BB). The MODIS Characterization Support Team (MCST) at NASA/GSFC has been responsible for supporting sensor calibration and characterization tasks from pre-launch to post launch. In this paper,we describe current MCST efforts and progress made to examine sensor stability and intercalibration consistency using observations over Dome Concordia, Antarctica. Results show that this site can provide useful calibration reference for Earth-observing sensors.

Xiong, Xiaoxiong↗
NASA NTRS2011

VLF and HF Plasma Waves Associated with Spread-F Plasma Depletions Observed on the C/NOFS Satellite

The C/NOFS spacecraft frequently encounters structured plasma depletions associated with equatorial spread-F along its trajectory that varies between 401 km perigee and 867 km apogee in the low latitude ionosphere. We report two classes of plasma waves detected with the Vector Electric Field Investigation (VEFI) that appear when the plasma frequency is less than the electron gyro frequency, as is common in spread-F depletions where the plasma number density typically decreases below 10(exp 4)/cu cm. In these conditions, both broadband VLF waves with a clear cutoff at the lower hybrid frequency and broadband HF waves with a clear cutoff at the plasma frequency are observed. We interpret these waves as "hiss-type" emissions possibly associated with the flow of suprathermal electrons within the inter-hemispherical magnetic flux tubes. We also report evidence of enhanced wave "transients" sometimes embedded in the broader band emissions that are associated with lightning sferics detected within the depleted plasma regions that appear in both the VLF and HF data. Theoretical implications of these observations are discussed.

Pfaff, Robert↗