Search NASA⌕ Search

SEARCH · Search NASA

Results for “CO2 capture and storage”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15

Fine Calcium Carbonate Production by CO2 Mineralization of Industrial Waste Brines

Calcium carbonate production via CO2 mineralization offers an attractive route for carbon capture and utilization. The process sequesters CO2 in a stable form of fine precipitated calcium carbonate, a high-value product with unit price in the range of $230-$280/t and a global market projected to reach 99 M tons in 2020. However, two critical barriers hinders CO2 mineralization—(i) the need for costly processes such as electrolysis or addition of alkali hydroxides to maintain alkalinity during mineralization, and (ii) the geographic location mismatch between Ca-rich solutions (or brines) CO2 generation sources (e.g. power plants) which often renders efficient integration of feedstocks impractical. To simultaneously address these challenges, a new process is developed to integrate CO2 mineralization-based carbonate production into the zero liquid discharge water (ZLD) treatment systems at coal-fired power plants. In this process, Ca-rich streams, such as produced water from oil and gas extraction or carbon storage operations, serves as the Ca-source. An H+/Na+ ion-exchange cycle is designed to provision alkalinity during mineralization and regenerate the ion-exchange reagent in solutions with high salinity. Ca-depleted streams are then treated within a centralized ZLD system. The process beneficially utilizes reject streams that are available at substantial quantities in the vicinity of coal power plants within several U.S regions. In addition, the process utilizes post-desulfurization flue gas from coal-fired power plants as is. The CO2 conversion reactions are performed in alkaline streams at ambient pressure, thereby minimizing the energy burden. By beneficiation of industrial waste streams with low energy input, this process offers significant technical advantages in energy and CO2 footprint over the current paradigm of precipitated calcium carbonate production. Overall, the new process provides a unique route to integrate CO2 emissions control and wastewater treatment for coal power plants, while producing high-value product to offset the economic burden associated with waste management.

Simonetti, Dante↗

Fine Calcium Carbonate Production by CO2 Mineralization of Industrial Waste Brines

Calcium carbonate production via CO2 mineralization offers an attractive route for carbon capture and utilization. The process sequesters CO2 in a stable form of fine precipitated calcium carbonate, a high-value product with unit price in the range of $230-$280/t and a global market projected to reach 99 M tons in 2020. However, two critical barriers hinders CO2 mineralization—(i) the need for costly processes such as electrolysis or addition of alkali hydroxides to maintain alkalinity during mineralization, and (ii) the geographic location mismatch between Ca-rich solutions (or brines) CO2 generation sources (e.g. power plants) which often renders efficient integration of feedstocks impractical. To simultaneously address these challenges, a new process is developed to integrate CO2 mineralization-based carbonate production into the zero liquid discharge water (ZLD) treatment systems at coal-fired power plants. In this process, Ca-rich streams, such as produced water from oil and gas extraction or carbon storage operations, serves as the Ca-source. An H+/Na+ ion-exchange cycle is designed to provision alkalinity during mineralization and regenerate the ion-exchange reagent in solutions with high salinity. Ca-depleted streams are then treated within a centralized ZLD system. The process beneficially utilizes reject streams that are available at substantial quantities in the vicinity of coal power plants within several U.S regions. In addition, the process utilizes post-desulfurization flue gas from coal-fired power plants as is. The CO2 conversion reactions are performed in alkaline streams at ambient pressure, thereby minimizing the energy burden. By beneficiation of industrial waste streams with low energy input, this process offers significant technical advantages in energy and CO2 footprint over the current paradigm of precipitated calcium carbonate production. Overall, the new process provides a unique route to integrate CO2 emissions control and wastewater treatment for coal power plants, while producing high-value product to offset the economic burden associated with waste management.

Simonetti, Dante↗

Land management and climate change determine second‐generation bioenergy potential of the US Northern Great Plains

Bioenergy with carbon capture and storage (BECCS) has been proposed as a potential climate mitigation strategy raising concerns over trade‐offs with existing ecosystem services. We evaluate the feasibility of BECCS in the Upper Missouri River Basin (UMRB), a landscape with diverse land use, ownership, and bioenergy potential. We develop land‐use change scenarios and a switchgrass (Panicum virgatum L.) crop functional type to use in a land‐surface model to simulate second‐generation bioenergy production. By the end of this century, average annual switchgrass production over the UMRB ranges from 60 to 210 Tg dry mass/year and is dependent on the Representative Concentration Pathway for greenhouse gas emissions and on land‐use change assumptions. Under our simple phase‐in assumptions this results in a cumulative total production of 2,000–6,000 Tg C over the study period with the upper estimates only possible in the absence of climate change. Switchgrass yields decreased as average CO2 concentrations and temperatures increased, suggesting the effect of elevated atmospheric CO2 was small because of its C4 photosynthetic pathway. By the end of the 21st century, the potential energy stored annually in harvested switchgrass averaged between 1 and 4 EJ/year assuming perfect conversion efficiency, or an annual electrical generation capacity of 7,000–28,000 MW assuming current bioenergy efficiency rates. Trade‐offs between bioenergy and ecosystem services were identified, including cumulative direct losses of 1,000–2,600 Tg C stored in natural ecosystems from land‐use change by 2090. Total cumulative losses of ecosystem carbon stocks were higher than the potential ~300 Tg C in fossil fuel emissions from the single largest power plant in the region over the same time period, and equivalent to potential carbon removal from the atmosphere from using biofuels grown in the same region. Numerous trade‐offs from BECCS expansion in the UMRB must be balanced against the potential benefits of a carbon‐negative energy system.

climate change↗

Compact Absorber Technology Leads to Significant Reduction in the Cost of Point Source CO 2 Capture

The size of columns in traditional absorption-based processes for CO 2 capture contributes significantly to the overall capital cost. A demonstrated method to reduce the cost of point source CO 2 capture, focusing on reducing the absorber height by increasing the liquid-to-gas reaction contact area and decreasing the CO 2 diffusion resistance without increasing gas-side pressure drop is presented along with techno-economic analysis results. Bench-scale tests on the unique Compact Absorber showed overall CO 2 mass transfer enhancement of varying degrees compared to a traditional packed column for similar process conditions, demonstrating that a 60+% reduction in size of a typical post-combustion absorber with a packing height of 70-100 ft and total height of 150-180 ft can be achieved. The techno-economic analysis showed significant cost reductions when the Compact Absorber is combined with other transformative aspects of the University of Kentucky Institute for Decarbonization and Energy Advancement point source CO 2 capture process compared to the U.S. Department of Energy National Energy Technology Laboratory pertinent reference case for pulverized coal plants with CO 2 capture. Here, a levelized cost of electricity excluding CO 2 transportation and storage of $\$95.6$/MWh was estimated, which is a 9% reduction, with a total capital cost contribution of $45/MWh, which is a 12% reduction. Additionally, a breakeven CO 2 sales price also referred to as the cost of CO 2 capture, of $36.70/tonne was estimated when the UK hindered primary amine solvent is used, which is a 20% reduction compared to the reference case.

CO2 capture↗

Ion Storage with the High Performance Antiproton Trap (HiPAT)

The matter antimatter reaction represents the densest form of energy storage/release known to modern physics: as such it offers one of the most compact sources of power for future deep space exploration. To take the first steps along this path, NASA-Marshall Space Flight Center is developing a storage system referred to as the High Performance Antiproton Trap (HiPAT) with a goal of maintaining 10(exp 12) particles for up to 18 days. Experiments have been performed with this hardware using normal matter (positive hydrogen ions) to assess the device's ability to hold charged particles. These ions are currently created using an electron gun method to ionize background gas; however, this technique is limited by the quantity that can be captured. To circumvent this issue, an ion source is currently being commissioned which will greatly increase the number of ions captured and more closely simulate actual operations expected at an antiproton production facility. Ions have been produced, stored for various time intervals, and then extracted against detectors to measure species, quantity and energy. Radio frequency stabilization has been tested as a method to prolong ion lifetime: results show an increase in the baseline 1/e lifetime of trapped particles from hours to days. Impurities in the residual background gas (typically carbon-containing species CH4, CO, CO2, etc.) present a continuing problem by reducing the trapped hydrogen population through the mechanism of ion charge exchange.

Martin, James↗

Design of Modular Test Facility for Particle/sCO2 Heat Exchanger Evaluation

Heliogen has designed a 1.3 MW particle and supercritical carbon dioxide (sCO2) test loop to retire technical and manufacturing risks. The data from this facility will be used to validate near commercial-scale particle heat exchanger modules. The heat exchanger is scaled to capture all features of the full-scale modules. Testing will be conducted with CARBOBEAD HSP 16/30, a larger particle size than other recent testing. The system was designed to ASME codes with the constraint that sCO2 piping and other major components are stainless steels.

14 SOLAR ENERGY↗

SECARB-USA: Needs Assessment Framework for Storage Complexes

The goal of this task is to develop an assessment to identify data needed to advance geologic storage projects, with a focus on the SECARB region. The GCCC team considers the needs of CO2 source, storage, and utilization operators and stakeholders, finance and insurance institutions, state and local government relators and agencies, property owners, local stakeholders at prospective storage complexes, and environmental non-governmental organizations (NGOs). Many of these needs are spelled out in the requirements of the Class VI permit. However, at the initial stages of project development, the workflow will not start with permit writing. A number of other factors must be evaluated prior to this major investment. The team’s goal in this report is to inventory the range of typical needs for a wide variety of projects. For subsequent tasks, the team will consider how these needs vary among projects and through the stages of investment, so that project developers can plan the early stages of capitalization.

54 ENVIRONMENTAL SCIENCES↗

Performance and Cost Assessment of a Natural Gas-Fueled Direct sCO 2 Power Plant

This final report details the cost and performance baseline developed at NETL for a natural gas-fueled direct sCO 2 plant, which holds promise as an efficient, cost-effective method of power production with carbon capture and storage (CCS). The steady state plant model includes turbine cooling flows based on a semi-empirical cooling model, and thermal integration with the air separation unit and oxygen compression train. Discussion of the performance of the baseline plant design is followed by details on the costing methodology, overall plant capital cost, and resulting cost of electricity (COE). Performance results yield a baseline sCO 2 plant thermal efficiency of 48.2% (HHV) with 98.2% carbon capture, an improvement over the reference NGCC plant with CCS (45.7% and 90.7% carbon capture). Cost analyses yield a 5% reduction in COE versus the NGCC plant, albeit with significant uncertainty. Finally, the effects of incomplete combustion on the overall plant performance are assessed.

03 NATURAL GAS↗

Distributed Mafic Rock Resources for Carbon Mineralization in Arizona

Ex-situ carbon mineralization is a process by which CO2 is reacted with alkaline silicate minerals and rocks to produce stable carbonate materials, which can be used for other industrial processes. Arizona, U.S.A., hosts abundant surficial mafic rocks in three young volcanic fields, Geronimo-San Bernardino, San Francisco, and Springerville, and other distributed locations throughout the state. We created a Mafic Rock Resource Inventory (MRRI) that categorizes geochemical, physical, and textural characteristics of a diverse suite of surficial mafic rock samples and provide a benchmark reaction dataset parameterizing the temperature, pressure, and pH conditions best suited ex-situ mineralization in different rock types. MRRI data is publicly available online via a map-viewer. We establish two reaction condition sets, varied in temperature, pressure, and pH, where crystal-rich and glassy rocks reach maximum reaction extent and different carbonate phases are formed. Systematic ex-situ mineralization experiments on 21 diverse rock types show trends in geochemical, mineralogical, and reactivity behavior and establish maximum effective capture capacity. From this, scoria cones in three Arizona volcanic fields have a ~62 Gt effective CO₂ storage capacity with one of the fields having a ~42 Gt storage capacity in lava flows. Reactivity results have applications to alkaline mafic rock resources exposed globally, including producing additional effective storage capacity estimates and scaled commercialization of mafic rock ex-situ mineralization, should reaction extents be improved through advances in mineralization techniques. MRRI data were used to create a Direct Air Capture to Mineralization (DACM) systems model, technoeconomic analysis, and life-cycle assessment. These documents are presented as three appendices.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Automated High Power Permanent Borehole Seismic Source Systems for Long-Term Monitoring of Subsurface CO2 Containment and Storage

The geologic storage of CO2 emitted from fixed sources, such as coal or gas power plants, is currently considered one of the prime technologies for short term (~50 year) mitigation of greenhouse gas emissions. The subsurface storage of CO2 for greenhouse gas mitigation will require monitoring to verify that CO2 remains effectively trapped underground, thus permanent seismic sources are needed to provide 24/7 monitoring. GPUSA Inc. has developed and successfully demonstrated numerous prototype vibratory seismic sources with power and performance far beyond any available on the market. The primary objective of this project was to validate in an operational field environment GPUSA’s powerful, low cost, automated borehole seismic source systems for the CO2 storage monitoring application. GPUSA originally proposed the building and testing of two types of permanent sources but ended up building and delivering three types of permanent seismic sources. These sources were delivered to the field test site (Carbon Management Canada’s Containment and Monitoring site near Calgary), however, only two of the systems were able to be tested before the contract ended (despite two contract extensions). The reasons for the delay were primarily weather related both at the US preliminary field test site and Carbon Management Canada site. But in the end, based upon the preliminary field testing in the US and the limited testing that was completed at the Carbon Management Canada site, the results were very impressive, and in some cases far exceeding expectations.

02 PETROLEUM↗

Multiscale Electricity Modeling for Evaluating Carbon Capture and Sequestration Technologies (MEME-CCS)

This effort employs and adapts a rigorous multiscale electricity modeling platform at the National Renewable Energy Laboratory (NREL) to evaluate carbon capture and sequestration (CCS) and negative emissions technologies (NET) from the ARPA-E FLECCS program. NREL's modeling platform includes the Regional Energy Deployment System (ReEDS) electric sector capacity expansion model, which projects future electricity generation mixes at sub-state-level resolution that are downscaled to the unit-level to enable hourly, zonal or nodal electricity production cost modeling in the PLEXOS model. The ReEDS-PLEXOS modeling suite is well-established for examining electric sector futures with high renewable energy penetrations, energy storage, electrification, and distributed generation. The key advancement proposed herein utilizes collaboration with CCS experts at the University of Wyoming (U.WY) and the FLECCS technology development teams to create innovative methods for representing CCS and NET in the ReEDS and PLEXOS models. Expanded technology options and new operational parameterizations are integrated into these models to allow an unprecedented combination of scope and resolution for exploring the future of CCS and NET. The resulting capabilities permit wide-ranging scenario analysis to assess CCS and NET deployment under alternative scenarios of CO2 prices and competitiveness of flexible CCS and NET technologies. We demonstrate sample deployment and operational outcomes to show how these models are being used to assess the future potential for FLECCS technologies and their impacts on the U.S. electricity system. These products will help an emerging CCS/NET industry in the United States by providing economics-driven guidance to technology developers while informing policy and investment decisions in the public and private sectors.

capacity expansion↗

Carbon neutrality in Malaysia and Kuala Lumpur: Insights from stakeholder-driven integrated assessment modeling

Several cities in Malaysia have established plans to reduce their CO2 emissions, in addition to Malaysia submitting a Nationally Determined Contribution to reduce its carbon intensity (against GDP) by 45% in 2030 compared to 2005. Meeting these emissions reduction goals will require a joint effort between governments, industries, and corporations at different scales and across sectors. In collaboration with national and sub-national stakeholders, we developed and used a global integrated assessment model to explore emissions mitigation pathways in Malaysia and Kuala Lumpur. Guided by current climate action plans, we created a suite of scenarios to reflect uncertainties in policy ambition, level of adoption, and implementation for reaching carbon neutrality. Through iterative engagement with all parties, we refined the scenarios and focus of the analysis to best meet the stakeholders’ needs. We found that Malaysia can reduce its carbon intensity and reach carbon neutrality by 2050, and that action in Kuala Lumpur can play a significant role. Decarbonization of the power sector paired with extensive electrification, energy efficiency improvements in buildings, transportation, and industry, and the use of advanced technologies such as hydrogen and carbon capture and storage will be major drivers to mitigate emissions, with carbon dioxide removal strategies being key to eliminate residual emissions. This study highlights the participatory process in which stakeholders contributed to the development of the model and guided the analysis, as well as insights into Malaysia’s decarbonization potential and the role of multilevel governance.

cities↗

The Energy Transition: Advanced Nuclear Needed but Address Climate Vulnerabilities Now

The term “Energy Transition” is an attempt to capture an elaborate set of activities related to the modernization and decarbonization of energy grids. Performed concurrently and often in an ad hoc manner across local, state, regional and national boundaries, it is bringing chaos to what should arguably be one of the most conservatively managed of all critical infrastructure sectors. What’s more, with climate change producing an increasing tempo of extreme events, confidence in the intended resilient and redundant structure of the electric grids is likely to ebb. Even without these climate induced stressors, the nation’s electric grid was built for an earlier century. In addition to a drive towards greater efficiency via digitization and a continuing price decline in distributed energy resources (DERs), one could argue that climate change concerns are the primary driver of the energy transition. Non-CO2 emitting generation sources like wind and solar have become an important part of the overall generation fleet, albeit ones that cannot be counted upon to provide dispatchable power. Current projections indicate deployment of even larger percentages of DERs in coming years. Until far better storage capabilities arrive, the variability of wind and solar, inconsistent performance of traditional thermal generation plants, and energy delivery failures associated with natural gas pipelines will reinforce mounting reliability concerns. This pertains to both electric transmission and distribution. The recent shuttering of nuclear power plants in Germany, Japan, the US and elsewhere are also putting more downward pressure on dispatchable generation. Russia’s attack on Ukraine has roiled energy markets worldwide and forced some countries to return to coal as a primary fuel. In view circumstances such as these, it is essential that significant changes be made to policies and planning criteria, and to the standards and code on which they are based. Given the accelerating pace of extreme weather events, this needs to occur as soon as possible.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Opportunities and Strategies for Testing and Infusion of ISRU in the Evolvable Mars Campaign

HE Evolvable Mars Campaign (EMC) is developing the plans and systems needed for a robust, evolutionary strategy to explore cis-lunar space, the Mars sphere of influence (including the moons of Mars), and the surface of Mars. Recently, the emphasis of NASA's plans has changed to focus on the prolonged pioneering of space, rather than focusing on a single crewed mission as the ultimate goal. A sustainable, pioneering vision of space would include in-situ resource utilization (ISRU) in multiple forms and at multiple destinations: atmospheric capture of Mars CO2 and/or volatiles for consumables and propellants, regolith for bulk and refined materials, and in-situ manufacturing at the Moon, Mars, and other bodies. These resources would enable a reduction in the logistical needs from Earth for future missions, thus preparing the way for a sustained presence on Mars. Although the EMC initially relies only on propellant production for the Mars ascent vehicle via ISRU, one of its primary objectives is to prospect at every EMC destination to understand the potential for ISRU; this will permit true pioneering to be enabled after the first crew arrives at Mars. Recent and ongoing analysis has considered the possible prospecting measurements that can be performed at the asteroid returned to cis-lunar space by the Asteroid Robotic Redirect Mission (ARRM), at the lunar surface, at Phobos and Deimos, and on the surface of Mars to identify available resources for future use. These opportunities will be available on missions currently in the Evolvable Mars Campaign construct, and will also facilitate the testing and demonstration of resource acquisition, processing, storage, and useage technologies that can play a role in later missions. This analysis has also led to the identification of several objectives that should be targeted during the missions building up to and including the initial crewed missions. These objectives are mapped to strategies for incorporating ISRU to support resource cycle closure and reduce mass requirements from Earth. This analysis has yielded engineering constraints, based on ISRU, that impact the evaluation of landing sites for missions to the surface of Mars. The terrain of a particular site must be sufficiently flat to permit ISRU systems, as well as ancillary systems such as power and propellant storage tanks, to be landed, moved into position, set up, and operated. Water must be accessible in a form that can be acquired via ISRU, in quantities that align with demands. The chosen method of acquiring and processing water should align with the available resources at a particular site, and that site must have sufficient quantities to meet the requirements (based on crew consumables and propellant demands). Lower altitude landing sites are preferred, as the increase in density can facilitate carbon dioxide acquisition from the atmosphere. Another preference is for sites with a greater ability to move regolith for civil engineering purposes; for example, this would be conducive to both bulk regolith uses (such as the manufacture of berms), and processed regolith uses (such as microwave sintering).

Evolvable Mars Campaign↗

Literature Review of Selected Publications Relevant to Carbon Dioxide Pipeline and Storage Systems

The annotated bibliographies provided in this document focus on identifying and reviewing environmental impact statements (EIS), environmental assessments (EA), and scientific literature relevant to aspects of CO 2 pipeline and storage construction and operation. The purpose of these summaries is to aid stakeholders responsible for the preparation of documents compliant with the National Environmental Policy Act (NEPA) requirements to have access to a quick and comprehensive guide of the literature that can inform their activities. They aim to inform the development of EISs and EAs by identifying potential environmental concerns and mitigation strategies. The annotated bibliographies captured in this document cover the general environmental assessment and impact topics relevant to CO 2 pipeline and storage construction and operation activities, with the subject of waste creation and handling being specifically pulled out into its own section. The reasoning behind a dedicated section for waste is that many EAs and EISs focus on the description of waste and its impacts, be it caused in routine operation or as a result of an accident.

54 ENVIRONMENTAL SCIENCES↗

Net-Zero Ethylene: On the Sustainability, Economics, and Scalability of Synthetic and Fossil Production Pathways

The ethylene industry has contributed over 260 million tons of CO 2 annually, warranting a more sustainable approach. The conversion of CO 2 and H 2 O into ethylene is an appealing technology capable of decoupling chemical production from fossil fuels. However, the large energy demand from this process can potentially lead to adverse environmental impacts. Here, in this article, we critically analyze the economic viability, environmental impact, and scalability of the conversion of CO 2 to ethylene via electrochemical reduction (CO 2 R) and compare this with those of CO 2 -neutral fossil routes utilizing carbon capture and direct air capture. Ethylene derived from CO 2 may be economically competitive under optimistic conditions; however, its large energy requirements pose environmental and scalability challenges. Meeting forecast 2050 ethylene demand using CO 2 R would require half of all electricity produced globally today, and, if powered by solar PV, may have greater CO 2 emissions than current petrochemical ethylene production, negating the purpose of this technology. Using Carbon Capture and Storage and Direct Air Capture to decarbonize petrochemical pathways would require roughly an order of magnitude less energy but would have disproportionate health and climate impacts. Lastly, the analysis highlights the importance of low-carbon energy sources to ensure sustainable CO 2 R ethylene production.

CO2R↗

Hydrogen Storage for Flexible Fossil Fuel Power Generation: Integration of Underground Hydrogen Storage with Gas Turbine (Final Report)

As the nation continues to encourage, through market structures and financial incentives, the proliferation of intermittent renewable electricity, how to optimize the ever-changing electric grid and identify means to retain and improve resilience, while ensuring continued reductions in GHG emissions, will be critical. According to Bloomberg, wind & solar generated 10.5% of US electricity in 2020 and that percentage continues to grow. In support of expanding renewable energy use, and to address its intermittent nature, this project will develop the Hydrogen Storage for Flexible Fossil Fuel Power Generation platform that is dispatchable, reliable, repeatable and have the ability to produce zero or negative carbon power while interfacing with geology capable of CO2 and hydrogen storage. GTI Energy (GTIE) and team members Illinois State Geological Survey (ISGS), Mitsubishi Heavy Industries America (MHIA), Ameren Illinois, Hexagon Purus, and the Low Carbon Resources Initiative (LCRI) completed a Phase I Conceptual Study under contract DE-FE0032012 for Hydrogen Storage for Flexible Fossil Fuel Power Generation: Integration of Underground Hydrogen Storage with Gas Turbine. The Hydrogen Storage for Flexible Fossil Fuel Power Generation platform addresses the intermittent nature of the expanding use of Variable Renewable Energy (VRE) generation. The low cost of the electricity (COE) generated results in greater dispatch and more operation at higher power levels (higher efficiency), fewer short intervals, and fewer start/stop cycles. The reliable, resilient system can produce zero carbon power and store hydrogen. It will demonstrate hydrogen storage in geologic formations like those used in natural gas underground storage thus enabling large scale storage of hydrogen in sedimentary strata across the United States rather than in geographically restricted salt caverns. The Phase I study confirmed the system is feasible and generates power at lower cost than other low carbon approaches. The demonstration defines the pathway for broad commercial application and will accelerate the development of larger systems suitable for centralized utility scale electricity production. The study advanced the maturity of the H 2 storage-based system with flexible power generation by completing a Pre-FEED study (Phase II). The Pre-FEED focused on the selected Energy Farm on the University of Illinois Urbana-Champaign (UIUC) site that includes above ground and underground hydrogen storage, low-carbon hydrogen production (GTI’s Compact Hydrogen Generator, CHG) with underground CO2 sequestration, and a 40-MW class gas turbine. The Pre-FEED addressed the entire system and its interconnection to the natural gas and electric grid and mitigation of key risks, such as storage behavior, load-following, and system operation. During Phase 1 of the project, the team completed key tasks, which moved the entire demonstration project, specific components and approaches closer to commercialization. These Phase I Accomplishments include: Completing System Requirements Review; Completing System Layout and Modeling - Heat & Mass Balance and Process Flow Diagram; Completing modelling of 9 turbine performance cases; Evaluating rock strata for underground storage of hydrogen and sequestration of carbon dioxide; Completing initial modelling of underground storage of hydrogen and withdrawal with evaluation of loss and water production; Identifying roadable storage for above ground hydrogen storage; Identifying existing electrical infrastructure for receiving/delivering electricity; Identifying existing gas supply infrastructure for receiving natural gas; Document concept design/development plans in required reports. Conclusions: The 12-month Feasibility study in Phase I study was completed and confirmed the system is feasible and generates power at lower cost than other low carbon approaches and even lower cost than the reference NGCC plant without carbon capture when taking advantage of 45Q carbon credits. The study enabled the fidelity of the concept to be improved and allowed identification of the requirements for the system. Defining the individual system and component requirements was performed via the system requirements review with the whole team. These requirements were then incorporated into and iterated with our Heat & Mass Balance process model and process flow diagrams were generated to reflect the overall system. This information was then used to complete the TEA and show economic feasibility. Large scale non-salt geologic storage of hydrogen is an enabling technology for a hydrogen-fired turbine that can be retrofitted into large-scale electric generating units (EGU). Our demonstration will include 428 MWh or ~4 hours full load of hydrogen storage (above and underground). Carbon capture inherent to the CHG process can capture 90% CO 2 (with upgrades to >98%). This system provides a COE of 23% savings relative to an NGCC with a post combustion amine system. Our proposed storage system decouples carbon capture and hydrogen production from power production; therefore, we expect our proposed system’s efficiency and variable COE to be superior resulting in overall higher dispatch and reduced deep cycling. Our demonstration will be full to multi-day hydrogen storage and has the potential for longer (seasonal) duration commercially. The demonstration defines the pathway for broad commercial application and will accelerate the development of larger systems suitable for centralized utility scale electricity production.

03 NATURAL GAS↗

Optimizing Alabama’s CO 2 Storage in Shelby County (OASIS) (Final Report)

Optimizing Alabama’s CO 2 Storage in Shelby County (Project OASIS) is a CarbonSAFE Phase II designed to support the U.S. Department of Energy’s goals of reducing project risks and costs for future carbon dioxide (CO 2 ) capture, utilization, and storage (CCUS) projects, bringing more storage resources into commercial classifications that support business and financial decisions, and encouraging more rapid growth of a vibrant, geographically widespread industry for geologic carbon storage.

01 COAL, LIGNITE, AND PEAT↗