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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Determination of monomer concentrations in crystallizing lysozyme solutions

We have developed a non-optical technique for the study of aggregation in lysozyme and other protein solutions. By monitoring the rate at which lysozyme traverses a semipermeable membrane it was possible to quantitate the degree of aggregation in supersaturated solutions. Using this technique, we have measured the concentration of monomers and larger aggregates in under- and oversaturated lysozyme solutions, and in the presence of crystals, at pH 4.0 and 3 percent NaCl (0.1M NaAc). Comparison of these concentration profiles with (110) face growth rate data supports the theory that tetragonal lysozyme crystals grow by addition of preformed aggregates and not by monomer addition. The data suggest that a considerable population of aggregates larger than dimers are present at lysozyme concentrations above 22 mg/ml. Determination of dimer concentrations, and equilibrium constants for subsequent aggregation levels, are currently underway.

Wilson, L. J.↗
NASA NTRS1993

Coastal zone color scanner pigment concentrations in the southern ocean and relationships to geophysical surface features

Climatological data on the distribution of surface pigment fields in the entire southern ocean over a seasonal cycle are examined. The occurrence of intense phytoplankton blooms during austral summer months and during other seasons in different regions is identified and analyzed. The highest pigment concentrations are observed at high latitudes and over regions with water depths usually less than 600 m. Basin-scale pigment distribution shows a slightly asymmetric pattern of enhanced pigment concentrations about Antarctica, with enhanced concentrations extending to lower latitudes in the Atlantic and Indian sectors than in the Pacific sector. A general increase in pigment concentrations is evident from the low latitudes toward the Antarctic circumpolar region. Spatial relationships between pigment and archived geophysical data reveal significant correlation between pigment distributions and both bathymetry and wind stress, while general hemispheric scale patterns of pigment distributions are most coherent with the geostrophic flow of the Antarctic Circumpolar Current.

Comiso, J. C.↗
NASA NTRS1993

The concentration and isotopic composition of carbon in basaltic glasses from the Juan de Fuca Ridge, Pacific Ocean

The abundance and C-13/C-12 ratios of carbon were analyzed in basaltic glass from twenty locations along the Juan de Fuca Ridge using a 3-step combustion/extraction technique. Carbon released during the first two combustion steps at 400-500 C and 600-650 C is interpreted to be secondary, and only the carbon recovered during a final combustion step at about 1200 C is thought to be indigenous to the samples. For carbon released at about 1200 C, glasses analyzed as 1-2 mm chips contained 23-146 ppm C with delta C-13 values of -4.8 to -9.3 per mil, whereas samples crushed to 38-63 microns or 63-90 microns yielded 56-103 ppm C with delta C-13 values of -6.1 to -9.2 per mil. The concentrations and isotopic compositions of the primary carbon dissolved in the glasses and present in the vesicles are similar to those previously reported for other ocean-ridge basalts. The Juan de Fuca basaltic magmas were not in equilibrium with respect to carbon when they erupted and quenched on the sea floor. Evidence of disequilibrium includes (1) a large range of carbon contents among glasses collected at similar depths, (2) a highly variable calculated carbon isotopic fractionation between melt and vapor determined by comparing crushed and uncrushed splits of the same sample, and (3) a lack of correlation between vesicle abundance, carbon concentration, and depth of eruption. Variations in carbon concentration and delta C-13 ratios along the ridge do not correlate with major element chemistry. The observed relationship between carbon concentrations and delta C-13 values may be explained by late-stage, variable degrees of open-system (Rayleigh-like) degassing.

Blank, Jennifer G.↗
NASA NTRS1993

Probabilistic simulation of stress concentration in composite laminates

A computational methodology is described to probabilistically simulate the stress concentration factors in composite laminates. This new approach consists of coupling probabilistic composite mechanics with probabilistic finite element structural analysis. The probabilistic composite mechanics is used to probabilistically describe all the uncertainties inherent in composite material properties while probabilistic finite element is used to probabilistically describe the uncertainties associated with methods to experimentally evaluate stress concentration factors such as loads, geometry, and supports. The effectiveness of the methodology is demonstrated by using it to simulate the stress concentration factors in composite laminates made from three different composite systems. Simulated results match experimental data for probability density and for cumulative distribution functions. The sensitivity factors indicate that the stress concentration factors are influenced by local stiffness variables, by load eccentricities and by initial stress fields.

Chamis, C. C.↗
NASA NTRS1993

Relation of major volcanic center concentration on Venus to global tectonic patterns

Global analysis of Magellan image data indicates that a major concentration of volcanic centers covering about 40 percent of the surface of Venus occurs between the Beta, Atla, and Themis regions. Associated with this enhanced concentration are geological characteristics commonly interpreted as rifting and mantle upwelling. Interconnected low plains in an annulus around this concentration are characterized by crustal shortening and infrequent volcanic centers that may represent sites of mantle return flow and net downwelling. Together, these observations suggest the existence of relatively simple, large-scale patterns of mantle circulation similar to those associated with concentrations of intraplate volcanism on earth.

Crumpler, L. S.↗
NASA NTRS1988

Effects of hemorrhagic hypotension on tyrosine concentrations in rat spinal cord and plasma

Tyrosine is the precursor for catecholamine neurotransmitters. When catecholamine-containing neurons are physiologically active (as sympathoadrenal cells are in hypotension), tyrosine administration increases catecholamine synthesis and release. Since hypotension can alter plasma amino acid composition, the effects of an acute hypotensive insult on tyrosine concentrations in plasma and spinal cord were examined. Rats were cannulated and bled until the systolic blood pressure was 50 mmHg, or were kept normotensive for 1 h. Tyrosine and other large neutral amino acids (LNAA) known to compete with tyrosine for brain uptake were assayed in plasma and spinal cord. The rate at which intra-arterial (H-3)tyrosine disappeared from the plasma was also estimated in hemorrhaged and control rats. In plasma of hemorrhaged animals, both the tyrosine concentration and the tyrosine/LNAA ratio was elevated; moreover, the disappearance of (H-3)tyrosine was slowed. Tyrosine concentrations also increased in spinal cords of hemorrhaged-hypotensive rats when compared to normotensive controls. Changes in plasma amino acid patterns may thus influence spinal cord concentrations of amino acid precursors for neurotransmitters during the stress of hemorrhagic shock.

Conlay, L. A.↗
NASA NTRS1953

A study of elastic and plastic stress concentration factors due to notches and fillets in flat plates

Six large 24s-t3 aluminum-alloy-sheet specimens containing various notches or fillets were tested in tension to determine their stress concentration factors in both the elastic and plastic ranges. The elastic stress concentration factors were found to be slightly higher than those calculated by Neuber's method and those obtained photoelastically by Frocht. The results showed further that the stress concentration factor decreases as strains at the discontinuity enter the plastic range. A generalization of Stowell's relation for the plastic stress concentration factor at a circular hole in an infinite plate was applied to the specimen shapes tested and gave good agreement with test results.

Hardrath, Herbert F↗
NASA NTRS1993

Recent developments in refractive concentrators for space photovoltaic power systems

Since SPRAT 11, significant progress has been made in the development of refractive concentrator elements and components designed specifically for space applications. The status of the mini-dome Fresnel lens concentrator array is discussed and then the results of work recently completed in the area of prismatic cell covers for concentrator systems are summarized. This is followed by a brief discussion of some work just starting in the area of line-focus refractive concentrators for space.

Piszczor, Michael F.↗
NASA NTRS1994

Spacecraft maximum allowable concentrations for selected airborne contaminants, volume 1

As part of its efforts to promote safe conditions aboard spacecraft, NASA requested the National Research Council (NRC) to develop guidelines for establishing spacecraft maximum allowable concentrations (SMAC's) for contaminants, and to review SMAC's for various spacecraft contaminants to determine whether NASA's recommended exposure limits are consistent with the guidelines recommended by the subcommittee. In response to NASA's request, the NRC organized the Subcommittee on Guidelines for Developing Spacecraft Maximum Allowable Concentrations for Space Station Contaminants within the Committee on Toxicology (COT). In the first phase of its work, the subcommittee developed the criteria and methods for preparing SMAC's for spacecraft contaminants. The subcommittee's report, entitled Guidelines for Developing Spacecraft Maximum Allowable Concentrations for Space Station Contaminants, was published in 1992. The executive summary of that report is reprinted as Appendix A of this volume. In the second phase of the study, the Subcommittee on Spacecraft Maximum Allowable Concentrations reviewed reports prepared by NASA scientists and contractors recommending SMAC's for 35 spacecraft contaminants. The subcommittee sought to determine whether the SMAC reports were consistent with the 1992 guidelines. Appendix B of this volume contains the first 11 SMAC reports that have been reviewed for their application of the guidelines developed in the first phase of this activity and approved by the subcommittee.

National Research Council↗
NASA NTRS1994

Concentration and temperature effects on ovostatin activity

Light scattering experiments performed at Mississippi State University using MSFC ovostatin preparations indicated that at low ovostatin concentrations, below 0.2 mg/ml, the protein was dissociating from a tetramer into dimers. Since the proposed mechanism of action involved the tetrameric form of the protein, we hypothesized that perhaps under the conditions of our assays at various O/T ratios the ovostatin was becoming dissociated into an inactive dimer. To examine this possibility we assayed the ovostatin activity as a function of ovostatin concentration and of temperature of the assay. Data are presented that show the results of these assays at 23 C, 30 C, 37 C and 42 C respectively. The data are highly suggestive that there is a decrease in ovostatin activity as the concentration of the protein falls below 0.06 mg/ml. This may not be of any physiological importance, however, since the concentration of ovostatin in the egg is about 0.5 mg/ml. Curiously, the dissociation of the tetramer into dimers does not show a significant temperature dependence as would be expected for an equilibrium reaction. Whether this is in fact the case, or whether the differences are so small as to not be discerned from the current data remains to be seen. Another aspect to consider is that in the egg the primary role of the ovostatin may or may not be as a protease inhibitor. Although the inhibition of collagenase by ovostatin may be an important aspect of embryogenesis, it is also possible that it functions as a binding protein for some substance. In this regard, all ovostatin preparations from MSFC have shown an approximately 88,000 MW protein associated with the ovostatin. The identity of this protein is not currently known and may be the subject of future studies.

Moriarity, Debra M.↗
NASA NTRS1994

An update on the development of a line-focus refractive concentrator array

Concentrator arrays offer a number of generic benefits for space (i.e. high array efficiency, protection from space radiation effects, minimized plasma interactions, etc.). The line-focus refractive concept, however, also offers two very important advantages: (1) relaxation of precise array tracking requirements to only a single axis and (2) low-cost mass production of the lens material. The linear refractive concentrator can be designed to provide an essentially flat response over a wide range of longitudinal errors for satellites having only single-axis tracking capability. New panel designs emphasize light weight, high stiffness, storability, and ease of manufacturing and assembly. This paper addresses the current status of the concentrator program with special emphasis on the design implications, and flexibility, of using a linear refractive concentrator lens as well as details recent fabrication of prototype hardware.

Piszczor, Michael F.↗
NASA NTRS1994

Comparison of the seasonal and interannual variability of phytoplankton pigment concentrations in the Peru and California Current systems

Monthly composite images from the global coastal zone color scanner (CZCS) data set are used to provide an initial illustration and comparison of seasonal and interannual variability of phytoplankton pigment concentration along the western coasts of South and North America in the Peru Current system (PCS) and California Current system (CCS). The analysis utilizes the entire time series of available data (November 1978 to June 1986) to form a mean annual cycle and an index of interannual variability for a series of both latitudinal and cross-shelf regions within each current system. Within 100 km of the coast, the strongest seasonal cycles in the CCS are in two regions, one between 34 deg and 45 deg N and the second between 24 deg and 29 deg N, each with maximum concentrations (greater than 3.0 mg m(exp-3)) in May-June. Weaker seasonal variability is present north of 45 deg N and in the Southern California Bight region (32 deg N). Within the PCS, in the same 100-km-wide coastal region, highest (greater than 45 deg S) and lowest (less than 20 deg S) latitude regions have a similar seasonal cycle with maximum concentrations (greater than 1.5 mg m(exp -3)) during the austral spring, summer, and fall, matching that evident throughout the CCS. Between these regions, off northern and central Chile, the seasonal maximum occurs during July-August (austral winter), contrary to the influence of upwelling favorable winds. Within the CCS, the dominant feature of interannual variability in the 8-year time series is a strong negative concentration anomaly in 1983, an El Nino year. The relative value of this negative anomaly is strongest off central California and is followed by an even stronger negative anomaly is strongest off central California and is followed by an even stronger negative anomaly in 1984 off Baja, California. In the PCS, strong negative anomalies during the 1982-1983 El Nino period are evident only off the Peruvian coast and are evident there only in the regions 100 km or more from the coast. Although negative anomalies associated with the El Nino were not present at higher latitudes (more than approximately 20 deg S) in the PCS, the extremely sparse sampling weakens our confidence in the results of the interannual analysis in this region. An upper estimate of the systematic winter bias remaining in the global CZCS data after reprocessing with the multiple scattering algorithm is given in the appendix.

Thomas, A. C.↗
NASA NTRS1994

Superconducting YBa2Cu3O7 Powder: Reduction of Carbon, Moisture, and Impurity Phase Concentrations in Commercial Powders and the Reactivity with Moisture and Carbon Dioxide

The purpose of this study was to determine the experimental parameters under which commercially pure YBa2Cu3O7 (1237) powders would be converted into a single phase (1237) powder only. Carbon (present as carbonate) and impurity phase concentrations in the (1237) powder are very dependent upon the firing temperatures, heat-treating temperatures and times, and atmosphere, while the moisture concentration is not. YBa2Cu3O7 powder with about 0.03 wt/%, carbon, 0.03 wt% moisture, and low impurity phase concentrations was obtained. Moisture and carbon concentrations in heat-treated powders did not increase significantly after 48 and 72 h of exposure to air, respectively, and after 144 h of exposure they were less than 0.26 and 0.08 wt/%, respectively. The (1237) powder first reacts with moisture and then hydroxide reacts with CO2. Firing the as received powders in air led to the decomposition of the superconducting (1237) phase.

Stecura, Stephan↗
NASA NTRS1996

Spacecraft Maximum Allowable Concentrations for Selected Airborne Contaminants

As part of its efforts to promote safe conditions aboard spacecraft, NASA requested the National Research Council (NRC) to develop guidelines for establishing spacecraft maximum allowable concentrations (SMACs) for contaminants, and to review SMACs for various spacecraft contaminants to determine whether NASA's recommended exposure limits are consistent with the guidelines recommended by the subcommittee. In response to this request, the NRC first developed criteria and methods for preparing SMACs for spacecraft contaminants, published in its 1992 report Guidelines for Developing Spacecraft Maximum Allowable Concentrations for Space Station Contaminants . Since then, the Subcommittee on Spacecraft Maximum Allowable Concentrations has been reviewing NASA's documentation of chemical-specific SMACs as described in the Introduction to this volume. This report is the third volume in the series Spacecraft Maximum Allowable Concentrations for Space Station Contaminants . The first volume was published in 1994 and the second in 1996.

National Research Council↗
NASA NTRS1996

Gravity Induced Formation of Concentration Gradients in Supersaturated Binary Solutions

Experimental and theoretical studies of the formation of solute concentration gradient in supersaturated binary solutions in a gravitational field were carried out. The formation of solute concentration gradient was associated with the gravity induced redistribution of subcritical solute clusters. The birth-death process of the new solute-rich phase domains (subcritical solute clusters) was described in terms of the time-dependent Ginzburg Landau model developed for metastable state relaxation in binary (solute + solvent) non-critical solutions in the presence of a gravitational field. A new mathematical Ansatz was developed for solution of the model equations. This Ansatz has allowed to approach for the first time the following important problems: (1) Microstructure of solute distribution inside of the subcritical solute clusters. The analytical results obtained demonstrate that solute inside of the subcritical solute clusters is heterogeneously distributed with a spatially periodic structure. (2) Macrostructure of the solute subcritical clusters distribution in a gravitational field. The subcritical solute clusters are found to be distributed heterogeneously in a gravitational field. This heterogeneity, which is due to the heterogeneous birth-death process of the subcritical solute clusters in a gravitational field, initiates a noticeable solute concentration gradient in vertical columns of supersaturated binary solutions. An analysis and comparison of theoretical results and experimental data related to the solute concentration gradient formation in a gravitational field are presented. It is also demonstrated that the critical radius of solute clusters (radius of nucleation) and induction time are gravity-dependent.

Izmailov, Alexander F.↗
NASA NTRS1997

Design and Fabrication of a Dielectric Total Internal Reflecting Solar Concentrator and Associated Flux Extractor for Extreme High Temperature (2500K) Applications

The Analex Corporation, under contract to the NASA Lewis Research Center (LeRC), Cleveland, Ohio, recently evaluated the feasibility of utilizing refractive secondary concentrators for solar heat receivers operating at temperatures up to 2500K. The feasibility study pointed out a number of significant advantages provided by solid single crystal refractive devices over the more conventional hollow reflective compound parabolic concentrators (CPCs). In addition to the advantages of higher concentration ratio and efficiency, the refractive concentrator, when combined with a flux extractor rod, provides for flux tailoring within the heat receiver cavity. This is a highly desirable, almost mandatory, feature for solar thermal propulsion engine designs presently being considered for NASA and Air Force thermal applications. Following the feasibility evaluation, the NASA-LeRC, NASA-Marshall Space Flight Center (MSFC), and Analex Corporation teamed up to design, fabricate, and test a refractive secondary concentrator/flux extractor system for potential use in the NASA-MSFC "Shooting Star" flight experiment. This paper describes the advantages and technical challenges associated with the design methodologies developed and utilized and the material and fabrication limitations encountered.

Soules, Jack A.↗
NASA NTRS1997

Dimerization in Highly Concentrated Solutions of Phosphoimidazolide Activated Mononucleotides

Phosphoimidazolide activated ribomononucleotides (*pN) are useful substrates for the non-enzymatic synthesis of polynucleotides. However, dilute neutral aqueous solutions of *pN typically yield small amounts of dimers and traces of polymers; most of *pN hydrolyzes to yield nucleoside 5'-monophosphate. Here we report the self-condensation of nucleoside 5'-phosphate 2- methylimidazolide (2-MeImpN with N = cytidine, uridine or guanosine) in the presence of Mg2(+) in concentrated solutions, such as might have been found in an evaporating lagoon on prebiotic Earth. The product distribution indicates that oligomerization is favored at the expense of hydrolysis. At 1.0 M, 2-MelmpU and 2-MelmpC produce about 65% of oligomers including 4% of the 3',5'-Iinked dimer. Examination of the product distribution of the three isomeric dimers in a self-condensation allows identification of reaction pathways that lead to dimer formation. Condensations in a concentrated mixture of all three nucleotides (U,C,G mixtures) is made possible by the enhanced solubility of 2-MeImpG in such mixtures. Although percent yield of intemucleotide linked dimers is enhanced as a function of initial monomer concentration, pyrophosphate dimer yields remain practically unchanged at about 20% for 2-MelmpU, 16% for 2-MeImpC and 25% of the total pyrophosphate in the U,C,G mixtures. The efficiency by which oligomers are produced in these concentrated solutions makes the evaporating lagoon scenario a potentially interesting medium for the prebiotic synthesis of dimers and short RNAs.

Kanavarioti, Anastassia↗
NASA NTRS1998

The Optical Design of a System using a Fresnel Lens that Gathers Light for a Solar Concentrator and that Feeds into Solar Alignment Optics

The Marshall Space Flight Center (MSFC) has been developing a space deployable, lightweight membrane concentrator to focus solar energy into a solar furnace while remaining aligned to the sun. For an inner surface, this furnace has a cylindrical heat exchanger cavity coaligned to the optical axis; the furnace warms gas to propel the spacecraft. The membrane concentrator is a 1727 mm (68.00 in.) diameter, F/1.7 Fresnel lens. This large membrane is made from polyimide and is 0.076 mm (0.0030 in.) thick; it has the Fresnel grooves cast into it. The solar concentrator system has a super fast paraboloid reflector near the lens focus and immediately adjacent to the cylindrical exchanger cavity. The paraboloid collects the wide bandwidth and some of the solar energy scattered by the Fresnel lens. Finally, the paraboloid feeds the light into the cylinder. The Fresnel lens also possesses a narrow annular zone that focuses a reference beam toward four detectors that keep the optical system aligned to the sun; thus, occurs a refracting lens that focuses two places! The result can be summarized as a composite Fresnel lens for solar concentration and alignment.

Wilkerson, Gary W.↗