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At least 271 records · Page 15

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for Mn ions in low-density high-temperature plasmas

The analysis of optically-thin far-ultraviolet and X-ray emission lines of multiply-charged ions is one of the basic methods for determining the temperatures and densities of laboratory and astrophysical plasmas. In addition, the energy balance in these plasmas can be significantly influenced by the emission of radiation from relatively low concentrations of multiple-charged atomic ions. Because the populations of the excited levels are expected to depart substantially from their local thermodynamic equilibrium values a detailed treatment of the elementary collisional and radiative processes must be employed in order to predict the emission line intensities. In this investigation the authors present the results of calculations based on a corona equilibrium model in which a detailed evaluation is made of the dielectronic recombination rate coefficients. The ionization and autoionization following inner-shell electron excitation from each ground state are balanced by direct radiative and dielectronic recombination. The spectral line intensities emitted by the low-lying excited states, which are assumed to undergo spontaneous radiative decay in times that are short compared with the collision time, are evaluated in terms of the corona ionization equilibrium distributions of the ground states and their electron-impact excitation states.

Jacobs, V. L.↗

The ionosphere above Alma Ata during a solar eclipse

The eclipse effect was manifested during the second phase: the ionization of the F1- and F2-layers decreased and the minimum effective heights of E and F2 increased due to recombination processes. The manner in which electron density is distributed over the levels was ascertained from analysis of N(t) curves.

Rudina, M. P.↗

A model of the Venus ionosphere

Results of model calculations of the Venus ionosphere from 120 to 300 km are presented. The chemical scheme and reaction rates used are the same as given by Kumar and Hunten (1974) except that the electron temperature dependence of the dissociative recombination rates is taken into account. Calculations are made for low and high atomic oxygen models in which the O/CO2 ratios are 0.4% and 4% respectively at 140 km, and the results agree well in shape and magnitude with the Mariner 5 and 10 occultation results in the chemically controlled region. Reasonable agreement is obtained at higher altitudes if diffusive equilibrium and high vertical flow velocities (10 km/s) are assumed as upper boundaries for the Mariner 5 and 10 conditions respectively, although solar wind-ionosphere interactions are considered to be the controlling mechanism for the Mariner 10 results.

Nagy, A. F.↗

A model of carbon production in a cometary coma

A model of the cometary ionosphere is developed in order to account for the large population of metastable C(D-1) atoms detected via the ultraviolet spectrum of Comet West (1976 VI). Dissociative recombination of CO(plus) ions and electrons is shown to be the dominant source of carbon atoms rather than photodissociation of CO so that the derived carbon production rate is only a lower limit to the evaporation rate of the carbon bearing mother molecule.

Feldman, P. D.↗

Theory of the intercluster medium

A set of computer models for the evolution of intercluster matter (ICM) in expanding cosmologies which includes processes of electron impact ionization/excitation, radiative and dielectronic recombination, thermal bremsstrahlung, Compton scattering, and photoionization is presented. The thermal, ionization, and excitation histories of major constituents were found as functions of time, and predictions of emission spectra, the possible distortions of the cosmic 3 K microwave background, and optical depths of absorption troughs in QSO continua at various redshifts were obtained. It is concluded that the present Friedmann cosmology can be dominated by hot intercluster matter which would contain H and He in their cosmic ratio and traces of heavier elements. For a narrow range of parameters it is possible to generate cosmologies with a closure density of ICM which do not exceed the diffuse X-ray measurements. In open cosmologies distortion of the 3 K microwave background occurs, while closed cases show negligible change from the unperturbed spectrum.

Sherman, R. D.↗

Comparison of the N2/+/ photochemistry at different phases of the solar cycle

Thermospheric and ionospheric data obtained on 12 orbits throughout 1978 are analyzed using the chemical scheme established during 1974 when the solar EUV intensities were less than half of those encountered in 1978. It is shown that this scheme, with some modification, applies to the more active period. Photoionization of N2 is found to be the major source of N2(+) in the F2 layer, by contrast with the charge exchange reaction of O+(2D) with N2, which was dominant for the lower solar activity. The results confirm the laboratory measurements of the dissociative recombination rate coefficient for N2 with electrons, as well as the theoretically calculated rate coefficient for the quenching of O+(2D) by electrons.

Torr, M. R.↗

Bulk compositions of chondrules in the Allende meteorite

The bulk chemistries of 33 chondrules from the Allende meteorite were determined by electron microbeam analyses and the modal recombination model. Chondrules were selected on the basis of a petrographic study of 2755 inclusions, of which 997 are chondrules, classified as recrystallized olivine chondrules, euhedral olivine chondrules, anhedral olivine chondrules, glassy/skeletal olivine chondrules, barred olivine chondrules, and pyroxene type chondrules. The data indicate that nonequilibrium metastable paths of crystallization were followed, a model which is supported by olivine-liquid (glassy mesostases) relationships. Variations in olivine morphology are related to cooling rate, degree of supercooling, normative olivine, and calculated viscosities. The chondrules in Allende were derived from highly undersaturated ultramafic melts in which Fe-Ni-S-O immiscible liquids were produced. The chondrule suite exhibits systematic variations in volatile loss, and this relationship is used to support a melting event (however, neither the nature of this event nor the mechanism of melt formation is established).

Simon, S. B.↗

A new source of ozone in the terrestrial upper atmosphere?

The simultaneous measurements of atomic O, O2, O3, and N2 between 90 and 110 km obtained by a rocket-borne mass spectrometer flown during the Aladdin 74 program provide an opportunity to test directly the simple atmosphperic chemical model first proposed more than 50 years ago by S. Chapman, which is today the core of the complex chemistry controlling stratospheric O3. The Aladdin 74 O3 results are found to be significantly in excess of model abundances computed using the most current values of the key chemical parameters. The calculations may possibly be in error due to uncertainties in these key parameters and/or in the measurement of the related species. However, the extra O3 may be a consequence of reactions between ground state O2 and electronically excited O2 resulting from the recombination of atomic O.

Allen, M.↗

Ionospheric holes - A review of theory and recent experiments

Artificially induced ionospheric holes result from in situ injections of highly reactive molecules, which greatly enhance the chemical recombination rates between the ions and electrons found in the upper atmosphere. During the past decade, experiment-of-opportunity observations, theory and computer simulations have succeeded in establishing plasma-depletion experiments as a useful tool for probing the normal and disturbed behavior of the ionosphere. Ionospheric-hole experiments now focus on applications of the technique to laboratory-in-space investigations of various space plasma processes.

Mendillo, Michael↗

Introduction to dissociative recombination

Dissociative recombination (DR) of molecular ions with electrons has important consequences in many areas of physical science. Ab-initio calculations coupled with resonant scattering theory and multichannel quantum defect studies have produced detailed results illuminating the role of ion vibrational excitation, the quantum yields of the DR products, and the role of Rydberg states. The theoretical and experimental results are discussed.

Guberman, Steven L.↗

Optically Addressable Spatial Light Modulators

Integrated multiple-quantum-well/Fabry-Perot structure provides high-contrast variation of reflection of reading beam, under control of writing beam. Periodic potential barriers separate photogenerated electrons from holes, leading to long recombination lifetimes and large concentrations of free charge carriers. Concentrations quench excitons or fill energy bands in quantum wells, altering absorption of reading beam.

Maserjian, Joseph↗

Theoretical studies of interstellar processes

We have been studying the dissociative recombination (DR) of HeH(+) with an electron with the goal of calculating accurate cross sections and rate coefficients to allow for the accurate modelling of the abundance of HeH(+) in planetary nebulae and supernova envelopes. A unique feature of the HeH potential curves is that none of the neutral states cross the ion curve. This required a new approach to the calculation of DR cross sections and rate coefficients that had not yet appeared in the literature. Because of the lack of a potential curve crossing, the initial electron capture occurs by Born-Oppenheimer breakdown, i.e. by the interaction of the motion of the incoming electron with the nuclear motion. This same mechanism also drives DR in H3(+) and the methods developed and described below for HeH(+) DR will be used for the future calculation of H3(+) DR.

Guberman, Steven L.↗

Theoretical Studies of Interstellar Processes

During the current reporting period we have continued our studies of the dissociative recombination (DR) of HeH(+) with an electron with the goal of calculating accurate cross sections and rate coefficients to allow for the accurate modelling of the abundance of HeH(+) in planetary nebulae and supernova envelopes. We have also started studies of the DR of H3(+), a process of great importance in the interstellar medium.

Guberman, Steven↗

The upper ionospheres of Jupiter and Saturn

The electron-density profiles of Jupiter's and Saturn's ionospheres are modeled with a 1D chemical diffusive model incorporating measured parameters of the neutral atmospheric structure. The Voyager RSS ion-density data are modeled by accounting for ion chemistry, the H3(+) recombination-rate coefficient, and H2O chemistry. Electron-density peaks for both ionospheres are 900-1000 km lower in the model than the measured values, and the role of vibrational excitation of H2 is discussed in converting H(+) to H2(+) and H3(+). Vertical ion flow is also considered which can maintain the plasma peaks under the conditions of electrical fields or horizontal neutral winds. An assumed influx of H2O molecules of a specific quantity is theorized to reproduce the measured values on Saturn when combined with a vertical plasma drift.

Majeed, Tariq↗

A Polarized Universe

The CMB polarization was produced as light scattered off a primordial cloud of protons and electrons nearly 14 billion years ago, about 400,000 years after the Big Bang. This marks the moment of recombination, when the universe finally cooled enough to allow electrons to join protons. The CMB is the light that broke through the fog.

Wanjek, Christopher↗