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At least 271 records · Page 15

Mesosiderites and howardites - Igneous formation and possible genetic relationships

Neutron activation data are presented for major, minor, and trace elements in whole rock howardites and silicates from mesosiderites. Compositions of howardites and mesosiderites are similar and intermediate between those of eucrites and diogenites. It is indicated that mesosiderites have a higher normative silica component than howardites. It appears that this results partly from a higher content of a highly evolved igneous component and partly from in situ reduction of FeO to Fe followed by magnetic separation of metal prior to analysis. It is shown that light rare earth elements are enriched in some mesosiderites.

Mittlefehldt, D. W.↗

Pyroxenes in Serra de Mage - Cooling history in comparison with Moama and Moore County

Thin sections and single grains of pyroxenes from the Serra de Mage feldspar cumulate eucrites were studied by X-ray crystallography, electron microprobe and optical techniques. It was concluded that the pyroxene crystallized as pigeonite. On cooling augite was exsolved along (001) and inverted to hypersthene, with exsolution of (100) augite from hypersthene during continued slow cooling. The estimated original bulk composition of the pigeonite pyroxene is Wo10En51Fs39. The compositional data, textural relations, and existence of P2 sub 1 ca hypersthene suggest very low cooling (about 0.0004 deg C/year) below 800 deg. The Serra de Mage augite lamellae were found to be as thick or thicker than those of Moore County and Moama meteorites.

Harlow, G. E.↗

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗

Chemical composition of Mars

The chemical composition of Mars is estimated from the cosmochemical model of Ganapathy and Anders (1974) with additional petrological and geophysical constraints. The model assumes that planets and chondrites underwent the same fractionation processes in the solar nebula, and constraints are imposed by the abundance of the heat-producing elements, U, Th and K, the volatile-rich component and the high density of the mantle. Global abundances of 83 elements are presented, and it is noted that the mantle is an iron-rich garnet wehrlite, nearly identical to the bulk moon composition of Morgan at al. (1978) and that the core is sulfur poor (3.5% S). The comparison of model compositions for the earth, Venus, Mars, the moon and a eucrite parent body suggests that volatile depletion correlates mainly with size rather than with radial distance from the sun.

Morgan, J. W.↗

Planetary basalts - Chemistry and petrology

Recent literature (1975-1978) on planetary basalts is reviewed. Terrestrial basalts are considered in relation to Nd and Sm isotopic studies, magma mixing, chemical and mineralogical heterogeneities in basalt source regions, and partial melting controls on basalt chemistry. Attention is also given to features of mare basalts, eucrites, and comparisons of basalts for the earth, the moon, and the parent body of basaltic achondrites.

Papike, J. J.↗

Carbonaceous chondrites. I - Characterization and significance of carbonaceous chondrite /CM/ xenoliths in the Jodzie howardite

Mineralogical, chemical, textural, and isotopic studies of the abundant carbonaceous inclusions in the Jodzie howardite which are consistent with carbonaceous chondrite (CM) characteristics are examined. These CM xenoliths show regolith alteration comparable to the Murray and Murchison meteorites but less than Nogoya, flow-oriented development of phyllosilicates and 'poorly characterized phases', and partial oxidation of sulfides. Temperature-programmed pyrolysis mass spectrometry indicates that gas release patterns of volatiles and hydrocarbons, and N, C, and S contents are typical of CM meteorites. The fact that the Ne content is typical for 'solar' values and the isotopic structure of Xe is 'planetary' indicates that these gases were entrapped by different mechanisms, and cosmic ray exposure ages for the xenoliths agree with the reported exposure age for the eucritic host.

Bunch, T. E.↗

The condensation and fractionation of refractory lithophile elements

It is noted that Cr, Mg, and Si are fractionated in chondritic material along with, but to a lesser extent than, a large group of more refractory elements. These patterns are reexamined with the reasoning that this might imply some unique distribution at the time of fractionation. It is shown that apparently two distinct fractionization patterns can be resolved: one involving ordinary and enstatite chondrites and the other involving carbonaceous chondrites, the earth, the moon, and the eucrite parent body. It is noted that the two trends intersect at C1 composition. Attention is given to the range in which the largest fraction of planetary matter condenses. It is concluded that the appearance of large amounts of condensed materials is conceivably in some way related to the fractionization process, although the exact relationship cannot be specified.

Larimer, J. W.↗

Basaltic volcanism - The importance of planet size

The volumetrically abundant basalts on the earth, its moon, and the eucrite parent planet all have chemical compositions that are controlled to a large extent by dry, low-pressure, crystal-liquid equilibria. Since this generalization is valid for these three planetary bodies, we infer that it may also apply to the other unsampled terrestrial planets. Other characteristics of basaltic volcanism show variations which appear to be related to planet size: the eruption temperatures, degrees of fractionation, and chemical variety of basalts and the endurance of basaltic volcanism all increase with planet size. Although the processes responsible for chemical differences between basalt suites are known, no simple systematization of the chemical differences between basalts from planet to planet has emerged.

Walker, D.↗

Non-equilibrium effects on the chemistry of nebular condensates - Implications for the planets and asteroids

Kinetic effects, for example nucleation constraints and slow reactions, should have been important in nebular condensation. Consideration of these effects leads to the prediction of pressure-dependent compositions and physical properties of nebular condensates which is consistent with (1) the differences between different classes of chondritic meteorites, (2) some of the differences between planets, and (3) the presence of oxidized iron on the moon and in the eucrite parent body (presumably an asteroid) despite the low abundance of volatiles. Diffusion effects appear to be important for understanding oxygen isotope anomalies in refractory inclusions in Allende. The consideration of kinetic effects leads to more information concerning nebular processes than if equilibrium is assumed.

Blander, M.↗

Surface texture of Vesta from optical polarimetry

Polarimetric, photometric, and reflective spectroscopic properties of asteroid 4 Vesta are simulated in the laboratory by a preparation of eucrite Bereba consisting of a broad mixture of particle sizes (mainly greater than 50-micron) mixed and partially coated with particles of size 10 microns and less. Coarse grains are necessary for producing the same albedo and a very fine dust coating is necessary for producing the same polarization inversion angle as observed for Vesta. There are less small grains and fine dust in this sample than in lunar soils. Photometrically, if coating a sphere, this sample shows a constant brightness on the sunward half of the observed hemisphere, the brightness being given on the other half by the Minnaert reciprocity principle. With such a photometric behavior, the global geometric albedo and the sub-earth point geometric albedo differ by no more than 5%. The microscopic phase coefficient is 0.021 magnitude per degree for the sample; the larger value, 0.025, observed telescopically for Vesta, indicates that large-scale roughness is present on this asteroid.

Le Bertre, T.↗

The composition of mesosiderite olivine clasts and implications for the origin of pallasites

The composition of olivine clasts from the mesosiderites Emery, Mincy and Pinnaroo is investigated, and implications of the results for the origin of the pallasites, which, although chemically distinct, may be related to the diogenites, eucrites, howardites and mesosiderites, are discussed. Centimeter-sized olivines were analyzed by electron microprobe, and instrumental neutron activation analysis was performed on one olivine each from Emery and Pinnaroo and an olivine separate from the Brenham pallasite. The olivine compositions are found to range from Fa8 to Fa28, with Emery samples having values from Fa18 to Fa28, and to require essentially total melting of a source composition rich enough in FeO to produce basaltic clasts. It is argued that the mesosiderite olivines were formed in the outer few kilometers of their parent body, as were those of the pallasites, which have the same compositions as the mesosiderite olivines. A model is then developed for the origin of the pallasites as a by-product of igneous differentiation in the external heating of a chondritic parent body.

Mittlefehldt, D. W.↗

Orthopyroxene-olivine assemblages in diogenites and mesosiderites

Diogenites contain equilibrated orthopyroxene-olivine assemblages. Mn is very regularly partitioned between olivine and orthopyroxene in pallasites, diogenites and synthetic eucrite melts, with an FeO/MnO partition ratio for olivine versus orthopyroxene of 1.6 by weight over a very wide range of FeO contents. In contrast to diogenites, Fe and Mn are not regularly partitioned between the olivine and orthopyroxene of mesosiderites and these minerals were not in equilibrium. Mesosiderite olivine differs from diogenite olivine in Fe/Mn and Ca/Mn ratios. Lack of olivine-orthopyroxene equilibrium suggests that olivine in mesosiderites was derived not from a pyroxenite component analogous to diogenites but from dunites.

Hewins, R. H.↗

Hafnium isotope variations in oceanic basalts

Hafnium isotope ratios generated by the beta(-) decay of Lu-176 are investigated in volcanic rocks derived from the suboceanic mantle. Hf-176/Hf-177 and Lu/Hf ratios were determined to precisions of 0.01-0.04% and 0.5%, respectively, by routine, low-blank chemistry. The Hf-176/Hf-177 ratio is found to be positively correlated with the Nd-143/Nd-144 ratio and negatively correlated with the Sr-87/Sr-86 and Pb-206/Pb-204 ratios, and to increase southwards along the Iceland-Reykjanes ridge traverse. An approximate bulk earth Hf-176/Hf-177 ratio of 0.28295 is inferred from the bulk earth Nd-143/Nd-144 ratio, which requires a bulk earth Lu/Hf ratio of 0.25, similar to the Juvinas eucrite. Midocean ridge basalts are shown to account for 60% of the range of Hf isotope ratios, and it is suggested that Lu-Hf fractionation is decoupled from Sm-Nd and Rb-Sr fractionation in very trace-element-depleted source regions as a result of partial melting.

Patchett, P. J.↗

Lunar and Planetary Science Conference, 11th, Houston, TX, March 17-21, 1980, Proceedings. Volume 2 - Meteorite and regolith studies

Topics discussed include studies of chondrites, mesosiderites, and achondrites; isotope modeling; Antarctic weathering; irradiation effects; lunar regolith studies; the Apollo 17 drill core; soils and agglutinates; and volatiles. Particular attention is given to the proportional retention of I and Xe-129 in preheated Allende, olivine clasts from mesosiderites and howardites as clues to the nature of achondritic parent bodies, a record of solar corpuscular radiation in minerals from lunar soils, the experimental shock metamorphism of lunar soil, and the clouding of pyroxene and plagioclase in eucrites.

Merrill, R. B.↗

Olivine clasts from mesosiderites and howardites - Clues to the nature of achondritic parent bodies

The compositional ranges of olivine clasts from mesosiderites and most clasts from howardites (FO90-55 and FO89-45 respectively) overlap. Only one clast in howardite Allan Hills A78006,9 (FO16) differs significantly. Differences in FeO/MnO in olivines from the two groups may be explained by different redox states of their source regions. Whether the two meteorite groups were derived from the same parent body is not clear, but the lack of Fe-rich eucritic clasts in mesosiderites together with the lack of tridymite-phosphate rich gabbros and basalts in howardites, suggests that different bodies are required since both meteorite groups are near-surface polymict breccias, which have probably sampled significant portions of their parent body surfaces.

Delaney, J. S.↗

Constraints on the moon's origin from the partitioning behaviour of tungsten

An evaluation is conducted of the parameters which control the partitioning of W between metal and silicate in the moon, taking into account information on the possible magnitudes of the lunar W depletion and the possible lunar metal content. A major question regarding depletion of W during partial melting is found to be related to the very homogeneous W/La ratios in lunar samples. It is concluded that a metal content consistent with present geophysical constraints on the size of a metallic lunar core could account for the depletion of W observed in lunar rocks. The low W/La ratio of the moon cannot be used as evidence for the formation of the moon from the earth's mantle by fission following terrestrial core formation. The approximate coincidence of W/La ratios in the earth, moon, and eucrite parent body may only reflect the operation of the same depletion mechanism in similar conditions on several parent bodies.

Newsom, H. E.↗

Chemical composition of the Howardite Parent Body deduced from Kapoeta primary 'mafic' magmas

Chemical data are presented for three 'mafic' clasts extracted from the Kapoeta howardite. Bulk compositions and petrologic observations suggest that two of these lithic clasts represent olivine-plagioclase bearing orthopyroxenites. Chondrite-relative refractory large ion lithophile abundances of two of the clasts are inferred to represent primary Mg-rich magmas produced by extensive (greater than about 70%) partial melting of a source composition indistinguishable from the silicate fraction of average CH-CL ordinary chondrites, with the exception of the depletion of the alkalis Na and K by a factor of 13 + or - 1 in the source composition. A metal-free and volatile depleted Kapoeta Parent Body (KPB) is subsequently deduced and is shown to compare very well with other similarly derived Achondrite Parent Body and Howardite Parent Body estimates but not to parent body estimates derived from inferences based on eucrite phase equilibrium studies. Other implications suggest that the KPB is heterogeneous with respect to Fe/Mg ratios.

Smith, M. R.↗

Brachina - A new type of meteorite, not a Chassignite

The results of a study of the small achondrite found in 1974 near Brachina, Australia are presented and discussed. Trace element data for Brachina were found to be quite different from that for Chassigny. The major differences are higher FeO/MnO, Ge/Al, and K/La ratios, W depletion, high siderophile content, near-horizontal REE pattern at about 1 x chondrite level, high refractory/nonrefractory metal ratios (e.g., Ir/Au), and chalcophile element depletion. Brachina's 4.5 billion year age and oxygen isotropic signature within the eucritic field further suggest that it is not related to Chassigny or SNC meteorites, though it may be related to primitive meteorites, such as silicate inclusions in IAB irons and winonaites.

Nehru, C. E.↗