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Northwest Combined Heat and Power Technical Assistance Partnership: Final Scientific/Technical Report

During the years of 2018 through 2023, The Washington State University Energy Program (WSU EP) operated the Northwest Combined Heat and Power Technical Assistance Partnership under contract to the US Department of Energy’s Advanced Manufacturing Office (AMO), a part of DOE’s larger Office of Energy Efficiency and Renewable Energy. This contract provided direction and funding for providing technical outreach, information and technical/economic analysis services in support of expanding development of Combined Heat and Power (CHP) over a four state region in the Pacific Northwest. The states served included Alaska, Idaho, Oregon and Washington. During the duration of this contract, the WSU EP delivered performed specific assigned tasks and provided services of various generally prescribed types, with the overall goal of increasing adoption of CHP as an efficient heat and power supply in the region. Indications – though not formally evaluated to our knowledge – are that this goal was achieved. Over many years, the WSU team has provided support for CHP developments in these states under similar previous Department of Energy contracts, and many such projects have been built. While the early-phase outreach, education and techno-economic assessments that the NW CHP TAP provides rarely immediately result in project construction, there is no doubt that the WSU EP team has had substantial influence in the construction of a number of important CHP projects in the region. Examples of projects implemented directly under the current team’s guidance and services during this contract cycle include an 875 kilowatt biomass fueled CHP system installed at the University of Idaho, and 5 megawatt natural gas fueled CHP system at the University of Montana ( UM Breaks Ground on New Power Facility, Slashes Emissions 30% (umt.edu) ). Many other CHP systems recently installed are also either directly or at least partially the result of information and technical services provided by the team. Finally, though much more difficult to quantify and less glamorous, the team has helped countless organizations to understand CHP and determine whether and how CHP may be a fit for them, before they consider paying for engineering services. Whether the ultimate outcome has been to include CHP or not, the expert skills provided by the NW CHP TAP team have provided real value to these organizations considering this relatively complex technology. Over the duration of the contract our team provided 71 Initial Technical Assessments and 17 Advanced Technical Assessments; 53 End-User Engagements and 33 Stakeholder Engagements of various types; 42 Technical Profiles (Project Profiles, Program Profiles and Policy Profiles), and produced 14 technical articles for the Department of Energy. Unfortunately, these quantities provide no measure of the value that the team has provided. Only our clients can judge that, and we are confident that they are pleased with the benefits we have offered them.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Renewable Energy and Storage Cybersecurity Research (RESCue) Pilot Final Report

The Renewable Energy and Storage Cybersecurity Research (RESCue) project is a collaborative effort aimed at securing the rapidly growing deployment of distributed energy resources (DERs) and transmission-connected hybrid renewable energy systems against escalating cyber threats. This project brings together major original equipment manufacturers (OEMs) of wind, solar, and energy storage, along with major asset owners and DOE National Laboratories, to collectively identify cyber threats, assess risks, and develop robust cybersecurity strategies and solutions. This publication the final report for the first year of the project.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Kansas City, Missouri, Streetlight Electric Vehicle Charging: Strategies and challenges for site selection of streetlight electric vehicle infrastructure in Kansas City, Missouri (Final Report)

Public streetlight charging, whether on streets in central business districts or residential areas, provides easy charging access for apartment residents and homeowners alike. While most electric vehicle (EV) drivers charge at home, they do so in garages or on driveways they own. For renters and residents of multifamily housing (MFH), however, this may not be an option. EVs have a lower cost of ownership compared to conventional vehicles, and a used EV may be an affordable option for a lower-income household. But without easy access to charging, even a low-cost used EV may not be an option for a prospective buyer. An affordable curbside charging network has the potential to expand EV adoption into neighborhoods that have to date seen minimal interest and uptake of the technology and associated charging infrastructure. Streetlight charging networks can provide an economical, scalable, and effective approach to providing equitable and convenient charging. Metropolitan Energy Center (MEC) is dedicated to the mission of creating resource efficiency, environmental health, and economic vitality in the Kansas City region and beyond. Since 1983, MEC has provided resources, outreach, and training to make alternative fuels and energy efficiency commonplace. MEC led a streetlight charging pilot project that installed limited EV charging infrastructure on the streetlight system in Kansas City, Missouri, to demonstrate and test the benefits of curbside charging for EVs at existing on-street parking locations. The project aimed to cost-effectively expand the charging network in Kansas City to support residential charging and provide infrastructure in one or more charging deserts throughout the city. This pilot evaluates the impact and overall success of streetlight charging based on community feedback, utilization of charging infrastructure, technical feasibility, and cost. The project has pursued a data- and community-driven site selection process designed to identify sites with high demand and high opportunity for EV charging. This project was funded by the U.S. Department of Energy (DOE) and awarded to MEC through a competitive proposal process. The novelty and complexity of this project required an organization that could facilitate collaboration across levels of government, community members, and industry partners. For the past 25 years, through Kansas City Regional Clean Cities, MEC has worked with numerous public and private fleets on a variety of projects to improve the environmental performance and efficiency of the regional vehicle fleet. To advance affordable, efficient, and clean transportation efforts, DOE Clean Cities and Communities coalitions create local networks of public and private sector stakeholders and engage communities. Rooted within their local communities, the coalitions serve as experts and ambassadors, bringing to bear the collective knowledge, experience, and practical know-how of the entire network from within DOE, its national laboratories, and diverse stakeholders in the field. MEC and its project partners made in-kind contributions to leverage federal dollars for the benefit of the Kansas City community. Findings from this project will help determine the best applications for streetlight charging technologies to maximize funding impact and serve community needs. The team evaluated locations based on expected charging demand, technical feasibility, safety considerations, and enhanced charging network siting needs. Throughout the project, the team gathered feedback and evaluated ways to make public charging for EVs available to all community members. The insights will help Kansas City and other communities streamline future efforts to support EV drivers through public charging in the city right-of-way. Furthermore, this project will inform citywide guidance for future installations. MEC is committed to a transparent and publicly accessible approach that encourages the collaborative evaluation of streetlight charging. The project has engaged the community to proactively identify and evaluate the benefits and impacts of streetlight charging. It was a priority for the project to ensure the benefits of this pilot are distributed equitably to all members of the Kansas City community and that new charging opportunities and associated resources are available in diverse neighborhoods across the city. The charging infrastructure supports an affordable curbside charging network that will enable more drivers to choose EVs and provide easy charging access for all community members interested in driving an EV. The community feedback received through this project informed future resources and opportunities to make EVs more accessible to all members of the Kansas City community. MEC worked with several community partners on this project, including Missouri University of Science and Technology (MST), Pennsylvania State University (Penn State), the National Renewable Energy Laboratory (NREL); the city of Kansas City, Missouri; Evergy; Black and McDonald (B&M); LilyPad EV; EVNoire; and Westside Housing Organization (WHO). Project partners contributed to the cost match required for DOE grants through capital expenditures, personnel, and other in-kind contributions. Detailed descriptions of project team organizations can be found in Appendix A. Project Partners. Analysts at NREL and MST/PennState developed site maps based on demand and equity considerations. MEC conducted outreach to community members to garner input on project design and site selection, and received approval from the Missouri Public Service Commission (PSC) for Evergy’s EV charging station ownership. MEC worked with all partners to gather additional siting criteria and developed a site selection evaluation checklist, and partners conducted site visits to proposed installation sites. Next, B&M, Evergy, and the city executed all site agreements, conducted site-specific engineering design, acquired associated permits, and issued notices to proceed site by site or in small batches. Finally, from January to April 2023, the project team installed 23 EV charging stations built on Kansas City’s streetlight system in six council districts. Evergy will own, operate, and monitor the stations for 10 years, sharing charging data with MEC for at least 1 year.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Transport Analysis & Optimization in a MW-Scale CO2 Electrolyzer (Final Report)

As Twelve continues to scale up their CO2 electrolyzers, both in the size of a single cell and in the number of cells used in a stack, thermal management becomes a growing concern, since excess heat can affect reaction yield and accelerate degradation. In this project, we aim to computationally explore how the anode flow fields used in Twelve’s CO2 electrolyzers function as heat exchangers. In particular, using a homogenized model of a CO2 electrolyzer, we first estimate the amount of heat generated in a cell. Then, we develop a computational fluid dynamics (CFD) model of the so-called “flow field”, i.e. a flow manifold, based on Twelve’s CAD drawings, to evaluate how these flow fields perform as a heat exchanger for the generated heat. We explore both a single cell and a 3-cell stack operating in parallel, where heat generated in one cell can now be transferred to another cell. We evaluate how performance is affected when environmental heat losses are taken into account. Finally, we leverage topology optimization to explore the types of design features a computational optimization algorithm would suggest to supplement our intuition. Overall, our work aims to provide design recommendations for CO2 electrolyzer flow fields and provides a foundation for future studies of flow field optimization.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

FEED Study for Climeworks Direct Air Capture at a California Geothermal Facility with Long-Term Storage (Final Scientific/Technical Report)

The overall objective of the project is to execute and complete a front-end engineering and design (FEED) study of an advanced Direct Air Capture (DAC) and Storage (DAC+S) system that is capable of removing and sequestering a minimum of 5,000 tonne/yr of CO 2 from the air based on cradle-to-gate life cycle assessment (LCA). The project will examine retrofitting and utilizing an existing domestic geothermal resource. The selected DAC system will be technology from Climeworks AG (Climeworks) that consists of an adsorption-desorption process to remove CO 2 from ambient air by using a selective filter. The geothermal host site is operated by Ormat Technologies Inc. (ORMAT). The DAC system will capture CO 2 using thermal energy from the host geothermal resource. This Final Scientific/Technical Report is a collection of the deliverables for the project. The project team was not able to successfully complete all the necessary tasks for this project. Shortly after the start of the project, two (2) project partners removed themselves from the study. The Awardee attempted to find a replacement for the direct air capture technology provider and geothermal energy provider. Due to this the awardee submitted a letter of cancellation for the project, letter is attached in the appendix. No funds were expended during the course of the project.

15 GEOTHERMAL ENERGY↗

Modeling and Design of the Triton OWC System (Final Report)

Two versions of the Triton Oscillating Water Column type device will be modeled in WEC Sim. First, a model of a wave-tank scale device which can be tuned and validated against tank test data. Second, a model of the deployment-scale device will be constructed following the method of the tank-scale device to ensure that relevant physics are captured. In the latter case, the geometry, PTO architecture, and other design details are not yet finalized, so the model will serve as a platform for design iteration as time and budget allows. A subset of this iteration will be automated using existing WEC-Sim capabilities. A primary focus of this work will be familiarizing Triton personnel with the WEC-Sim workflow and model details so that the model of the deployment device can continue to be enhanced after project end.

16 TIDAL AND WAVE POWER↗

Low-Cost Heliostat for High-Flux Small-Area Receivers (Final Technical Report)

This project analyzed a two-stage heliostat concept consisting of a tracking stage and a concentrating stage. The tracking stage uses mirrors mounted on a common drive that move to track the sun. The concentrating stage consists of stationary mirrors that each have a unique angle to direct rays towards a small-area, high-flux, point-focused receiver. By splitting the collection and concentrating process into two stages, multiple small, inexpensive mirrors can share a structure and be controlled by a single drive in the tracking stage. The project effort developed modeling techniques that were specifically relevant to this two-stage heliostat concept. Both field-level and unit-level models were developed. The field-level model does not explicitly consider unit-level losses which are predicted by the unit-level model and then integrated into the field-level model through a correlation referred to as an efficiency modifier. This approach is referred to as the two-model approach; the development and demonstration of this two-model approach for a multi-stage heliostat technology is a key outcome of this work. The field-level model is used to design a field that hits a specific design day power given a set of heliostat design parameters. An oversized field is simulated and then heliostat units are removed based on their annual energy production in order to generate the highest performing field. The field reduction procedure fits a smooth curve fit to annual energy production as a function of position in the field which has the effect of reducing the noise that is otherwise caused by the Monte Carlo ray tracing technique. This approach is referred to as the annual energy fit method and substantially reduces computational run time for a given field level modeling accuracy. The annual energy fit approach enables the selection of a properly sized, high-performing field using orders of magnitude fewer rays than would otherwise be possible and the development of this approach is a second key outcome of this work. These models are used within a genetic optimization algorithm in order to optimize the geometric parameters associated with a heliostat in order to achieve the lowest cost per unit of collected design day power. The cost modeling that underlies the optimization is a simple, scaling type analysis backed up by a much more detailed Design for Manufacture and Assembly (DFMA) analysis. Although the figure of merit used for optimization was not cost per mirror area, this metric is reasonable to use as a means of comparison. The optimally designed 500 kW design has a tracking mirror specific cost of $181.85/m 2 , which is significantly larger than the target value and also larger than the current state of the art. The cost of the torque-tube type linkages contributed substantially to the overall cost. Based on this observation, potentially attractive alternative design configuration utilizing a capstan type actuation system should be investigated. Finally, NREL compared the performance of the two-stage heliostat to the performance of a focused and different sized flat conventional heliostats and showed that, as expected, additional losses versus the convention heliostat caused by a worse cosine efficiency, two stages of reflection, and interstage interactions. The two-stage heliostat requires around 75% more reflective area than a flat 1x1 meter conventional heliostat (similar to a focused heliostat) and 40% more than a flat 2x2 meter conventional heliostat.

14 SOLAR ENERGY↗

Directed Flow and the Chiral Magnetic Effect in Ultrarelativistic Collisions with CMS at the LHC (Final Technical Report for DOE Grant # DE-SC0021080)

This Final Technical Report covers the years of activity for the Grant DE-SC0021080. It reflects the efforts of Alice Mignerey, the PI, Timothy Koeth, the co-PI, graduate students Eric Adams and Samuel Lascio, and undergraduates Alyssa Marinelli and Max Bernard. Results from three separate aspects of the project are presented: 1) understanding the radiation damage of the positive and negative sides of the Spectator Reaction Plane detector (SRPD) for data from the 2018 PbPb run at the CERN LHC. 2) Results of the directed flow in PbPb collisions at $\sqrt{SNN}$ = 5.02 TeV. 3) Activation studies of the sectors of the positive side of the SRPD and radiation damage studies on fused quartz using the Maryland 4-MeV electron accelerator. The most significant result is that the reaction plane derived directed flow for both participant and spectator reaction planes is many times larger than that obtained by ALICE.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Directed Flow and the Chiral Magnetic Effect in Ultrarelativistic Collisions with CMS at the LHC (Final Technical Report for DOE Grant # DE-SC0021080)

This Final Technical Report covers the years of activity for the Grant DE-SC0021080. It reflects the efforts of Alice Mignerey, the PI, Timothy Koeth, the co-PI, graduate students Eric Adams and Samuel Lascio, and undergraduates Alyssa Marinelli and Max Bernard. Results from three separate aspects of the project are presented: 1) understanding the radiation damage of the positive and negative sides of the Spectator Reaction Plane Detector (SRPD) for data from the 2018 PbPb run at the CERN LHC. 2) Results of the directed flow in PbPb collisions at √sN N = 5.02 TeV. 3) Activation studies of the sectors of the positive side of the SRPD and radiation damage studies on fused quartz using the Maryland 4-MeV electron accelerator. The most significant result is that the reaction plane derived directed flow for both participant and spectator reaction planes is many times larger than that obtained by ALICE.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Conversion Of Coal To Li-Ion Battery Grade (Potato) Graphite (Final Technical Report)

It was previously shown that biomass could be readily transformed to Li-ion battery grade graphite with performance that is equivalent to commercial graphite. This project extended that result to lignite coal, an abundant and inexpensive resource in the United States. It was found that lignite from North Dakota (ND), following charring and exposure to near-infrared light from a laser in the presence of an iron metal catalyst, graphitizes with high yield, crystallinity and purity. Furthermore, spheroidal (“potato”) shaped graphite agglomerates can be produced from ND lignite with performance that rivals that of commercial graphite. Finally, the process was found to be potentially economical, to that extent that it may be able to disrupt the current market, if the laboratory results obtained under this project can be successfully translated to industrial scale.

01 COAL, LIGNITE, AND PEAT↗

Joint analyses of lensing, clustering, and galaxy clusters with DES and LSST (Early Career Award DE-SC0020247 Final Report)

Final technical report for Early Career Award DE-SC0020247 "Joint analyses of lensing, clustering, and galaxy clusters with DES and LSST". This report summarizes contributions to Dark Energy Survey analyses of weak lensing, clustering, and galaxy clusters, and contributions to the development of LSST-DESC cosmology analysis pipelines.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Final Report

This is the final project report.

14 SOLAR ENERGY↗

Single-Volume Scatter Camera (Final Report)

This document serves as a comprehensive final report for the Single-Volume Scatter Camera (SVSC) project. Most of the work over the course of this project has been documented in journal articles, conference papers, and other reports. We therefore reference those materials for detailed presentation of our technical results. The most recent efforts on the project have not been published and are presented in detail here. We present characterizations of two neutron scatter camera prototypes; one using a monolithic geometry, and one using an optically segmented geometry. Both detectors employ plastic scintillator with SiPM-based readout. For the monolithic prototype, we present calibrations of several detector parameters made using a set of dark counts. In particular, we employ a coincidence analysis to characterize the distribution external optical crosstalk, along with the relative timing of the different SiPMs. For the optically segmented prototype we present the results of calibrations made using a tagged 22 Na source, as well as the results of an imaging measurement made using a tagged AmBe source.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Coupling Metabolic Source Isotopic Pair Labeling and Genome Wide Association for Metabolite and Gene Annotation in Plants (Final Technical Report)

In this project, we applied our labeling pipeline to Arabidopsis and sorghum by feeding tissues with isotopically labeled versions of commercially available amino acids to identify all metabolite features that incorporate the label. In sorghum, we fed five accessions, sampled across the diversity of sorghum, to identify the precursor-of-origin for metabolites that vary between accessions as well as those that may be missing from a single reference genotype. This provided us with precursor-of-origin annotation for thousands of unknown metabolites. We then used GWA to map genes responsible for the synthesis of precursor-of-origin classified metabolites. For sorghum leaf and root ducible metabolites, we performed untargeted metabolomics on leaf and root tissues from 300 diverse genotyped sorghum inbred lines. The amino acid precursor-of-origin metabolite library were then used to identify the corresponding metabolites in the GWA data sets and to identify novel gene-metabolite associations. Finally, we utilized existing and newly generated sequenced EMS mutants of sorghum to validate the predicted gene-metabolite relationships that our labelling analysis identified. In parallel, we conducted similar feeding experiments in Arabidopsis to categorize metabolites based on precursor-of-origin, identify those that vary across our existing Arabidopsis metabolite GWA dataset, and identify genes required for the synthesis of each metabolite. To provide an independent test of gene annotation and pathway involvement, we tested the GWA gene-metabolite associations in Arabidopsis by analyzing the metabolic phenotypes of gene knockouts. Genes of particular interest from both sorghum and Arabidopsis were studied in detail by directly measuring the activity of the corresponding enzymes following heterologous expression. In summary, this work classified as-yet-unknown amino acid-derived metabolites and identified genes involved in their production generated through “omics” technologies. This information was used to validate gene function and identify new metabolism in Arabidopsis and sorghum.

09 BIOMASS FUELS↗

Theory of Novel Superconductors (Final Technical Report)

This Final Technical Report gives the results of a series of problems related to the origin of superconductivity, the quantum mechanical state of matter where electrical resistance vanishes, in several classes of new materials where the conventional mechanism that binds electrons into pairs based on the electron-phonon interaction apparently fails. In several families of quantum materials including cuprates, iron-based superconductors, and heavy fermion materials, it is believed that the repulsive Coulomb interaction between electrons can create effective attractive interactions, generally in higher pair momentum channels. These "unconventional" superconductors include materials with the highest critical temperatures at ambient pressure known, so it is imperative to understand how superconductivity arises to guide the search for materials that superconduct at or near room temperature, which would have enormous technological impact. A second objective has been to construct a theory that can quantitatively explain the properties of existing materials, based on information from first-principles electronic structure calculations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Flexible Perovskite-Perovskite PV for Mobile Power Applications (Final Technical Report)

This is the final report for the referenced TCF award which ran from Oct. 2019 through Jan. 2024 in conjunction with the industry partner Swift Solar. The long duration of the program was due to several factors including the pandemic and a technical work stoppage due to changes in the scope. Additionally, Swift’s business focus shifted during the course of the program. As a result of these factors, this program underwent two distinct modifications that dramatically changed the work scope. The following report is organized into three separate sections, each of which addresses a distinct work scope. Those scope changes, what necessitated them, and any new tasks/milestones are given, briefly, at the top of each section. The work performed was research on the hybrid halide perovskites (HHP), both the absorber material itself as well as other material layers that are required in a full device stack. At the start of the period of performance, there were two distinct challenges that we sought to address: (1) a wide band gap absorber (>1.6 eV), and (2) a recombination layer for tandem devices that provided good sequestration of the individual cell absorber materials in their respective device layers. NREL had previously published, and patented, advancements in both of these areas and they were the focus of much of the work throughout the program.

14 SOLAR ENERGY↗

DECOVALEX-2023: Task A Final Report

Task A, also known as HGFrac, examines the fracturing processes that may occur in the Callovo-Oxfordian claystone (COx) in the context of the high-level (HLW) and intermediate-level long-lived (ILW-LL) radioactive waste repository in France. Understanding these processes and improving numerical models to reproduce them will aid in the design, optimization, and safety of the repository. Heat and gas fracturing are studied in two independent subtasks following a stepwise approach: laboratory tests/benchmark exercises, in-situ experiment, and finally, an application case. The in-situ heater experiment aimed to thermally induce a hydraulic fracture; temperature and pore pressure were monitored to detect any evidence of fracturing. The in-situ gas injection experiment aimed to study the effect of the stress orientation and gas injection kinetics on the gas fracturing process. The occurrence of fracturing was monitored by gas pressure measured in the injection interval. In both experiments, the excavation-induced fracture network around the heater/injection boreholes played an important role in the reduction of the compressive stress state, leading to both a tensile and shear failure response of the COx. During the first two years of the project, the research teams working on each task developed and/or proposed numerical approaches for reproducing the occurrence of fracturing in the in-situ experiments. The failure criteria were defined by reproducing the measurements from laboratory extension tests for the heat fracturing subtask. In the gas fracturing subtask, their approaches were used for simulating several benchmark exercises, and an inter-comparison between models was carried out. In both tasks, the developed approaches were compared with a simplified approach considering poro-elasticity for the mechanical behaviour of the COx. Most of the developed approaches are based on a continuous medium that takes into account variations in hydraulic properties due to mechanical degradation, such as plastic deformation or damage. Other approaches implicitly modelled weak planes or embedded discontinuities to reproduce fracture propagation. The potential for fracture initiation was also studied through of a discrete approach. In the second half of the project, the research teams mainly focused on interpretative modelling of two in-situ experiments and a blind prediction exercise to test their respective approaches. The models developed by the research teams were also applied at the repository scale to evaluate fracture initiation in a case study under vi unfavourable conditions, particularly in terms of spacing between High-Level Waste cells. The results showed that the poro-elasticity approach could be an efficient tool for understanding the main processes occurring in the COx. One example is the explicit representation of the excavation-induced fracture network around the boreholes, which yielded acceptable results compared to the measurement data. However, advanced approaches were needed to evaluate the potential increase of the excavation-induced fracture network extend and better understand fracture initiation. The stress analyses carried out by the teams revealed that hydraulic boundary conditions had a strong impact on fracture initiation in the heater experiment. Furthermore, in most cases, the results required higher pore pressure increments to reach fracturing than those measured in the experiment. This implies that the measurements may have been biased by the packer’s capacity to fully isolate the piezometric chambers, leading to lower pressures. On the contrary, there was no agreement on the fracturing mode, as some reported either shear or tensile fracturing, while others reported a combination of the two modes. In the case of gas fracturing, the research teams were limited to the comparison of a single point, which complicated their task. Nonetheless, the numerical results were able to reproduce the measurements and capture processes such as longitudinal gas flow through the excavation-induced fracture network, as suggested by some evidence in the observation piezometric chambers. The numerical models also agreed with the measurements in the sense of higher probability of developing along the injection borehole than radially towards the sound rock. The approaches developed by the research teams showed that they are capable of analysing and reproducing fracture initiation in the COx. However, areas of future work should focus on the fracture propagation and fracture aperture, which were out of the scope of this task. To this end, additional data must be gathered for the parameter characterisation and validation of the numerical models. Nonetheless, various approaches showed promising results as they were able to reproduce fracture development under certain conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗