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At least 271 records · Page 15

A compact time-of-flight mass spectrometer for ion source characterization

A compact time-of-flight mass spectrometer with overall dimension of about 413 × 250 × 414 mm based on orthogonal injection and angle reflection has been developed for ion source characterization. Configuration and principle of the time-of-flight mass spectrometer are introduced in this paper. The mass resolution is optimized to be about 1690 (FWHM), and the ion energy detection range is tested to be between about 3 and 163 eV with the help of electron impact ion source. High mass resolution and compact configuration make this spectrometer useful to provide a valuable diagnostic for ion spectra fundamental research and study the mass to charge composition of plasma with wide range of parameters.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The long-term corrosion performance of Alloy 22 in heated brine solutions

Long-term corrosion experiments have been performed on Alloy 22 (UNS N06022), in a series of heated brines formulated to represent evaporatively concentrated ground water, to evaluate the long-term corrosion performance of the material. These solutions included 0.5 M NaCl, in addition to two simulated concentrated ground water solutions. Under conditions where Alloy 22 was anticipated to be passive, the corrosion rate was found to be vanishingly small (i.e., below the resolution of the weight-loss technique used to quantify corrosion in this study). However, under low pH conditions where Alloy 22 was anticipated to be active, or more specifically, where the chromium oxide passive film was not thermodynamically stable, the corrosion rate was appreciable. Furthermore, under such conditions the corrosion rate was observed to be a strong function of temperature, with an activation energy of 72.9±1.8 kJ/mol. Time of Flight-Secondary Ion Mass Spectroscopy analysis of the oxide layer revealed that, while sulfur was present within the oxide for all test conditions, no accumulation was observed at or near the metal/oxide interface. Furthermore, these observations confirm that inhibition of passive film formation via sulfur accumulation does not occur during the corrosion of Alloy 22.

36 MATERIALS SCIENCE↗

An integrated time-of-flight versus residual energy subsystem for a compact dual ion composition experiment for space plasmas

We have developed a novel concept for a Compact Dual Ion Composition Experiment (CoDICE) that simultaneously provides high quality plasma and energetic ion composition measurements over 6 decades in ion energy in a wide variety of space plasma environments. CoDICE measures the two critical ion populations in space plasmas: (1) mass and ionic charge state composition and 3D velocity and angular distributions of ∼10 eV/q–40 keV/q plasma ions—CoDICE-Lo and (2) mass composition, energy spectra, and angular distributions of ∼30 keV–10 MeV energetic ions—CoDICE-Hi. CoDICE uses a common, integrated Time-of-Flight (TOF) versus residual energy (E) subsystem for measuring the two distinct ion populations. This paper describes the CoDICE design concept, and presents results of the laboratory tests of the TOF portion of the TOF vs. E subsystem, focusing specifically on (1) investigation of spill-over and contamination rates on the start and stop microchannel plate (MCP) anodes vs. secondary electron steering and focusing voltages, scanned around their corresponding model-optimized values, (2) TOF measurements and resolution and angular resolution, and (3) cross-contamination of the start and stop MCPs’ singles rates from CoDICE-Lo and -Hi, and (4) energy resolution of avalanche photodiodes near the lower end of the CoDICE-Lo energy range. We also discuss physical effects that could impact the performance of the TOF vs. E subsystem in a flight instrument. Finally, we discuss advantages of the CoDICE design concept by comparing with capabilities and resources of existing flight instruments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Pathways towards break even for low convergence ratio direct-drive inertial confinement fusion

Following indirect-drive experiments which demonstrated promising performance for low convergence ratios (below 17), previous direct-drive simulations identified a fusion-relevant regime which is expected to be robust to hydrodynamic instability growth. This paper expands these results with simulated implosions at lower energies of 100 and 270 kJ, and ‘hydrodynamic equivalent’ capsules which demonstrate comparable convergence ratio, implosion velocity and in-flight aspect ratio without the need for cryogenic cooling, which would allow the assumptions of one-dimensional-like performance to be tested on current facilities. A range of techniques to improve performance within this regime are then investigated, including the use of two-colour and deep ultraviolet laser pulses. Finally, further simulations demonstrate that the deposition of electron energy into the hotspot of a low convergence ratio implosion through auxiliary heating also leads to significant increases in yield. Results include break even for 1.1 MJ of total energy input (including an estimated 370 kJ of short-pulse laser energy to produce electron beams for the auxiliary heating), but are found to be highly dependent upon the efficiency with which electron beams can be created and transported to the hotspot to drive the heating mechanism.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Electromagnetic Shower from Cosmic Muons in NOvA Detector

NO$\nu$A (NuMI Off-Axis $\nu_e$ Appearance) experiment is a neutrino $\nu_\mu \rightarrow \nu_e$ oscillation experiment with a baseline of 810 km. The signature for a $\nu_\mu \rightarrow \nu_e$ oscillation in the far detector is the production of an electromagnetic (EM) shower due to the charge current (CC) interaction of $\nu_e$ with the detector material. Cosmic muon induced electromagnetic showers can serve as a source of EM shower sample that can be used as a data-driven method for validating the EM shower modelling and EM shower identification algorithms at NO$\nu$A. The work reported in the thesis is the first ever implementation of cosmic muon induced EM shower for such a purpose in the NO$\nu$A experiment. We extracted EM shower sample from two sources - muon undergoing bremsstrahlung (Brem) and muon decay in flight to electron (DiF). Brem sample, extracted from cosmic muon, turns out to be a very useful data-driven method for testing EM shower modelling and the part icle identification (PID) algorithms for the detection of $\nu_e$-CC interactions. A new muon removal (MR) technique is developed and applied to remove the muon hits inside the bremsstrahlung shower. However, a complete removal of the muon energy in the event is not possible with high efficiency. DiF induced EM shower, on the other hand, is exactly similar to $\nu_e$-CC EM shower because DiF is a pure electron initiated EM shower. Therefore, DiF EM shower, once extracted, mimicks the shower of a $\nu_e$-CC interaction event. We present the extraction methods for both brem and DiF events in MC and cosmic data in far and near detector of NO$\nu$A and its use in data driven validation of $\nu_e$ EM shower modelling and $\nu_e$ signal selection efficiency across the detector. A systematic uncertainty is also assigned on $\nu_e$ appearance signal selection based on this study to take into account the difference in EM shower modelling in data and MC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Air Blast Mesh Sensitivity and Pressure Mapping Study

Nose cone structural and aerodynamic characteristics are essential for intelligent design of aircraft, spacecraft, and ballistic systems. Finite element analysis can be used to help understand the structural integrity and flight characteristics of different nose cones. A mesh sensitivity study was undertaken for a particular nose cone geometry that was used in tests at LANL facilities in order to confirm the integrity of the meshed geometry. A simple cone that best matched closed-form theoretical solutions was modeled, and received good correlation to the theory. Complexity was then added back to the nose cone. Parameters applied to the simple cone were then implemented in the nose cone geometry giving assurance of accuracy after the geometry was changed. Nose cone results averaged 6.3% error for radial displacement when compared with the theoretical. Hoop stress averaged 6.0% error and meridional stress averaged 5.7% error at the finest mesh level. Meshes showed signs of convergence when compared to all three theoretical solutions. Finally, pressure time-history data from LANL computational fluid dynamics simulations was applied to the surface of the final nose cone geometry. The pressure data was interpolated from pressure gauge locations onto nearby meshed elements, which allowed for FEA software to run simulations on the cone with the pressure data as a loading condition. The pressure mapping resulted in the ability to understand the nose cone’s rigid body motion that in turn can inform design of future nose cones.

42 ENGINEERING↗

Prompt-gamma detection towards absorbed energy monitoring during hadrontherapy

Hadrontherapy is an emerging technique which exploits the fact that a large quantity of the energy of the incident particles is deposited at the end of their flight path. This allows a conformation of the applied dose to the tumor volume and a simultaneous sparing of surrounding healthy tissue. A real-time control of the ion range during the treatment is possible via the detection of prompt secondary radiation (gamma rays or charged particles). Besides a monitoring of the ion range, the knowledge of the total energy absorbed inside the patient is also of importance for an improvement of the treatment quality. It has been shown that the ambient dose in a treatment room is correlated to the monitoring units, i.e. the number of protons of the beam delivery system. The present study consists in applying time-of-flight (TOF) information to identify prompt gamma-rays generated by interactions inside the patient which provides a direct information on the energy imparted. Results from test measurements will be given, which show that events generated in the nozzle and the target phantom can be discriminated. Furthermore, a standalone detection system is being developed which will be read out by a standard PC. The status of the developments for the corresponding electronics will be presented. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Physicochemical and antibacterial characterization of ionocity Ag/Cu powder nanoparticles

Metal ion in bimetallic nanoparticles has shown vast potential in a variety of applications. In this paper we show the results of physical and chemical investigations of powder Ag/Cu nanoparticles obtained by chemical synthesis. Transmission electron microscopy (TEM) experiment indicated the presence of bimetallic nanoparticles in the agglomerated form. The average size of silver and copper nanoparticles is 17.1(4) nm (Ag) and 28.9(2) nm (Cu) basing on the X-ray diffraction (XRD) data. X-ray photoelectron (XPS) and Raman spectroscopies revealed the existence of metallic silver and copper as well as Cu{sub 2}O and CuO being a part of the nanoparticles. Moreover, UV–Vis spectroscopy showed surface alloy of Ag and Cu while Time of Flight Secondary Ion Mass Spectroscopy (ToF-SIMS) and Energy Dispersive X-ray Spectroscopy (EDX) showed heterogeneously distributed Ag structures placed on spherical Cu nanoparticles. The tests of antibacterial activity show promising killing/inhibiting growth behaviour for Gram positive and Gram negative bacteria. - Highlights: • Ag/Cu nanoparticles were obtained in the powder form. • The average size of nanoparticles is 17.1(4) nm (Ag) and 28.9(2) nm (Cu). • Ag/Cu powder nanoparticle shows promising antibacterial properties.

36 MATERIALS SCIENCE↗

SU-D-BRA-04: Computerized Framework for Marker-Less Localization of Anatomical Feature Points in Range Images Based On Differential Geometry Features for Image-Guided Radiation Therapy

Purpose: To propose a computerized framework for localization of anatomical feature points on the patient surface in infrared-ray based range images by using differential geometry (curvature) features. Methods: The general concept was to reconstruct the patient surface by using a mathematical modeling technique for the computation of differential geometry features that characterize the local shapes of the patient surfaces. A region of interest (ROI) was firstly extracted based on a template matching technique applied on amplitude (grayscale) images. The extracted ROI was preprocessed for reducing temporal and spatial noises by using Kalman and bilateral filters, respectively. Next, a smooth patient surface was reconstructed by using a non-uniform rational basis spline (NURBS) model. Finally, differential geometry features, i.e. the shape index and curvedness features were computed for localizing the anatomical feature points. The proposed framework was trained for optimizing shape index and curvedness thresholds and tested on range images of an anthropomorphic head phantom. The range images were acquired by an infrared ray-based time-of-flight (TOF) camera. The localization accuracy was evaluated by measuring the mean of minimum Euclidean distances (MMED) between reference (ground truth) points and the feature points localized by the proposed framework. The evaluation was performed for points localized on convex regions (e.g. apex of nose) and concave regions (e.g. nasofacial sulcus). Results: The proposed framework has localized anatomical feature points on convex and concave anatomical landmarks with MMEDs of 1.91±0.50 mm and 3.70±0.92 mm, respectively. A statistically significant difference was obtained between the feature points on the convex and concave regions (P<0.001). Conclusion: Our study has shown the feasibility of differential geometry features for localization of anatomical feature points on the patient surface in range images. The proposed framework might be useful for tasks involving feature-based image registration in range-image guided radiation therapy.

60 APPLIED LIFE SCIENCES↗

Quantitative texture analysis using the NOMAD time-of-flight neutron diffractometer

Strategies for efficient and reliable texture measurements have been explored using the Nanoscale Ordered Materials Diffractometer (NOMAD) at the Spallation Neutron Source located at Oak Ridge National Laboratory (ORNL). To test these strategies, the texture of an Al alloy was also investigated using another neutron diffraction instrument, a constant-wavelength neutron diffractometer (NRSF2) located at the High Flux Isotope Reactor, also at ORNL. Reasonable agreement was found across the two experimental methods, but differences in overall texture strength and the symmetry of some components were noted, depending on the data reduction and analysis method selected. Finally, on the basis of these results, potential improvements are identified which would enhance the texture measurement capability on NOMAD.

47 OTHER INSTRUMENTATION↗

5.1.6 Demo #6: NanoStitch (NAWAStitch) Multifunctional Composites Trade Validation

The overall objective of the NanoStitch Multifunctional Composites Trade Validation Demonstration project was to determine the value proposition of adding NanoStitch to rapid-cure composite systems for structures used in the expanding sector of advanced air mobility (AAM) and specifically electric vertical take-off and landing (eVTOL) aircraft. The expected value proposition was stronger composite parts, with new multifunctional attributes, that are lower cost to fabricate and maintain. NanoStitch is a new composite innovation where a contiguous vertically aligned carbon nanotube (VACNT) forest is located between each ply of a laminate composite resulting in improved mechanical properties as well as other multifunctional properties such as enhanced thermal and electrical conductivity. NanoStitch was originally distributed by N12, later acquired by NAWA Technologies, now called NAWAStitch, and henceforth referred to in this document as NAWAStitch. Two significant evaluations were framed to help meet the overall objective. First, was Task 1 to evaluate the effects that adding NAWAStitch to a rapid cure material system would have on the mechanical and processing properties of the material. Second, was Task 2 to evaluate the workability of adding NAWAStitch to practical flight demonstration articles. From previous research, it was already known that the application of NAWAStitch to a composite structure can enhance the mechanical properties of that structure. However, this project will help the engineering community understand those benefits and the basic structural strength values to apply when incorporating NAWAStitch material into composite structure that utilizes a rapid-cure resin system, which is novel. Testing showed that by adding NAWAStitch to the prepreg, most material properties were improved because the VACNTs strengthened the resin to fiber interface, and the interface itself, between plies. For example compression strength improved by more than 20%, and erosion resistance by more than 50%. The UDRI team identified two flight demonstration articles through discussions with Aurora Flight Sciences (Aurora) and reviewing literature on air mobility and the eVTOL market. The demonstration articles were a thin skin honeycomb panel and a section from an eVTOL propeller blade. The manufacturing and testing trials of the demonstration articles were as follows: • NAWAStitch added no manufacturing complexity or detriment to the article physical qualities, while at the same time added multifunctional properties such as enhanced rain erosion and electrothermal de-icing besides enhanced mechanical properties • VACNTs did not increase or hurt the mechanical properties of the interface between honeycomb core materials and the thin skin face sheet • Demonstrated successful de-icing function in an eVTOL propeller meeting real-world specifications in uniformity and endurance • Multifunctional eVTOL propeller cost analysis showed a cost savings of at least 67 % for a single propeller blade with multifunctional de-icing capability and improved mechanical properties which equates to a potential savings of $10,116 per eVTOL aircraft with six three-bladed propellers Overall, the results of this project can provide additional tools for the composite industry to optimize energy efficiency through faster and stronger composite parts that are lower cost to fabricate and maintain. Additionally, the results of this effort can help US industry like NAWA America set the stage for rapid growth and establishment of a manufacturing facility in Ohio. The project has given NAWA America the basic understanding of how the addition of VACNTs to a composite structure can affect the mechanical properties and hence point them to potential commercial applications. The project has also provided Teijin Carbon US with another potential material application for their rapid cure materials that are manufactured at the Renegade facility in Miamisburg, OH.

36 MATERIALS SCIENCE↗

An Open Source Perovskite Solar Cell Curve Tracer

When developing systems for perovskite solar cells (PSCs), it is important to have a testing platform that closely resembles your deployed systems. While developing a 1 U CubeSat, the Big Red Sat-1 at the University of Nebraska-Lincoln, we found a lack of passive curve tracing instrumentation, which we needed for our mission. To that end, we developed a benchtop passive curve tracer that leverages the Ossila Solar Simulator as an AM1.5 light source. This device utilizes a ladder of switched resistors and a precision voltage and current measurement to achieve the curve tracing. It also integrates a common-anode multiplexer to switch through multipixel PSCs. Finally, the solar cell holder is separate from the main measurement system, so various substrates sizes and pixel counts can be supported. This system is tested using various PSCs. It has been open sourced to enable reuse in future systems that may benefit from the lower power consumption and flight heritage.

14 SOLAR ENERGY↗

Qualification of quantum cascade lasers for space environments

Laser-based instruments are enabling a new generation of scientific instruments for space environments such as those used in the exploration of Mars. The lasers must be robust and able to withstand the harsh environment of space, including radiation exposure. Quantum cascade lasers (QCLs), which are semiconductor lasers that emit in the infrared spectral region, offer the potential for the development of novel laser-based instruments for space applications. The performance of QCLs after radiation exposure, however, has not been reported. We report on work to quantify the performance of QCLs after exposure to two different radiation sources, 64 MeV protons and Cobalt-60 gamma rays, at radiation levels likely to be encountered during a typical space flight mission. No significant degradation in threshold current or slope efficiency is observed for any of the seven Fabry-Perot QCLs that are tested.

gamma radiation↗

Instrument development continues in Oak Ridge

Peer review panels composed of 80 external scientists recently visited Oak Ridge National Laboratory (ORNL) to review almost 700 proposals for experiments on 23 instruments at the Spallation Neutron Source (SNS) and High Flux Isotope Reactor (HFIR). These were proposed for the time period from January-June 2012. About 40% of the proposals were approved for beam time and 20% were placed on an alternate list if time becomes available. The Hybrid Spectrometer HYSPEC at SNS began its commissioning in September 2011. HYSPEC is otpimized for studying low energy dynamics in single-crystal samples using a broad variety of sample environments, and is equipped with a polarization analysis capability. It is expected to be available for users on a limited basis in the second half of 2012. The detector tank of CORELLI has been installed on beamline 9 at SNS. Now that the tank is in place, banks of neutron detectors and boron carbide shielding will be installed around the interior. CORELLI is optimized to probe complex disorder in crystalline materials through diffuse scattering from single-crystal samples. It will begin commissioning in 2014. CORELLI is one of four instruments being developed under the SING II (SNS Instruments Next Generation II) project. The others are the Macromolecular Neutron Diffractometer (MANDI), the Vibrational Spectrometer (VISION, scheduled to begin commissioning in 2012), and the Time of Flight Ultra Small Angle Neutron Scattering Instrument (TOF-USANS). The single crystal neutron diffractometer IMAGINE, was deliverd to HFIR in October 2011. Preliminary testing has been carried out. IMAGINE will provide atomic resolution information on chemical, organic, metallo-organic and protein single crystals that will enable their chemical, physical and biological structure and function to be understood. This instrument will benefit scientists with interests in pharmaceuticals, minerals and other inorganic crystals, small molecules, molecular organo-metallic crystals and metal-organic frameworks (MOFs) molecular crystal structures. The quasi-Laue geometry, combined with a large solid angle detector, will enable rapid data collection from crystals with volume < 1mm{sup 1} and unit cell < 100 {angstrom}. Construction and installation of the optical system is in progress. Commissioning is expected to start in April 2012.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Test beam results of micro channel plates in 'ionisation mode' for the detection of single charged particle and electromagnetic showers

IMCP is an R and D project aimed at the exploitation of secondary emission of electrons from the surface of microchannel plates (MCP) for fast timing of showers in high rate environments. The usage of MCPs in 'ionisation' mode has long been proposed and is used extensively in ion time-of-flight mass spectrometers. What has not been investigated in depth is their use to detect the ionizing component of showers. The fast time resolution of MCPs exceeds anything that has been previously used in calorimeters, and, if exploited effectively, could aid in the event reconstruction at high luminosities. Results from tests with electrons with energies up to 150 GeV of MCP devices with different characteristics will be presented, in particular detection efficiency and time resolution. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A guided-ion beam study of the collisions and reactions of I{sup +} and I{sub 2}{sup +} with I{sub 2}

Growing interest in developing and testing iodine Hall effect thrusters requires measurements of the cross sections of reactions that generate low energy plasma following discharge. Limited experimental and theoretical work necessitates a decisive experiment to elucidate the charge exchange and collision-induced dissociation channels. To this end, we have used guided-ion beam techniques to measure cross sections for both I{sup +} + I{sub 2} and I{sub 2}{sup +}+I{sub 2} collisions. We present total collision cross sections as well as collision-induced dissociation cross sections for center-of-mass collision energies ranging from 0.5 to 200 eV for molecular iodine cations. Similarly, we present total collision cross section and charge-exchange cross sections for atomic iodine cations for center-of-mass collision energies ranging from 0.67 to 167 eV. Time-of-flight measurements of the collision products allow determination of velocity distributions, which show evidence of complex formation of I{sub 3}{sup +} from the I{sup +} + I{sub 2} reaction at collision energies below 6 eV.

74 ATOMIC AND MOLECULAR PHYSICS↗

Studying Corrosion Using Miniaturized Particle Attached Working Electrodes and the Nafion Membrane

We developed a new approach to attach particles onto a conductive layer as a working electrode (WE) in a microfluidic electrochemical cell with three electrodes. Nafion, an efficient proton transfer molecule, is used to form a thin protection layer to secure particle electrodes. Spin coating is used to develop a thin and even layer of Nafion membrane. The effects of Nafion (5 wt% 20 wt%) and spinning rates were evaluated using multiple sets of replicates. The electrochemical performance of various devices was demonstrated. Additionally, the electrochemical performance of the devices is used to select and optimize fabrication conditions. The results show that a higher spinning rate and a lower Nafion concentration (5 wt%) induce a better performance, using cerium oxide (CeO2) particles as a testing model. The WE surfaces were characterized using atomic force microscopy (AFM), scanning electron microscopy-focused ion beam (SEM-FIB), time-of-flight secondary ion mass spectrometry (ToF-SIMS), and X-ray photoelectron spectroscopy (XPS). The comparison between the pristine and corroded WE surfaces shows that Nafion is redistributed after potential is applied. Our results verify that Nafion membrane offers a reliable means to secure particles onto electrodes. Furthermore, the electrochemical performance is reliable and reproducible. Thus, this approach provides a new way to study more complex and challenging particles, such as uranium oxide, in the future.

42 ENGINEERING↗

Evaluation Of Saltstone Mixer Paddle Configuration For Improved Wear Resistance

A soft metal with low wear resistance (6000 series aluminum), was used to minimize run time while maximizing wear rate. Two paddle configurations were tested, with the first four paddles after the augers replaced by the wear paddles. The first configuration was all flat paddles, with the first paddle not aligned with the augers and is consistent with present SPF mixer. The second configuration had helical paddles for the first three stages after the augers and a flat paddle at the fourth stage. The first helical paddle was aligned with the auger flight for the second configuration. The all flat paddle configuration wear rate was approximately double the wear rate of the helical paddles for the first two sets of paddles after the augers. For both configurations, there was little or no wear on the third and fourth paddle sets based on mass change, indicating that the fully wetted premix materials are much less abrasive than the un-wetted or partially wetted premix. Additionally, inspection of the wear surface of the paddles at higher magnification showed the flat paddles were worn much more than the helical and is consistent with the wear rates. Aligning the auger discharge flight with the first set of helical paddles was effective in reducing the wear rate as compared to the flat paddle configuration. Changing the paddle configuration from flat to helical resulted in a slight increase in rheological properties. Although, both tests produced grout-like material that is within the processing rage of the SPF, it should be noted that cement is not included in the premix and water was used rather than salt solution, which does affect the rheology of the fresh grout. The higher rheological properties from the helical wear test are most likely due to the reduced number of shearing paddles in the mixer. In addition, there is variation in the rheological data for each wear test. This is most likely due to the way that the dry feeds enter the mixer from the dry feeder. The premix is discharged from the hopper in an unsteady fashion, where irregular sized clumps were observed leaving the discharge of the auger, though the auger speed is constant.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗