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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
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NASA NTRS1991

Optical and microwave detection using Bi-Sr-Ca-Cu-O thin films

Recent progress at the Johns Hopkins University Applied Physics Laboratory (JHU/APL) in the development of optical and microwave detectors using high temperature superconducting thin films is described. Several objectives of this work have been accomplished, including: deposition of Bi-Sr-Ca-Cu-O thin films by laser abation processing (LAP); development of thin film patterning techniques, including in situ masking, wet chemical etching, and laser patterning; measurements of bolometric and non-bolometric signatures in patterned Bi-Sr-Ca-Cu-O films using optical and microwave sources, respectively; analysis and design of an optimized bolometer through computer simulation; and investigation of its use in a Fourier transform spectrometer. The focus here is primarily on results from the measurement of the bolometric and non-bolometric response.

Grabow, B. E.↗
NASA NTRS1991

Upcoming planetary missions and the applicability of high temperature superconductor bolometers

Planetary missions to Mars and beyond can last 11 years and longer, making impractical the use of stored cryogens. Passive radiative coolers and single-stage mechanical coolers remain possibilities. Cassini and Comet Rendezvous/Asteroid Fly-by (CRAF), both using the newly developed Mariner Mark 2 spacecraft, will be the next outer planet missions after Galileo; they are intended to provide information on the origin and evolution of the solar system. CRAF is slated for a 1994 launch. Cassini was chosen by ESA and will be launched by a Titan 4/Centaur in 1996. It will fly by Jupiter in 2000, inject an ESA-supplied probe into Titan in 2002, and take data in Saturn's orbit from 2002 to 2006. NASA/Goddard is currently developing a prototype Fourier transform spectrometer, the Composite Infrared Spectrometer (CIRS), for the Cassini mission. The baseline infrared detectors for CIRS are HgCdTe to 16 microns and Schwarz-type thermopiles from 16 to 1000 microns. The far infrared focal plane could be switched from thermopiles to high temperature superconductor (HTS) bolometers between now and 1996. An HTS bolometer could be built using the kinetic inductance effect, or the sharp resistance change at the transition. The transition-edge bolometer is more straightforward to implement, and initial efforts at NASA/Goddard are directed to that device. A working device was made and tested in early 1989. It also has somewhat elevated noise levels below 100 Hz. Upcoming efforts will center on reducing the time constant of the HTS bolometer by attempting to deposit an HTS film on a diamond substrate, and by thinning SrTiO3 substrates. Attempts will be made to improve the film quality to reduce the 1/4 noise level, and to improve the thermal isolation to increase the bolometer sensitivity. An attempt is being made to deposit good-quality HTS films on diamond films using a metal-organic chemical vapor deposition (MOCVD) technique.

Brasunas, J.↗
NASA NTRS1990

Cirrus cloud characteristics derived from volume imaging lidar, high spectral resolution lidar, HIS radiometer, and satellite

Preliminary measurement results are presented from the Cirrus Remote Sensing Pilot Experiment which used a unique suite of instruments to simultaneously retrieve cirrus cloud visible and IR optical properties, while addressing the disparities between satellite volume averages and local point measurements. The experiment employed a ground-based high resolution interferometer sounder (HIS) and a second Fourier transform spectrometer to measure the spectral radiance in the 4-20 micron band, a correlated high spectral resolution lidar, a volume imaging lidar, a CLASS radiosonde system, the Scripps Whole Sky Imager, and multispectral VAS, HIRS, and AVHRR satellite data from polar orbiting and geostationary satellites. Data acquired during the month long experiment included continuous daytime monitoring with the Whole Sky Imager.

Grund, Christian J.↗
NASA NTRS1991

Spectroscopic measurement of HO2, H2O2, and OH in the stratosphere

Stratospheric concentrations of HO2, H2O2, and OH have been retrieved simultaneously from the far-infrared emission spectra obtained with a balloon-borne Fourier transform spectrometer in June 1983 at 32 deg N latitude. Retrieved concentrations of HO2 and H2O2 are reported, along with vertical distributions of OH which were reported in an earlier paper for the afternoon, sunset, and nighttime periods for altitudes from 26 to 38 km. HO2 distributions are obtained with uncertainties that are about the same as OH for the same vertical range and for the afternoon and sunset periods. H2O2 concentration is obtained at an altitude of 30 km for the period that covers afternoon and sunset hours. The retrieved concentrations of these HO(x) species agree well with other individually measured results and the steady state photochemical predictions. The ratio HO2/OH at around 32 km seems to increase from the afternoon period to the sunset period.

Park, J. H.↗
NASA NTRS1991

Line-frequency measurements and analysis of N2O between 900 and 4700/cm

The N2O infrared spectrum from 900 to 4700/cm has been studied with a high-resolution Fourier-transform spectrometer. Measurements were made of line frequencies of several N2O isotopes for several ground-state and hot bands. These bands include the 1530-0330, 2330-0330, 0441-0440, 0441-0330, 0531-0330, and 1331-0330 bands of (N-14)2(O-16). Also, perturbation-enhanced transitions in the 0710-0110 and 0730-0110 bands were assigned and measured. The frequencies have been analyzed to obtain a unique set of effective vibration-rotation parameters for each vibrational state. The results obtained from this research are of high accuracy for the ground-state, and the first-excited-state bands of (N-14)2(O-16), in which the computed frequencies derived from the least-squares fits, are known to an absolute uncertainty of only +/-4 x 10 exp -5 for nonperturbed transitions.

Toth, Robert A.↗
NASA NTRS1991

Measurements of Lorentz-broadening coefficients and pressure-induced line shift coefficients in the nu2 band of D2(O-16)

Lorentz-broadening and pressure-induced line-shift coefficients are determined experimentally for 126 transitions in the nu2 band of D2(O-16) from laboratory spectra with a Fourier-transform spectrometer. A nonlinear least-squares fitting procedure is employed to measure transitions up to J double-prime = 12 in the buffer gases air, nitrogen, and oxygen. The N2-broadening/O2-broadening coefficient ratio is correlated with the magnitude of the O2-broadening coefficient, and the pressure coefficients are not correlated with line widths.

Rinsland, Curtis P.↗
NASA NTRS1992

Upper limit for stratospheric HBr using far-infrared thermal emission spectroscopy

An upper limit is measured for stratospheric HBr from three balloon flights. The observations were made with the FIRS-2 far-infrared Fourier transform spectrometer. The 1sigma upper limits from the 1988, 1989, and 1990 balloon flights are 13 pptv at 35 km, 7 pptv at 32 km, and 3 pptv at 31 km, respectively. Combining all 3 flights, the weighted average 1sigma upper limit for HBr is 4 pptv at 32 km. This value is significantly smaller than the only other previously published spectroscopic value of 20 +/- 7 pptv (2sigma), but is consistent with a theoretical estimate which predicts roughly 0.4 pptv at this altitude.

Traub, W. A.↗
NASA NTRS1992

Stratospheric minor constituent distributions from far-infrared thermal emission spectra

We retrieve mixing ratio profiles of O3, H2(O-16), H2(O-17), H2(O-18), HF, and HCl from far-infrared thermal emission observations of the limb in the 80-220 cm/sec spectral region. The observations were made with a balloon-borne Fourier transform spectrometer as a part of the 1983 Balloon Intercomparison Campaign (BIC-2). A subset of the data was analyzed previously using the method in the work of Traub et al. (1982, 1991); in the present paper we use an alternative method of calibration and analysis, given by Abbas et al. (1985). The retrieved constituent profiles are compared with the measurements made with other instruments on the BIC-2 flights. The results for the concentrations of H2(O-17) and H2(O-18) obtained in this study indicate no isotopic enhancement or depletion with a standard deviation of about 20 percent.

Abbas, Mian M.↗
NASA NTRS1992

Measurements of pressure broadening and pressure shifting by nitrogen in the 4.3-micron band of (C-12)(O-16)2

Lorentz-broadening coefficients and pressure-induced line-shift coefficients of 34 individual lines have been determined for the P(40) to R(40) vibration-rotation transitions in the nu(3) fundamental of CO2 using N2 as the buffer gas. The parameters were derived from 0.01/cm resolution infrared absorption spectra recorded using the McMath Fourier transform spectrometer and a nonlinear, least-squares fitting algorithm. It is concluded that the N2-broadening coefficients obtained in the present study agree well with recent high resolution measurements. The results are considered to be of importance not only for predicting the infrared spectrum of the atmosphere due to CO2 absorption or emission but also for verifying theoretical calculations.

Devi, V. M.↗
NASA NTRS1992

Search for infrared absorption lines of atmospheric chlorine monoxide (ClO)

A search for features of the ClO (1-0) vibration-rotation band has been conducted based on a 5000 signal-to-rms noise ratio IR spectrum derived by coadding 39 high-quality 0.0053/cm resolution solar spectra recorded with the McMath Fourier transform spectrometer on Kitt Peak. Evidence for absorption has been found at the locations of several of the stronger ClO P-branch lines with minimal interference. Detailed results are presented for the P(8.5) and P(7.5) 2Pi3/2-2Pi3/2 lines of Cl-35O at 833.2974 and 834.6249/cm, respectively. If ClO is present in the stratosphere at the concentrations indicated by other methods, our analysis indicates that modest improvements in signal-to-noise ratio and spectral resolution would permit a definitive detection of ClO in IR ground-based spectra.

Rinsland, Curtis P.↗
NASA NTRS1992

Water vapor column abundance retrievals during FIFE

A variation of the modified Langley plot algorithm is reported here and applied to the retrieval of atmospheric water column abundance from a filtered sunphotometer. In this new methodology an absorption data base (LOWTRAN 7) is used to compute a water abundance versus transmittance curve of growth, rather than the square-root dependence previously assumed. Validation of the technique is provided from an uncertainty analysis, and plans to further validate using Fourier transform spectrometers are detailed. The new sunphotometer technique is used to report local column water vapor during the First ISLSCP Field Experiment (FIFE), and comparisons are made with abundances retrieved via FIFE radiosonde observations. The sunphotometer data can best be utilized, however, to in turn validate data from airborne or in-orbit measurements of water vapor. With these flight sensors, horizontal and topographic variability within the scene can be viewed. An example of the airborne data set is given using an image from the airborne visible infrared imaging spectrometer, as acquired on August 31, 1990.

Bruegge, Carol J.↗
NASA NTRS1992

Middle and upper atmosphere pressure-temperature profiles and the abundances of CO2 and CO in the upper atmosphere from ATMOS/Spacelab 3 observations

An improved method for retrieving pressure-temperature profiles is described and is used to retrieve profiles of the kinetic-temperature and atmospheric-pressure profiles between 20 and 116 km altitudes and the CO2 and CO volume-mixing ratios between 70 and 116 km, using the IR occultation spectra recorded by the Spacelab 3 atmospheric trace molecular spectroscopy (ATMOS) Fourier transform spectrometer between April 29 and May 6, 1985. Profiles are derived for six ATMOS occultations. The CO2 and CO volume-mixing profiles are compared with previous observations and model predictions. Evidence is found for vibrational non-LTE by analyzing the lines of the (nu-2 + nu-3 - nu-2) (C-12)(O-16) band. Results are used for deriving (C-12)(O-16) (010) vibrational temperatures, which are compared with the retrieved kinetic temperatures and the predictions of non-LTE effects by recent models.

Rinsland, C. P.↗
NASA NTRS1992

Absolute absorption of ozone in the midinfrared

The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1 percent using a Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared.

Pickett, H. M.↗
NASA NTRS1992

High resolution spectroscopy of the Martian atmosphere - Study of seasonal variations of CO, O3, H2O, and T on the north polar cap and a search for SO2, H2O2, and H2CO

An overview is presented of an observational campaign which will measure (1) the seasonal variations of the CO mixing ratio on the Martian polar cap due to accumulation and depletion of CO during the condensation and evaporation of CO2, as well as (2) the early spring ozone and water vapor of the Martian north polar cap, and (3) the presence of H2CO, H2O2, and SO2. The lines of these compounds will be measured by a combined 4-m telescope and Fourier-transform spectrometer 27097.

Krasnopolsky, V. A.↗
NASA NTRS1992

Transition frequencies and absolute strengths of H2 O-17 and H2 O-18 in the 6.2-micron region

High-resolution spectra of oxygen-enriched samples of water vapor were recorded with a Fourier-transform spectrometer covering transitions in the (010)-(000) bands. The measured line frequencies were used along with measurements taken from studies at microwave and far-infrared frequencies to obtain rotational energy levels in the (000) and (010) states of H2 O-17 and H2 O-18. Measurements of the line strengths were fitted to a model in which as many as 18 transition moment parameters were determined. The results produced computed line-strength values that are in excellent agreement with the 623 H2 O-17 experimental transition strengths and 696 H2 O-18 values. These results provide a more accurate representation of the line positions and strengths for the (010)-(000) bands of H2 O-17 and H2 O-18 than those previously available.

Toth, Robert A.↗
NASA NTRS1991

nu-2 band of H2 O-16 - Line strengths and transition frequencies

High-resolution spectra of H2 O-16 were recorded with a Fourier-transform spectrometer covering transitions in the (010)-(000) band from 1066 to 2582/cm. The measured line frequencies were used along with additional data taken from studies at microwave and far-infrared frequencies in an analysis to obtain rotational energies of levels in the (000) and (010) states. Measurements of the line strengths were fitted by least squares to a model in which the dipole moment matrix elements were represented by as many as 19 expansion coefficients. The results produced computed line strength values that are in excellent agreement, on the average, with the 874 experimental transitions included in the analysis. These results provide a more accurate representation of the line positions and strengths for the (010)-(000) band than are currently available on the HITRAN absorption line parameter compilation.

Toth, Robert A.↗
NASA NTRS1993

The fundamental bands of HCl-35 and HCl-37 - Line positions from high-resolution laboratory data

Accurate measurements of the positions of lines of the (1-0) vibration-rotation bands of HCl-35 and HCl-37 are reported. The new measurements have been derived from a laboratory spectrum recorded with a Fourier transform spectrometer operated at an unapodized spectral resolution of 0.0060/cm. Molecular constants are reported from a simultaneous least-squares analysis of these measurements and selected infrared and far-infrared data taken from the literature. The motivation for the present investigation is the need for improved HCl line positions for use in IR atmospheric remote sensing investigations.

Rinslad, Curtis P.↗
NASA NTRS1993

Fourier transform spectrometry for fiber-optic sensor systems

An integrated-optic Mach-Zehnder interferometer is used as a Fourier transform spectrometer to analyze the input and output spectra of a temperature-sensing thin-film etalon. This type of spectrometer has an advantage over conventional grating spectrometers because it is better suited for use with time-division-multiplexed sensor networks. In addition, this spectrometer has the potential for low cost due to its use of a component that could be manufactured in large quantities for the optical communications industry.

Beheim, Glenn↗