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At least 271 records · Page 15

Coherence mapping to identify the intermediates of multi-channel dissociative ionization

Identifying the short-lived intermediates and reaction mechanisms of multi-channel radical cation fragmentation processes remains a current and important challenge to understanding and predicting mass spectra. We find that coherent oscillations in the femtosecond time-dependent yields of several product ions following ultrafast strong-field ionization represent spectroscopic signatures that elucidate their mechanism of formation and identify the intermediate(s) they originate from. Experiments on endo-dicyclopentadiene show that vibrational frequencies from various intermediates are mapped onto their resulting products. Aided by ab initio methods, we identify the vibrational modes of both the cleaved and intact molecular ion intermediates. These results confirm stepwise and concerted fragmentation pathways of the dicyclopentadiene ion. This study highlights the power of tracking the femtosecond dynamics of all product ions simultaneously and sheds further light onto one of the fundamental reaction mechanisms in mass spectrometry, the retro-Diels Alder reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Glass Can Be Half Full: Even in Microgravity

When conducting physical science research in space, the smallest vibration or disturbance can disrupt sensitive experiments. Back in the 1990s we developed an instrument, the Space Acceleration Measurement System (SAMS) that flew on the shuttle to monitor the vibration environment - but it wasn't very flexible. It could only measure vibrations for three users and only at fixed frequency ranges, and it had to be disassembled after each two-week mission to be readied for reuse. Then the International Space Station came along. Our researchers needed a second-generation system, the SAMS-II, which would measure acceleration and vibrations for multiple payloads conducting experiments throughout the life of the station. Measurement requirements were all over the map with a variety of frequencies that needed measuring over a broad dynamic range, so it was essential to develop a robust system that would be flexible enough to accommodate all the particular users. We came up with a concept using the Space Station's Ethernet as the means to talk between multiple remote triaxial sensor systems and a remote controller box. Ultimately, our job was to acquire data within the existing constraints of the station and to quickly and effectively get that information to the scientists. In 1994 we had a $2.1-million budget and a four-year development schedule aimed at achieving these goals. Technical risks were few and primarily resulted from uncertainty of ISS capabilities. At that point, we didn't worry about a thing programmatically; our cup runneth over.

Sutliff, Thomas↗

Direct torsional actuation of microcantilevers using magnetic excitation

Torsional mode dynamic force microscopy can be used for a wide range of studies including mapping lateral contact stiffness, torsional frequency or amplitude modulation imaging, and dynamic friction measurements of various materials. Piezo-actuation of the cantilever is commonly used, but it introduces spurious resonances, limiting the frequency range that can be sampled, and rendering the technique particularly difficult to apply in liquid medium where the cantilever oscillations are significantly damped. Here, we demonstrate a method that enables direct torsional actuation of cantilevers with high uniformity over wide frequency ranges by attaching a micrometer-scale magnetic bead on the back side of the cantilever. We show that when beads are magnetized along the width of the cantilever, efficient torsional actuation of the cantilevers can be achieved using a magnetic field produced from a solenoid placed underneath the sample. We demonstrate the capability of this technique by imaging atomic steps on graphite surfaces in tapping mode near the first torsional resonance of the cantilever in dodecane. The technique is also applied to map the variations in the lateral contact stiffness on the surface of graphite and polydiacetylene monolayers.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

An analysis of fracture trace patterns in areas of flat-lying sedimentary rocks for the detection of buried geologic structure

Two study areas in a cratonic platform underlain by flat-lying sedimentary rocks were analyzed to determine if a quantitative relationship exists between fracture trace patterns and their frequency distributions and subsurface structural closures which might contain petroleum. Fracture trace lengths and frequency (number of fracture traces per unit area) were analyzed by trend surface analysis and length frequency distributions also were compared to a standard Gaussian distribution. Composite rose diagrams of fracture traces were analyzed using a multivariate analysis method which grouped or clustered the rose diagrams and their respective areas on the basis of the behavior of the rays of the rose diagram. Analysis indicates that the lengths of fracture traces are log-normally distributed according to the mapping technique used. Fracture trace frequency appeared higher on the flanks of active structures and lower around passive reef structures. Fracture trace log-mean lengths were shorter over several types of structures, perhaps due to increased fracturing and subsequent erosion. Analysis of rose diagrams using a multivariate technique indicated lithology as the primary control for the lower grouping levels. Groupings at higher levels indicated that areas overlying active structures may be isolated from their neighbors by this technique while passive structures showed no differences which could be isolated.

Podwysocki, M. H.↗

90 GHz and 150 GHz Observations of the Orion M42 Region. A Submillimeter to Radio Analysis

We have used the new 90GHz MUSTANG camera on the Robert C. Green Bank Telescope (GBT)to map the bright Huygens region of the star-forming region M42 with a resolution of 9" and a sensitivity of 2.8 mJy/beam. Ninety GHz is an interesting transition frequency, as MUSTANG detects both the free-free emission characteristic of the H II region created by the Trapezium stars, normally seen at lower frequencies, and thermal dust emission from the background OMCI molecular cloud, normally mapped at higher frequencies. We also present similar data from the 150 GHz GISMO camera taken on the IRAM 30 m telescope. This map has 15" resolution. By combining the MUSTANG data with 1.4, 8. and 31 GHz radio data from the VLA and GBT, we derive a new estimate of the emission measure averaged electron temperature of T(sub e) = 11376+/-1050 K by an original method relating free-free emission intensities at optically thin and optically thick frequencies. Combining Infrared Space Observatory-long wavelength spectrometer (ISO-LWS) data with our data, we derive a new estimate of the dust temperature and spectral emissivity index within the 80" ISO-LWS beam toward Orion KL/BN, T(sub d) = 42+/-3 K and Beta(sub d) = 1.3+/-0.1. We show that both T(sub d) and Beta(sub d) decrease when going from the H II region and excited OMCI interface to the denser UV shielded part OMCI (Orion KL/BN, Orion S). With a model consisting of only free-free and thermal dust emission, we are able to fit data taken at frequencies from 1.5 GHz to 854 GHz (350 micrometers).

Dicker, S. R.↗

An Acoustic Emission and Acousto-Ultrasonic Analysis of Impact Damaged Composite Pressure Vessels

The research presented herein summarizes the development of acoustic emission (AE) and acousto-ultrasonic (AU) techniques for the nondestructive evaluation of filament wound composite pressure vessels. Vessels fabricated from both graphite and kevlar fibers with an epoxy matrix were examined prior to hydroburst using AU and during hydroburst using AE. A dead weight drop apparatus featuring both blunt and sharp impactor tips was utilized to produce a single known energy 'damage' level in each of the vessels so that the degree to which the effects of impact damage could be measured. The damage levels ranged from barely visible to obvious fiber breakage and delamination. Independent neural network burst pressure prediction models were developed from a sample of each fiber/resin material system. Here, the cumulative AE amplitude distribution data collected from low level proof test (25% of the expected burst for undamaged vessels) were used to measure the effects of the impact on the residual burst pressure of the vessels. The results of the AE/neural network model for the inert propellant filled graphite/epoxy vessels 'IM7/3501-6, IM7/977-2 and IM7/8553-45' demonstrated that burst pressures can be predicted from low level AE proof test data, yielding an average error of 5.0%. The trained network for the IM7/977-2 class vessels was also able to predict the expected burst pressure of taller vessels (three times longer hoop region length) constructed of the same material and using the same manufacturing technique, with an average error of 4.9%. To a lesser extent, the burst pressure prediction models could also measure the effects of impact damage to the kevlar/epoxy 'Kevlar 49/ DPL862' vessels. Here though, due to the higher attenuation of the material, an insufficient amount of AE amplitude information was collected to generate robust network models. Although, the worst case trial errors were less than 6%, when additional blind predictions were attempted, errors as high as 50% were produced. An acousto-ultrasonic robotic evaluation system (AURES) was developed for mapping the effects of damage on filament wound pressure vessels prior to hydroproof testing. The AURES injects a single broadband ultrasonic pulse into each vessel at preprogrammed positions and records the effects of the interaction of that pulse on the material volume with a broadband receiver. A stress wave factor in the form of the energy associated with the 750 to 1000 kHz and 1000 to 1250 kHz frequency bands were used to map the potential failure sites for each vessel. The energy map associated with the graphite/epoxy vessels was found to decrease in the region of the impact damage. The kevlar vessels showed the opposite trend, with the energy values increasing around the damage/failure sites.

Walker, James L.↗

On the proper kinetic quadrupole CMB removal and the quadrupole anomalies

It has been pointed out recently that the quadrupole-octupole alignment in the CMB data is significantly affected by the so-called kinetic Doppler quadrupole (DQ), which is the temperature quadrupole induced by our proper motion. Assuming our velocity is the dominant contribution to the CMB dipole we have v/c=β=(1.231 ± 0.003) × 10{sup −3}, which leads to a non-negligible DQ of O(β{sup 2}). Here we stress that one should properly take into account that CMB data are usually not presented in true thermodynamic temperature, which induces a frequency dependent boost correction. The DQ must therefore be multiplied by a frequency-averaged factor, which we explicitly compute for several Planck CMB maps finding that it varies between 1.67 and 2.47. This is often neglected in the literature and turns out to cause a small but non-negligible difference in the significance levels of some quadrupole-related statistics. For instance the alignment significance in the SMICA 2013 map goes from 2.3σ to 3.3σ with the frequency dependent DQ, instead of 2.9σ ignoring the frequency dependence in the DQ. Moreover as a result of a proper DQ removal, the agreement across different map-making techniques is improved.

79 ASTRONOMY AND ASTROPHYSICS↗

A SPATIALLY RESOLVED STUDY OF THE SYNCHROTRON EMISSION AND TITANIUM IN TYCHO’S SUPERNOVA REMNANT USING NuSTAR

We report results from deep observations (∼750 ks) of Tycho's supernova remnant (SNR) with NuSTAR. Using these data, we produce narrow-band images over several energy bands to identify the regions producing the hardest X-rays and to search for radioactive decay line emission from {sup 44}Ti. We find that the hardest (>10 keV) X-rays are concentrated in the southwest of Tycho, where recent Chandra observations have revealed high emissivity “stripes” associated with particles accelerated to the knee of the cosmic-ray spectrum. We do not find evidence of {sup 44}Ti, and we set limits on its presence and distribution within the SNR. These limits correspond to an upper-limit {sup 44}Ti mass of M{sub 44} < 2.4 × 10{sup −4} M{sub ⊙} for a distance of 2.3 kpc. We perform a spatially resolved spectroscopic analysis of 66 regions across Tycho. We map the best-fit rolloff frequency of the hard X-ray spectra, and we compare these results to measurements of the shock expansion and ambient density. We find that the highest energy electrons are accelerated at the lowest densities and in the fastest shocks, with a steep dependence of the rolloff frequency with shock velocity. Such a dependence is predicted by models where the maximum energy of accelerated electrons is limited by the age of the SNR rather than by synchrotron losses, but this scenario requires far lower magnetic field strengths than those derived from observations in Tycho. One way to reconcile these discrepant findings is through shock obliquity effects, and future observational work is necessary to explore the role of obliquity in the particle acceleration process.

79 ASTRONOMY AND ASTROPHYSICS↗

FREQUENCY MODULATION OF DIRECTLY IMAGED EXOPLANETS: GEOMETRIC EFFECT AS A PROBE OF PLANETARY OBLIQUITY

We consider the time–frequency analysis of a scattered light curve of a directly imaged exoplanet. We show that the geometric effect due to planetary obliquity and orbital inclination induce the frequency modulation of the apparent diurnal periodicity. We construct a model of the frequency modulation and compare it with the instantaneous frequency extracted from the pseudo-Wigner distribution of simulated light curves of a cloudless Earth. The model provides good agreement with the simulated modulation factor, even for the light curve with Gaussian noise comparable to the signal. Notably, the shape of the instantaneous frequency is sensitive to the difference between the prograde, retrograde, and pole-on spin rotations. While our technique requires the albedo map to be static, it does not need to solve the albedo map of the planet. The time–frequency analysis is complementary to other methods which utilize the amplitude modulation. This paper demonstrates the importance of the frequency domain of the photometric variability for the characterization of directly imaged exoplanets in future research.

79 ASTRONOMY AND ASTROPHYSICS↗

Planck 2015 results: XVI. Isotropy and statistics of the CMB

In this paper, we test the statistical isotropy and Gaussianity of the cosmic microwave background (CMB) anisotropies using observations made by the Planck satellite. Our results are based mainly on the full Planck mission for temperature, but also include some polarization measurements. In particular, we consider the CMB anisotropy maps derived from the multi-frequency Planck data by several component-separation methods. For the temperature anisotropies, we find excellent agreement between results based on these sky maps over both a very large fraction of the sky and a broad range of angular scales, establishing that potential foreground residuals do not affect our studies. Tests of skewness, kurtosis, multi-normality, N-point functions, and Minkowski functionals indicate consistency with Gaussianity, while a power deficit at large angular scales is manifested in several ways, for example low map variance. The results of a peak statistics analysis are consistent with the expectations of a Gaussian random field. The “Cold Spot” is detected with several methods, including map kurtosis, peak statistics, and mean temperature profile. We thoroughly probe the large-scale dipolar power asymmetry, detecting it with several independent tests, and address the subject of a posteriori correction. Tests of directionality suggest the presence of angular clustering from large to small scales, but at a significance that is dependent on the details of the approach. We perform the first examination of polarization data, finding the morphology of stacked peaks to be consistent with the expectations of statistically isotropic simulations. Finally, where they overlap, these results are consistent with the Planck 2013 analysis based on the nominal mission data and provide our most thorough view of the statistics of the CMB fluctuations to date.

79 ASTRONOMY AND ASTROPHYSICS↗

The Atacama Cosmology Telescope: Data Characterization and Map Making

We present a description of the data reduction and mapmaking pipeline used for the 2008 observing season of the Atacama Cosmology Telescope (ACT). The data presented here at 148 GHz represent 12% or the 90 TB collected by ACT from 2007 to 2010. In 2008 we observed for 136 days, producing a total of 142h of data (11 TB for the 148 GHz band only), with a daily average of 10.5 h of observation. From these, 108.5 h were devoted to 850 sq deg stripe (11.2 h by 9 deg.1) centered on a declination of -52 deg.7, while 175 h were devoted to a 280 square deg stripe (4.5 h by 4 deg.8) centered at the celestial equator. We discuss sources of statistical and systematic noise, calibration, telescope pointing and data selection. Out of 1260 survey hours and 1024 detectors per array, 816 h and 593 effective detectors remain after data selection for this frequency band, yielding a 38 % survey efficiency. The total sensitivity in 2008, determined from the noise level between 5 Hz and 20 Hz in the time-ordered data stream (TOD), is 32 muK square root of s in CMB units. Atmospheric brightness fluctuations constitute the main contaminant in the data and dominate the detector and noise covariance at low frequencies in the TOD. The maps were made by solving the lease squares problem using the Preconditioned Conjugate Gradient method, incorporating the details of the detector and noise correlations. Cross-correlation with WMAP sky maps as well as analysis from simulations reveal the our maps are unbiased at l > 300. This paper accompanies the public release of the 148 GHz southern stripe maps from 2008. The techniques described here will be applied to future maps and data releases.

Duenner, Rolando↗

(abstract) Topographic Signatures in Geology

Topographic information is required for many Earth Science investigations. For example, topography is an important element in regional and global geomorphic studies because it reflects the interplay between the climate-driven processes of erosion and the tectonic processes of uplift. A number of techniques have been developed to analyze digital topographic data, including Fourier texture analysis. A Fourier transform of the topography of an area allows the spatial frequency content of the topography to be analyzed. Band-pass filtering of the transform produces images representing the amplitude of different spatial wavelengths. These are then used in a multi-band classification to map units based on their spatial frequency content. The results using a radar image instead of digital topography showed good correspondence to a geologic map, however brightness variations in the image unrelated to topography caused errors. An additional benefit to the use of Fourier band-pass images for the classification is that the textural signatures of the units are quantative measures of the spatial characteristics of the units that may be used to map similar units in similar environments.

topography geology texture Fourier analysis↗

Improvements to the Simulated CubeSpark Satellite Constellation and Their Effects on Lightning Geolocation Accuracy from Orbit

The CubeSpark mission concept is being developed as a constellation of up to six satellites in low-Earth orbit (LEO) for high resolution 3D lightning mapping using optical and radio frequency (RF) sensors. Individual lightning VHF signals are simulated from Earth’s atmosphere through the ionosphere to each satellite, using their arrival times to reconstruct source locations. Here we present recent updates to these simulations based on improved ionospheric modeling, with a focus on the expected three-dimensional resolution. These studies include testing from the equator up to high latitudes, with varying vertical total electron content (vTEC), and using between one and six orbiting stations. In addition to the more robust ionosphere model, the constellation formation has also been updated to reduce its resulting errors and increase the effective range of VHF geolocation from space. The goals of CubeSpark include mapping thundercloud charge structure as well as lightning channel lengths relevant to climatology, meteorology, and more. These applications require location uncertainty less than 1-2 km in each dimension. This improved algorithm shows sufficient resolution up to high latitudes, including significantly larger areas having 3D resolution less than 1 km. Analysis of the distributions of biases in simulated arrival times has also revealed the unexpected relationship between the shape of those distributions and the resulting uncertainties. This work helps to refine our understanding of the sources of error in lightning geolocation and reinforces the potential for post-processing improvements in this and other similar systems.

Lightning↗

Mapping the sky with the COBE differential microwave radiometers

The Differential Microwave Radiometers (DMR) instrument on COBE is designed to determine the anisotropy of the Cosmic Microwave Background by providing all-sky maps of the diffuse sky brightness at microwave frequencies. The principal intent of this lecture is to show how these maps are generated from differential measurements.

Janssen, M. A.↗

Planck intermediate results: XXVII. High-redshift infrared galaxy overdensity candidates and lensed sources discovered by Planck and confirmed by Herschel -SPIRE

We have used the Planck all-sky submillimetre and millimetre maps to search for rare sources distinguished by extreme brightness, a few hundred millijanskies, and their potential for being situated at high redshift. These “cold” Planck sources, selected using the High Frequency Instrument (HFI) directly from the maps and from the Planck Catalogue of Compact Sources (PCCS), all satisfy the criterion of having their rest-frame far-infrared peak redshifted to the frequency range 353–857 GHz. This colour-selection favours galaxies in the redshift range z = 2–4, which we consider as cold peaks in the cosmic infrared background. With a 4'.5 beam at the four highest frequencies, our sample is expected to include overdensities of galaxies in groups or clusters, lensed galaxies, and chance line-of-sight projections. In this paper, we perform a dedicated Herschel-SPIRE follow-up of 234 such Planck targets, finding a significant excess of red 350 and 500μm sources, in comparison to reference SPIRE fields. About 94% of the SPIRE sources in the Planck fields are consistent with being overdensities of galaxies peaking at 350μm, with 3% peaking at 500μm, and none peaking at 250μm. About 3% are candidate lensed systems, all 12 of which have secure spectroscopic confirmations, placing them at redshifts z> 2.2. Only four targets are Galactic cirrus, yielding a success rate in our search strategy for identifying extragalactic sources within the Planck beam of better than 98%. The galaxy overdensities are detected with high significance, half of the sample showing statistical significance above 10σ. The SPIRE photometric redshifts of galaxies in overdensities suggest a peak at z ≃ 2, assuming a single common dust temperature for the sources of T d = 35 K. Under this assumption, we derive an infrared (IR) luminosity for each SPIRE source of about 4 × 10 12 L ⊙ , yielding star formation rates of typically 700 M ⊙ yr -1 . If the observed overdensities are actual gravitationally-bound structures, the total IR luminosity of all their SPIRE-detected sources peaks at 4 × 10 13 L ⊙ , leading to total star formation rates of perhaps 7 × 10 3 M ⊙ yr -1 per overdensity. Taken together, these sources show the signatures of high-z (z> 2) protoclusters of intensively star-forming galaxies. Finally, all these observations confirm the uniqueness of our sample compared to reference samples and demonstrate the ability of the all-skyPlanck-HFI cold sources to select populations of cosmological and astrophysical interest for structure formation studies.

79 ASTRONOMY AND ASTROPHYSICS↗

Probing star formation in the dense environments of z 1 lensing haloes aligned with dusty star-forming galaxies detected with the South Pole Telescope

We probe star formation in the environments of massive ~1013M⊙ dark matter halos at redshifts of z~1. This star formation is linked to a sub-millimetre clustering signal which we detect in maps of the Planck High Frequency Instrument that are stacked at the positions of a sample of high-redshift (z>2) strongly-lensed dusty star-forming galaxies (DSFGs) selected from the South Pole Telescope (SPT) 2500 deg2 survey. The clustering signal has sub-millimetre colours which are consistent with the mean redshift of the foreground lensing halos (z~1). We report a mean excess of star formation rate (SFR) compared to the field, of (2700±700)M⊙yr-1 from all galaxies contributing to this clustering signal within a radius of 3.5' from the SPT DSFGs. The magnitude of the Planck excess is in broad agreement with predictions of a current model of the cosmic infrared background. The model predicts that 80% of the excess emission measured by Planck originates from galaxies lying in the neighbouring halos of the lensing halo. Using Herschel maps of the same fields, we find a clear excess, relative to the field, of individual sources which contribute to the Planck excess. The mean excess SFR compared to the field is measured to be (370±40)M⊙yr-1 per resolved, clustered source. Our findings suggest that the environments around these massive z~1 lensing halos host intense star formation out to about 2Mpc. The flux enhancement due to clustering should also be considered when measuring flux densities of galaxies in Planck data.

79 ASTRONOMY AND ASTROPHYSICS↗

Planck intermediate results: XLVI. Reduction of large-scale systematic effects in HFI polarization maps and estimation of the reionization optical depth

This study describes the identification, modelling, and removal of previously unexplained systematic effects in the polarization data of the Planck High Frequency Instrument (HFI) on large angular scales, including new mapmaking and calibration procedures, new and more complete end-to-end simulations, and a set of robust internal consistency checks on the resulting maps. These maps, at 100, 143, 217, and 353 GHz, are early versions of those that will be released in final form later in 2016. The improvements allow us to determine the cosmic reionization optical depth τ using, for the first time, the low-multipole EE data from HFI, reducing significantly the central value and uncertainty, and hence the upper limit. Two different likelihood procedures are used to constrain τ from two estimators of the CMB E- and B-mode angular power spectra at 100 and 143 GHz, after debiasing the spectra from a small remaining systematic contamination. These all give fully consistent results. A further consistency test is performed using cross-correlations derived from the Low Frequency Instrument maps of the Planck 2015 data release and the new HFI data. For this purpose, end-to-end analyses of systematic effects from the two instruments are used to demonstrate the near independence of their dominant systematic error residuals. The tightest result comes from the HFI-based τ posterior distribution using the maximum likelihood power spectrum estimator from EE data only, giving a value 0.055 ± 0.009. Finally, in a companion paper these results are discussed in the context of the best-fit PlanckΛCDM cosmological model and recent models of reionization.

79 ASTRONOMY AND ASTROPHYSICS↗

Martian crater counts on Elysium Mons

Without returned samples from the Martian surface, relative age chronologies and stratigraphic relationships provide the best information for determining the ages of geomorphic features and surface regions. Crater-size frequency distributions of six recently mapped geological units of Elysium Mons were measured to establish their relative ages. Most of the craters on Elysium Mons and the adjacent plains units are between 500 and 1000 meters in diameter. However, only craters 1 km in diameter or larger were used because of inadequate spatial resolution of some of the Viking images and to reduce probability of counting secondary craters. The six geologic units include all of the Elysium Mons construct and a portion of the plains units west of the volcano. The surface area of the units studied is approximately 128,000 sq km. Four of the geologic units were used to create crater distribution curves. There are no craters larger than 1 km within the Elysium Mons caldera. Craters that lacked raised rims, were irregularly shaped, or were arranged in a linear pattern were assumed to be endogenic in origin and not counted. A crater frequency distribution analysis is presented.

Mcbride, Kathleen↗